Abstract: Adsorption of a boron nitride nanotube (BNNT) was
examined toward ethylacetylene (C4H6) molecule by using density
functional theory (DFT) calculations at the B3LYP/6-31G (d) level,
and it was found that the adsorption energy (Ead) of ethylacetylene
the pristine nanotubes is about -1.60kcal/mol. But when nanotube has
been doped with Si and Al atoms, the adsorption energy of
ethylacetylene molecule was increased. Calculation showed that
when the nanotube is doping by Al, the adsorption energy is about -
24.19kcal/mol and also the amount of HOMO/LUMO energy gap
(Eg) will reduce significantly. Boron nitride nanotube is a suitable
adsorbent for ethylacetylene and can be used in separation processes
ethylacetylene. It is seem that nanotube (BNNT) is a suitable
semiconductor after doping, and the doped BNNT in the presence of
ethylacetylene an electrical signal is generating directly and therefore
can potentially be used for ethylacetylene sensors.
Abstract: Although it is not intended to identify distance
education students as a homogeneous group, recent research has
demonstrated that there are some demographic and personality
common traits among most of them that provide the basis for the
description of a typical distance learning student. The purpose of this
paper is to describe these common traits and to facilitate their
learning journey within a distance education program. The described
research is an initiative of the Distance Education Unit at the
European University Cyprus (Laureate International Universities) in
the context of its action for the improvement of the students’
performance.
Abstract: A Silver (Ag) thin film is introduced as a template and
doping source for vertically aligned p–type ZnO nanorods. ZnO
nanorods were grown using an ammonium hydroxide based
hydrothermal process. During the hydrothermal process, the Ag thin
film was dissolved to generate Ag ions in the solution. The Ag ions can
contribute to doping in the wurzite structure of ZnO and the (111)
grain of Ag thin film can be the epitaxial temporal template for the
(0001) plane of ZnO. Hence, Ag–doped p–type ZnO nanorods were
successfully grown on the substrate, which can be an electrode or
semiconductor for the device application. To demonstrate the
potentials of this idea, p–n diode was fabricated and its electrical
characteristics were demonstrated.
Abstract: A thermosyphon system is a heat transfer loop which
operates on the basis of gravity and buoyancy forces. It guarantees a
good reliability and low maintenance cost as it does not involve any
mechanical pump. Therefore, it can be used in many industrial
applications such as refrigeration and air conditioning, electronic
cooling, nuclear reactors, geothermal heat extraction, etc. But flow
instabilities and loop configuration are the major problems in this
system. Several previous researchers studied that stabilities can be
suppressed by using nanofluids as loop fluid. In the present study a
rectangular thermosyphon loop with end heat exchangers are
considered for the study. This configuration is more appropriate for
many practical applications such as solar water heater, geothermal
heat extraction, etc. In the present work, steady-state analysis is
carried out on thermosyphon loop with parallel flow coaxial heat
exchangers at heat source and heat sink. In this loop nanofluid is
considered as the loop fluid and water is considered as the external
fluid in both hot and cold heat exchangers. For this analysis onedimensional
homogeneous model is developed. In this model,
conservation equations like conservation of mass, momentum, energy
are discretized using finite difference method. A computer code is
written in MATLAB to simulate the flow in thermosyphon loop. A
comparison in terms of heat transfer is made between water and
nanofluid as working fluids in the loop.
Abstract: Water spray cooling is a technique typically used in
heat treatment and other metallurgical processes where controlled
temperature regimes are required. Water spray cooling is used in
static (without movement) or dynamic (with movement of the steel
plate) regimes. The static regime is notable for the fixed position of
the hot steel plate and fixed spray nozzle. This regime is typical for
quenching systems focused on heat treatment of the steel plate. The
second application of spray cooling is the dynamic regime. The
dynamic regime is notable for its static section cooling system and
moving steel plate. This regime is used in rolling and finishing mills.
The fixed position of cooling sections with nozzles and the
movement of the steel plate produce nonhomogeneous water
distribution on the steel plate. The length of cooling sections and
placement of water nozzles in combination with the nonhomogeneity
of water distribution lead to discontinued or interrupted cooling
conditions. The impact of static and dynamic regimes on cooling
intensity and the heat transfer coefficient during the cooling process
of steel plates is an important issue.
Heat treatment of steel is accompanied by oxide scale growth. The
oxide scale layers can significantly modify the cooling properties and
intensity during the cooling. The combination of static and dynamic
(section) regimes with the variable thickness of the oxide scale layer
on the steel surface impact the final cooling intensity. The study of
the influence of the oxide scale layers with different cooling regimes
was carried out using experimental measurements and numerical
analysis. The experimental measurements compared both types of
cooling regimes and the cooling of scale-free surfaces and oxidized
surfaces. A numerical analysis was prepared to simulate the cooling
process with different conditions of the section and samples with
different oxide scale layers.
Abstract: Supply chain (SC) is an operational research (OR)
approach and technique which acts as catalyst within central nervous
system of business today. Without SC, any type of business is at
doldrums, hence entropy. SC is the lifeblood of business today
because it is the pivotal hub which provides imperative competitive
advantage. The paper present a conceptual framework dubbed as
Homomorphic Conceptual Framework for Effective Supply Chain
Strategy (HCEFSC).The term Homomorphic is derived from abstract
algebraic mathematical term homomorphism (same shape) which
also embeds the following mathematical application sets:
monomorphisms, isomorphism, automorphisms, and endomorphism.
The HCFESC is intertwined and integrated with wide and broad sets
of elements.
Abstract: We present an analytical model for the calculation of
the sensitivity, the spectral current noise and the detective parameter
for an optically illuminated In0.53Ga0.47As n+nn+ diode. The
photocurrent due to the excess carrier is obtained by solving the
continuity equation. Moreover, the current noise level is evaluated at
room temperature and under a constant voltage applied between the
diode terminals. The analytical calculation of the current noise in the
n+nn+ structure is developed by considering the free carries
fluctuations. The responsivity and the detection parameter are
discussed as functions of the doping concentrations and the emitter
layer thickness in one-dimensional homogeneous n+nn+ structure.
Abstract: It is usually difficult for students to understand some
basic theories in learning thermal energy and power engineering
course. A new teaching method was proposed that we should introduce
the comparison research method of those theories to help them being
understood. “Homogeneous and heterogeneous catalysis” teaching is
analyzed as an example by comparison research method.
Abstract: The reliability of the filtered HVBK model is now
investigated via some large eddy simulations (LES) of freely
decaying isotropic superfluid turbulence. For homogeneous
turbulence at very high Reynolds numbers, comparison of the terms
in the spectral kinetic energy budget equation indicates, in the
energy-containing range, that the production and energy transfer
effects become significant except for dissipation. In the inertial range,
where the two fluids are perfectly locked, the mutual friction maybe
neglected with respect to other terms. Also, the LES results for the
other terms of the energy balance are presented.
Abstract: The Quad Tree Decomposition based performance
analysis of compressed image data communication for lossy and
lossless through wireless sensor network is presented. Images have
considerably higher storage requirement than text. While transmitting
a multimedia content there is chance of the packets being dropped
due to noise and interference. At the receiver end the packets that
carry valuable information might be damaged or lost due to noise,
interference and congestion. In order to avoid the valuable
information from being dropped various retransmission schemes have
been proposed. In this proposed scheme QTD is used. QTD is an
image segmentation method that divides the image into homogeneous
areas. In this proposed scheme involves analysis of parameters such
as compression ratio, peak signal to noise ratio, mean square error,
bits per pixel in compressed image and analysis of difficulties during
data packet communication in Wireless Sensor Networks. By
considering the above, this paper is to use the QTD to improve the
compression ratio as well as visual quality and the algorithm in
MATLAB 7.1 and NS2 Simulator software tool.
Abstract: Two micromechanical models for 3D smart composite
with embedded periodic or nearly periodic network of generally
orthotropic reinforcements and actuators are developed and applied to
cubic structures with unidirectional orientation of constituents.
Analytical formulas for the effective piezothermoelastic coefficients
are derived using the Asymptotic Homogenization Method (AHM).
Finite Element Analysis (FEA) is subsequently developed and used
to examine the aforementioned periodic 3D network reinforced smart
structures. The deformation responses from the FE simulations are
used to extract effective coefficients. The results from both
techniques are compared. This work considers piezoelectric materials
that respond linearly to changes in electric field, electric
displacement, mechanical stress and strain and thermal effects. This
combination of electric fields and thermo-mechanical response in
smart composite structures is characterized by piezoelectric and
thermal expansion coefficients. The problem is represented by unitcell
and the models are developed using the AHM and the FEA to
determine the effective piezoelectric and thermal expansion
coefficients. Each unit cell contains a number of orthotropic
inclusions in the form of structural reinforcements and actuators.
Using matrix representation of the coupled response of the unit cell,
the effective piezoelectric and thermal expansion coefficients are
calculated and compared with results of the asymptotic
homogenization method. A very good agreement is shown between
these two approaches.
Abstract: The biosynthesis of nanoparticles by microorganisms,
on the contrary to chemical synthesis, is an environmentally-friendly
process which has low energy requirements. In this investigation, we
used the microorganism Geobacillus wiegelii, strain GWE1, an
aerobic thermophile belonging to genus Geobacillus, isolated from a
drying oven. This microorganism has the ability to reduce selenite
evidenced by the change of color from colorless to red in the culture.
Elemental analysis and composition of the particles were verified
using transmission electron microscopy and energy-dispersive X-ray
analysis. The nanoparticles have a defined spherical shape and a
selenium elemental state. Previous experiments showed that the
presence of the whole microorganism for the reduction of selenite
was not necessary. The results strongly suggested that an intracellular
NADPH/NADH-dependent reductase mediates selenium
nanoparticles synthesis under aerobic conditions. The enzyme was
purified and identified by mass spectroscopy MALDI-TOF TOF
technique. The enzyme is a 1-pyrroline-5-carboxylate dehydrogenase.
Histograms of nanoparticles sizes were obtained. Size distribution
ranged from 40-160 nm, where 70% of nanoparticles have less than
100 nm in size. Spectroscopic analysis showed that the nanoparticles
are composed of elemental selenium. To analyse the effect of pH in
size and morphology of nanoparticles, the synthesis of them was
carried out at different pHs (4.0, 5.0, 6.0, 7.0, 8.0). For
thermostability studies samples were incubated at different
temperatures (60, 80 and 100 ºC) for 1 h and 3 h. The size of all
nanoparticles was less than 100 nm at pH 4.0; over 50% of
nanoparticles have less than 100 nm at pH 5.0; at pH 6.0 and 8.0 over
90% of nanoparticles have less than 100 nm in size. At neutral pH
(7.0) nanoparticles reach a size around 120 nm and only 20% of them
were less than 100 nm. When looking at temperature effect,
nanoparticles did not show a significant difference in size when they
were incubated between 0 and 3 h at 60 ºC. Meanwhile at 80 °C the
nanoparticles suspension lost its homogeneity. A change in size was
observed from 0 h of incubation at 80ºC, observing a size range
between 40-160 nm, with 20% of them over 100 nm. Meanwhile
after 3 h of incubation at size range changed to 60-180 nm with 50%
of them over 100 nm. At 100 °C the nanoparticles aggregate forming
nanorod structures. In conclusion, these results indicate that is
possible to modulate size and shape of biologically synthesized
nanoparticles by modulating pH and temperature.
Abstract: The North-eastern part of India, which receives
heavier rainfall than other parts of the subcontinent, is of great
concern now-a-days with regard to climate change. High intensity
rainfall for short duration and longer dry spell, occurring due to
impact of climate change, affects river morphology too. In the present
study, an attempt is made to delineate the North-eastern region of
India into some homogeneous clusters based on the Fuzzy Clustering
concept and to compare the resulting clusters obtained by using
conventional methods and nonconventional methods of clustering.
The concept of clustering is adapted in view of the fact that, impact
of climate change can be studied in a homogeneous region without
much variation, which can be helpful in studies related to water
resources planning and management. 10 IMD (Indian Meteorological
Department) stations, situated in various regions of the North-east,
have been selected for making the clusters. The results of the Fuzzy
C-Means (FCM) analysis show different clustering patterns for
different conditions. From the analysis and comparison it can be
concluded that nonconventional method of using GCM data is
somehow giving better results than the others. However, further
analysis can be done by taking daily data instead of monthly means to
reduce the effect of standardization.
Abstract: This entry concerned with dense silica bricks
microstructure was produced as a part of a project within the
Technology Agency of the Czech Republic which is being
implemented in cooperation of the biggest producer of refractories
the P-D Refractories CZ company with the research organisation
Brno University of Technology. The paper is focused on the
influence of mixture homogenisation and the influence of grain size
of the mineraliser on the resulting utility properties of the material as
well as its microstructure. It has a decisive influence on the durability
of the material in a building structure. This paper is a continuation of
a previously published study dealing with the suitability of various
types of mineralising agents in terms of density, strength and mineral
composition of silica brick.
The entry describes the influence of the method of mixture
homogenisation and the influence of granulometry of the applied Femineralising
agent on the resulting silica microstructure. Porosity,
density, phase composition and microstructure of the experimentally
prepared silica bricks samples were examined and the results were
discussed in context with the technology of homogenisation and
firing temperature used. The properties of silica bricks samples were
compared to the sample without any Fe-mineraliser.
Abstract: Malathion (ML) is a well known pesticide commonly
used in many agricultural and non-agricultural processes. Its toxicity
has been attributed primarily to the accumulation of acetylcholine
(Ach) at nerve junctions, due to the inhibition of acetylcholinesterase
(AChE). The aim of the current research was to study the protective
effect of the melissa plant extract against reproductive impairment
induced by malathion in 32 male albino rats, and the biological
experiment was divided into four groups (8 in each) that given
malathion (27 mg/kg; 1/50 of the LD50 for an oral dose) and/or
Melissa officinalis (MO) extract (200mg/kg/day) by gavages
technique. The sperm counts, sperm motility, sperm morphology,
FSH, LH, and testosterone levels had been determined in testes
homogenate at the end of the experiment. It is worthy to report that,
rats treated with melissa extract did not show a significant difference
when compared with the control group, while rats given malathion
alone had significantly lower sperm count, sperm motility, and
significantly higher abnormal sperm numbers, than the untreated
control rats as well as having significantly lower serum FSH, LH, and
testosterone levels compared with the control group. Administrations
of melissa extract restore all mentioned histological parameters
towards the control group and the melissa extract had a strong
positive protective effect against malathion toxicity. Results the of
biological parameters were confirmed by the histological
examination of rat testes and indicated that, both control and melissa
groups showing normal seminiferous tubules, while malathion group
testicular tissues had necrosis, edema in the seminiferous tubules and
degeneration of spermatogonial cells lining the seminiferous tubules
with incomplete spermatogenesis. The use of melissa against
malathion improved the histological picture and showing normal
seminiferous tubules with complete spermatogenesis and almost there
was no histopathological changes could be noted.
Abstract: In this study, six bacterial isolates of a slightly
thermophilic organism from the Sg. Klah hot spring, Malaysia were
successfully isolated and designated as M7T55D1, M7T55D2,
M7T55D3, M7T53D1, M7T53D2 and M7T53D3 respectively. The
bacterial isolates were screened for their cellulose hydrolytic ability
on Carboxymethlycellulose agar medium. The isolated bacterial
strains were identified morphologically, biochemically and
molecularly with the aid of 16S rDNA sequencing. All of the bacteria
showed their optimum growth at a slightly alkaline pH of 7.5 with a
temperature of 55°C. All strains were Gram-negative, non-spore
forming type, strictly aerobic, catalase-positive and oxidase-positive
with the ability to produce thermostable cellulase. Based on BLASTn
results, bacterial isolates of M7T55D2 and M7T53D1 gave the
highest homology (97%) with similarity to Tepidimonas ignava while
isolates M7T55D1, M7T55D3, M7T53D2 and M7T53D3 showed
their closest homology (97%-98%) with Tepidimonas thermarum.
These cellulolytic thermophiles might have a commercial potential to
produce valuable thermostable cellulase.
Abstract: The effect of non-homogeneity on the free transverse vibration of thin rectangular plates of bilinearly varying thickness has been analyzed using generalized differential quadrature (GDQ) method. The non-homogeneity of the plate material is assumed to arise due to linear variations in Young’s modulus and density of the plate material with the in-plane coordinates x and y. Numerical results have been computed for fully clamped and fully simply supported boundary conditions. The solution procedure by means of GDQ method has been implemented in a MATLAB code. The effect of various plate parameters has been investigated for the first three modes of vibration. A comparison of results with those available in literature has been presented.
Abstract: Solid lipid nanoparticles (SLNs) have gained great attention for the topical treatment of skin associated fungal infection as they facilitate the skin penetration of loaded drugs. Our work deals with the preparation of nystatin loaded solid lipid nanoparticles (NystSLNs) using the hot homogenization and ultrasonication method. The prepared NystSLNs were characterized in terms of entrapment efficiency, particle size, zeta potential, transmission electron microscopy, differential scanning calorimetry, rheological behavior and in vitro drug release. A stability study for 6 months was performed. A microbiological study was conducted in male rats infected with Candida albicans, by counting the colonies and examining the histopathological changes induced on the skin of infected rats. The results showed that SLNs dispersions are spherical in shape with particle size ranging from 83.26±11.33 to 955.04±1.09 nm. The entrapment efficiencies are ranging from 19.73±1.21 to 72.46±0.66% with zeta potential ranging from -18.9 to -38.8 mV and shear-thinning rheological Behavior. The stability studies done for 6 months showed that nystatin (Nyst) is a good candidate for topical SLN formulations. A least number of colony forming unit/ ml (cfu/ml) was recorded for the selected NystSLN compared to the drug solution and the commercial Nystatin® cream present in the market. It can be fulfilled from this work that SLNs provide a good skin targeting effect and may represent promising carrier for topical delivery of Nyst offering the sustained release and maintaining the localized effect, resulting in an effective treatment of cutaneous fungal infection.
Abstract: A novel new vanadium (IV) complexes incorporating the chelating diamido cyclopentadienyl {ArN(CH2)3NAr)}2-((ηn-Cp)Cp)} (Ar = 2,6-Pri2C6H3)(Cp = C5H5 and n = 1,2,3,4 and 5) have been studied with calculation of the properties of species involved in various of cyclopentadienyl reaction. These were carried out under investigation of density functional theory (DFT) calculation, and comparing together. Other methods, explicitly including electron correlation, are necessary for more accurate calculations; MB3LYP (Becke) (Lee–Yang–Parr) level of theory often being used to obtain more exact results. These complexes were estimated of electronic energy for molecular system, because it accounts for all electron correlation interactions.
The optimised of [V(ArN(CH2)3NAr)2Cl(η5-Cp)] (Ar = 2,6-Pri2C6H3 and Cp= C5H5) was found to be thermally more stable than others of vanadium cyclopentadienyl. In the meantime the complex [V(ArN(CH2)3NAr)2Cl(η1-Cp)] (Ar = 2,6-Pri2C6H3 and Cp= C5H5) which is showed a low thermal stability in case of the just one carbon of cyclopentadienyl can be insertion with vanadium metal centre. By using Dewar-Chatt-Duncanson model, as a basis of the molecular orbital (MO) analysis and showed the highest occupied molecular orbital (HOMO) and lowest occupied molecular orbital LUMO.
Abstract: We offer a new technique for research of stability of current sheaths in space plasma taking into account the effect of polarization. At the beginning, the found perturbation of the distribution function is used for calculation of the dielectric permeability tensor, which simulates inhomogeneous medium of a current sheath. Further, we in the usual manner solve the system of Maxwell's equations closed with the material equation. The amplitudes of Fourier perturbations are considered to be exponentially decaying through the current sheath thickness. The dispersion equation follows from the nontrivial solution requirement for perturbations of the electromagnetic field. The resulting dispersion equation allows one to study the temporal and spatial characteristics of instability modes of the current sheath (within the limits of the proposed model) over a wide frequency range, including low frequencies.