Abstract: Hydrogen produced by means of polymer electrolyte
membrane electrolyzer (PEME) is one of the most promising
methods due to clean and renewable energy source. In the process,
some energy loss due to mass transfer through a PEM is caused by
diffusion, electro-osmotic drag, and the pressure difference between
the cathode channel and anode channel. In PEME, water molecules
and ionic particles transferred between the electrodes from anode to
cathode, Extensive mixing of the hydrogen and oxygen at anode
channel due to gases cross-over must be avoided. In recent times the
consciousness of safety issue in high pressure PEME where the
oxygen mix with hydrogen at anode channel could create, explosive
conditions have generated a lot of concern. In this paper, the steady
state and simulation analysis of gases crossover in PEME on the
temperature and pressure effect are presented. The simulations have
been analysis in MATLAB based on the well-known Fick’s Law of
molecular diffusion. The simulation results indicated that as
temperature increases, there is a significant decrease in operating
voltage.
Abstract: Nowadays, with the increasing of the wafer's size and
the decreasing of critical size of integrated circuit manufacturing in
modern high-tech, microelectronics industry needs a maximum
attention to challenge the contamination control. The move to 300
[mm] is accompanied by the use of Front Opening Unified Pods for
wafer and his storage. In these pods an airborne cross contamination
may occur between wafers and the pods. A predictive approach using
modeling and computational methods is very powerful method to
understand and qualify the AMCs cross contamination processes.
This work investigates the required numerical tools which are
employed in order to study the AMCs cross-contamination transfer
phenomena between wafers and FOUPs. Numerical optimization and
finite element formulation in transient analysis were established.
Analytical solution of one dimensional problem was developed and
the calibration process of physical constants was performed. The least
square distance between the model (analytical 1D solution) and the
experimental data are minimized. The behavior of the AMCs
intransient analysis was determined. The model framework preserves
the classical forms of the diffusion and convection-diffusion
equations and yields to consistent form of the Fick's law. The
adsorption process and the surface roughness effect were also
traduced as a boundary condition using the switch condition Dirichlet
to Neumann and the interface condition. The methodology is applied,
first using the optimization methods with analytical solution to define
physical constants, and second using finite element method including
adsorption kinetic and the switch of Dirichlet to Neumann condition.