Abstract: This paper is an attempt to describe some of the results that had been found through a journey of study in the field of particle physics. This study consists of two parts, one about the measurement of the cross section of the decay of the Z particle in two electrons, and the other deals with the measurement of the cross section of the multi-photon absorption process using a beam of Laser in the Liquid Argon Time Projection Chamber.
The first part of the paper concerns the results based on the analysis of a data sample containing 8120 ee candidates to reconstruct the mass of the Z particle for each event where each event has an ee pair with PT(e) > 20GeV, and η(e) < 2.5. Monte Carlo templates of the reconstructed Z particle were produced as a function of the Z mass scale. The distribution of the reconstructed Z mass in the data was compared to the Monte Carlo templates, where the total cross section is calculated to be equal to 1432pb.
The second part concerns the Liquid Argon Time Projection Chamber, LAr TPC, the results of the interaction of the UV Laser, Nd-YAG with λ= 266mm, with LAr and through the study of the multi-photon ionization process as a part of the R&D at Bern University. The main result of this study was the cross section of the process of the multi-photon ionization process of the LAr, σe = 1.24±0.10stat±0.30sys.10 -56cm4.
Abstract: Nowadays, with the increasing of the wafer's size and
the decreasing of critical size of integrated circuit manufacturing in
modern high-tech, microelectronics industry needs a maximum
attention to challenge the contamination control. The move to 300
[mm] is accompanied by the use of Front Opening Unified Pods for
wafer and his storage. In these pods an airborne cross contamination
may occur between wafers and the pods. A predictive approach using
modeling and computational methods is very powerful method to
understand and qualify the AMCs cross contamination processes.
This work investigates the required numerical tools which are
employed in order to study the AMCs cross-contamination transfer
phenomena between wafers and FOUPs. Numerical optimization and
finite element formulation in transient analysis were established.
Analytical solution of one dimensional problem was developed and
the calibration process of physical constants was performed. The least
square distance between the model (analytical 1D solution) and the
experimental data are minimized. The behavior of the AMCs
intransient analysis was determined. The model framework preserves
the classical forms of the diffusion and convection-diffusion
equations and yields to consistent form of the Fick's law. The
adsorption process and the surface roughness effect were also
traduced as a boundary condition using the switch condition Dirichlet
to Neumann and the interface condition. The methodology is applied,
first using the optimization methods with analytical solution to define
physical constants, and second using finite element method including
adsorption kinetic and the switch of Dirichlet to Neumann condition.
Abstract: Alginite has been evaluated as an efficient pollution control material. In this paper, alginite from maar Pinciná (SR) for removal of Cd2+ ions from aqueous solution was studied. The potential sorbent was characterized by X-ray fluorescence analysis (RFA) analysis, Fourier transform infrared spectral analysis (FT-IR) and specific surface area (SSA) was also determined. The sorption process was optimized from the point of initial cadmium concentration effect and effect of pH value. The Freundlich and Langmuir models were used to interpret the sorption behavior of Cd2+ ions, and the results showed that experimental data were well fitted by the Langmuir equation. Alginite maximal sorption capacity (Qmax) for Cd2+ ions calculated from Langmuir isotherm was 34 mg/g. Sorption process was significantly affected by initial pH value in the range from 4.0-7.0. Alginite is a comparable sorbent with other materials for toxic metals removal.
Abstract: In this study, a new reliable technique use to handle the foam drainage equation. This new method is resulted from VIM by a simple modification that is Reconstruction of Variational Iteration Method (RVIM). The drainage of liquid foams involves the interplay of gravity, surface tension, and viscous forces. Foaming occurs in many distillation and absorption processes. Results are compared with those of Adomian’s decomposition method (ADM).The comparisons show that the Reconstruction of Variational Iteration Method is very effective and overcome the difficulty of traditional methods and quite accurate to systems of non-linear partial differential equations.
Abstract: This article is presented an experimental and modeling
study of a four-bed pressure swing adsorption process using
zeolite13X to provide oxygen-enriched air. The binary mixture N2/O2
(79/21 vol %) was used as a feed stream. The effects of purge/feed
ratio (P/F), adsorption pressure, cyclic time and product flow rate on
product purity and recovery under nonisothermal condition were
studied. The adsorption dynamics of process were determined using
a mathematical model incorporated mass and energy balances. A
Mathlab code using finite difference method was developed to solve
the set of coupled differential-algebraic equations, and the simulation
results are agreed well with experimental results.
Abstract: The persistent nature of perfluorochemicals (PFCs) has attracted global concern in recent years. Perfluorooctanesulfonate (PFOS) and perfluorooctanoate (PFOA) are the most commonly found PFC compounds, and thus their fate and transport play key roles in PFC distribution in the natural environment. The kinetic behavior of PFOS or PFOA on boehmite consists of a fast adsorption process followed by a slow adsorption process which may be attributed to the slow transport of PFOS or PFOA into the boehmite pore surface. The adsorption isotherms estimated the maximum adsorption capacities of PFOS and PFOA on boehmite as 0.877 μg/m2 and 0.633 μg/m2, with the difference primarily due to their different functional groups. The increase of solution pH led to a moderate decrease of PFOS and PFOA adsorption, owing to the increase of ligand exchange reactions and the decrease of electrostatic interactions. The presence of NaCl in solution demonstrated negative effects for PFOS and PFOA adsorption on boehmite surfaces, with potential mechanisms being electrical double layer compression, competitive adsorption of chloride.
Abstract: In recent years, there have been attempts to store
natural gas in adsorptive form. This is called adsorptive natural gas,
or ANG. The problem with this technology is the low sorption
capacity. The purpose is to achieve compressed natural gas (CNG)
capacity of 230 V/V. Further research is required to achieve such
target. Several research studies have been performed with this target;
through either the modification or development of new sorbents or
the optimization of the operation sorption process itself. In this work,
storage of methane on molecular sieves 5A and 13X was studied on
dry basis, and on wet basis to certain extent. The temperature and the
pressure dynamics were investigated. The results indicated that
regardless of the charge pressure, the time for the peak temperature
during the methane charge process is always the same. This can be
used as a characteristic of the adsorbent. The total achieved
deliveries using molecular sieves were much lower than that of
activated carbons; 53.0 V/V for the case of 13X molecular sieves and
43 V/V for the case of 5A molecular sieves, both at 2oC and 4 MPa
(580 psi). Investigation of charge pressure dynamic using wet
molecular sieves at 2oC and a mass ratio of 0.5, revealed slowness of
the process and unexpected behavior.
Abstract: Activated carbon was prepared from agricultural waste “almond (Prunus amygdalus) nut shells" by chemical activation with phosphoric acid as an activating agent at 450 °C for 24 hr soaking time. The physical and chemical properties were analyzed. The adsorption of chromium VI from aqueous solution on almond nut shell activated carbon (ASAC) was investigated. The adsorption process parameters pH, agitation speed, agitation time, adsorbent dose were optimized. 98% of Cr VI was sorbed at pH 2 and stirring speed 200 rpm.. Surface structure showed that ASAC has a spongy type structure showing large number of pores
Abstract: In situ observation of absorption spectral change of
heptil viologen cation radical (HV+.) was performed by slab optical
waveguide (SOWG) spectroscopy utilizing indium-tin-oxide (ITO)
electrodes. Synchronizing with electrochemical techniques, we
observed the adsorption process of HV+.on the ITO electrode. In this
study, we carried out the ITO-SOWG observations using KBr aqueous
solution containing different concentration of HV to investigate the
concentration dependent spectral change. A few specific absorption
bands, which indicated HV+.existed as both monomer and dimer on
ITO electrode surface with a monolayer or a few layers deposition,
were observed in UV-visible region. The change in the peak position
of the absorption spectra from adsorption species of HV+. were
correlated with the concentration of HV as well as the electrode
potential.
Abstract: Heavy metals have bad effects on environment and
soils and it can uptake by natural HAP .natural Hap is an inexpensive
material that uptake large amounts of various heavy metals like Zn
(II) .Natural HAP (N-HAP), extracted from bovine cortical bone ash,
is a good choice for substitution of commercial HAP. Several
experiments were done to investigate the sorption capacity of Zn (II)
to N-HAP in various particles sizes, temperatures, initial
concentrations, pH and reaction times. In this study, the sorption of
Zinc ions from a Zn solution onto HAP particles with sizes of 1537.6
nm and 47.6 nm at three initial pH values of 4.50, 6.00 and 7.50 was
studied. The results showed that better performance was obtained
through a 47.6 nm particle size and higher pH values. The
experimental data were analyzed using Langmuir, Freundlich, and
Arrhenius equations for equilibrium, kinetic and thermodynamic
studies. The analysis showed a maximum adsorption capacity of NHAP
as being 1.562 mmol/g at a pH of 7.5 and small particle size.
Kinetically, the prepared N-HAP is a feasible sorbent that retains Zn
(II) ions through a favorable and spontaneous sorption process.
Abstract: Fuller’s earth is a fine-grained, naturally occurring substance that has a substantial ability to adsorb impurities. In the present study Fuller’s earth has been characterized and used for the removal of Pb(II) from aqueous solution. The effect of various physicochemical parameters such as pH, adsorbent dosage and shaking time on adsorption were studied. The result of the equilibrium studies showed that the solution pH was the key factor affecting the adsorption. The optimum pH for adsorption was 5. Kinetics data for the adsorption of Pb(II) was best described by pseudo-second order model. The effective diffusion co-efficient for Pb(II) adsorption was of the order of 10-8 m2/s. The adsorption data for metal adsorption can be well described by Langmuir adsorption isotherm. The maximum uptake of metal was 103.3 mg/g of adsorbent. Mass transfer analysis was also carried out for the adsorption process. The values of mass transfer coefficients obtained from the study indicate that the velocity of the adsorbate transport from bulk to the solid phase was quite fast. The mean sorption energy calculated from Dubinin-Radushkevich isotherm indicated that the metal adsorption process was chemical in nature.
Abstract: Carbon dioxide is one of the major green house gases.
It is removed from different streams using amine absorption process.
Sterically hindered amines are suggested as good CO2 absorbers.
Solubility of carbon dioxide (CO2) was measured in aqueous
solutions of 2-Amino-2-methyl-1-propanol (AMP) at temperatures 30
oC, 40 oC and 60 oC. The effect of pressure and temperature was
studied over various concentrations of AMP. It has been found that
pressure has positive effect on CO2 solubility where as solubility
decreased with increasing temperature. Absorption performance of
AMP increased with increasing pressure. Solubility of aqueous AMP
was compared with mo-ethanolamine (MEA) and the absorption
capacity of aqueous solutions of AMP was found to be better.
Abstract: CTMA-bentonite and BTEA-Bentonite prepared by Na-bentonite cation exchanged with cetyltrimethylammonium(CTMA) and benzyltriethylammonium (BTEA). Products were characterized by XRD and IR techniques.The d001 spacing value of CTMA-bentonite and BTEA-bentonite are 7.54Å and 3.50Å larger than that of Na-bentonite at 100% cation exchange capacity, respectively. The IR spectrum showed that the intensities of OH stretching and bending vibrations of the two organoclays decreased greatly comparing to untreated Na-bentonite. Batch experiments were carried out at 303 K, 318 K and 333 K to obtain the sorption isotherms of Crystal violet onto the two organoclays. The results show that the sorption isothermal data could be well described by Freundlich model. The dynamical data for the two organoclays fit well with pseudo-second-order kinetic model. The adsorption capacity of CTMA-bentonite was found higher than that of BTEA-Bentonite. Thermodynamic parameters such as changes in the free energy (ΔG°), the enthalpy (ΔH°) and the entropy (ΔS°) were also evaluated. The overall adsorption process of Crystal violet onto the two organoclays were spontaneous, endothermic physisorption. The CTMA-bentonite and BTEA-Bentonite could be employed as low-cost alternatives to activated carbon in wastewater treatment for the removal of color which comes from textile dyes.
Abstract: Waste lubricating oil re-refining adsorption process by
different adsorbent materials was investigated. Adsorbent materials
such as oil adsorbent, egg shale powder, date palm kernel powder,
and acid activated date palm kernel powder were used. The
adsorption process over fixed amount of adsorbent at ambient
conditions was investigated. The adsorption/extraction process was
able to deposit the asphaltenic and metallic contaminants from the
waste oil to lower values. It was found that the date palm kernel
powder with contact time of 4 h was able to give the best conditions
for treating the waste oil. The recovered solvent could be also reused.
It was also found that the activated bentonite gave the best
physical properties followed by the date palm kernel powder.
Abstract: The present study based on removal of natural dyes of
Roselle petals, then used Roselle petals powder (RPP) as an
adsorbent for the removal of methylene blue dye (as a typical cationic
or basic dye) from aqueous solutions. The present study shows that
used Roselle petals powder exhibit adsorption trend for the dye. The
adsorption processes were carried out at various conditions of
temperatures ranging from 278 to 338 K ± 2 K , concentrations,
processing time and a wide range of pH between 2.5-11. Adsorption
isotherm equations such as Freundlich, and Langmuir were applied to
calculate the values of respective constants. Adsorption study was
found that the currently introduced adsorbent can be used to remove
cationic dyes such as methylene blue from aqueous solutions.
Abstract: From environmental aspect purification of ammonia
containing wastewater is expected. High efficiency ammonia
desorption can be done from the water by air on proper temperature.
After the desorption process, ammonia can be recovered and used in
another technology. The calculation method described below give
some methods to find either the minimum column height or ammonia
rich solution of the effluent.
Abstract: Chicken feathers were used as biosorbent for Pb
removal from aqueous solution. In this paper, the kinetics and
equilibrium studies at several pH, temperature, and metal
concentration values are reported. For tested conditions, the Pb
sorption capacity of this poultry waste ranged from 0.8 to 8.3 mg/g.
Optimal conditions for Pb removal by chicken feathers have been
identified. Pseudo-first order and pseudo-second order equations
were used to analyze the experimental data. In addition, the sorption
isotherms were fitted to classical Langmuir and Freundlich models.
Finally, thermodynamic parameters for the sorption process have
been determined. In summary, the results showed that chicken
feathers are an alternative and promising sorbent for the treatment of
effluents polluted by Pb ions.
Abstract: The adsorption properties of CO and H2 on iron-based
catalyst with addition of Zr and Ni were investigated using
temperature programmed desorption process. It was found that on the
carburized iron-based catalysts, molecular state and dissociative state
CO existed together. The addition of Zr was preferential for the
molecular state adsorption of CO on iron-based catalyst and the
presence of Ni was beneficial to the dissociative adsorption of CO. On
H2 reduced catalysts, hydrogen mainly adsorbs on the surface iron
sites and surface oxide sites. On CO reduced catalysts, hydrogen
probably existed as the most stable CH and OH species. The addition
of Zr was not benefit to the dissociative adsorption of hydrogen on
iron-based catalyst and the presence of Ni was preferential for the
dissociative adsorption of hydrogen.
Abstract: The present paper reports the removal of Cd(II) and
Zn(II) ions using synthetic Zeolit NaA. The adsorption capacity of
the sorbent (Zeolite NaA) strongly depends on simultaneous or not
simultaneous (concurrent) presence of Cd(II) and Zn(II) in the
sorbate. When Cd(II) and Zn(II) are present simultaneously
(concurrently) in the sorbate, Zn(II) ions were sorbed at higher rate.
Equilibrium data fitted Langmuir, Freundlich and Tempkin isotherms
well. The applicability of the isotherm equation to describe the
adsorption process was judged by the correlation coefficients R2. The
Langmuir model yielded the best fit with R2 values equal to or higher
than 0.970, as compared to the Freundlich and Tempkin models. The
fact that 1/n values range from 0.322 to 0.755 indicates that the
adsorption of Cd(II) and Zn(II) ions from aqueous solutions also
favored by the Freundlich model.
Abstract: In this study the adsorption of Cu (II) ions from aqueous solutions on synthetic zeolite NaA was evaluated. The effect of solution temperature and the determination of the kinetic parameters of adsorption of Cu(II) from aqueous solution on zeolite NaA is important in understanding the adsorption mechanism. Variables of the system include adsorption time, temperature (293- 328K), initial solution concentration and pH for the system. The sorption kinetics of the copper ions were found to be strongly dependent on pH (the optimum pH 3-5), solute ion concentration and temperature (293 – 328 K). It was found, the pseudo-second-order model was the best choice among all the kinetic models to describe the adsorption behavior of Cu(II) onto ziolite NaA, suggesting that the adsorption mechanism might be a chemisorptions process The activation energy of adsorption (Ea) was determined as Cu(II) 13.5 kJ mol-1. The low value of Ea shows that Cu(II) adsorption process by zeolite NaA may be an activated chemical adsorption. The thermodynamic parameters (ΔG0, ΔH0, and ΔS0) were also determined from the temperature dependence. The results show that the process of adsorption Cu(II) is spontaneous and endothermic process and rise in temperature favors the adsorption.