Abstract: A novel calibration approach that aims to reduce
ASM2d parameter subsets and decrease the model complexity is
presented. This approach does not require high computational
demand and reduces the number of modeling parameters required to
achieve the ASMs calibration by employing a sensitivity and iteration
methodology. Parameter sensitivity is a crucial factor and the
iteration methodology enables refinement of the simulation parameter
values. When completing the iteration process, parameters values are
determined in descending order of their sensitivities. The number of
iterations required is equal to the number of model parameters of the
parameter significance ranking. This approach was used for the
ASM2d model to the evaluated EBPR phosphorus removal and it was
successful. Results of the simulation provide calibration parameters.
These included YPAO, YPO4, YPHA, qPHA, qPP, μPAO, bPAO, bPP, bPHA,
KPS, YA, μAUT, bAUT, KO2 AUT, and KNH4 AUT. Those parameters were
corresponding to the experimental data available.
Abstract: Recently, nanomaterials are developed in the form of nano-films, nano-crystals and nano-pores. Lanthanide phosphates as a material find extensive application as laser, ceramic, sensor, phosphor, and also in optoelectronics, medical and biological labels, solar cells and light sources. Among the different kinds of rare-earth orthophosphates, yttrium orthophosphate has been shown to be an efficient host lattice for rare earth activator ions, which have become a research focus because of their important role in the field of light display systems, lasers, and optoelectronic devices. It is in this context that the 4fn- « 4fn-1 5d transitions of rare earth in insulating materials, lying in the UV and VUV, are the aim of large number of studies .Though there has been a few reports on Eu3+, Nd3+, Pr3+,Er3+, Ce3+, Tm3+ doped YPO4. The 4fn- « 4fn-1 5d transitions of the rare earth dependent to the host-matrix, several matrices ions were used to study these transitions, in this work we are suggesting to study on a very specific class of inorganic material that are orthophosphate doped with rare earth ions. This study focused on the effect of Ce3+ concentration on the structural and optical properties of Ce3+ doped YPO4 yttrium orthophosphate with powder form prepared by the Sol Gel method.