Abstract: Elastic scattering of Protons and deuterons from 11B nuclei at different p, d energies have been analyzed within the framework of optical model code (ECIS88). The elastic scattering of 3He+11B nuclear system at different 3He energies have been analyzed using double folding model code (FRESCO). The real potential obtained from the folding model was supplemented by a phenomenological imaginary potential, and during the fitting process the real potential was normalized and the imaginary potential optimized. Volumetric integrals of the real and imaginary potential depths (JR, JW) have been calculated for 3He+11B system. The agreement between the experimental data and the theoretical calculations in the whole angular range is fairly good. Normalization factor Nr is calculated in the range between 0.70 and 1.236.
Abstract: Nanofibers are defined as fibers with diameters less
than 100 nanometers. In this study, behaviours of activated carbon
nanofiber (ACNF), carbon nanofiber (CNF), polyacrylonitrile/ carbon
nanotube (PAN/CNT), polyvinyl alcohol/nanosilver (PVA/Ag) in
proton exchange membrane (PEM) fuel cells are investigated
experimentally. This material was used as gas diffusion layer (GDL)
in PEM fuel cells. In this study, the electrical conductivities of
nanofiber and nanofiber/nanoparticles have been studied to
understand their effects on PEM fuel cell performance. According to
the experimental results, the maximum electrical conductivity
performance of the fuel cell with nanofiber was found to be at
PVA/Ag (at UConn condition). The electrical conductivities of CNF,
ACNF, PAN/CNT are lower for PEM. The resistance of cell with
PVA/Ag is lower than the resistance of cell with PAN/CNT, ACNF,
CNF.
Abstract: Searching the “Island of stability” is a topic of
extreme interest in theoretical as well as experimental modern
physics today. This “island of stability” is spanned by superheavy
elements (SHE's) that are produced in the laboratory. SHE's are
believed to exist primarily due to the “magic” stabilizing effects of
nuclear shell structure. SHE synthesis is extremely difficult due to
their very low production cross section, often of the order of pico
barns or less. Stabilizing effects of shell closures at proton number
Z=82 and neutron number N=126 are predicted theoretically. Though
stabilizing effects of Z=82 have been experimentally verified, no
concluding observations have been made with N=126, so far. We
measured and analyzed the total evaporation residue (ER) cross
sections for a number of systems with neutron number around 126 to
explore possible shell closure effects in ER cross sections, in this
work.
Abstract: In this paper, a prototype PEM fuel cell vehicle
integrated with a 1 kW air-blowing proton exchange membrane fuel
cell (PEMFC) stack as a main power sources has been developed for
a lightweight cruising vehicle. The test vehicle is equipped with a
PEM fuel cell system that provides electric power to a brushed DC
motor. This vehicle was designed to compete with industrial
lightweight vehicle with the target of consuming least amount of
energy and high performance. Individual variations in driving style
have a significant impact on vehicle energy efficiency and it is well
established from the literature. The primary aim of this study was to
assesses the power and fuel consumption of a hydrogen fuel cell
vehicle operating at three difference driving technique (i.e. 25 km/h
constant speed, 22-28 km/h speed range, 20-30 km/h speed range).
The goal is to develop the best driving strategy to maximize
performance and minimize fuel consumption for the vehicle system.
The relationship between power demand and hydrogen consumption
has also been discussed. All the techniques can be evaluated and
compared on broadly similar terms. Automatic intelligent controller
for driving prototype fuel cell vehicle on different obstacle while
maintaining all systems at maximum efficiency was used. The result
showed that 25 km/h constant speed was identified for optimal
driving with less fuel consumption.
Abstract: In this paper, we present an application of Riemannian
geometry for processing non-Euclidean image data. We consider the
image as residing in a Riemannian manifold, for developing a new
method to brain edge detection and brain extraction. Automating this
process is a challenge due to the high diversity in appearance brain
tissue, among different patients and sequences. The main contribution, in this paper, is the use of an edge-based
anisotropic diffusion tensor for the segmentation task by integrating
both image edge geometry and Riemannian manifold (geodesic,
metric tensor) to regularize the convergence contour and extract
complex anatomical structures. We check the accuracy of the
segmentation results on simulated brain MRI scans of single
T1-weighted, T2-weighted and Proton Density sequences. We
validate our approach using two different databases: BrainWeb
database, and MRI Multiple sclerosis Database (MRI MS DB). We
have compared, qualitatively and quantitatively, our approach with
the well-known brain extraction algorithms. We show that using
a Riemannian manifolds to medical image analysis improves the
efficient results to brain extraction, in real time, outperforming the
results of the standard techniques.
Abstract: Thermal enhancement of a single mini channel in
Proton Exchange Membrane Fuel Cell (PEMFC) cooling plate is
numerically investigated. In this study, low concentration of Al2O3 in
Water - Ethylene Glycol mixtures is used as coolant in single channel
of carbon graphite plate to mimic the mini channels in PEMFC
cooling plate. A steady and incompressible flow with constant heat
flux is assumed in the channel of 1mm x 5mm x 100mm. Nano
particle of Al2O3 used ranges from 0.1, 0.3 and 0.5 vol %
concentration and then dispersed in 60:40 (water: Ethylene Glycol)
mixture. The effect of different flow rates to fluid flow and heat
transfer enhancement in Re number range of 20 to 140 was observed.
The result showed that heat transfer coefficient was improved by
18.11%, 9.86% and 5.37% for 0.5, 0.3 and 0.1 vol. % Al2O3 in 60:40
(water: EG) as compared to base fluid of 60:40 (water: EG). It is also
showed that the higher vol. % concentration of Al2O3 performed
better in term of thermal enhancement but at the expense of higher
pumping power required due to increase in pressure drop
experienced. Maximum additional pumping power of 0.0012W was
required for 0.5 vol % Al2O3 in 60:40 (water: EG) at Re number 140.
Abstract: A comparison of activity and stability of the as-formed
Pt/C, Pt-Co and Pt-Pd/C electrocatalysts, prepared by a combined
approach of impregnation and seeding, was performed. According to
the activity test in a single Proton Exchange Membrane (PEM) fuel
cell, the Oxygen Reduction Reaction (ORR) activity of the Pt-M/C
electrocatalyst was slightly lower than that of Pt/C. The j0.9 V and
E10 mA/cm2 of the as-prepared electrocatalysts increased in the order of
Pt/C > Pt-Co/C > Pt-Pd/C. However, in the medium-to-high current
density region, Pt-Pd/C exhibited the best performance. With regard to
their stability in a 0.5 M H2SO4 electrolyte solution, the
electrochemical surface area decreased as the number of rounds of
repetitive potential cycling increased due to the dissolution of the
metals within the catalyst structure. For long-term measurement, Pt-
Pd/C was the most stable than the other three electrocatalysts.
Abstract: Let us consider that the entire universe is composed of
a single hydrogen atom within which the electron is moving around
the proton. In this case, according to classical theories of physics,
radiation, photons respectively, should be absorbed by the electron.
Depending on the number of photons absorbed, the electron radius of
rotation around the proton is established. Until now, the principle of
photons absorption by electrons and the electron transition to a new
energy level, namely to a higher radius of rotation around the proton,
is not clarified in physics. This paper aims to demonstrate that
radiation, photons respectively, have mass and negative electrostatic
charge similar to electrons but infinitely smaller. The experiments
which demonstrate this theory are simple: thermal expansion,
photoelectric effect and thermonuclear reaction.
Abstract: Durability of Membrane Electrode Assembly for
Proton Exchange Membrane Fuel Cells was evaluated in both steady
state and accelerated decay modes. Steady state mode was carried out
at constant current of 800mA/cm2 for 2500 hours using air as cathode
feed and pure hydrogen as anode feed. The degradation of the cell
voltage was 0.015V after such 2500 hrs operation. The degradation
rate was therefore calculated to be 6uV/hr. Continuously Vigorous
fluctuation of the cell voltage, which was switched between OCV and
0.2V, was employed for the accelerated decay mode. No obvious
change in performance of the MEA was observed after 10000 cycles
of such operation.
Abstract: Considering palm oil as non-drying oil owing to its
low iodine value, an attempt was taken to increase the unsaturation in
the fatty acid chains of palm oil for the preparation of alkyds. To
increase the unsaturation in the palm oil, sulphuric acid (SA) and
para-toluene sulphonic acid (PTSA) was used prior to alcoholysis for
the dehydration process. The iodine number of the oil samples was
checked for the unsaturation measurement by Wijs method. Alkyd
resin was prepared using the dehydrated palm oil by following
alcoholysis and esterification reaction. To improve the film properties
0.5wt.% multi-wall carbon nano tubes (MWCNTs) were used to
manufacture polymeric film. The properties of the resins were
characterized by various physico-chemical properties such as density,
viscosity, iodine value, saponification value, etc. Structural
elucidation was confirmed by Fourier transform of infrared
spectroscopy and proton nuclear magnetic resonance; surfaces of the
films were examined by field-emission scanning electron microscope.
In addition, pencil hardness and chemical resistivity was also
measured by using standard methods. The effect of enhancement of
the unsaturation in the fatty acid chain found significant and
motivational. The resin prepared with dehydrated palm oil showed
improved properties regarding hardness and chemical resistivity
testing. The incorporation of MWCNTs enhanced the thermal
stability and hardness of the films as well.
Abstract: Doxorubicin, also known as Adriamycin, is an
anthracycline class of drug used in cancer chemotherapy. It is used in
the treatment of non-Hodgkin’s lymphoma, multiple myeloma, acute
leukemia, breast cancer, lung cancer, endometrium cancer and ovary
cancers. It functions via intercalating DNA and ultimately killing
cancer cells. The major side effects of doxorubicin are hair loss,
myelosuppression, nausea & vomiting, oesophagitis, diarrhea, heart
damage and liver dysfunction. The minor modifications in the
structure of compound exhibit large variation in the biological
activity, has prompted us to carry out the synthesis of sulfonamide
derivatives. Sulfonamide is an important feature with broad spectrum
of biological activity such as antiviral, antifungal, diuretics, antiinflammatory,
antibacterial and anticancer activities. Structure of the
synthesized compound N-(1-methyl-2-oxo-2-N-methyl anilinoethyl)
benzene sulfonamide confirmed by proton nuclear magnetic
resonance (1H NMR),13C NMR, Mass and FTIR spectroscopic tools
to assure the position of all protons and hence stereochemistry of the
molecule. Further we have reported the binding potential of
synthesized sulfonamide analogues in comparison to doxorubicin
drug using Auto Dock 4.2 software. Computational binding energy
(B.E.) and inhibitory constant (Ki) has been evaluated for the
synthesized compound in comparison of doxorubicin against Poly
(dA-dT).Poly (dA-dT) and Poly (dG-dC).Poly (dG-dC) sequences.
The in vitro cytotoxic study against human breast cancer cell lines
confirms the better anticancer activity of the synthesized compound
over currently in use anticancer drug doxorubicin. The IC50 value of
the synthesized compound is 7.12 μM whereas for doxorubicin is 7.2
μM.
Abstract: We study the anomalous WWγ and WWZ couplings by
calculating total cross sections of two processes at the LHeC with
electron beam energy Ee=140 GeV and the proton beam energy Ep=7
TeV, and at the FCC-ep collider with the polarized electron beam
energy Ee=80 GeV and the proton beam energy Ep=50 TeV. At the
LHeC with electron beam polarization, we obtain the results for the
difference of upper and lower bounds as (0.975, 0.118) and (0.285,
0.009) for the anomalous (Δκγ, λγ) and (Δκz, λz) couplings,
respectively. As for FCC-ep collider, these bounds are obtained as
(1.101, 0.065) and (0.320, 0.002) at an integrated luminosity of
Lint=100 fb^-1.
Abstract: The effect of the modification of ZnO powders by ZrO2, Al2O3, TiO2, SiO2, CeO2 and Y2O3 nanoparticles with a concentration of 1-30 wt % is investigated by diffuse reflectance spectra within the wavelength range 200 to 2500 nm before and after 100 keV proton and electron irradiation. It has been established that the introduction of nanoparticles ZrO2, Al2O3 enhances the optical stability of the pigments under proton irradiation, but reduces it under electron irradiation. Modifying with TiO2, SiO2, CeO2, Y2O3 nanopowders leads to decrease radiation stability in both types of irradiation. Samples modified by 5 wt. % of ZrO2 nanoparticles have the highest stability of optical properties after proton exposure. The degradation of optical properties under electron irradiation is not high for this concentration of nanoparticles. A decrease in the absorption of pigments modified with nanoparticles proton exposure is determined by a decrease in the intensity of bands located in the UV and visible regions. After electron exposure the absorption bands have in the whole spectrum range.
Abstract: A proton exchange membrane has been developed for
direct methanol fuel cell (DMFC). The nanofiber network composite
membranes were prepared by interconnected network of Nafion
(perfuorosulfonic acid) nanofibers that have been embedded in an
uncharged and inert polymer matrix, by electro-spinning. The
spinning solution of Nafion with a low concentration (1 wt%
compared to Nafion) of high molecular weight poly(ethylene oxide),
as a carrier polymer. The interconnected network of Nafion
nanofibers with average fiber diameter in the range of 160-700nm,
were used to make the membranes, with the nanofiber occupying up
to 85% of the membrane volume. The matrix polymer was
crosslinked with Norland Optical Adhesive 63 under UV. The
resulting membranes showed proton conductivity of 0.10 S/cm at
25°C and 80% RH; and methanol permeability of 3.6 x 10-6 cm2/s.
Abstract: The Proton Exchange Membranes (PEM) are largely studied because they operate at low temperatures and they are suitable for mobile applications. However, there are some deficiencies in their operation, mainly those that use ethanol as a hydrogen source, that require a certain attention. Therefore, this research aimed to develop Nafion® composite membranes, mixing clay minerals, kaolin and halloysite to the polymer matrix in order to improve the ethanol molecule retentions and, at the same time, to keep the system’s protonic conductivity. The modified Nafion/Kaolin, Nafion/Halloysite composite membranes were prepared in weight proportion of 0.5, 1.0 and 1.5. The membranes obtained were characterized as to their ethanol permeability, protonic conductivity and water absorption. The composite morphology and structure are characterized by SEM and EDX and the thermal behavior is determined by TGA and DSC. The analysis of the results shows ethanol permeability reduction from 48% to 63%. However, the protonic conductivity results are lower in relation to pure Nafion®. As to the thermal behavior, the Nafion® composite membranes were stable up to a temperature of 325ºC.
Abstract: This article deals with the carbon nanotubes (CNT) synthesized from a novel precursor, sugar cane and Anodic Aluminum Oxide (AAO). The objective was to produce CNTs to be used as catalyst supports for Proton Exchange Membranes. The influence of temperature, inert gas flow rate and concentration of the precursor is presented. The CNTs prepared were characterized using TEM, XRD, Raman Spectroscopy, and the surface area determined by BET. The results show that it is possible to form CNT from sugar cane by pyrolysis and the CNTs are the type multi-walled carbon nanotubes. The MWCNTs are short and closed at the two ends with very small surface area of SBET= 3.691m,/g.
Abstract: Solar cells used in orbit are exposed to radiation environment mainly protons and high energy electrons. These particles degrade the output parameters of the solar cell. The aim of this work is to characterize the effects of electron irradiation fluence on the J (V) characteristic and output parameters of GaAs solar cell by numerical simulation. The results obtained demonstrate that the electron irradiation-induced degradation of performances of the cells concerns mainly the short circuit current
Abstract: Using form factors of the proton and the neutron for different of Q2, bag radius of the proton and the neutron can be obtained based on bag models. Then using static bag radius, magnetic moments of the proton and the neutron can be obtained and compared with other results.
Abstract: Proton transfer and hydrogen bonding are two aspects
of the chemistry of hydrogen that respectively govern the behaviour
and structure of many molecules, both simple and complex. All the
theoretical enol and keto conformations of 1,3-diphenyl-1,3-
propandion known as dibenzoylmethane (DBM), have been
investigated by means of atoms in molecules (AIM) theory. It was
found that the most stable conformers are those stabilized by
hydrogen bridges.The aim of the present paper is a thorough
conformational analysis of DBM (with special attention on chelated
cis-enol conformers) in order to obtain detailed information on the
geometrical parameters, relative stabilities and rotational motion of
the phenyl groups. It is also important to estimate the barrier height
for ptoton transfer and hydrogen bond strength, which are the main
factors governing conformational stability.
Abstract: The presented work is motivated by a French law
regarding nuclear waste management. A new conceptual Accelerator
Driven System (ADS) designed for the Minor Actinides (MA)
transmutation has been assessed by numerical simulation. The
MUltiple Spallation Target (MUST) ADS combines high thermal power (up to 1.4 GWth) and high specific power. A 30 mA and 1
GeV proton beam is divided into three secondary beams transmitted on three liquid lead-bismuth spallation targets. Neutron and thermalhydraulic
simulations have been performed with the code MURE, based on the Monte-Carlo transport code MCNPX. A methodology has been developed to define characteristic of the MUST ADS concept according to a specific transmutation scenario. The reference
scenario is based on a MA flux (neptunium, americium and curium)
providing from European Fast Reactor (EPR) and a plutonium multireprocessing
strategy is accounted for. The MUST ADS reference
concept is a sodium cooled fast reactor. The MA fuel at equilibrium is mixed with MgO inert matrix to limit the core reactivity and
improve the fuel thermal conductivity. The fuel is irradiated over five
years. Five years of cooling and two years for the fuel fabrication are
taken into account. The MUST ADS reference concept burns about 50% of the initial MA inventory during a complete cycle. In term of
mass, up to 570 kg/year are transmuted in one concept. The methodology to design the MUST ADS and to calculate fuel
composition at equilibrium is precisely described in the paper. A detailed fuel evolution analysis is performed and the reference scenario is compared to a scenario where only americium transmutation is performed.