Abstract: Economic Load Dispatch (ELD) proves to be a vital optimization process in electric power system for allocating generation amongst various units to compute the cost of generation, the cost of emission involving global warming gases like sulphur dioxide, nitrous oxide and carbon monoxide etc. In this dissertation, we emphasize ramp rate constriction factor based particle swarm optimization (RRCPSO) for analyzing various performance objectives, namely cost of generation, cost of emission, and a dual objective function involving both these objectives through the experimental simulated results. A 6-unit 30 bus IEEE test case system has been utilized for simulating the results involving improved weight factor advanced ramp rate limit constraints for optimizing total cost of generation and emission. This method increases the tendency of particles to venture into the solution space to ameliorate their convergence rates. Earlier works through dispersed PSO (DPSO) and constriction factor based PSO (CPSO) give rise to comparatively higher computational time and less good optimal solution at par with current dissertation. This paper deals with ramp rate and constriction factor based well defined ramp rate PSO to compute various objectives namely cost, emission and total objective etc. and compares the result with DPSO and weight improved PSO (WIPSO) techniques illustrating lesser computational time and better optimal solution.
Abstract: In this study, the precipitation conditions of Chevreul’s salt were evaluated. The structure of Chevreul’s salt was examined by considering the previous studies. Thermodynamically, the most important precipitation parameters were pH, temperature, and sulphite-copper(II) ratio. The amount of Chevreul’s salt increased with increasing the temperature and sulphite-copper(II) ratio at the certain range, while it increased with decreasing the pH value at the chosen range. The best solution medium for recovery of Chevreul’s salt is sulphur dioxide gas-water system. Moreover, the soluble sulphite salts are used as efficient precipitating reagents. Chevreul’s salt is generally used to produce the highly pure copper powders from synthetic copper sulphate solutions and impure leach solutions. When the pH of the initial ammoniacal solution is greater than 8.5, ammonia in the medium is not free, and Chevreul’s salt from solution does not precipitate. In contrast, copper ammonium sulphide is precipitated. The pH of the initial solution containing ammonia for precipitating of Chevreul’s salt must be less than 8.5.
Abstract: Monitoring is essential to assessing the effectiveness of air pollution control actions. The goal of the air quality information system is through monitoring, to keep authorities, major polluters and the public informed on the short and long-term changes in air quality, thereby helping to raise awareness. Mathematical models are the best tools available for the prediction of the air quality management. The main objective of the work was to apply a Model that predicts the concentration levels of different pollutants at any instant of time. In this study, distribution of air pollutants concentration such as nitrogen dioxides (NO2), sulphur dioxides (SO2) and total suspended particulates (TSP) of industries are determined by using Gaussian model. Besides that, the effect of wind speed and its direction on the pollutant concentration within the affected area were evaluated. In order to determine the efficiency and percentage of error in the modeling, validation process of data was done. Sampling of air quality was conducted in getting existing air quality around a factory and the concentrations of pollutants in a plume were inversely proportional to wind velocity. The resultant ground level concentrations were then compared to the quality standards to determine if there could be a negative impact on health. This study concludes that concentration of pollutants can be significantly predicted using Gaussian Model. The data base management is developed for the air data of Hubli-Dharwad region.
Abstract: The proof of concept experiments were conducted to
determine the feasibility of using small amounts of Dissolved
Sulphur (DS) from the gaseous phase to precipitate platinum ions in
chloride media. Two sets of precipitation experiments were
performed in which the source of sulphur atoms was either a
thiosulphate solution (Na2S2O3) or a sulphur dioxide gas (SO2). In
liquid-liquid (L-L) system, complete precipitation of Pt was achieved
at small dosages of Na2S2O3 (0.01 – 1.0 M) in a time interval of 3-5
minutes. On the basis of this result, gas absorption tests were carried
out mainly to achieve sulphur solubility equivalent to 0.018 M. The
idea that huge amounts of precious metals could be recovered
selectively from their dilute solutions by utilizing the waste SO2
streams at low pressure seemed attractive from the economic and
environmental point of views. Therefore, mass transfer characteristics
of SO2 gas associated with reactive absorption across the gas-liquid
(G-L) interface were evaluated under different conditions of pressure
(0.5 – 2 bar), solution temperature ranges from 20 – 50 oC and acid
strength (1 – 4 M, HCl). This paper concludes with information about
selective precipitation of Pt in the presence of cations (Fe2+, Co2+,
and Cr3+) in a CSTR and recommendation to scale up laboratory data
to industrial pilot scale operations.
Abstract: The main purpose of this research is the calculation of implicit prices of the environmental level of air quality in the city of Moscow on the basis of housing property prices. The database used contains records of approximately 20 thousand apartments and has been provided by a leading real estate agency operating in Russia. The explanatory variables include physical characteristics of the houses, environmental (industry emissions), neighbourhood sociodemographic and geographic data: GPS coordinates of each house. The hedonic regression results for ecological variables show «negative» prices while increasing the level of air contamination from such substances as carbon monoxide, nitrogen dioxide, sulphur dioxide, and particles (CO, NO2, SO2, TSP). The marginal willingness to pay for higher environmental quality is presented for linear and log-log models.
Abstract: Acid rain occurs when sulphur dioxide (SO2) and
nitrogen oxides (Nox) gases react in the atmosphere with water,
oxygen, and other chemicals to form various acidic compounds. The
result is a mild solution of sulfuric acid and nitric acid. Soil has a
greater buffering capacity than aquatic systems. However excessive
amount of acids introduced by acid rains may disturb the entire soil
chemistry. Acidity and harmful action of toxic elements damage
vegetation while susceptible microbial species are eliminated. In
present study, the effects of simulated sulphuric acid and nitric acid
rains were investigated on crop Glycine max. The effect of acid rain
on change in soil fertility was detected in which pH of control sample
was 6.5 and pH of 1%H2SO4 and 1%HNO3 were 3.5. Nitrogen nitrate
in soil was high in 1% HNO3 treated soil & Control sample.
Ammonium nitrogen in soil was low in 1% HNO3 & H2SO4 treated
soil. Ammonium nitrogen was medium in control and other samples.
The effect of acid rain on seed germination on 3rd day of germination
control sample growth was 7 cm, 0.1% HNO3 was 8cm, and 0.001%
HNO3 & 0.001% H2SO4 was 6cm each. On 10th day fungal growth
was observed in 1% and 0.1%H2SO4 concentrations, when all plants
were dead. The effect of acid rain on crop productivity was
investigated on 3rd day roots were developed in plants. On12th day
Glycine max showed more growth in 0.1% HNO3, 0.001% HNO3 and
0.001% H2SO4 treated plants growth were same as compare to control
plants. On 20th day development of discoloration of plant pigments
were observed on acid treated plants leaves. On 38th day, 0.1, 0.001%
HNO3 and 0.1, 0.001% H2SO4 treated plants and control plants were
showing flower growth. On 42th day, acid treated Glycine max variety
and control plants were showed seeds on plants. In Glycine max
variety 0.1, 0.001% H2SO4, 0.1, 0.001% HNO3 treated plants were
dead on 46th day and fungal growth was observed. The toxicological
study was carried out on Glycine max plants exposed to 1% HNO3
cells were damaged more than 1% H2SO4. Leaf sections exposed to
0.001% HNO3 & H2SO4 showed less damaged of cells and
pigmentation observed in entire slide when compare with control
plant. The soil analysis was done to find microorganisms in HNO3 &
H2SO4 treated Glycine max and control plants. No microorganism
growth was observed in 1% HNO3 & H2SO4 but control plant showed
microbial growth.
Abstract: The Bangalore City is facing the acute problem of
pollution in the atmosphere due to the heavy increase in the traffic
and developmental activities in recent years. The present study is an
attempt in the direction to assess trend of the ambient air quality
status of three stations, viz., AMCO Batteries Factory, Mysore Road,
GRAPHITE INDIA FACTORY, KHB Industrial Area, Whitefield
and Ananda Rao Circle, Gandhinagar with respect to some of the
major criteria pollutants such as Total Suspended particular matter
(SPM), Oxides of nitrogen (NOx), and Oxides of sulphur (SO2). The
sites are representative of various kinds of growths viz., commercial,
residential and industrial, prevailing in Bangalore, which are
contributing to air pollution. The concentration of Sulphur Dioxide
(SO2) at all locations showed a falling trend due to use of refined
petrol and diesel in the recent years. The concentration of Oxides of
nitrogen (NOx) showed an increasing trend but was within the
permissible limits. The concentration of the Suspended particular
matter (SPM) showed the mixed trend. The correlation between
model and observed values is found to vary from 0.4 to 0.7 for SO2,
0.45 to 0.65 for NOx and 0.4 to 0.6 for SPM. About 80% of data is
observed to fall within the error band of ±50%. Forecast test for the
best fit models showed the same trend as actual values in most of the
cases. However, the deviation observed in few cases could be
attributed to change in quality of petro products, increase in the
volume of traffic, introduction of LPG as fuel in many types of
automobiles, poor condition of roads, prevailing meteorological
conditions, etc.
Abstract: Sulphur dioxide is a harmful gaseous product that
needs to be minimized in the atmosphere. This research work
investigates the use of zeolite as a possible additive that can improve
the sulphur dioxide capture in wet flue gas desulphurisation
dissolution process. This work determines the effect of temperature,
solid to liquid ratio, acid concentration and stirring speed on the
leaching of zeolite using a pH stat apparatus. The atomic absorption
spectrometer was used to measure the calcium ions from the solution.
It was found that the dissolution rate of zeolite decreased with
increase in solid to liquid ratio and increases with increase in
temperature, stirring speed and acid concentration. The activation
energy for the dissolution rate of zeolite in hydrochloric acid was
found to be 9.29kJ/mol. and therefore the product layer diffusion was
the rate limiting step.
Abstract: This work deals with modeling and simulation of SO2 removal in a ceramic membrane by means of FEM. A mass transfer model was developed to predict the performance of SO2 absorption in a chemical solvent. The model was based on solving conservation equations for gas component in the membrane. Computational fluid dynamics (CFD) of mass and momentum were used to solve the model equations. The simulations aimed to obtain the distribution of gas concentration in the absorption process. The effect of the operating parameters on the efficiency of the ceramic membrane was evaluated. The modeling findings showed that the gas phase velocity has significant effect on the removal of gas whereas the liquid phase does not affect the SO2 removal significantly. It is also indicated that the main mass transfer resistance is placed in the membrane and gas phase because of high tortuosity of the ceramic membrane.