Abstract: Surface sediment samples were collected from the
Canon River mouth, Taiwan and analyzed for polycyclic aromatic
hydrocarbons (PAHs). Total PAHs concentrations varied from 337 to
1,252 ng/g dry weight, with a mean concentration of 827 ng/g dry
weight. The spatial distribution of PAHs reveals that the PAHs
concentration is relatively high in the river mouth region, and
gradually diminishes toward the harbor region. Diagnostic ratios
showed that the possible source of PAHs in the Canon River mouth
could be petroleum combustion. The toxic equivalent concentrations
(TEQcarc) of PAHs varied from 47 to 112 ng TEQ/g dry weight. Higher
total TEQcarc values were found in the river mouth region. As
compared with the US Sediment Quality Guidelines (SQGs), the
observed levels of PAHs at Canon River mouth were lower than the
effects range low (ERL), and would probably not exert adverse
biological effects.
Abstract: Twenty seven tektites from the Wenchang area, Hainan
province (south China) and five tektites from the Khon Kaen area
(northeast Thailand) were analyzed for major and trace element
contents and Rb-Sr isotopic compositions. All the samples studied are
splash-form tektites. Tektites of this study are characterized by high
SiO2 contents ranging from 71.95 to 74.07 wt% which is consistent
with previously published analyses of Australasian tektites. The trace
element ratios Ba/Rb (avg. 3.89), Th/Sm (avg. 2.40), Sm/Sc (avg.
0.45), Th/Sc (avg. 0.99) and the rare earth elements (REE) contents of
tektites of this study are similar to the average upper continental crust.
Based on the chemical composition, it is suggested that tektites in this
study are derived from similar parental material and are similar to the
post-Archean upper crustal rocks. The major and trace element
abundances of tektites analyzed indicate that the parental material of
tektites may be a terrestrial sedimentary deposit. The tektites from the
Wenchang area, Hainan Island have high positive εSr(0)
values-ranging from 184.5~196.5 which indicate that the parental
material for these tektites have similar Sr isotopic compositions to old
terrestrial sedimentary rocks and they were not dominantly derived
from recent young sediments (such as soil or loess). Based on Rb-Sr
isotopic data, it has been suggested by Blum (1992) [1]that the
depositional age of sedimentary target materials is close to 170Ma
(Jurassic). According to the model suggested by Ho and Chen
(1996)[2], mixing calculations for various amounts and combinations
of target rocks have been carried out. We consider that the best fit for
tektites from the Wenchang area is a mixture of 47% shale, 23%
sandstone, 25% greywacke and 5% quartzite, and the other tektites
from Khon Kaen area is a mixture of 46% shale, 2% sandstone, 20%
greywacke and 32% quartzite.
Abstract: We measured the major and trace element contents
and Rb-Sr isotopic compositions of 12 tektites from the Maoming
area, Guandong province (south China). All the samples studied are
splash-form tektites which show pitted or grooved surfaces with
schlieren structures on some surfaces. The trace element ratios Ba/Rb
(avg. 4.33), Th/Sm (avg. 2.31), Sm/Sc (avg. 0.44), Th/Sc (avg. 1.01) ,
La/Sc (avg. 2.86), Th/U (avg. 7.47), Zr/Hf (avg. 46.01) and the rare
earth elements (REE) contents of tektites of this study are similar to the
average upper continental crust. From the chemical composition, it is
suggested that tektites in this study are derived from similar parental
terrestrial sedimentary deposit which may be related to post-Archean
upper crustal rocks. The tektites from the Maoming area have high
positive εSr(0) values-ranging from 176.9~190.5 which indicate that
the parental material for these tektites have similar Sr isotopic
compositions to old terrestrial sedimentary rocks and they were not
dominantly derived from recent young sediments (such as soil or
loess). The Sr isotopic data obtained by the present study support the
conclusion proposed by Blum et al. (1992)[1] that the depositional age
of sedimentary target materials is close to 170Ma (Jurassic). Mixing
calculations based on the model proposed by Ho and Chen (1996)[2]
for various amounts and combinations of target rocks indicate that the
best fit for tektites from the Maoming area is a mixture of 40% shale,
30% greywacke, 30% quartzite.
Abstract: Simulation of the flow and sedimentation process in
the reservoir dams can be made by two methods of physical and mathematical modeling. The study area was within a region which
ranged from the Jelogir hydrometric station to the Karkheh reservoir
dam aimed at investigating the effects of stream tubes on the
GSTARS-3 model behavior. The methodologies was to run the model based on 5 stream tubes in order to observe the influence of
each scenario on longitudinal profiles, cross-section, flow velocity and bed load sediment size. Results further suggest that the use of
two stream tubes or more which result in the semi-two-dimensional
model will yield relatively closer results to the observational data
than a singular stream tube modeling. Moreover, the results of
modeling with three stream tubes shown to yield a relatively close
results with the observational data. The overall conclusion of the paper is with applying various stream tubes; it would be possible to yield a significant influence on the modeling behavior Vis-a Vis the bed load sediment size.
Abstract: Arsenic in the sediments of the ash lagoons of the coal-fired power plant in Pagbilao, Quezon Province in the Philippines was sequentially extracted to determine its potential for leaching to the groundwater and the adjacent marine environment. Results show that 89% of the As is bound to the quasi-crystalline Fe/Mn oxides and hydroxide matrix in the sediments, whereas, the adsorbed and exchangeable As hosted by the clay minerals, representing those that are easiest to release from the sediment matrix, is below 10% of the acid leachable As. These As in these sediment matrices represent the possible maximum amount of As that can be released and supplied to the groundwater and the adjacent marine environment. Of the 89% reducible As, up to 4% is associated with the easily reducible variety, whereas, the rest is more strongly bonded by the moderately reducible variety. Based on the long-term As content of the lagoon water, the average desorption rate of As is calculated to be very low -- 0.3-0.5% on the average and 0.6% on the maximum. This indicates that As is well-fixed by its sediment matrices in the ash lagoon, attenuating the influx of As into the adjacent groundwater and marine environments.
Abstract: The heavy metal contamination of the technogenous
sediments and soils at the investigated dump-field show irregular
planar distribution. Also the heavy metal content in the surface water,
drainage water and in the groundwater was studied both in the dry as
well as during the rainy periods. The cementation process causes
substitution of iron by copper. Natural installation and development
of plant species was observed at the old mine waste dumps, specific
to the local chemical conditions such as low content of essential
nutrients and high content of heavy metals. The individual parts of
the plant tissues (roots, branches/stems, leaves/needles, flowers/
fruits) are contaminated by heavy metals and tissues are damaged
differently, respectively.
Abstract: The coastal sediments of West Port of Malaysia was monitored from Nov. 2009 to Oct. 2010 to assess spatial distribution of heavy metals As, Cu, Cd, Cr, Hg, Ni, Zn and Pb. Sediment samples were collected from 10 stations in dry and rainy season in West Port. The range concentrations measured (Mg/g dry weight ) were from 23.4 to 98.3 for Zn, 22.3 to 80 for Pb, 7.4 to 27.6 Cu, 0.244 to 3.53 for Cd, 7.2 to 22.2 for Ni, 20.2 to 162 for As, 0.11 to 0.409 for Hg and 11.5 to 61.5 for Cr. The geochemical indexes used in this study were Geoaccumulation (Igeo), Contamination Factor (CF) and Pollution Load Index (PLI); these indexes were used to evaluate the levels of sediment contaminations. The results of these indexes show that, the status of West Port sediment quality are moderately polluted by heavy metals except in arsenic which shows the high level of pollution.
Abstract: Sedimentation formation is a complex hydraulic phenomenon that has emerged as a major operational and maintenance consideration in modern hydraulic engineering in general and river engineering in particular. Sediments accumulation along the river course and their eventual storage in a form of islands affect water intake in the canal systems that are fed by the storage reservoirs. Without proper management, sediment transport can lead to major operational challenges in water distribution system of arid regions like the Dez and Hamidieh command areas. The paper aims to investigate sedimentation in the Western Canal of Dez Diversion Weir using the SHARC model and compare the results with the two intake structures of the Hamidieh dam in Iran using SSIIM model. The objective was to identify the factors which influence the process, check reliability of outcome and provide ways in which to mitigate the implications on operation and maintenance of the structures. Results estimated sand and silt bed loads concentrations to be 193 ppm and 827ppm respectively. This followed ,ore or less similar pattern in Hamidieh where the sediment formation impeded water intake in the canal system. Given the available data on average annual bed loads and average suspended sediment loads of 165ppm and 837ppm in the Dez, there was a significant statistical difference (16%) between the sand grains, whereas no significant difference (1.2%) was find in the silt grain sizes. One explanation for such finding being that along the 6 Km river course there was considerable meandering effects which explains recent shift in the hydraulic behavior along the stream course under investigation. The sand concentration in downstream relative to present state of the canal showed a steep descending curve. Sediment trapping on the other hand indicated a steep ascending curve. These occurred because the diversion weir was not considered in the simulation model. The comparative study showed very close similarities in the results which explains the fact that both software can be used as accurate and reliable analytical tools for simulation of the sedimentation in hydraulic engineering.
Abstract: Scouring around a bridge pier is a complex
phenomenon. More laboratory experiments are required to
understand the scour mechanism. This paper focused on time
development of local scour around piers and piles in semi integral
bridges. Laboratory data collected at Hydraulics Laboratory,
University of Malaya was analyzed for this purpose. Tests were
performed with two different uniform sediment sizes and five ranges
of flow velocities. Fine and coarse sediments were tested in the
flume. Results showed that scour depths for both pier and piles
increased with time up to certain levels and after that they became
almost constant. It had been found that scour depths increased when
discharges increased. Coarser sediment also produced lesser scouring
at the piers and combined piles.
Abstract: The distribution, enrichment, accumulation, and potential ecological risk of copper (Cu) in the surface sediments of northern Kaohsiung Harbor, Taiwan were investigated. Sediment samples from 12 locations of northern Kaohsiung Harbor were collected and characterized for Cu, aluminum, water content, organic matter, total nitrogen, total phosphorous, total grease and grain size. Results showed that the Cu concentrations varied from 6.9–244 mg/kg with an average of 109±66 mg/kg. The spatial distribution of Cu reveals that the Cu concentration is relatively high in the river mouth region, and gradually diminishes toward the harbor entrance region. This indicates that upstream industrial and municipal wastewater discharges along the river bank are major sources of Cu pollution. Results from the enrichment factor and geo-accumulation index analyses imply that the sediments collected from the river mouth can be characterized between moderate and moderately severe degree enrichment and between none to medium and moderate accumulation of Cu, respectively. However, results of potential ecological risk index indicate that the sediment has low ecological potential risk.
Abstract: The authors report a case of swine urolithiasis caused
by improper administration of sulfamonomethoxine and which was
diagnosed by examination of urinary sediments and analyzing the
composition of the uroliths. The chemical composition of urinary
calculi obtained from affected pigs with urolithiasis was further
confimed as sulfamonomethoxine by fourier transform infrared
(FTIR). It is suggested that appearance of typical fanlike or wheat
bunchy crystals in urinary sediments under observation of lightmicroscope
and determination by FTIR for the crystals are helpful in
diagnosing sulfa calculi causced swine urolithiasis.
Abstract: Mining tailings represent a generating source of rich heavy metal material with a potential danger the public health and the environment, since these metals, under certain conditions, can leach and contaminate aqueous systems that serve like supplying potable water sources. The strategy for this work is based on the observation, experimentation and the simulation that can be obtained by binding real answers of the hydrodynamic behavior of metals leached from mining tailings, and the applied mathematics that provides the logical structure to decipher the individual effects of the general physicochemical phenomenon. The case of study presented herein focuses on mining tailings deposits located in Monte San Nicolas, Guanajuato, Mexico, an abandoned mine. This was considered the contamination source that under certain physicochemical conditions can favor the metal leaching, and its transport towards aqueous systems. In addition, the cartography, meteorology, geology and the hydrodynamics and hydrological characteristics of the place, will be helpful in determining the way and the time in which these systems can interact. Preliminary results demonstrated that arsenic presents a great mobility, since this one was identified in several superficial aqueous systems of the micro watershed, as well as in sediments in concentrations that exceed the established maximum limits in the official norms. Also variations in pH and potential oxide-reduction were registered, conditions that favor the presence of different species from this element its solubility and therefore its mobility.
Abstract: In designing river intakes and diversion structures, it is paramount that the sediments entering the intake are minimized or, if possible, completely separated. Due to high water velocity, sediments can significantly damage hydraulic structures especially when mechanical equipment like pumps and turbines are used. This subsequently results in wasting water, electricity and further costs. Therefore, it is prudent to investigate and analyze the performance of lateral intakes affected by sediment control structures. Laboratory experiments, despite their vast potential and benefits, can face certain limitations and challenges. Some of these include: limitations in equipment and facilities, space constraints, equipment errors including lack of adequate precision or mal-operation, and finally, human error. Research has shown that in order to achieve the ultimate goal of intake structure design – which is to design longlasting and proficient structures – the best combination of sediment control structures (such as sill and submerged vanes) along with parameters that increase their performance (such as diversion angle and location) should be determined. Cost, difficulty of execution and environmental impacts should also be included in evaluating the optimal design. This solution can then be applied to similar problems in the future. Subsequently, the model used to arrive at the optimal design requires high level of accuracy and precision in order to avoid improper design and execution of projects. Process of creating and executing the design should be as comprehensive and applicable as possible. Therefore, it is important that influential parameters and vital criteria is fully understood and applied at all stages of choosing the optimal design. In this article, influential parameters on optimal performance of the intake, advantages and disadvantages, and efficiency of a given design are studied. Then, a multi-criterion decision matrix is utilized to choose the optimal model that can be used to determine the proper parameters in constructing the intake.
Abstract: The Yazd-Ardakan basin in Central Iran has two separated aquifers. The shallow unconfined aquifer is supplies 40 Qanats. The deep saturated confined aquifer is the main water storage. Due to over-withdrawal, water table has been decreasing during last 25 years. Recent study shows that the shortage of the aquifer is about 16 meters and land subsidence is 0.5 - 1.2 meters. Long deep cracks are found just above the aquifer and devour the irrigation water and floods. Although the most cracks direction is NW-SE and could be compared to the main direction of YA basin, there is no direct evidence for relation between land subsidence and the huge cracks. Large-scale water pumping has been decreased the water pressure in aquifer. The pressure decline disturbed the balance and increased the pressure of overlying sediments. So porosity decreased and compaction started. Then, sediments compaction developed and made land subsidence and some huge cracks slowly.
Abstract: The pollution of sediments sampled from the North
Port by polycyclic aromatic hydrocarbons (PAHs) was investigated.
Concentrations of PAHs estimated in the port sediments ranged from
199 to 2851.2 μg/kg dw. The highest concentration was found which
is closed to the Berth line, this locations affected by intensive
shipping activities and Land based runoff and they were dominated
by the high molecular weight PAHs (4–6- rings). Source
identification showed that PAHs originated mostly from the
pyrogenic source either from the combustion of fossil fuels, grass,
wood and coal (majority of the samples). Ecological Risk Assessment
on the port sediments presented that slightly adverse ecological
effects to biological community are expected to occur at the vicinity
of the stations 1 and 4. Thus PAHs are not considered as pollutants of
concern in the North Port.
Abstract: Lake Nasser is one of the largest reservoirs in the
world. Over 120 million metric tons of sediments are deposited in its
dead storage zone every year. The main objective of the present work
was to determine the physical and chemical characteristics of Lake
Nasser sediments. The sample had a relatively low surface area of 2.9
m2/g which increased more than 3-fold upon chemical activation. The
main chemical elements of the raw sediments were C, O and Si with
some traces of Al, Fe and Ca. The organic functional groups for the
tested sample included O-H, C=C, C-H and C-O, with indications of
Si-O and other metal-C and/or metal-O bonds normally associated
with clayey materials. Potentiometric titration of the sample in
different ionic strength backgrounds revealed an alkaline material with
very strong positive surface charge at pH values just a little less than
the pH of zero charge which is ~9. Surface interactions of the
sediments with the background electrolyte were significant. An
advanced surface complexation model was able to capture these
effects, employing a single-site approach to represent protolysis
reactions in aqueous solution, and to determine the significant surface
species in the pH range of environmental interest.
Abstract: The distribution, enrichment, and accumulation of zinc
(Zn) in the sediments of Kaohsiung Ocean Disposal Site (KODS),
Taiwan were investigated. Sediment samples from two outer disposal
site stations and nine disposed stations in the KODS were collected per
quarterly in 2009 and characterized for Zn, aluminum, organic matter,
and grain size. Results showed that the mean Zn concentrations varied
from 48 mg/kg to 456 mg/kg. Results from the enrichment factor (EF)
and geo-accumulation index (Igeo) analyses imply that the sediments
collected from the KODS can be characterized between moderate and
moderately severe degree enrichment and between none and none to
medium accumulation of Zn, respectively. However, results of
potential ecological risk index indicate that the sediment has low
ecological potential risk. The EF, Igeo, and Zn concentrations at the
disposed stations were slightly higher than those at outer disposal site.
This indicated that the disposed area centers may be subjected to the
disposal impaction of harbor dredged sediments.
Abstract: The mixing of pollutions and sediments in near shore regions of natural water bodies depends heavily on the characteristics such as the strength and frequency of flow instability. In the present paper, the instability of natural convection induced by absorption of solar radiation in littoral regions is considered. Spectral analysis is conducted on the quasi-steady state flow to reveal the power and frequency modes of the instability at various positions. Results indicate that the power of instability, the number of frequency modes, the prominence of higher frequency modes, and the highest frequency mode increase with the offshore distance and/or Rayleigh number. Harmonic modes are present at relatively low Rayleigh numbers. For a given offshore distance, the position with the strongest power of instability is located adjacent to the sloping bottom while the frequency modes are the same over the local depth. As the Rayleigh number increases, the unstable region extends toward the shore.
Abstract: Surface water pollution is one of the serious
environmental problems in rural areas of South Africa due to
discharge of household waste into the streams, turning them into
open sewers. In this study, samples of water were collected from a
stream in Soshanguve and analysed. The result showed that pollution
in the area was caused by man and its activities. The water quality in
the area was found to have deterioted significantly after water runoff
from farms and household wastes. The result shows, fertilizer runoff
contributes 50% of the pollution while pesticides and sediments
contribute up to 10% respectively in the streams, while household
waste contributes up to 30%. This study gives an outline of the
sources of water pollution in the area and provides a process of
creating a clean and unpolluted environment for Soshanguve
community in Pretoria north in order to achieve the 7th aim of the
millennium development goals by 2015, which is ensuring
environmental sustainability.
Abstract: Sedimentation in reservoirs and the corresponding
loss of storage capacity is one of the most serious problems in dam
engineering. Pressurized flushing, a way to remove sediments from the reservoir, is flushing under a pressurized flow condition and
nearly constant water level. Pressurized flushing has only local
effects around the outlet. Sediment in the vicinity of the outlet openings is scoured and a funnel shaped crater is created. In this study, the temporal development of flushing cone under various
hydraulic conditions was studied experimentally. Time variations of
parameters such as maximum length and width of flushing and also
depth of scouring cone was measured. Results indicated that an
increase in flow velocity (and consequently in Froude number)
established new hydraulically conditions for flushing mechanism and
so a sudden growth was observed in the amount of sediment released
and also scouring dimenssions. In addition, a set of nondimensional
relationships were identified for temporal variations of flushing scour
dimenssions, which can eventuallt be used to estimate the development of flushing cone.