Abstract: Copolymerization of ethylene with 1-hexene was
carried out using two ansa-fluorenyl titanium derivative complexes.
The substituent effect on the catalytic activity, monomer reactivity
ratio and polymer property was investigated. It was found that the
presence of t-Bu groups on fluorenyl ring exhibited remarkable
catalytic activity and produced polymer with high molecular weight.
However, these catalysts produce polymer with narrow molecular
weight distribution, indicating the characteristic of single-site
metallocene catalyst. Based on 13C NMR, we can observe that
monomer reactivity ratio was affected by catalyst structure. The rH
values of complex 2 were lower than that of complex 1 which might
be result from the higher steric hindrance leading to a reduction of 1-
hexene insertion step.
Abstract: Bleeding in the digestive duct is an important diagnostic parameter for patients. Blood in the endoscopic image can be determined by investigating the color tone of blood due to the degree of oxygenation, under- or over- illumination, food debris and secretions, etc. However, we found that how to pre-process raw images obtained from the capsule detectors was very important. We applied various image process methods suitable for the capsule endoscopic image in order to remove noises and unbalanced sensitivities for the image pixels. The results showed that much improvement was achieved by additional pre-processing techniques on the algorithm of determining bleeding areas.
Abstract: Cardiovascular diseases, principally atherosclerosis, are responsible for 30% of world deaths. Atherosclerosis is due to the formation of plaque. The fatty plaque may be at risk of rupture, leading typically to stroke and heart attack. The plaque is usually associated with a high degree of lumen reduction, called a stenosis.It is increasingly recognized that the initiation and progression of disease and the occurrence of clinical events is a complex interplay between the local biomechanical environment and the local vascular biology. The aim of this study is to investigate the flow behavior through a stenosed artery. A physical experiment was performed using an artery model and blood analogue fluid. An axisymmetric model constructed consists of contraction and expansion region that follow a mathematical form of cosine function. A 30% diameter reduction was used in this study. The flow field was measured using particle image velocimetry (PIV). Spherical particles with 20μm diameter were seeded in a water-glycerol-NaCl mixture. Steady flow Reynolds numbers are 250. The area of interest is the region after the stenosis where the flow separation occurs. The velocity field was measured and the velocity gradient was investigated. There was high particle concentration in the recirculation zone. High velocity gradient formed immediately after the stenosis throat created a lift force that enhanced particle migration to the flow separation area.
Abstract: Responses of the dynamical systems are highly affected by the natural frequencies and it has a huge impact on design and operation of high-rise and high-speed elevators. In the present paper, the variational iteration method (VIM) is employed to investigate better understanding the dynamics of elevator cable as a single-degree-of-freedom (SDOF) swing system. Comparisons made among the results of the proposed closed-form analytical solution, the traditional numerical iterative time integration solution, and the linearized governing equations confirm the accuracy and efficiency of the proposed approach. Furthermore, based on the results of the proposed closed-form solution, the linearization errors in calculating the natural frequencies in different cases are discussed.
Abstract: This paper investigates the effect of product substitution in the single-period 'newsboy-type' problem in a fuzzy environment. It is supposed that the single-period problem operates under uncertainty in customer demand, which is described by imprecise terms and modelled by fuzzy sets. To perform this analysis, we consider the fuzzy model for two-item with upward substitution. This upward substitutability is reasonable when the products can be stored according to certain attribute levels such as quality, brand or package size. We show that the explicit consideration of this substitution opportunity increase the average expected profit. Computational study is performed to observe the benefits of product's substitution.
Abstract: Increasing demand on the performance of Subsea
Production Systems (SPS) suggests a need for more detailed
investigation of fluid behavior taking place in subsea equipment.
Complete CFD cool down analyses of subsea equipment are very
time demanding. The objective of this paper is to investigate a
Locked CFD approach, which enables significant reduction of the
computational time and at the same time maintains sufficient
accuracy during thermal cool down simulations. The result
comparison of a dead leg simulation using the Full CFD and the three
LCFD-methods confirms the validity of the locked flow field
assumption for the selected case. For the tested case the LCFD
simulation speed up by factor of 200 results in the absolute thermal
error of 0.5 °C (3% relative error), speed up by factor of 10 keeps the
LCFD results within 0.1 °C (0.5 % relative error) comparing to the
Full CFD.
Abstract: Methanol-to-olefins coupled with transformation of
coal or natural gas to methanol gives an interesting and promising way
to produce ethylene and propylene. To investigate solid concentration
in gas-solid fluidized bed for methanol-to-olefins process catalyzed by
SAPO-34, a cold model experiment system is established in this paper.
The system comprises a gas distributor in a 300mm internal diameter
and 5000mm height acrylic column, the fiber optic probe system and
series of cyclones. The experiments are carried out at ambient
conditions and under different superficial gas velocity ranging from
0.3930m/s to 0.7860m/s and different initial bed height ranging from
600mm to 1200mm. The effects of radial distance, axial distance,
superficial gas velocity, initial bed height on solid concentration in the
bed are discussed. The effects of distributor shape and porosity on
solid concentration are also discussed. The time-averaged solid
concentration profiles under different conditions are obtained.
Abstract: In the closed quantum system, if the control system is
strongly regular and all other eigenstates are directly coupled to the
target state, the control system can be asymptotically stabilized at the
target eigenstate by the Lyapunov control based on the state error.
However, if the control system is not strongly regular or as long as
there is one eigenstate not directly coupled to the target state, the
situations will become complicated. In this paper, we propose an
implicit Lyapunov control method based on the state error to solve the
convergence problems for these two degenerate cases. And at the same
time, we expand the target state from the eigenstate to the arbitrary
pure state. Especially, the proposed method is also applicable in the
control system with multi-control Hamiltonians. On this basis, the
convergence of the control systems is analyzed using the LaSalle
invariance principle. Furthermore, the relation between the implicit
Lyapunov functions of the state distance and the state error is
investigated. Finally, numerical simulations are carried out to verify
the effectiveness of the proposed implicit Lyapunov control method.
The comparisons of the control effect using the implicit Lyapunov
control method based on the state distance with that of the state error
are given.
Abstract: There is a complex situation on the transport environment in the cities of the world. For the analysis and prevention of environmental problems an accurate calculation hazardous substances concentrations at each point of the investigated area is required. In the turbulent atmosphere of the city the wellknown methods of mathematical statistics for these tasks cannot be applied with a satisfactory level of accuracy. Therefore, to solve this class of problems apparatus of mathematical physics is more appropriate. In such models, because of the difficulty as a rule the influence of uneven land surface on streams of air masses in the turbulent atmosphere of the city are not taken into account. In this paper the influence of the surface roughness, which can be quite large, is mathematically shown. The analysis of this problem under certain conditions identified the possibility of areas appearing in the atmosphere with pressure tending to infinity, i.e. so-called "wall effect".
Abstract: Controlled modification of appropriate sharpness for
nanotips is of paramount importance to develop novel materials and
functional devices at a nanometer resolution. Herein, we present a
reliable and unique strategy of laser irradiation enhanced
physicochemical etching to manufacture super sharp tungsten tips
with reproducible shape and dimension as well as high yields
(~80%). The corresponding morphology structure evolution of
tungsten tips and laser-tip interaction mechanisms were
systematically investigated and discussed using field emission
scanning electron microscope (SEM) and physical optics statistics
method with different fluences under 532 nm laser irradiation. This
work paves the way for exploring more accessible metallic tips
applications with tunable apex diameter and aspect ratio, and,
furthermore, facilitates the potential sharpening enhancement
technique for other materials used in a variety of nanoscale devices.
Abstract: This study investigates the capacity of granular
activated carbon (GAC) for the storage of methane through the
equilibrium adsorption. An experimental apparatus consist of a dual
adsorption vessel was set up for the measurement of equilibrium
adsorption of methane on GAC using volumetric technique (pressure
decay). Experimental isotherms of methane adsorption were
determined by the measurement of equilibrium uptake of methane in
different pressures (0-50 bar) and temperatures (285.15-328.15°K).
The experimental data was fitted to Freundlich and Langmuir
equations to determine the model isotherm. The results show that the
experimental data is equally well fitted by the both model isotherms.
Using the experimental data obtained in different temperatures the
isosteric heat of methane adsorption was also calculated by the
Clausius-Clapeyron equation from the Sips isotherm model. Results
of isosteric heat of adsorption show that decreasing temperature or
increasing methane uptake by GAC decrease the isosteric heat of
methane adsorption.
Abstract: Pulse width modulation (PWM) techniques have been
the subject of intensive research for different industrial and power
sector applications. A large variety of methods, different in concept
and performance, have been newly developed and described. This
paper analyzes the comparative merits of Sinusoidal Pulse Width
Modulation (SPWM) and Space Vector Pulse Width Modulation
(SVPWM) techniques and the suitability of these techniques in a
Shunt Active Filter (SAF). The objective is to select the scheme that
offers effective utilization of DC bus voltage and also harmonic
reduction at the input side. The effectiveness of the PWM techniques
is tested in the SAF configuration with a non linear load. The
performance of the SAF with the SPWM and (SVPWM) techniques
are compared with respect to the THD in source current. The study
reveals that in the context of closed loop SAF control with the
SVPWM technique there is only a minor improvement in THD. The
utilization of the DC bus with SVPWM is also not significant
compared to that with SPWM because of the non sinusoidal
modulating signal from the controller in SAF configuration.
Abstract: Road rage is an increasingly prevalent expression of
aggression in our society. Its dangers are apparent and understanding
its causes may shed light on preventative measures. This study
involved a fifteen-minute survey administered to 147 undergraduate
students at a North Eastern suburban university. The survey
consisted of a demographics section, questions regarding financial
investment in respondents- vehicles, experience driving, habits of
driving, experiences witnessing role models driving, and an
evaluation of road rage behavior using the Driving Vengeance
Questionnaire. The study found no significant differences in driving
aggression between respondents who were financially invested in
their vehicle compared to those who were not, or between
respondents who drove in heavy traffic hours compared to those who
did not, suggesting internal factors correlate with aggressive driving
habits. The study also found significant differences in driving
aggression between males versus females, those with more points on
their license versus fewer points, and those who witnessed parents
driving aggressively very often versus rarely or never. Additional
studies can investigate how witnessing parents driving aggressively
is related to future driving behaviors.
Abstract: This paper presents a numerical investigation of the
unsteady flow around an American 19th century vertical-axis
windmill: the Stevens & Jolly rotor, patented on April 16, 1895. The
computational approach used is based on solving the complete
transient Reynolds-Averaged Navier-Stokes (t-RANS) equations: a
full campaign of numerical simulation has been performed using the
k-ω SST turbulence model. Flow field characteristics have been
investigated for several values of tip speed ratio and for a constant
unperturbed free-stream wind velocity of 6 m/s, enabling the study of
some unsteady flow phenomena in the rotor wake. Finally, the global
power generated from the windmill has been determined for each
simulated angular velocity, allowing the calculation of the rotor
power-curve.
Abstract: Martingale model diagnostic for assessing the fit of logistic regression model to recurrent events data are studied. One way of assessing the fit is by plotting the empirical standard deviation of the standardized martingale residual processes. Here we used another diagnostic plot based on martingale residual covariance. We investigated the plot performance under several types of model misspecification. Clearly the method has correctly picked up the wrong model. Also we present a test statistic that supplement the inspection of the two diagnostic. The test statistic power agrees with what we have seen in the plots of the estimated martingale covariance.
Abstract: A rigorous two-dimensional model is developed for simulating the operation of a less-investigated type steam reformer having a considerably lower operating Reynolds number, higher tube diameter, and non-availability of extra steam in the feed compared with conventional steam reformers. Simulation results show that reasonable predictions can only be achieved when certain correlations for wall to fluid heat transfer equations are applied. Due to severe operating conditions, in all cases, strong radial temperature gradients inside the reformer tubes have been found. Furthermore, the results show how a certain catalyst loading profile will affect the operation of the reformer.
Abstract: This paper describes an experimental investigation of
the drying behavior and conditions of rosehip in a convective
cyclone-type dryer. Drying experiments were conducted at air inlet
temperatures of 50, 60 and 70 o C and air velocities of 0.5, 1 and 1.5
ms–1. The parametric values obtained from the experiments were
fitted to the Newton mathematical models. Consequently, the drying
model developed by Newton model showed good agreement with the
data obtained from the experiments. Concluding, it was obtained that;
(i) the temperature is the major effect on the drying process, (ii) air
velocity has low effect on the drying of rosehip, (iii) the C-vitamin is
observed to change according to the temperature, moisture, drying
time and flow types. The changing ratio is found to be in the range of
0.70-0.74.
Abstract: Though nonlinear dynamic analysis using a specialized
hydro-code such as AUTODYN is accurate and useful tool for
progressive collapse assessment of a multi-story building subjected to
blast load, it takes too much time to be applied to a practical simulation
of progressive collapse of a tall building. In this paper, blast analysis of
a RC frame structure using a simplified model with Reinforcement
Contact technique provided in Ansys Workbench was introduced and
investigated on its accuracy. Even though the simplified model has a
fraction of elements of the detailed model, the simplified model with
this modeling technique shows similar structural behavior under the
blast load to the detailed model. The proposed modeling method can
be effectively applied to blast loading progressive collapse analysis of
a RC frame structure.
Abstract: Owing to the stringent environmental legislations,
CO2 capture and sequestration is one of the viable solutions to reduce
the CO2 emissions from various sources. In this context, Ionic liquids
(ILs) are being investigated as suitable absorption media for CO2
capture. Due to their non-evaporative, non-toxic, and non-corrosive
nature, these ILs have the potential to replace the existing solvents
like aqueous amine solutions for CO2 separation technologies. Thus,
the present work aims at studying the important aspects such as the
interactions of CO2 molecule with different anions (F-, Br-, Cl-, NO3
-,
BF4
-, PF6
-, Tf2N-, and CF3SO3
-) that are commonly used in ILs
through molecular modeling. In this, the minimum energy structures
have been obtained using Ab initio based calculations at MP2
(Moller-Plesset perturbation) level. Results revealed various degrees
of distortion of CO2 molecule (from its linearity) with the anions
studied, most likely due to the Lewis acid-base interactions between
CO2 and anion. Furthermore, binding energies for the anion-CO2
complexes were also calculated. The implication of anion-CO2
interactions to the solubility of CO2 in ionic liquids is also discussed.
Abstract: The free and forced in-plane vibrations of axially
moving plates are investigated in this work. The plate possesses an
internal damping of which the constitutive relation obeys the
Kelvin-Voigt model, and the excitations are arbitrarily distributed on
two opposite edges. First, the equations of motion and the boundary
conditions of the axially moving plate are derived. Then, the extended
Ritz method is used to obtain discretized system equations. Finally,
numerical results for the natural frequencies and the mode shapes of
the in-plane vibration and the in-plane response of the moving plate
subjected to arbitrary edge excitations are presented. It is observed that
the symmetry class of the mode shapes of the in-plane vibration
disperses gradually as the moving speed gets higher, and the u- and
v-components of the mode shapes belong to different symmetry class.
In addition, large response amplitudes having shapes similar to the
mode shapes of the plate can be excited by the edge excitations at the
resonant frequencies and with the same symmetry class of distribution
as the u-components.