Abstract: In the present study, an attempt was made to examine
the potential of aerobic mixed culture for decolourization of Remazol Black B dye in batch reactors. The effect of pH, temperature, inoculum, initial concentration of dye and initial concentration of
glucose was studied with an aim to determine the optimal conditions
required for maximum decolourization and degradation. The culture
exhibited maximum decolourization ability at pH between 7-8 and at
30°C. A 10% (v/v) inoculum and 1% (w/v) glucose concentration
were found to be the optimum for decolourization. A maximum of
98% decolourization was observed at 25 ppm initial concentration of
dye after 18 hours of incubation period. At higher dye concentration
of 300 ppm, the removal in colour was found to be 75% in 48 hours of incubation period. The results show that the enriched mixed culture from activated sludge has good potential in removal of Remazol Black B dye from wastewater under aerobic conditions.
Abstract: EEG signal is one of the oldest measures of brain
activity that has been used vastly for clinical diagnoses and
biomedical researches. However, EEG signals are highly
contaminated with various artifacts, both from the subject and from
equipment interferences. Among these various kinds of artifacts,
ocular noise is the most important one. Since many applications such
as BCI require online and real-time processing of EEG signal, it is
ideal if the removal of artifacts is performed in an online fashion.
Recently, some methods for online ocular artifact removing have
been proposed. One of these methods is ARMAX modeling of EEG
signal. This method assumes that the recorded EEG signal is a
combination of EOG artifacts and the background EEG. Then the
background EEG is estimated via estimation of ARMAX parameters.
The other recently proposed method is based on adaptive filtering.
This method uses EOG signal as the reference input and subtracts
EOG artifacts from recorded EEG signals. In this paper we
investigate the efficiency of each method for removing of EOG
artifacts. A comparison is made between these two methods. Our
undertaken conclusion from this comparison is that adaptive filtering
method has better results compared with the results achieved by
ARMAX modeling.
Abstract: Nitrogen loss from irrigated cropland, particularly
sandy soils, significantly contributes to nitrate (NO3
-) levels in
surface and groundwaters. Thus, it is of great interest to use
inexpensive natural products that can increase the fertilizer efficiency
and decrease nitrate leaching. In this study, the ability of natural
Iranian zeolite clinoptilolite (Cp) and surfactant modified zeolite
clinoptilolite (SMZ) to remove NH4
+ and NO3
-, respectively, from
aqueous solutions was determined. The feasibility of using Cp and
SMZ as soil amendment to reduce nitrate leaching from soil using
lysimeters was also investigated. Zeolite showed 10.23% to 88.42%
NH4
+ removal efficiency over a wide range of initial NH4
+
concentrations. Nitrate removal efficiency by SMZ was 32.26% to
82.26%. Field study results showed that Cp and SMZ significantly (p
< 0.05) reduced leachate NO3-N concentration compared to control.
There was no significant difference between maximum and mean
leachate NO3-N concentration of SMZ lysimeters and those of Cp
lysimeters.
Abstract: Heavy metals have bad effects on environment and
soils and it can uptake by natural HAP .natural Hap is an inexpensive
material that uptake large amounts of various heavy metals like Zn
(II) .Natural HAP (N-HAP), extracted from bovine cortical bone ash,
is a good choice for substitution of commercial HAP. Several
experiments were done to investigate the sorption capacity of Zn (II)
to N-HAP in various particles sizes, temperatures, initial
concentrations, pH and reaction times. In this study, the sorption of
Zinc ions from a Zn solution onto HAP particles with sizes of 1537.6
nm and 47.6 nm at three initial pH values of 4.50, 6.00 and 7.50 was
studied. The results showed that better performance was obtained
through a 47.6 nm particle size and higher pH values. The
experimental data were analyzed using Langmuir, Freundlich, and
Arrhenius equations for equilibrium, kinetic and thermodynamic
studies. The analysis showed a maximum adsorption capacity of NHAP
as being 1.562 mmol/g at a pH of 7.5 and small particle size.
Kinetically, the prepared N-HAP is a feasible sorbent that retains Zn
(II) ions through a favorable and spontaneous sorption process.
Abstract: This paper describes a combined mathematicalgraphical
approach for optimum tool path planning in order to
improve machining efficiency. A methodology has been used that
stabilizes machining operations by adjusting material removal rate in
pocket milling operations while keeping cutting forces within limits.
This increases the life of cutting tool and reduces the risk of tool
breakage, machining vibration, and chatter. Case studies reveal the
fact that application of this approach could result in a slight increase
of machining time, however, a considerable reduction of tooling cost,
machining vibration, noise and chatter can be achieved in addition to
producing a better surface finish.
Abstract: The pollutant removal efficiency of the Intermittently
Decanted Extended Aeration (IDEA) wastewater treatment system at
Curtin University Sarawak Campus, and conventional activated
sludge wastewater treatment system at a local resort, Resort A, is
monitored. The influent and effluent characteristics are tested during
wet and dry weather conditions, and peak and off peak periods. For
the wastewater treatment systems at Curtin Sarawak and Resort A,
during dry weather and peak season, it was found that the BOD5
concentration in the influent is 121.7mg/L and 80.0mg/L
respectively, and in the effluent, 18.7mg/L and and 18.0mg/L
respectively. Analysis of the performance of the IDEA treatment
system showed that the operational costs can be minimized by 3%, by
decreasing the number of operating cycles. As for the treatment
system in Resort A, by utilizing a smaller capacity air blower, a
saving of 12% could be made in the operational costs.
Abstract: This study focused on arsenate removal by nano
zero-valent iron (NZVI) in the gas-bubbled aqueous solution. It
appears that solution acidified by H2SO4 is far more favorable than by
CO2-bubbled acidification. In addition, as dissolved oxygen was
stripped out of solution by N2 gas bubbling, the arsenate removal
dropped significantly. To take advantages of common practice of
carbonation and oxic condition, pretreatment of CO2 and air bubbling
in sequence are recommended for a better removal of arsenate.
Abstract: The copper flotation tailings from Konkola Copper
mine in Nchanga, Zambia were used in the study. The purpose of this
study was to determine the leaching characteristics of the tailings
material prior and after the physical beneficiation process is
employed. The Knelson gravity concentrator (KC-MD3) was used for
the beneficiation process. The copper leaching efficiencies and
impurity co-extraction percentages in both the upgraded and the raw
feed material were determined at different pH levels and temperature.
It was observed that the copper extraction increased with an increase
in temperature and a decrease in pH levels. In comparison to the raw
feed sample, the upgraded sample reported a maximum copper
extraction of 69% which was 9%, higher than raw feed % extractions.
The impurity carry over was reduced from 18% to 4 % on the
upgraded sample. The reduction in impurity co-extraction was as a
result of the removal of the reactive gangue elements during the
upgrading process, this minimized the number of side reaction
occurring during leaching.
Abstract: The critical period for weed control (CPWC) is the period in the crop growth cycle during which weeds must be controlled to prevent unacceptable yield losses. Field studies were conducted in 2005 and 2006 in the University of Birjand at the south east of Iran to determine CPWC of corn using a randomized complete block design with 14 treatments and four replications. The treatments consisted of two different periods of weed interference, a critical weed-free period and a critical time of weed removal, were imposed at V3, V6, V9, V12, V15, and R1 (based on phonological stages of corn development) with a weedy check and a weed-free check. The CPWC was determined with the use of 2.5, 5, 10, 15 and 20% acceptable yield loss levels by non-linear Regression method and fitting Logistic and Gompertz nonlinear equations to relative yield data. The CPWC of corn was from 5- to 15-leaf stage (19-55 DAE) to prevent yield losses of 5%. This period to prevent yield losses of 2.5, 10 and 20% was 4- to 17-leaf stage (14-59 DAE), 6- to 12-leaf stage (25-47 DAE) and 8- to 9-leaf stage (31-36 DAE) respectively. The height and leaf area index of corn were significantly decreased by weed competition in both weed free and weed infested treatments (P
Abstract: Four phenylurea herbicides (isoproturon, chlortoluron, diuron and linuron) were dissolved in different water matrices in order to study their chemical degradation by using UV radiation, ozone and some advanced oxidation processes (UV/H2O2, O3/H2O2, Fenton reagent and the photo- Fenton system). The waters used were: ultra-pure water, a commercial mineral water, a groundwater and a surface water taken from a reservoir. Elimination levels were established for each herbicide and for several global quality parameters, and a kinetic study was performed in order to determine basic kinetic parameters of each reaction between the target phenylureas and these oxidizing systems.
Abstract: Fuller’s earth is a fine-grained, naturally occurring substance that has a substantial ability to adsorb impurities. In the present study Fuller’s earth has been characterized and used for the removal of Pb(II) from aqueous solution. The effect of various physicochemical parameters such as pH, adsorbent dosage and shaking time on adsorption were studied. The result of the equilibrium studies showed that the solution pH was the key factor affecting the adsorption. The optimum pH for adsorption was 5. Kinetics data for the adsorption of Pb(II) was best described by pseudo-second order model. The effective diffusion co-efficient for Pb(II) adsorption was of the order of 10-8 m2/s. The adsorption data for metal adsorption can be well described by Langmuir adsorption isotherm. The maximum uptake of metal was 103.3 mg/g of adsorbent. Mass transfer analysis was also carried out for the adsorption process. The values of mass transfer coefficients obtained from the study indicate that the velocity of the adsorbate transport from bulk to the solid phase was quite fast. The mean sorption energy calculated from Dubinin-Radushkevich isotherm indicated that the metal adsorption process was chemical in nature.
Abstract: The performance of an image filtering system depends
on its ability to detect the presence of noisy pixels in the image. Most
of the impulse detection schemes assume the presence of salt and
pepper noise in the images and do not work satisfactorily in case of
uniformly distributed impulse noise. In this paper, a new algorithm is
presented to improve the performance of switching median filter in
detection of uniformly distributed impulse noise. The performance of
the proposed scheme is demonstrated by the results obtained from
computer simulations on various images.
Abstract: Cu-mesoporous TiO2 is developed for removal acid
odor cooperated with ozone assistance and online- regeneration
system with/without UV irradiation (all weather) in study. The results
showed that Cu-mesoporous TiO2 present the desirable adsorption
efficiency of acid odor without UV irradiation, due to the larger
surface area, pore sizeand the additional absorption ability provided by
Cu. In the photocatalysis process, the material structure also benefits
Cu-mesoporous TiO2 to perform the more outstanding efficiency on
degrading acid odor. Cu also postponed the recombination of
electron-hole pairs excited from TiO2 to enhance photodegradation
ability. Cu-mesoporous TiO2 could gain the conspicuous increase on
photocatalysis ability from ozone assistance, but without any benefit
on adsorption. In addition, the online regeneration procedure could
process the used Cu-mesoporous TiO2 to reinstate the adsorption
ability and maintain the photodegradtion performance, depended on
scrubbing, desorping acid odor and reducing Cu to metal state.
Abstract: The present work was conducted for the synthesis of
nano size zerovalent iron (nZVI) and hexavalent chromium (Cr(VI))
removal as a highly toxic pollutant by using this nanoparticles. Batch
experiments were performed to investigate the effects of Cr(VI),
nZVI concentration, pH of solution and contact time variation on
the removal efficiency of Cr(VI). nZVI was synthesized by
reduction of ferric chloride using sodium borohydrid. SEM and
XRD examinations applied for determination of particle size and
characterization of produced nanoparticles. The results showed that
the removal efficiency decreased with Cr(VI) concentration and pH
of solution and increased with adsorbent dosage and contact time.
The Langmuir and Freundlich isotherm models were used for the
adsorption equilibrium data and the Langmuir isotherm model was
well fitted. Nanoparticle ZVI presented an outstanding ability to
remove Cr(VI) due to high surface area, low particle size and high
inherent activity.
Abstract: This study evaluates the performance of horizontal
subsurface flow constructed wetland (HSSF-CW) for the removal of
chlorinated resin and fatty acids (RFAs) from pulp and paper mill
wastewater. The dimensions of the treatment system were 3.5 m x 1.5
m x 0.28 m with surface area of 5.25 m2, filled with fine sand and
gravel. The cell was planted with an ornamental plant species Canna
indica. The removal efficiency of chlorinated RFAs was in the range
of 92-96% at the hydraulic retention time (HRT) of 5.9 days. Plant
biomass and soil (sand and gravel) were analyzed for chlorinated
RFAs content. No chlorinated RFAs were detected in plant biomass
but detected in soil samples. Mass balance studies of chlorinated
RFAs in HSSF-CW were also carried out.
Abstract: Tomato powder has good potential as substitute of tomato paste and other tomato products. In order to protect physicochemical properties and nutritional quality of tomato during dehydration process, investigation was carried out using different drying methods and pretreatments. Solar drier and continuous conveyor (tunnel) drier were used for dehydration where as calcium chloride (CaCl2), potassium metabisulphite (KMS), calcium chloride and potassium metabisulphite (CaCl2 +KMS), and sodium chloride (NaCl) selected for treatment.. lycopene content, dehydration ratio, rehydration ratio and non-enzymatic browning in addition to moisture, sugar and titrable acidity were studied. Results show that pre-treatment with CaCl2 and NaCl increased water removal and moisture mobility in tomato slices during drying of tomatoes. Where CaCl2 used along with KMS the NEB was recorded the least compared to other treatments and the best results were obtained while using the two chemicals in combination form. Storage studies in LDPE polymeric and metalized polyesters films showed less changes in the products packed in metallized polyester pouches and even after 6 months lycopene content did not decrease more than 20% as compared to the control sample and provide extension of shelf life in acceptable condition for 6 months. In most of the quality characteristics tunnel drier samples presented better values in comparison to solar drier.
Abstract: The electrochemical coagulation of a kaolin
suspension was investigated at the currents of 0.06, 0.12, 0.22, 0.44,
0.85 A (corresponding to 0.68, 1.36, 2.50, 5.00, 9.66 mA·cm-2,
respectively) for the contact time of 5, 10, 20, 30, and 50 min. The
TSS removal efficiency at currents of 0.06 A, 0.12 A and 0.22 A
increased with the amount of iron generated by the sacrificial anode,
while the removal efficiencies did not increase proportionally with
the amount of iron generated at the currents of 0.44 and 0.85 A,
where electroflotation was clearly observed. Zeta potential
measurement illustrated the presence of the highly positive charged
particles created by sorption of highly charged polymeric metal
hydroxyl species onto the negative surface charged kaolin particles at
both low and high applied currents. The disappearance of the
individual peaks after certain contact times indicated the attraction
between these positive and negative charged particles causing
agglomeration. It was concluded that charge neutralization of the
individual species was not the only mechanism operating in the
electrocoagulation process at any current level, but electrostatic
attraction was likely to co-operate or mainly operate.
Abstract: The main objective of this research is to synthesize silk fibroin fiber for indoor air particulate removal. Silk cocoons were de-gummed using 0.5 wt % Na2CO3 alkaline solutions at 90 Ó╣ìC for 60 mins, washed with distilled water, and dried at 80 Ó╣ìC for 3 hrs in a vacuum oven. Two sets of experiment were conducted to investigate the impacts of initial particulate matter (PM) concentration and that of air flow rate on the removal efficiency. Rice bran collected from a local rice mill in Ubonratchathani province was used as indoor air contaminant in this work. The morphology and physical properties of silk fibroin (SF) fiber were measured. The SEM revealed the deposition of PM on the used fiber. The PM removal efficiencies of 72.29 ± 3.03 % and 39.33 ± 1.99 % were obtained of PM10 and PM2.5, respectively, when using the initial PM concentration at 0.040 mg/m3 and 0.020 mg/m3 of PM10 and PM2.5, respectively, with the air flow rate of 5 L/min.
Abstract: Boron minerals are very useful for various industrial
activities, such as glass industry and detergent industry, due to its
mechanical and chemical properties. During the production of boron
compounds, many of these are introduced into the environment in the
form of waste. Boron is also an important micro nutrient for the
plants to vegetate but if it exists in high concentrations, it could have
toxic effects. The maximum boron level in drinking water for human
health is given as 0.3 mg/L in World Health Organization (WHO)
standards. The toxic effects of boron should be noted especially for
dry regions, thus, in recent years, increasing attention has been paid
to remove the boron from waste waters. In this study, boron removal
is implemented by ion exchange process using Amberlite IRA-743
resin. Amberlite IRA-743 resin is a boron specific resin and it
belongs to the polymerizate sorbent group within the aminopolyol
functional group. Batch studies were performed to investigate the
effects of various experimental parameters, such as adsorbent dose,
initial concentration and pH, on the removal of boron. It is found
that, when the adsorbent dose increases removal of boron from the
liquid phase increases. However, an increase in the initial
concentration decreases the removal of boron. The effective pH
values for removal of boron are determined between 8.5 and 9.
Equilibrium isotherms were also analyzed by Langmuir and
Freundlich isotherm models. The Langmuir isotherm is obeyed better
than the Freundlich isotherm.
Abstract: This study investigated the removal efficiency of electrokinetic remediation of copper-contaminated soil at different combinations of enhancement reagents used as anolyte and catholyte. Sodium hydroxide (at 0.1, 0.5, and 1.0 M concentrations) and distilled water were used as anolyte, while lactic acid (at 0.01, 0.1, and 0.5 M concentrations), ammonium citrate (also at 0.01, 0.1, and 0.5 M concentrations) and distilled water were used as catholyte. A continuous voltage application (1.0 VDC/cm) was employed for 240 hours for each experiment. The copper content of the catholyte was determined at the end of the 240-hour period. Optimization was carried out with a Response Surface Methodology - Optimal Design, including F test, and multiple comparison method, to determine which pair of anolyte-catholyte was the most significant for the removal efficiency. "1.0 M NaOH" was found to be the most significant anolyte while it was established that lactic acid was the most significant type of catholyte to be used for the most successful electrokinetic experiments. Concentrations of lactic acid should be at the range of 0.1 M to 0.5 M to achieve maximum percent removal values.