Abstract: The feasibility of employing solar radiation for
enhanced Fenton process in degradation of combined chlorpyrifos,
cypermethrin and chlorothalonil pesticides was examined. The effect
of various operating conditions of the process on biodegradability
improvement and mineralization of the pesticides were also
evaluated. The optimum operating conditions for treatment of
aqueous solution containing 100, 50 and 250 mg L-1 chlorpyrifos
cypermethrin and chlorothalonil, respectively were observed to be
H2O2/COD molar ratio 2, H2O2/Fe2+ molar ratio 25 and pH 3. Under
the optimum operating conditions, complete degradation of the
pesticides occurred in 1 min. Biodegradability (BOD5/COD)
increased from zero to 0.36 in 60 min, and COD and TOC removal
were 74.19 and 58.32%, respectively in 60 min. Due to
mineralization of organic carbon, decrease in ammonia-nitrogen from
22 to 4.3 mg L-1 and increase in nitrate from 0.7 to 18.1 mg L-1 in
60 min were recorded. The study indicated that solar photo-Fenton
process can be used for pretreatment of chlorpyrifos, cypermethrin
and chlorothalonil pesticides in aqueous solution for further
biological treatment.
Abstract: Tomato powder has good potential as substitute of tomato paste and other tomato products. In order to protect physicochemical properties and nutritional quality of tomato during dehydration process, investigation was carried out using different drying methods and pretreatments. Solar drier and continuous conveyor (tunnel) drier were used for dehydration where as calcium chloride (CaCl2), potassium metabisulphite (KMS), calcium chloride and potassium metabisulphite (CaCl2 +KMS), and sodium chloride (NaCl) selected for treatment.. lycopene content, dehydration ratio, rehydration ratio and non-enzymatic browning in addition to moisture, sugar and titrable acidity were studied. Results show that pre-treatment with CaCl2 and NaCl increased water removal and moisture mobility in tomato slices during drying of tomatoes. Where CaCl2 used along with KMS the NEB was recorded the least compared to other treatments and the best results were obtained while using the two chemicals in combination form. Storage studies in LDPE polymeric and metalized polyesters films showed less changes in the products packed in metallized polyester pouches and even after 6 months lycopene content did not decrease more than 20% as compared to the control sample and provide extension of shelf life in acceptable condition for 6 months. In most of the quality characteristics tunnel drier samples presented better values in comparison to solar drier.
Abstract: The experiments were performed in a batch set up
under different concentrations of Cu (II) (0.2 g.l-1 to 0.9 g.l-1), pH (4-
6), temperatures (20oC – 40oC) with varying teak leaves powder (as
biosorbent) dosage of 0.3 g.l-1 to 0.5 g.l-1. The kinetics of interactions
were tested with pseudo first order Lagergran equation and the value
for k1 was found to be 6.909 x 10-3 min-1. The biosorption data gave
a good fit with Langmuir and Fruendlich isotherms and the Langmuir
monolayer capacity (qm) was found to be 166.78 mg. g-1. Similarly
the Freundlich adsorption capacity (Kf) was estimated as 2.49 l g-1.
The mean values of the thermodynamic parameters ΔH, ΔS, and ΔG
were -62.42 KJ. mol-1, -0.219 KJ.mol-1 K-1 and -1.747 KJ.mol-1 at
293 K from a solution containing 0.4 g l-1 of Cu(II) showing the
biosorption to be thermodynamically favourable. These results show
good potentiality of using teak leaves as a biosorbent for the removal
of Cu(II) from aqueous solutions.
Abstract: This study uses natural water and the surface properties of powdered activated carbon to acclimatize organics, forming biofilms on the surface of powdered activated carbon. To investigate the influence of different hydraulic retention times on the removal efficacy of trace organics in raw water, and to determine the optimal hydraulic retention time of a biological powdered activated carbon system, this study selects ozone-treated water processed by Feng-shan Advanced Water Purification Plant in southern Taiwan for the experiment. The evaluation indicators include assimilable organic carbon, dissolved organic carbon, and total organic carbon. The results of this study can improve the quality of drinking water treated using advanced water purification procedures.
Abstract: As the performance of the filtering system depends
upon the accuracy of the noise detection scheme, in this paper, we
present a new scheme for impulse noise detection based on two
levels of decision. In this scheme in the first stage we coarsely
identify the corrupted pixels and in the second stage we finally
decide whether the pixel under consideration is really corrupt or not.
The efficacy of the proposed filter has been confirmed by extensive
simulations.
Abstract: 17α-ethinylestradiol (EE2) is a recalcitrant micropollutant which is found in small amounts in municipal wastewater. But these small amounts still adversely affect for the reproductive function of aquatic organisms. Evidence in the past suggested that full-scale WWTPs equipped with nitrification process enhanced the removal of EE2 in the municipal wastewater. EE2 has been proven to be able to be transformed by ammonia oxidizing bacteria (AOB) via co-metabolism. This research aims to clarify the EE2 degradation pattern by different consortium of ammonia oxidizing microorganism (AOM) including AOA (ammonia oxidizing archaea) and investigate contribution between the existing ammonia monooxygenase (AMO) and new synthesized AOM. The result showed that AOA or AOB of N. oligotropha cluster in enriched nitrifying activated sludge (NAS) from 2mM and 5mM, commonly found in municipal WWTPs, could degrade EE2 in wastewater via co-metabolism. Moreover, the investigation of the contribution between the existing ammonia monooxygenase (AMO) and new synthesized AOM demonstrated that the new synthesized AMO enzyme may perform ammonia oxidation rather than the existing AMO enzyme or the existing AMO enzyme may has a small amount to oxidize ammonia.
Abstract: The ionizing radiation of livestock wastewater for the
removal of nitrogen and phosphorus was studied in the presence of a
natural zeolite. The feasibility of a combined process of zeolite ion
exchange and electron beam irradiation of livestock wastewater was
also investigated. The removal efficiencies of NH4
+-N, T-N and T-P
were significantly enhanced by electron beam irradiation after zeolite
ion exchange as a pre-treatment. The presence of silica zeolite
accelerated the decomposition rate of livestock wastewater in the
electron beam irradiation process. These results indicate that the
combined process of zeolite ion exchange and electron beam
irradiation has the potential for the treatment of livestock wastewater
Abstract: The upgrading of low quality crude natural gas (NG) is attracting interest due to high demand of pipeline-grade gas in recent years. Membrane processes are commercially proven technology for the removal of impurities like carbon dioxide from NG. In this work, cross flow mathematical model has been suggested to be incorporated with ASPEN HYSYS as a user defined unit operation in order to design the membrane system for CO2/CH4 separation. The effect of operating conditions (such as feed composition and pressure) and membrane selectivity on the design parameters (methane recovery and total membrane area required for the separation) has been studied for different design configurations. These configurations include single stage (with and without recycle) and double stage membrane systems (with and without permeate or retentate recycle). It is shown that methane recovery can be improved by recycling permeate or retentate stream as well as by using double stage membrane systems. The ASPEN HYSYS user defined unit operation proposed in the study has potential to be applied for complex membrane system design and optimization.
Abstract: Inconel718 has been widely used as a super alloy in aerospace application due to the high strength at elevated temperatures, satisfactory oxidation resistance and heat corrosion resistance. In this study, the Inconel718 has been fabricated using high technology of Metal Injection Molding (MIM) process due to the cost effective technique for producing small, complex and precision parts in high volume compared with conventional method through machining. Through MIM, the binder system is one of the most important criteria in order to successfully fabricate the Inconel718. Even though, the binder system is a temporary, but failure in the selection and removal of the binder system will affect on the final properties of the sintered parts. Therefore, the binder system based on palm oil derivative which is palm stearin has been formulated and developed to replace the conventional binder system. The rheological studies of the mixture between the powder and binders system have been determined properly in order to be successful during injection into injection molding machine. After molding, the binder holds the particles in place. The binder system has to be removed completely through debinding step. During debinding step, solvent debinding and thermal pyrolysis has been used to remove completely of the binder system. The debound part is then sintered to give the required physical and mechanical properties. The results show that the properties of the final sintered parts fulfill the Standard Metal Powder Industries Federation (MPIF) 35 for MIM parts.
Abstract: Heavy metal pollution is an environmental concern.
Phytoremediation is a low-cost, environmental-friendly approach to
solve this problem. Mustard has the potential in reducing heavy metal
contents in soils. Among mustard (Brassica juncea (L.) Czern &
Coss) genotypes in Sri Lanka, accessions 7788, 8831 and 5088 give
significantly a high yield. Therefore, present study was conducted to
quantify the phytoextractive potential among these local mustard
accessions and to assess the interaction of heavy metals, Pb, Co, Mn
on phytoextraction. A pot experiment was designed with acid washed
sand (quartz) and a series of heavy metal solutions of 0, 25, 50, 75
and 100 μg/g. Experiment was carried out with factorial
experimental design. Mustard accessions were tolerant to heavy
metals and could be successfully used in removal of Pb, Co and Mn
and they are capable of accumulating significant quantities of heavy
metals in vegetative and reproductive organs. The order of the
accumulative potential of Pb, Co and Mn in mustard accessions is,
root > shoot >seed.
Abstract: In power systems, protective relays must filter their
inputs to remove undesirable quantities and retain signal quantities of
interest. This job must be performed accurate and fast. A new
method for filtering the undesirable components such as DC and
harmonic components associated with the fundamental system
signals. The method is s based on a dynamic filtering algorithm. The
filtering algorithm has many advantages over some other classical
methods. It can be used as dynamic on-line filter without the need of
parameters readjusting as in the case of classic filters. The proposed
filter is tested using different signals. Effects of number of samples
and sampling window size are discussed. Results obtained are
presented and discussed to show the algorithm capabilities.
Abstract: The surface water used in this study was collected from the Chao Praya River at the lower part at the Nonthaburi bridge. It was collected and used throughout the experiment. TOC (also known as DOC) in the range between 2.5 to 5.6 mg/l were investigated in this experiment. The use of conventional treatment methods such as FeCl3 and PAC showed that TOC removal was 65% using FeCl3 and 78% using PAC (powder activated carbon). The advanced oxidation process alone showed only 35% removal of TOC. Coupling advanced oxidation with a small amount of PAC (0.05g/L) increased efficiency by upto 55%. The combined BAC with advanced oxidation process and small amount of PAC demonstrated the highest efficiency of up to 95% of TOC removal and lower sludge production compared with other methods.
Abstract: The abundance and availability of rice husk, an agricultural waste, make them as a good source for precursor of activated carbon. In this work, rice husk-based activated carbons were prepared via base treated chemical activation process prior the carbonization process. The effect of carbonization temperatures (400, 600 and 800oC) on their pore structure was evaluated through morphology analysis using scanning electron microscope (SEM). Sample carbonized at 800oC showed better evolution and development of pores as compared to those carbonized at 400 and 600oC. The potential of rice husk-based activated carbon as an alternative adsorbent was investigated for the removal of Ni(II), Zn(II) and Pb(II) from single metal aqueous solution. The adsorption studies using rice husk-based activated carbon as an adsorbent were carried out as a function of contact time at room temperature and the metal ions were analyzed using atomic absorption spectrophotometer (AAS). The ability to remove metal ion from single metal aqueous solution was found to be improved with the increasing of carbonization temperature. Among the three metal ions tested, Pb(II) ion gave the highest adsorption on rice husk-based activated carbon. The results obtained indicate the potential to utilize rice husk as a promising precursor for the preparation of activated carbon for removal of heavy metals.
Abstract: In this research, a biofiltration process to remove
ammonia gas from gas stream using agricultural residue biofilter
medias is studied. The experiments were conducted in laboratoryscale
biofilter. The biofilter medias were a mixture of manure
fertilizer and bagasse at various ratios i.e., 1:3, 1:5 and 1:7. The
experiments were performed for a period of 40 days. The empty bed
retention time (EBRT) is 78s. The moisture content of biofilter media
was maintained at 45-60% using water. The results showed that the
agricultural residues (manure fertilizer and bagasse) are suitable as
biofilter media for ammonia gas removal in biofiltration process.
The maximum efficiency of ammonia gas removal is observed
from the 1:5 of manure fertilizer: bagasse ratio at 89.93%. The
biofiltration is more effective at low ammonia gas concentration. In
addition, the mixture ratio of biofilter media is not a significant factor
in biofiltration operation while the most significant factor for
biofiltration operation is the inlet ammonia gas concentration.
Abstract: FW4 is a newly developed hot die material widely
used in Forging Dies manufacturing. The right selection of the
machining conditions is one of the most important aspects to take
into consideration in the Electrical Discharge Machining (EDM) of
FW4. In this paper an attempt has been made to develop
mathematical models for relating the Material Removal Rate (MRR),
Tool Wear Ratio (TWR) and surface roughness (Ra) to machining
parameters (current, pulse-on time and voltage). Furthermore, a study
was carried out to analyze the effects of machining parameters in
respect of listed technological characteristics. The results of analysis
of variance (ANOVA) indicate that the proposed mathematical
models, can adequately describe the performance within the limits of
the factors being studied.
Abstract: Due to some reasons, observed images are degraded which are mainly caused by noise. Recently image denoising using the wavelet transform has been attracting much attention. Waveletbased approach provides a particularly useful method for image denoising when the preservation of edges in the scene is of importance because the local adaptivity is based explicitly on the values of the wavelet detail coefficients. In this paper, we propose several methods of noise removal from degraded images with Gaussian noise by using adaptive wavelet threshold (Bayes Shrink, Modified Bayes Shrink and Normal Shrink). The proposed thresholds are simple and adaptive to each subband because the parameters required for estimating the threshold depend on subband data. Experimental results show that the proposed thresholds remove noise significantly and preserve the edges in the scene.
Abstract: The purpose of this study is to investigate the chemical
degradation of the organophosphorus pesticide of parathion and
carbamate insecticide of methomyl in the aqueous phase through
Fenton process. With the employment of batch Fenton process, the
degradation of the two selected pesticides at different pH, initial
concentration, humic acid concentration, and Fenton reagent dosages
was explored. The Fenton process was found effective to degrade
parathion and methomyl. The optimal dosage of Fenton reagents (i.e.,
molar concentration ratio of H2O2 to Fe2+) at pH 7 for parathion
degradation was equal to 3, which resulted in 50% removal of
parathion. Similarly, the optimal dosage for methomyl degradation
was 1, resulting in 80% removal of methomyl. This study also found
that the presence of humic substances has enhanced pesticide
degradation by Fenton process significantly. The mass spectroscopy
results showed that the hydroxyl free radical may attack the single
bonds with least energy of investigated pesticides to form smaller
molecules which is more easily to degrade either through
physio-chemical or bilolgical processes.
Abstract: The photochemical and photo-Fenton oxidation of 1,3-dichloro-2-propanol was performed in a batch reactor, at room temperature, using UV radiation, H2O2 as oxidant, and Fenton-s reagent. The effect of the oxidative agent-s initial concentration was investigated as well as the effect of the initial concentration of Fe(II) by following the target compound degradation, the total organic carbon removal and the chloride ion production. Also, from the kinetic analysis conducted and proposed reaction scheme it was deduced that the addition of Fe(II) significantly increases the production and the further oxidation of the chlorinated intermediates.
Abstract: The objectives were to identify cyanide-degrading
bacteria and study cyanide removal efficiency. Agrobacterium
tumefaciens SUTS 1 was isolated. This is a new strain of
microorganisms for cyanide degradation. The maximum growth rate
of SUTS 1 obtained 4.7 × 108 CFU/ml within 4 days. The cyanide
removal efficiency was studied at 25, 50, and 150 mg/L cyanide. The
residual cyanide, ammonia, nitrate, nitrite, pH, and cell counts were
analyzed. At 25 and 50 mg/L cyanide, SUTS 1 obtained similar
removal efficiency approximately 87.50%. At 150 mg/L cyanide,
SUTS 1 enhanced the cyanide removal efficiency up to 97.90%. Cell
counts of SUTS 1 increased when the cyanide concentration was set
at lower. The ammonia increased when the removal efficiency
increased. The nitrate increased when the ammonia decreased but the
nitrite did not detect in all experiments. pH values also increased
when the cyanide concentrations were set at higher.
Abstract: The photocatalytic activity efficiency of TiO2 for the degradation of Toluene in photoreactor can be enhanced by nano- TiO2/LDPE composite film. Since the amount of TiO2 affected the efficiency of the photocatalytic activity, this work was mainly concentrated on the effort to embed the high amount of TiO2 in the Polyethylene matrix. The developed photocatalyst was characterized by XRD, UV-Vis spectrophotometer and SEM. The SEM images revealed the high homogeneity of the deposition of TiO2 on the polyethylene matrix. The XRD patterns interpreted that TiO2 embedded in the PE matrix exhibited mainly in anatase form. In addition, the photocatalytic results show that the toluene removal efficiencies of 30±5%, 49±4%, 68±5%, 42±6% and 33±5% were obtained when using the catalyst loading at 0%, 10%, 15%, 25% and 50% (wt. cat./wt. film), respectively.