Abstract: The remediation of water resources pollution in
developing countries requires the application of alternative
sustainable cheaper and efficient end-of-pipe wastewater treatment
technologies. The feasibility of use of South African cheap and
abundant pine tree (Pinus patula) sawdust for development of lowcost
AC of comparable quality to expensive commercial ACs in the
abatement of water pollution was investigated. AC was developed at
optimized two-stage N2-superheated steam activation conditions in a
fixed bed reactor, and characterized for proximate and ultimate
properties, N2-BET surface area, pore size distribution, SEM, pHPZC
and FTIR. The sawdust pyrolysis activation energy was evaluated by
TGA. Results indicated that the chars prepared at 800oC and 2hrs
were suitable for development of better quality AC at 800oC and 47%
burn-off having BET surface area (1086m2/g), micropore volume
(0.26cm3/g), and mesopore volume (0.43cm3/g) comparable to
expensive commercial ACs, and suitable for water contaminants
removal. The developed AC showed basic surface functionality at
pHPZC at 10.3, and a phenol adsorption capacity that was higher than
that of commercial Norit (RO 0.8) AC. Thus, it is feasible to develop
better quality low-cost AC from (Pinus patula) sawdust using twostage
N2-steam activation in fixed-bed reactor.
Abstract: TiO2/MgO composite films were prepared by coating
the magnesium acetate solution in the pores of mesoporous TiO2
films using a dip coating method. Concentrations of magnesium
acetate solution were varied in a range of 1x10-4 – 1x10-1 M. The
TiO2/MgO composite films were characterized by scanning electron
microscopy (SEM), transmission electron microscropy (TEM),
electrochemical impedance spectroscopy(EIS) , transient voltage
decay and I-V test. The TiO2 films and TiO2/MgO composite films
were immersed in a 0.3 mM N719 dye solution. The Dye-sensitized
solar cells with the TiO2/MgO/N719 structure showed an optimal
concentration of magnesium acetate solution of 1x10-3 M resulting in
the MgO film estimated thickness of 0.0963 nm and giving the
maximum efficiency of 4.85%. The improved efficiency of dyesensitized
solar cell was due to the magnesium oxide film as the wide
band gap coating decays the electron back transfer to the triiodide
electrolyte and reduce charge recombination.
Abstract: spherical porous carbon particles with
controllable porosity with a mean size of 2.5m have been
prepared using a spray drying method with organic particle
colloidal template. As a precursor, a mixing solution of carbon
nanopowder and polystyrene (PS) particles as a template was
used. The result showed that the particles with a good porous
structure could be obtained. The pore size and shape (spherical)
were identical to the initial template, giving a potential way for
further developments. The control of particle porosity was also
possible and reported in this paper, in which this control could
be achieved by means of PS concentration.
Abstract: Cement stabilization has been widely used for
improving the strength and stiffness of soft clayey soils. Cement
treated soil specimens used to investigate the stress-strain behaviour in
the laboratory study are usually cured for 7 days. This paper examines
the effects of curing time on the strength and stress strain behaviour of
cement treated marine clay under triaxial loading condition.
Laboratory-prepared cement treated Singapore marine clay with
different mix proportion S-C-W (soil solid-cement solid-water) and
curing time (7 days to 180 days) was investigated through conducting
unconfined compressive strength test and triaxial test. The results
show that the curing time has a significant effect on the unconfined
compressive strength u q , isotropic compression behaviour and stress
strain behaviour. Although the primary yield loci of the cement treated
soil specimens with the same mix proportion expand with curing time,
they are very narrowly banded and have nearly the same shape after
being normalized by isotropic compression primary stress '
py p . The
isotropic compression primary yield stress '
py p was shown to be
linearly related to unconfined compressive strength u q for specimens
with different curing time and mix proportion. The effect of curing
time on the hardening behaviour will diminish with consolidation
stress higher than isotropic compression primary yield stress but its
damping rate is dependent on the cement content.
Abstract: We have developed a database for membrane protein functions, which has more than 3000 experimental data on functionally important amino acid residues in membrane proteins along with sequence, structure and literature information. Further, we have proposed different methods for identifying membrane proteins based on their functions: (i) discrimination of membrane transport proteins from other globular and membrane proteins and classifying them into channels/pores, electrochemical and active transporters, and (ii) β-signal for the insertion of mitochondrial β-barrel outer membrane proteins and potential targets. Our method showed an accuracy of 82% in discriminating transport proteins and 68% to classify them into three different transporters. In addition, we have identified a motif for targeting β-signal and potential candidates for mitochondrial β-barrel membrane proteins. Our methods can be used as effective tools for genome-wide annotations.
Abstract: This paper demonstrates an effort of a serviceoriented
engineering department in improving the sharing and
transfer of knowledge. Although the department consist of only six
employees, but it provides services in various chemical application in
an oil and gas business. The services provided span across Asia
Pacific region mainly Indonesia, Myanmar, Vietnam, Brunei,
Thailand and Singapore. Currently there are no effective tools or
integrated systems that support the sharing or transfer and
maintenance of knowledge so the department has considered
preserving this valuable knowledge by developing a Knowledge
Management System (KMS). This paper presents the development of
a KMS to support the sharing of knowledge in a service-oriented
engineering department of an oil and gas company. The embedded
features in the KMS like blog and forum will encourage iterative
process of knowledge sharing among the employees in the
department. The information and knowledge being shared, discussed
and communicated will be then achieved for future re-use. The re-use
of the knowledge allows the department to reduce redundant efforts
in providing consistent, up-to-date and cost effective of the best
solution to the its clients.
Abstract: In this study, the effect of greywater irrigation on airwater interfacial area is investigated. Several soil column experiments were conducted for different greywater irrigation to develop the pressure-saturation curves. Surface tension was measured for different greywater concentration and fitted for Gibbs adsorption equation. Pressure-saturation curves show that the reduction of capillary rise stops when it reaches its critical micelle concentration (CMC). A simple theory is derived from pressure-saturation curves for calculating air-water interfacial area in porous medium during greywater irrigation by introducing a term 'hydraulic radius' for the pores. This term diminishes any effect of pore shapes on the air-water interfacial area. The air-water interfacial area was calculated using the pressure-saturation curves and found that it decreases with increasing moisture content. But no significant effect was observed on air-water interfacial area for different greywater irrigation. A maximum of 10% variation in interfacial area was observed at the residual saturation zone.
Abstract: Microtomographic images and thin section (TS)
images were analyzed and compared against some parameters of
geological interest such as porosity and its distribution along the
samples. The results show that microtomography ( CT) analysis,
although limited by its resolution, have some interesting information
about the distribution of porosity (homogeneous or not) and can also
quantify the connected and non-connected pores, i.e., total porosity.
TS have no limitations concerning resolution, but are limited by the
experimental data available in regards to a few glass sheets for
analysis and also can give only information about the connected
pores, i.e., effective porosity. Those two methods have their own
virtues and flaws but when paired together they are able to
complement one another, making for a more reliable and complete
analysis.
Abstract: Experimental investigation of the effect of
hydrophobic injection on siloxane basis on the properties of oldfashioned
type of ceramic brick is presented in the paper. At the
experimental testing, the matrix density, total open porosity, pore size
distribution, sorptivity, water absorption coefficient, sorption and
desorption isotherms are measured for the original, as well as the
hydrophobic-injection treated brick. On the basis of measured data,
the functionality of the hydrophobic injection for the moisture ingress
prevention into the studied ceramic brick is assessed.
Abstract: We fabricated multi-walled carbon nanotube (MCNT)
emitters by an electroporetic deposition (EPD) method using a
MCNT-sodium dodecyl sulfate (SDS) suspension. MCNT films were
prepared on graphite tip using EPD. We observe field emission
properties of MCNT film after heat treatment. Consequently, The
MCNT film on graphite tip exhibit good electron emission current.
Abstract: A high performance clarification system has been
discussed for advanced aqueous reprocessing of FBR spent fuel.
Dissolver residue gives the cause of troubles on the plant operation of
reprocessing. In this study, the new clarification system based on the
hybrid of centrifuge and filtration was proposed to get the high
separation ability of the component of whole insoluble sludge. The
clarification tests of simulated solid species were carried out to
evaluate the clarification performance using small-scale test apparatus
of centrifuge and filter unit. The density effect of solid species on the
collection efficiency was mainly evaluated in the centrifugal
clarification test. In the filtration test using ceramic filter with pore
size of 0.2μm, on the other hand, permeability and filtration rate
were evaluated in addition to the filtration efficiency. As results, it was
evaluated that the collection efficiency of solid species on the new
clarification system was estimated as nearly 100%. In conclusion, the
high clarification performance of dissolver liquor can be achieved by
the hybrid of the centrifuge and filtration system.
Abstract: In this work Membrane Distillation is applied to
concentrate orange Juice. Clarified orange juice (11o Brix) obtained
from fresh fruits and a sugar solution was subjected to membrane
distillation. The experiments were performed on a flat sheet module
using orange juice and sucrose solution as feeds. The concentration
of a sucrose solution, used as a model fruit juice and also orange
juice, was carried out in a direct contact membrane distillation using
hydrophobic PTFE membrane of pore size 0.2 μm and porosity 70%.
Surface modification of PTFE membrane has been carried out by
treating membrane with alcohol and water solution to make it
hydrophilic and then hydrophobicity was regained by drying. The
influences of the feed temperature, feed concentration, flow rate,
operating time on the permeate flux were studied for treated and non
treated membrane. In this work treated and non treated membrane
were compared in terms of water flux, Within the tested range, MD
with surface modified membrane the water flux has been
significantly improved by treating the membrane surface.
Abstract: The implementations of green roof have been widely
used in the developed countries such as Germany, United Kingdom,
United States and Canada. Green roof have many benefits such as
aesthetic and economic value, ecological gain which are optimization
of storm water management, urban heat island mitigation and energy
conservation. In term of pollution, green roof can control the air and
noise pollution in urban cities. The application of green roof in
Malaysian building has been studied with the previous work of green
roof either in Malaysia or other Asian region as like Indonesia,
Singapore, Thailand, Taiwan and several other countries that have
similar climate and environment as in Malaysia. These technologies
of adapting green roof have been compared to the Green Building
Index (GBI) of Malaysian buildings. The study has concentrated on
the technical aspect of green roof system having focused on i) waste
& recyclable materials ii) types of plants and method of planting and
iii) green roof as tool to reduce storm water runoff. The finding of
these areas will be compared to the suitability in achieving good
practice of the GBI in Malaysia. Results show that most of the
method are based on the countries own climate and environment.
This suggests that the method of using green roof must adhere to the
tropical climate of Malaysia. Suggestion of this research will be
viewed in term of the sustainability of the green roof. Further
research can be developed to implement the best method and
application in Malaysian climate especially in urban cities and
township.
Abstract: Sol-gel method has been used to fabricate
nanocomposite films on glass substrates composed halloysite clay
mineral and nanocrystalline TiO2. The methodology for the synthesis
involves a simple chemistry method utilized nonionic surfactant
molecule as pore directing agent along with the acetic acid-based solgel
route with the absence of water molecules. The thermal treatment
of composite films at 450oC ensures elimination of organic material
and lead to the formation of TiO2 nanoparticles onto the surface of
the halloysite nanotubes. Microscopy techniques and porosimetry
methods used in order to delineate the structural characteristics of the
materials. The nanocomposite films produced have no cracks and
active anatase crystal phase with small crystallite size were deposited
on halloysite nanotubes. The photocatalytic properties for the new
materials were examined for the decomposition of the Basic Blue 41
azo dye in solution. These, nanotechnology based composite films
show high efficiency for dye’s discoloration in spite of different
halloysite quantities and small amount of halloysite/TiO2 catalyst
immobilized onto glass substrates. Moreover, we examined the
modification of the halloysite/TiO2 films with silver particles in order
to improve the photocatalytic properties of the films. Indeed, the
presence of silver nanoparticles enhances the discoloration rate of the
Basic Blue 41 compared to the efficiencies obtained for unmodified
films.
Abstract: The Želazny Most tailing pond is one of the largest
facilities worldwide for waste disposal from the copper mines located
in South-West Poland. A potential failure of the dam would allow
more than 10 million cubic meters of contaminated slurry to flow to
the valley, causing immense environmental problems to the
surrounding area. Thus, the determination of the strength properties
of the dam's soils and their variability is of utmost importance.
An extensive site investigation consisting of more than 480 cone
penetration tests (CPTs) with or without pore water pressure
measurements were conducted within a period of 13 years to study
the mechanical properties of the tailings body. The present work
investigates the point variability of the soil strength parameters
(effective friction angle
Abstract: Recently, nanomaterials are developed in the form of nano-films, nano-crystals and nano-pores. Lanthanide phosphates as a material find extensive application as laser, ceramic, sensor, phosphor, and also in optoelectronics, medical and biological labels, solar cells and light sources. Among the different kinds of rare-earth orthophosphates, yttrium orthophosphate has been shown to be an efficient host lattice for rare earth activator ions, which have become a research focus because of their important role in the field of light display systems, lasers, and optoelectronic devices. It is in this context that the 4fn- « 4fn-1 5d transitions of rare earth in insulating materials, lying in the UV and VUV, are the aim of large number of studies .Though there has been a few reports on Eu3+, Nd3+, Pr3+,Er3+, Ce3+, Tm3+ doped YPO4. The 4fn- « 4fn-1 5d transitions of the rare earth dependent to the host-matrix, several matrices ions were used to study these transitions, in this work we are suggesting to study on a very specific class of inorganic material that are orthophosphate doped with rare earth ions. This study focused on the effect of Ce3+ concentration on the structural and optical properties of Ce3+ doped YPO4 yttrium orthophosphate with powder form prepared by the Sol Gel method.
Abstract: Deoxygenation of beef fat for the production of hydrogenated biodiesel is investigated in a high pressure continuous flow fixed bed reactor over palladium-supported mesoporous titania catalyst synthesized via a combined single-step sol-gel process with surfactant-assisted templating method (SATM). The catalyst possessed a mesoporous charactheristic with high surface area and narrow pore size distribution. The main products of all Pd/TiO2 catalysts are n-heptadecane (n-C17) and n-pentadecane (n-C15) resulting from decarbonylation reaction. Pd/TiO2 catalyst synthesized via a combined single-step sol-gel process with SATM (SSSG) gave higher activity and selectivity to the desired products when compared to IWI/SG-TiO2 and IWI/P25-TiO2, respectively. SSSG catalyst gave the average conversion up to 80-90 % and 80 % for the selectivity in diesel range hydrocarbons. This result may cause by the higher surface area and the ability in dispersion of palladium ion in mesoporous of TiO2 during sol-gel process.
Abstract: This study was conducted to explore the effects of two
countries model comparison program in Taiwan and Singapore in
TIMSS database. The researchers used Multi-Group Hierarchical
Linear Modeling techniques to compare the effects of two different
country models and we tested our hypotheses on 4,046 Taiwan
students and 4,599 Singapore students in 2007 at two levels: the class
level and student (individual) level. Design quality is a class level
variable. Student level variables are achievement and self-confidence.
The results challenge the widely held view that retention has a positive
impact on self-confidence. Suggestions for future research are
discussed.
Abstract: The equilibrium, thermodynamics and kinetics of the
biosorption of Cd (II) and Pb(II) by a Spore Forming Bacillus (MGL
75) were investigated at different experimental conditions. The
Langmuir and Freundlich, and Dubinin-Radushkevich (D-R)
equilibrium adsorption models were applied to describe the
biosorption of the metal ions by MGL 75 biomass. The Langmuir
model fitted the equilibrium data better than the other models.
Maximum adsorption capacities q max for lead (II) and cadmium (II)
were found equal to 158.73mg/g and 91.74 mg/g by Langmuir model.
The values of the mean free energy determined with the D-R equation
showed that adsorption process is a physiosorption process. The
thermodynamic parameters Gibbs free energy (ΔG°), enthalpy (ΔH°),
and entropy (ΔS°) changes were also calculated, and the values
indicated that the biosorption process was exothermic and
spontaneous. Experiment data were also used to study biosorption
kinetics using pseudo-first-order and pseudo-second-order kinetic
models. Kinetic parameters, rate constants, equilibrium sorption
capacities and related correlation coefficients were calculated and
discussed. The results showed that the biosorption processes of both
metal ions followed well pseudo-second-order kinetics.
Abstract: Characteristics and sonocatalytic activity of zeolite
Y catalysts loaded with TiO2 using impregnation and ion exchange
methods for the degradation of amaranth dye were investigated.
The Ion-exchange method was used to encapsulate the TiO2 into
the internal pores of the zeolite while the incorporation of TiO2
mostly on the external surface of zeolite was carried out using the
impregnation method. Different characterization techniques were
used to elucidate the physicochemical properties of the produced
catalysts. The framework of zeolite Y remained virtually
unchanged after the encapsulation of TiO2 while the crystallinity of
zeolite decreased significantly after the incorporation of 15 wt% of
TiO2. The sonocatalytic activity was enhanced by TiO2
incorporation with maximum degradation efficiencies of 50% and
68% for the encapsulated titanium and titanium loaded onto the
zeolite, respectively after 120min of reaction. Catalysts
characteristics and sonocatalytic behaviors were significantly
affected by the preparation method and the location of TiO2
introduced with zeolite structure. Behaviors in the sonocatalytic
process were successfully correlated with the characteristics of the
catalysts used.