Abstract: The present work was conducted for the synthesis of
nano size zerovalent iron (nZVI) and hexavalent chromium (Cr(VI))
removal as a highly toxic pollutant by using this nanoparticles. Batch
experiments were performed to investigate the effects of Cr(VI),
nZVI concentration, pH of solution and contact time variation on
the removal efficiency of Cr(VI). nZVI was synthesized by
reduction of ferric chloride using sodium borohydrid. SEM and
XRD examinations applied for determination of particle size and
characterization of produced nanoparticles. The results showed that
the removal efficiency decreased with Cr(VI) concentration and pH
of solution and increased with adsorbent dosage and contact time.
The Langmuir and Freundlich isotherm models were used for the
adsorption equilibrium data and the Langmuir isotherm model was
well fitted. Nanoparticle ZVI presented an outstanding ability to
remove Cr(VI) due to high surface area, low particle size and high
inherent activity.
Abstract: This paper presents the buckling analysis of short and
long functionally graded cylindrical shells under thermal and
mechanical loads. The shell properties are assumed to vary
continuously from the inner surface to the outer surface of the shell.
The equilibrium and stability equations are derived using the total
potential energy equations, Euler equations and first order shear
deformation theory assumptions. The resulting equations are solved
for simply supported boundary conditions. The critical temperature
and pressure loads are calculated for both short and long cylindrical
shells. Comparison studies show the effects of functionally graded
index, loading type and shell geometry on critical buckling loads of
short and long functionally graded cylindrical shells.