Abstract: Distillery spentwash contains high chemical oxygen
demand (COD), biological oxygen demand (BOD), color, total
dissolved solids (TDS) and other contaminants even after biological
treatment. The effluent can’t be discharged as such in the surface
water bodies or land without further treatment. Reverse osmosis (RO)
treatment plants have been installed in many of the distilleries at
tertiary level in many of the distilleries in India, but are not properly
working due to fouling problem which is caused by the presence of
high concentration of organic matter and other contaminants in
biologically treated spentwash. In order to make the membrane
treatment a proven and reliable technology, proper pre-treatment is
mandatory. In the present study, ultra-filtration (UF) for pretreatment
of RO at tertiary stage has been performed. Operating
parameters namely initial pH (pHo: 2–10), trans-membrane pressure
(TMP: 4-20 bars) and temperature (T: 15-43°C) were used for
conducting experiments with UF system. Experiments were
optimized at different operating parameters in terms of COD, color,
TDS and TOC removal by using response surface methodology
(RSM) with central composite design. The results showed that
removal of COD, color and TDS was 62%, 93.5% and 75.5%
respectively, with UF, at optimized conditions with increased
permeate flux from 17.5 l/m2/h (RO) to 38 l/m2/h (UF-RO). The
performance of the RO system was greatly improved both in term of
pollutant removal as well as water recovery.
Abstract: Biodiesel production from vegetable oil will produce
glycerol as by-product about 10% of the biodiesel production. The
amount of glycerol that was produced needed alternative way to
handling immediately so as to not become the waste that polluted
environment. One of the solutions was to process glycerol to
polyglycidyl nitrate (PGN). PGN is synthesized from glycerol by
three-step reactions i.e. nitration of glycerol, cyclization of 13-
dinitroglycerine and polymerization of glycosyl nitrate. Optimum
condition of nitration of glycerol with nitric acid has not been known.
Thermodynamic feasibility should be done before run experiments in
the laboratory. The aim of this study was to determine the parameters
those affect nitration of glycerol and nitric acid and chose the
operation condition. Many parameters were simulated to verify its
possibility to experiment under conditions which would get the
highest conversion of 1, 3-dinitroglycerine and which was the ideal
condition to get it. The parameters that need to be studied to obtain
the highest conversion of 1, 3-dinitroglycerine were mol ratio of
nitric acid/glycerol, reaction temperature, mol ratio of
glycerol/dichloromethane and pressure. The highest conversion was
obtained in the range of mol ratio of nitric acid /glycerol between 2/1
– 5/1, reaction temperature of 5-25oC and pressure of 1 atm. The
parameters that need to be studied further to obtain the highest
conversion of 1.3 DNG are mol ratio of nitric acid/glycerol and
reaction temperature.
Abstract: In this study, to clarify the effectiveness of an
aluminum/chromium/tungsten-based-coated tool for cutting sintered
steel, tool wear was experimentally investigated. The sintered steel
was turned with the (Al60,Cr25,W15)N-, (Al60,Cr25,W15)(C,N)- and
(Al64,Cr28,W8)(C,N)-coated cemented carbide tools according to the
physical vapor deposition (PVD) method. Moreover, the tool wear of
the aluminum/chromium/tungsten-based-coated item was compared
with that of the (Al,Cr)N coated tool. Furthermore, to clarify the tool
wear mechanism of the aluminum/chromium/tungsten-coating film for
cutting sintered steel, Scanning Electron Microscope observation and
Energy Dispersive x-ray Spectroscopy mapping analysis were
conducted on the abraded surface. The following results were
obtained: (1) The wear progress of the (Al64,Cr28,W8)(C,N)-coated
tool was the slowest among that of the five coated tools. (2) Adding
carbon (C) to the aluminum/chromium/tungsten-based-coating film
was effective for improving the wear-resistance. (3) The main wear
mechanism of the (Al60,Cr25,W15)N-, the (Al60,Cr25,W15)(C,N)-
and the (Al64,Cr28,W8)(C,N)-coating films was abrasive wear.
Abstract: The economic use and ease of construction of profiled
deck composite slab is marred with the complex and un-economic
strength verification required for the serviceability and general safety
considerations. Beside these, albeit factors such as shear span length,
deck geometries and mechanical frictions greatly influence the
longitudinal shear strength, that determines the ultimate strength of
profiled deck composite slab, and number of methods available for its
determination; partial shear and slope-intercept are the two methods
according to Euro-code 4 provision. However, the complexity
associated with shear behavior of profiled deck composite slab, the
use of these methods in determining the load carrying capacities of
such slab yields different and conflicting values. This couple with the
time and cost constraint associated with the strength verification is a
source of concern that draws more attentions nowadays, the issue is
critical. Treating some of these known shear strength influencing
factors as random variables, the load carrying capacity violation of
profiled deck composite slab from the use of the two-methods
defined according to Euro-code 4 are determined using reliability
approach, and comparatively studied. The study reveals safety values
from the use of m-k method shows good standing compared with that
from the partial shear method.
Abstract: The aim of the present study is to detect the chaotic
behavior in monetary economic relevant dynamical system. The
study employs three different forms of Taylor rules: current, forward,
and backward looking. The result suggests the existence of the
chaotic behavior in all three systems. In addition, the results strongly
represent that using expectations in policy rule especially rational
expectation hypothesis can increase complexity of the system and
leads to more chaotic behavior.
Abstract: Bicycle Level of Service (BLOS) is a measure for
evaluating street conditions for cyclists. Currently, various methods
are proposed for BLOS. These analytical methods however have
some drawbacks: they usually assume cyclists as users that can share
street facilities with motorized vehicles, it is not easy to link them to
design process and they are not easy to follow. In addition, they only
support a narrow range of cycling facilities and may not be applicable
for all situations. Along this, the current paper introduces various
effective design factors for bicycle-friendly streets. This study
considers cyclists as users of streets who have special needs and
facilities. Therefore, the key factors that influence BLOS based on
different cycling facilities that are proposed by developed guidelines
and literature are identified. The combination of these factors
presents a complete set of effective design factors for bicycle-friendly
streets. In addition, the weight of each factor in existing BLOS
models is estimated and these effective factors are ranked based on
these weights. These factors and their weights can be used in further
studies to propose special bicycle-friendly street design model.
Abstract: Superabsorbent polymers received much attention and
are used in many fields because of their superior characters to
traditional absorbents, e.g., sponge and cotton. So, it is very
important but challenging to prepare highly and fast-swelling
superabsorbents. A reliable, efficient and low-cost technique for
removing heavy metal ions from wastewater is the adsorption using
bio-adsorbents obtained from biological materials, such as
polysaccharides-based hydrogels superabsorbents. In this study, novel multi-functional superabsorbent composites
type semi-interpenetrating polymer networks (Semi-IPNs) were
prepared via graft polymerization of acrylamide onto chitosan
backbone in presence of gelatin, CTS-g-PAAm/Ge, using potassium
persulfate and N,N’-methylene bisacrylamide as initiator and
crosslinker, respectively. These hydrogels were also partially
hydrolyzed to achieve superabsorbents with ampholytic properties
and uppermost swelling capacity. The formation of the grafted
network was evidenced by Fourier Transform Infrared Spectroscopy
(ATR-FTIR) and Thermogravimetric Analysis (TGA). The porous
structures were observed by Scanning Electron Microscope (SEM).
From TGA analysis, it was concluded that the incorporation of the Ge
in the CTS-g-PAAm network has marginally affected its thermal
stability. The effect of gelatin content on the swelling capacities of
these superabsorbent composites was examined in various media
(distilled water, saline and pH-solutions). The water absorbency was
enhanced by adding Ge in the network, where the optimum value was
reached at 2 wt. % of Ge. Their hydrolysis has not only greatly
optimized their absorption capacity but also improved the swelling
kinetic.These materials have also showed reswelling ability. We
believe that these super-absorbing materials would be very effective
for the adsorption of harmful metal ions from wastewater.
Abstract: EEG correlates of mathematical and trait anxiety level
were studied in 52 healthy Russian-speakers during execution of
error-recognition tasks with lexical, arithmetic and algebraic
conditions. Event-related spectral perturbations were used as a
measure of brain activity. The ERSP plots revealed alpha/beta
desynchronizations within a 500-3000 ms interval after task onset
and slow-wave synchronization within an interval of 150-350 ms.
Amplitudes of these intervals reflected the accuracy of error
recognition, and were differently associated with the three conditions.
The correlates of anxiety were found in theta (4-8 Hz) and beta2 (16-
20 Hz) frequency bands. In theta band the effects of mathematical
anxiety were stronger expressed in lexical, than in arithmetic and
algebraic condition. The mathematical anxiety effects in theta band
were associated with differences between anterior and posterior
cortical areas, whereas the effects of trait anxiety were associated
with inter-hemispherical differences. In beta1 and beta2 bands effects
of trait and mathematical anxiety were directed oppositely. The trait
anxiety was associated with increase of amplitude of
desynchronization, whereas the mathematical anxiety was associated
with decrease of this amplitude. The effect of mathematical anxiety
in beta2 band was insignificant for lexical condition but was the
strongest in algebraic condition. EEG correlates of anxiety in theta
band could be interpreted as indexes of task emotionality, whereas
the reaction in beta2 band is related to tension of intellectual
resources.
Abstract: In this paper, influence of harmonics on medium
voltage distribution system of Bogazici Electricity Distribution Inc.
(BEDAS) which takes place at Istanbul/Turkey is investigated. A ring
network consisting of residential loads is taken into account for this
study. Real system parameters and measurement results are used for
simulations. Also, probable working conditions of the system are
analyzed for 50%, 75%, and 100% loading of transformers with
similar harmonic contents. Results of the study are exhibited the
influence of nonlinear loads on %THDV, P.F. and technical losses of
the medium voltage distribution system.
Abstract: The present study aimed to investigate the effect of
synchronous music in Gymnastics' motor skill performance among
undergraduate female students in physical education college at Basra
University. The researcher used experimental design. 20 female
students of physical education divided equally into two groups, (10)
experimental group with music, (10) control group without music.
All participants complete 6 weeks in testing. Data analysis based on
T-test shows significant difference at (α = 0.05) in all skills level
between experimental and control groups in favor of experimental
group. Results of this study contribute to developing the role of
synchronous music in improving gymnastic skills performance.
Abstract: It is necessary to predict a fatigue crack propagation
life for estimation of structural integrity. Because of an uncertainty
and a randomness of a structural behavior, it is also required to
analyze stochastic characteristics of the fatigue crack propagation life
at a specified fatigue crack size. The essential purpose of this study is to find the effect of load ratio
on probability distribution of the fatigue crack propagation life at a
specified grown crack size and to confirm the good probability
distribution in magnesium alloys under various fatigue load ratio
conditions. To investigate a stochastic crack growth behavior, fatigue
crack propagation experiments are performed in laboratory air under
several conditions of fatigue load ratio using AZ31. By Anderson-Darling test, a goodness-of-fit test for probability
distribution of the fatigue crack propagation life is performed. The
effect of load ratio on variability of fatigue crack propagation life is
also investigated.
Abstract: In present global scenario, aluminum alloys are
coining the attention of many innovators as competing structural
materials for automotive and space applications. Comparing to other
challenging alloys, especially, 7xxx series aluminum alloys have
been studied seriously because of benefits such as moderate strength;
better deforming characteristics and affordable cost. It is expected
that substitution of aluminum alloys for steels will result in great
improvements in energy economy, durability and recyclability.
However, it is necessary to improve the strength and the formability
levels at low temperatures in aluminum alloys for still better
applications. Aluminum–Zinc–Magnesium with or without other
wetting agent denoted as 7XXX series alloys are medium strength
heat treatable alloys. In addition to Zn, Mg as major alloying
additions, Cu, Mn and Si are the other solute elements which
contribute for the improvement in mechanical properties by suitable
heat treatment process. Subjecting to suitable treatments like age
hardening or cold deformation assisted heat treatments; known as low
temperature thermomechanical treatments (LTMT) the challenging
properties might be incorporated. T6 is the age hardening or
precipitation hardening process with artificial aging cycle whereas T8
comprises of LTMT treatment aged artificially with X% cold
deformation. When the cold deformation is provided after solution
treatment, there is increase in hardness related properties such as
wear resistance, yield and ultimate strength, toughness with the
expense of ductility. During precipitation hardening both hardness
and strength of the samples are increasing. The hardness value may
further improve when room temperature deformation is positively
supported with age hardening known as thermomechanical treatment.
It is intended to perform heat treatment and evaluate hardness, tensile
strength, wear resistance and distribution pattern of reinforcement in
the matrix. 2 to 2.5 and 3 to 3.5 times increase in hardness is reported
in age hardening and LTMT treatments respectively as compared to
as-cast composite. There was better distribution of reinforcements in
the matrix, nearly two fold increase in strength levels and up to 5
times increase in wear resistance are also observed in the present
study.
Abstract: In Electric Power Steering (EPS), spoke type
Brushless AC (BLAC) motors offer distinct advantages over other
electric motor types in terms torque smoothness, reliability and
efficiency. This paper deals with the shape optimization of spoke
type BLAC motor, in order to reduce cogging torque. This paper
examines 3 steps skewing rotor angle, optimizing rotor core edge and
rotor overlap length for reducing cogging torque in spoke type BLAC
motor. The methods were applied to existing machine designs and
their performance was calculated using finite- element analysis
(FEA). Prototypes of the machine designs were constructed and
experimental results obtained. It is shown that the FEA predicted the
cogging torque to be nearly reduce using those methods.
Abstract: Cyber exercises used to assess the preparedness of a
community against cyber crises, technology failures and Critical
Information Infrastructure (CII) incidents. The cyber exercises also
called cyber crisis exercise or cyber drill, involved partnerships or
collaboration of public and private agencies from several sectors.
This study investigates Organisation Cyber Resilience (OCR) of
participation sectors in cyber exercise called X Maya in Malaysia.
This study used a principal based cyber resilience survey called CSuite
Executive checklist developed by World Economic Forum in
2012. To ensure suitability of the survey to investigate the OCR, the
reliability test was conducted on C-Suite Executive checklist items.
The research further investigates the differences of OCR in ten
Critical National Infrastructure Information (CNII) sectors
participated in the cyber exercise. The One Way ANOVA test result
showed a statistically significant difference of OCR among ten CNII
sectors participated in the cyber exercise.
Abstract: In this paper, an autonomous hovering control method
of multicopter using only Web camera is proposed. Recently, various
control method of an autonomous flight for multicopter are proposed.
But, in the previous proposed methods, a motion capture system
(i. e., OptiTrack) and laser range finder are often used to measure
the position and posture of multicopter. To achieve an autonomous
flight control of multicopter with simple equipments, we propose
an autonomous flight control method using AR marker and Web
camera. AR marker can measure the position of multicopter with
Cartesian coordinate in three dimensional, then its position connects
with aileron, elevator, and accelerator throttle operation. A simple
PID control method is applied to the each operation and adjust
the controller gains. Experimental results are given to show the
effectiveness of our proposed method. Moreover, another simple
operation method for autonomous flight control multicopter is also
proposed.
Abstract: Numerical studies have been carried out using a
validated two-dimensional standard k-omega turbulence model for
the design optimization of a thrust vector control system using shock
induced self-impinging supersonic secondary double jet. Parametric
analytical studies have been carried out at different secondary
injection locations to identifying the highest unsymmetrical
distribution of the main gas flow due to shock waves, which produces
a desirable side force more lucratively for vectoring. The results from
the parametric studies of the case on hand reveal that the shock
induced self-impinging supersonic secondary double jet is more
efficient in certain locations at the divergent region of a CD nozzle
than a case with supersonic single jet with same mass flow rate. We
observed that the best axial location of the self-impinging supersonic
secondary double jet nozzle with a given jet interaction angle, built-in
to a CD nozzle having area ratio 1.797, is 0.991 times the primary
nozzle throat diameter from the throat location. We also observed
that the flexible steering is possible after invoking ON/OFF facility to
the secondary nozzles for meeting the onboard mission requirements.
Through our case studies we concluded that the supersonic self-impinging
secondary double jet at predesigned jet interaction angle
and location can provide more flexible steering options facilitating
with 8.81% higher thrust vectoring efficiency than the conventional
supersonic single secondary jet without compromising the payload
capability of any supersonic aerospace vehicle.
Abstract: In recent research copper and manganese systems
were found to be the most active in CO and organic compounds
oxidation among the base catalysts. The mixed copper manganese
oxide has been widely studied in oxidation reactions because of their
higher activity at low temperatures in comparison with single oxide
catalysts. The results showed that the formation of spinel
CuxMn3−xO4 in the oxidized catalyst is responsible for the activity
even at room temperature. That is why the most of the investigations
are focused on the hopcalite catalyst (CuMn2O4) as the best coppermanganese
catalyst. Now it’s known that this is true only for CO
oxidation, but not for mixture of CO and VOCs. The purpose of this
study is to investigate the alumina supported copper-manganese
catalysts with different Cu/Mn molar ratio in terms of oxidation of
CO, methanol and dimethyl ether. The catalysts were prepared by impregnation of γ-Al2O3 with
copper and manganese nitrates and the catalytic activity
measurements were carried out in two stage continuous flow
equipment with an adiabatic reactor for simultaneous oxidation of all
compounds under the conditions closest possible to the industrial. Gas
mixtures on the input and output of the reactor were analyzed with a
gas chromatograph, equipped with FID and TCD detectors. The
texture characteristics were determined by low-temperature (- 196oС)
nitrogen adsorption in a Quantachrome Instruments NOVA 1200e
(USA) specific surface area & pore analyzer. Thermal, XRD and
TPR analyses were performed. It was established that the active component of the mixed Cu-
Mn/γ–alumina catalysts strongly depends on the Cu/Mn molar ratio.
Highly active alumina supported Cu-Mn catalysts for CO, methanol
and DME oxidation were synthesized. While the hopcalite is the best
catalyst for CO oxidation, the best compromise for simultaneous
oxidation of all components is the catalyst with Cu/Mn molar ratio
1:5.
Abstract: Present work deals with the possible use of fertigation
in agriculture and its impact on the availability of mineral nitrogen
(Nmin) in topsoil and subsoil horizons. The aim of the present study is
to demonstrate the effect of the organic matter presence in fertigation
on microbial transformation and availability of mineral nitrogen
forms. The main investigation reason is the potential use of pretreated
waste water, as a source of organic carbon (Corg) and residual
nutrients (Nmin) for fertigation. Laboratory experiment has been
conducted to demonstrate the effect of the arable land fertilization
method on the Nmin availability in different depths of the soil with
the usage of model experimental containers filled with soil from
topsoil and podsoil horizons that were taken from the precise area.
Tufted hairgrass (Deschampsia caespitosa) has been chosen as a
model plant. The water source protection zone Brezova nad Svitavou
has been a research area where significant underground reservoirs of
drinking water of the highest quality are located. From the second
half of the last century local sources of drinking water show
nitrogenous compounds increase that get here almost only from
arable lands. Therefore, an attention of the following text focuses on
the fate of mineral nitrogen in the complex plant-soil. Research
results show that the fertigation application with Corg in a
combination with mineral fertilizer can reduce the amount of Nmin
leached from topsoil horizon of agricultural soils. In addition, some
plants biomass production reduces may occur.
Abstract: Traditionally, the embodied energy of design choices
which reduce operational energy were assumed to have a negligible
impact on the life cycle energy of buildings. However with new
buildings having considerably lower operational energy, the
significance of embodied energy increases. A life cycle assessment of
a population of house designs was conducted in a mild and mixed
climate zone. It was determined not only that embodied energy
dominates life cycle energy, but that the impact on embodied of
design choices was of equal significance to the impact on operational
energy.
Abstract: Zn alloy and composite coatings are widely used in
buildings and structures, automobile and fasteners industries to
protect steel component from corrosion. In this paper, Zn-Ni-Al2O3
nanocomposite coatings were electrodeposited on mild steel using a
novel sol enhanced electroplating method. In this method, transparent
Al2O3 sol was added into the acidic Zn-Ni bath to produced Zn-Ni-
Al2O3 nanocomposite coatings. The effect of alumina sol on the
electrodeposition process, and coating properties was investigated
using cyclic voltammetry, XRD, ESEM and Tafel test. Results from
XRD tests showed that the structure of all coatings was single γ-
Ni5Zn21 phase. Cyclic voltammetry results showed that the
electrodeposition overpotential was lower in the presence of alumina
sol in the bath, and caused the reduction potential of Zn-Ni to shift to
more positive values. Zn-Ni-Al2O3 nanocomposite coatings produced
more uniform and compact deposits, with fine grained microstructure
when compared to Zn-Ni coatings. The corrosion resistance of Zn-Ni
coatings was improved significantly by incorporation of alumina
nanoparticles into the coatings.