Abstract: This first-attempt study revealed that decolorized
intermediates of azo dyes could act as redox mediators to assist
wastewater (WW) decolorization due to enhancement of
electron-transport phenomena. Electrochemical impedance spectra
indicated that hydroxyl and amino-substituent(s) were functional
group(s) as redox-mediator(s). As azo dyes are usually multiple
benzene-rings structured, their derived decolorized intermediates are
likely to play roles of electron shuttles due to lower barrier of energy
gap for electron shuttling. According to cyclic voltammetric profiles,
redox mediating characteristics of decolorized intermediates of azo
dyes (e.g., RBu171, RR198, RR141, RBk5) were clearly disclosed.
With supplementation of biodecolorized metabolites of RR141 and
198, decolorization performance of could be evidently augmented.
This study also suggested the optimal modes of microbial fuel cell
(MFC)-assisted WW decolorization would be plug-flow or batch
mode of operation with no mix. Single chamber-MFCs would be more
favourable than double chamber MFCs due to non-mixing contacting
reactor scheme for operation.
Abstract: In the present work, forming limit diagrams and strain
distribution profile diagrams for extra deep drawing steel at room and
elevated temperatures have been determined experimentally by
conducting stretch forming experiments by using designed and
fabricated warm stretchforming tooling setup. With the help of
forming Limit Diagrams (FLDs) and strain, distribution profile
diagrams the formability of Extra Deep Drawing steel has been
analyzed and co-related with mechanical properties like strain
hardening COEFFICIENT (n) and normal anisotropy (r−). Mechanical
properties of EDD steel from room temperature to 4500C were
determined and discussed the impact of temperature on the properties
like work hardening exponent (n) anisotropy (r-) and strength
coefficient of the material. In addition, the fractured surfaces after
stretching have undergone the some metallurgical investigations and
attempt has been made to co-relate with the formability of EDD steel
sheets. They are co-related and good agreement with FLDs at various
temperatures.
Abstract: This article developed an ion thruster optic system
sputter erosion depth numerical 3D model by IFE-PIC (Immersed
Finite Element-Particle-in-Cell) and Mont Carlo method, and
calculated the downstream surface sputter erosion rate of accelerator
grid; compared with LIPS-200 life test data. The results of the
numerical model are in reasonable agreement with the measured data.
Finally, we predicted the lifetime of the 20cm diameter ion thruster via
the erosion data obtained with the model. The ultimate result
demonstrated that under normal operating condition, the erosion rate
of the grooves wears on the downstream surface of the accelerator grid
is 34.6μm⁄1000h, which means the conservative lifetime until
structural failure occurring on the accelerator grid is 11500 hours.
Abstract: A Reconfigurable Wilkinson power divider is
proposed in this paper. In existing system only a limited number of
bandwidth is used at the output ports, in the proposed Wilkinson
power divider different band of frequencies are obtained by using
PIN diode. By tuning the PIN diode, different frequencies are
achieved. The size of the power divider is reduced for the operating
frequency and increases the fractional bandwidth.
Abstract: By using a fixed point theorem of a sum operator, the
existence and uniqueness of positive solution for a class of
boundary value problem of nonlinear fractional differential equation
is studied. An iterative scheme is constructed to approximate it.
Finally, an example is given to illustrate the main result.
Abstract: Small-size and low-power sensors with sensing, signal
processing and wireless communication capabilities is suitable for the
wireless sensor networks. Due to the limited resources and battery
constraints, complex routing algorithms used for the ad-hoc networks
cannot be employed in sensor networks. In this paper, we propose
node-disjoint multi-path hexagon-based routing algorithms in wireless
sensor networks. We suggest the details of the algorithm and compare
it with other works. Simulation results show that the proposed scheme
achieves better performance in terms of efficiency and message
delivery ratio.
Abstract: Online measurement of the product quality is a
challenging task in cement production, especially in the production of
Celitement, a novel environmentally friendly hydraulic binder. The
mineralogy and chemical composition of clinker in ordinary Portland
cement production is measured by X-ray diffraction (XRD) and
X-ray fluorescence (XRF), where only crystalline constituents can be
detected. But only a small part of the Celitement components can be
measured via XRD, because most constituents have an amorphous
structure. This paper describes the development of algorithms
suitable for an on-line monitoring of the final processing step of
Celitement based on NIR-data. For calibration intermediate products
were dried at different temperatures and ground for variable
durations. The products were analyzed using XRD and
thermogravimetric analyses together with NIR-spectroscopy to
investigate the dependency between the drying and the milling
processes on one and the NIR-signal on the other side. As a result,
different characteristic parameters have been defined. A short
overview of the Celitement process and the challenging tasks of the
online measurement and evaluation of the product quality will be
presented. Subsequently, methods for systematic development of
near-infrared calibration models and the determination of the final
calibration model will be introduced. The application of the model on
experimental data illustrates that NIR-spectroscopy allows for a quick
and sufficiently exact determination of crucial process parameters.
Abstract: In this paper, we introduce a flexible box erecting
machine (BEM) that swiftly and automatically transforms cardboard
into a three dimensional box. Recently, the parcel service and
home-shopping industries have grown rapidly, and there is an
increasing need for various box types to ship various products.
However, workers cannot fold thousands of boxes manually in a day.
As such, automatic BEMs are garnering greater attention. This study
takes equipment operation into consideration as well as mechanical
improvements in order to design a BEM that is able to outperform its
conventional counterparts. We analyzed six dispatching rules – First In
First Out (FIFO), Shortest Processing Time (SPT), Earliest Due Date
(EDD), Setup Avoidance, EDD + SPT, and EDD + Setup Avoidance –
to determine which one was most suitable for BEM operation.
Consequently, SPT and Setup Avoidance were found to be the most
critical rules, followed by EDD + Setup Avoidance, EDD + SPT,
EDD, and FIFO. This hierarchy was valid for both our conventional
BEM and our new flexible BEM from the viewpoint of processing
time. We believe that this research can contribute to flexible BEM
management, which has the potential to increase productivity and
convenience.
Abstract: This study evaluated to facilitate separation of ABS
plastics from other waste plastics by froth flotation after surface
hydrophilization of ABS with heat treatment. The mild heat treatment
at 100oC for 60s could selectively increase the hydrophilicity of the
ABS plastics surface (i.e., ABS contact angle decreased from 79o to
65.8o) among other plastics mixture. The SEM and XPS results of
plastic samples sufficiently supported the increase in hydrophilic
functional groups and decrease contact angle on ABS surface, after
heat treatment. As a result of the froth flotation (at mixing speed 150
rpm and airflow rate 0.3 L/min) after heat treatment, about 85% of
ABS was selectively separated from other heavy plastics with 100%
of purity. The effect of optimum treatment condition and detailed
mechanism onto separation efficiency in the froth floatation was also
investigated. This research is successful in giving a simple, effective,
and inexpensive method for ABS separation from waste plastics.
Abstract: Cadmium oxide (CdO) nanoparticles have been
prepared by chemical coprecipitation method. The synthesized
nanoparticles were characterized by X-ray diffraction analysis
(XRD), scanning electron microscopy (SEM), transmission electron
microscopy (TEM), UV analysis, and dielectric studies. The
crystalline nature and particle size of the CdO nanoparticles were
characterized by Powder X-ray diffraction analysis (XRD). The
morphology of prepared CdO nanoparticles was studied by scanning
electron microscopy. The particle size was studied using the
transmission electron microscopy (TEM).The optical properties were
obtained from UV-Vis absorption spectrum. The dielectric properties
of CdO nanoparticles were studied in the frequency range of 50 Hz–5
MHz at different temperatures. The frequency dependence of the
dielectric constant and dielectric loss is found to decrease with an
increase in the frequency at different temperatures. The ac
conductivity of CdO nanoparticle has been studied.
Abstract: The question of legal liability over injury arising out
of the import and the introduction of GM food emerges as a crucial
issue confronting to promote GM food and its derivatives. There is a
greater possibility of commercialized GM food from the exporting
country to enter importing country where status of approval shall not
be same. This necessitates the importance of fixing a liability
mechanism to discuss the damage, if any, occurs at the level of
transboundary movement or at the market. There was a widespread consensus to develop the Cartagena
Protocol on Biosafety and to give for a dedicated regime on liability
and redress in the form of Nagoya Kuala Lumpur Supplementary
Protocol on the Liability and Redress (‘N-KL Protocol’) at the
international context. The national legal frameworks based on this
protocol are not adequately established in the prevailing food
legislations of the developing countries. The developing economy
like India is willing to import GM food and its derivatives after the
successful commercialization of Bt Cotton in 2002. As a party to the
N-KL Protocol, it is indispensable for India to formulate a legal
framework and to discuss safety, liability, and regulatory issues
surrounding GM foods in conformity to the provisions of the
Protocol. The liability mechanism is also important in the case where
the risk assessment and risk management is still in implementing
stage. Moreover, the country is facing GM infiltration issues with its
neighbors Bangladesh. As a precautionary approach, there is a need
to formulate rules and procedure of legal liability to discuss any kind
of damage occurs at transboundary trade. In this context, the
proposed work will attempt to analyze the liability regime in the
existing Food Safety and Standards Act, 2006 from the applicability
and domestic compliance and to suggest legal and policy options for
regulatory authorities.
Abstract: The strain intensity and redundant strains, dependent
in multistage TRIP wire drawing processes from values used single
partial reductions, should influence on the intensity of transformation
the retained austenite into martensite and thereby on mechanical
properties of drawn wires. The numerical analysis of drawing
processes with use of Drawing 2D programme, for steel wires made
from TRIP steel with 0,29% has been shown in the work. The change
of strain intensity εc and the values of redundant strain εxy, has been
determined for particular draws in dependence of used single partial
reductions.
Abstract: The increase in electric power demand in face of
environmental issues has intensified the participation of renewable
energy sources such as photovoltaics, in the energy matrix of various
countries. Due to their operational characteristics, they can generate
time-varying harmonic and inter-harmonic distortions. For this
reason, the application of methods of measurement based on
traditional Fourier analysis, as proposed by IEC 61000-4-7, can
provide inaccurate results. Considering the aspects mentioned herein,
came the idea of the development of this work which aims to present
the results of a comparative evaluation between a methodology
arising from the combination of the Prony method with the Kalman
filter and another method based on the IEC 61000-4-30 and IEC
61000-4-7 standards. Employed in this study were synthetic signals
and data acquired through measurements in a 50kWp photovoltaic
installation.
Abstract: A sign pattern is a matrix whose entries belong to the set
{+,−, 0}. An n-by-n sign pattern A is said to allow an eventually
positive matrix if there exist some real matrices A with the same
sign pattern as A and a positive integer k0 such that Ak > 0 for all
k ≥ k0. It is well known that identifying and classifying the n-by-n
sign patterns that allow an eventually positive matrix are posed as two
open problems. In this article, the tree sign patterns of small order
that allow an eventually positive matrix are classified completely.
Abstract: Highly stable and homogeneously dispersed amino
acid coated silver nanoparticles (ANP) of ≈ 10 nm diameter, ranging
from 420 to 430 nm are prepared on AgNO3 solution addition to gum
of Azadirachta indica solution at 373.15 K. The amino acids were
selected based on their polarity. The synthesized nanoparticles were
characterized by UV-Vis, FTIR spectroscopy, HR-TEM, XRD, SEM
and 1H-NMR. The coated nanoparticles were used as catalyst for the
reduction of methylene blue dye in presence of Sn(II) in aqueous,
anionic and cationic micellar media. The rate of reduction of dye was
determined by measuring the absorbance at 660 nm,
spectrophotometrically and followed the order: Kcationic > Kanionic >
Kwater. After 12 min and in absence of the ANP, only 2%, 3% and 6%
of the dye reduction was completed in aqueous, anionic and cationic
micellar media respectively while, in presence of ANP coated by
polar neutral amino acid with non-polar -R group, the reduction
completed to 84%, 95% and 98% respectively. The ANP coated with
polar neutral amino acid having non-polar -R group, increased the
rate of reduction of the dye by 94, 3205 and 6370 folds in aqueous,
anionic and cationic micellar media respectively. Also, the rate of
reduction of the dye increased by three folds when the micellar media
was changed from anionic to cationic when the ANP is coated by a
polar neutral amino acid having a non-polar -R group.
Abstract: Carbon dioxide is one of the major greenhouse gas
(GHG) contributors. It is an obligation of the industry to reduce the
amount of carbon dioxide emission to the acceptable limits.
Tremendous research and studies are reported in the past and still the
quest to find the suitable and economical solution of this problem
needed to be explored in order to develop the most plausible absorber
for carbon dioxide removal. Amino acids can be potential alternate
solvents for carbon dioxide capture from gaseous streams. This is due
to its ability to resist oxidative degradation, low volatility and its
ionic structure. In addition, the introduction of promoter-like
piperazine to amino acid helps to further enhance the solubility. In
this work, the effect of piperazine on thermo physical properties and
solubility of β-Alanine aqueous solutions were studied for various
concentrations. The measured physicochemical properties data was
correlated as a function of temperature using least-squares method
and the correlation parameters are reported together with it respective
standard deviations. The effect of activator piperazine on the CO2
loading performance of selected amino acid under high-pressure
conditions (1bar to 10bar) at temperature range of (30 to 60)oC was
also studied. Solubility of CO2 decreases with increasing temperature
and increases with increasing pressure. Quadratic representation of
solubility using Response Surface Methodology (RSM) shows that
the most important parameter to optimize solubility is system
pressure. The addition of promoter increases the solubility effect of
the solvent.
Abstract: Dengue is a mosquito-borne viral disease endemic in
many countries in the tropics and sub-tropics. The state of Punjab in
India shows cyclical and seasonal variation in dengue cases. The
Case Fatality Rate of Dengue has ranged from 0.6 to 1.0 in the past
years. The department has initiated review of the cases that have died
due to dengue in order to know the exact cause of the death in a case
of dengue. The study has been undertaken to know the other
associated co-morbidities and factors causing death in a case of
dengue. The study used the predesigned proforma on which the
records (medical and Lab) were recorded and reviewed by the expert
committee of the doctors. This study has revealed that cases of
dengue having co-morbidities have longer stay in hospital. Fluid
overload and co-morbidities have been found as major factors leading
to death, however, in a confirmed case of dengue hepatorenal
shutdown was found to be major cause of mortality. The data
obtained will help in sensitizing the treating physicians in order to
decrease the mortality due to dengue in future.
Abstract: This paper presents the effect of the orbit inclination
on the pointing error of the satellite antenna and consequently on its
footprint on earth for a typical Ku- band payload system. The performance assessment is examined using both analytical
simulations and practical measurements, taking into account all the
additional sources of the pointing errors, such as East-West station
keeping, orbit eccentricity, and actual attitude control performance. An implementation and computation of the sinusoidal biases in
satellite roll and pitch used to compensate the pointing error of the
satellite antenna coverage is studied and evaluated before and after
the pointing corrections performed. A method for evaluation of the performance of the implemented
biases has been introduced through measuring satellite received level
from a mono-pulse tracking 11.1m transmitting antenna before and
after the implementation of the pointing corrections.
Abstract: A myriad of environmental issues face the Nigerian
industrial region, resulting from; oil and gas production, mining,
manufacturing and domestic wastes. Amidst these, much effort has
been directed by stakeholders in the Nigerian oil producing regions,
because of the impacts of the region on the wider Nigerian economy.
Although collaborative environmental management has been noted as
an effective approach in managing environmental issues, little
attention has been given to the roles and practices of stakeholders in
effecting a collaborative environmental management framework for
the Nigerian oil-producing region. This paper produces a framework
to expand and deepen knowledge relating to stakeholders aspects of
collaborative roles in managing environmental issues in the Nigeria
oil-producing region. The knowledge is derived from analysis of
stakeholders’ practices – studied through multiple case studies using
document analysis. Selected documents of key stakeholders –
Nigerian government agencies, multi-national oil companies and host
communities, were analyzed. Open and selective coding was
employed manually during document analysis of data collected from
the offices and websites of the stakeholders. The findings showed
that the stakeholders have a range of roles, practices, interests, drivers
and barriers regarding their collaborative roles in managing
environmental issues. While they have interests for efficient resource
use, compliance to standards, sharing of responsibilities, generating
of new solutions, and shared objectives; there is evidence of major
barriers and these include resource allocation, disjointed policy,
ineffective monitoring, diverse socio- economic interests, lack of
stakeholders’ commitment and limited knowledge sharing. However,
host communities hold deep concerns over the collaborative roles of
stakeholders for economic interests, particularly, where government
agencies and multi-national oil companies are involved. With these
barriers and concerns, a genuine stakeholders’ collaboration is found
to be limited, and as a result, optimal environmental management
practices and policies have not been successfully implemented in the
Nigeria oil-producing region. A framework is produced that describes
practices that characterize collaborative environmental management
might be employed to satisfy the stakeholders’ interests. The
framework recommends critical factors, based on the findings, which
may guide a collaborative environmental management in the oil
producing regions. The recommendations are designed to re-define
the practices of stakeholders in managing environmental issues in the
oil producing regions, not as something wholly new, but as an
approach essential for implementing a sustainable environmental
policy. This research outcome may clarify areas for future research as
well as to contribute to industry guidance in the area of collaborative
environmental management.
Abstract: The change in orbit evolution between collocated
satellites (X, Y) inside +/-0.09° E/W and +/- 0.07° N/S cluster, after
one of these satellites is placed in an inclined orbit (satellite X) and
the effect of this change in the collocation safety inside the cluster
window has been studied and evaluated. Several collocation scenarios had been studied in order to adjust
the location of both satellites inside their cluster to maximize the
separation between them and safe the mission.