Abstract: This paper reviews the objectives, methods and results of previous studies on biodrying of solid waste in several countries. Biodrying of solid waste is a novel technology in developing countries such as in Malaysia where high moisture content in organic waste makes the segregation process for recycling purposes complicated and diminishes the calorific value for the use of fuel source. In addition, the high moisture content also encourages the breeding of vectors and disease-bearing animals. From the laboratory results, the average moisture content of organic waste, paper, plastics and metals are 58.17%, 37.93%, 29.79% and 1.03% respectively for UKM campus. Biodrying of solid waste is a simple method of waste treatment as well as a cost-efficient technology to dry the solid waste. The process depends on temperature monitoring and air flow control along with the natural biodegradable process of organic waste. This review shows that the biodrying of solid waste method has high potential in treatment and recycling of solid waste, be useful for biodrying study and implementation in Malaysia.
Abstract: We present the development of a new underwater laser
cutting process in which a water-jet has been used along with the
laser beam to remove the molten material through kerf. The
conventional underwater laser cutting usually utilizes a high pressure
gas jet along with laser beam to create a dry condition in the cutting
zone and also to eject out the molten material. This causes a lot of gas
bubbles and turbulence in water, and produces aerosols and waste
gas. This may cause contamination in the surrounding atmosphere
while cutting radioactive components like burnt nuclear fuel. The
water-jet assisted underwater laser cutting process produces much
less turbulence and aerosols in the atmosphere. Some amount of
water vapor bubbles is formed at the laser-metal-water interface;
however, they tend to condense as they rise up through the
surrounding water. We present the design and development of a
water-jet assisted underwater laser cutting head and the parametric
study of the cutting of AISI 304 stainless steel sheets with a 2 kW
CW fiber laser. The cutting performance is similar to that of the gas
assist laser cutting; however, the process efficiency is reduced due to
heat convection by water-jet and laser beam scattering by vapor. This
process may be attractive for underwater cutting of nuclear reactor
components.
Abstract: Pharmaceutical industries and effluents of sewage treatment plants are the main sources of residual pharmaceuticals in water resources. These emergent pollutants may adversely impact the biophysical environment. Pharmaceutical industries often generate wastewater that changes in characteristics and quantity depending on the used manufacturing processes. Carbamazepine (CBZ), {5Hdibenzo [b,f]azepine-5-carboxamide, (C15H12N2O)}, is a significant non-biodegradable pharmaceutical contaminant in the Jordanian pharmaceutical wastewater, which is not removed by the activated sludge processes in treatment plants. Activated carbon may potentially remove that pollutant from effluents, but the high cost involved suggests that more attention should be given to the potential use of low-cost materials in order to reduce cost and environmental contamination. Powders of Jordanian non-metallic raw materials namely, Azraq Bentonite (AB), Kaolinite (K), and Zeolite (Zeo) were activated (acid and thermal treatment) and evaluated by removing CBZ. The results of batch and column techniques experiments showed around 46% and 67% removal of CBZ respectively.
Abstract: This study investigated the seasonal prevalence of
Aedes aegypti and Ae. albopictus larvae in three topographical areas
(i.e. mangrove, rice paddy and mountainous areas). Samples were
collected from 300 households in both wet and dry seasons in nine
districts in Nakhon Si Thammarat province. Ae. aegypti and Ae.
albopictus were found in 21 out of 29 types of water containers in
mangrove, rice paddy and mountainous areas. Ae. aegypti and Ae.
albopictus laid eggs in different container types depending on season
and topographical areas. Ae. aegypti larvae were found most in metal
box in mangrove and mountainous areas in wet season. Ae.
albopictus larvae were also found most in metal box in mangrove and
mountainous areas in both wet and dry seasons. All Ae. albopictus
larval indices were higher than Ae. aegypti larval indices in all three
topographical areas and both seasons. HI and BI did not differ in
three topographical areas but differed between Aedes sp. HI for both
Ae. aegypti and Ae. albopictus in all three topographical areas in both
seasons were greater than 10 %, except Aedes aegypti in rice paddy
area in wet season. This indicated high risks of DHF transmission in
these areas.
Abstract: For more than 120 years, gold mining formed the
backbone the South Africa-s economy. The consequence of mine
closure was observed in large-scale land degradation and widespread
pollution of surface water and groundwater. This paper investigates
the feasibility of using natural zeolite in removing heavy metals
contaminating the Wonderfonteinspruit Catchment Area (WCA), a
water stream with high levels of heavy metals and radionuclide
pollution. Batch experiments were conducted to study the adsorption
behavior of natural zeolite with respect to Fe2+, Mn2+, Ni2+, and Zn2+.
The data was analysed using the Langmuir and Freudlich isotherms.
Langmuir was found to correlate the adsorption of Fe2+, Mn2+, Ni2+,
and Zn2+ better, with the adsorption capacity of 11.9 mg/g, 1.2 mg/g,
1.3 mg/g, and 14.7 mg/g, respectively. Two kinetic models namely,
pseudo-first order and pseudo second order were also tested to fit the
data. Pseudo-second order equation was found to be the best fit for
the adsorption of heavy metals by natural zeolite. Zeolite
functionalization with humic acid increased its uptake ability.
Abstract: The equilibrium, thermodynamics and kinetics of the
biosorption of Cd (II) and Pb(II) by a Spore Forming Bacillus (MGL
75) were investigated at different experimental conditions. The
Langmuir and Freundlich, and Dubinin-Radushkevich (D-R)
equilibrium adsorption models were applied to describe the
biosorption of the metal ions by MGL 75 biomass. The Langmuir
model fitted the equilibrium data better than the other models.
Maximum adsorption capacities q max for lead (II) and cadmium (II)
were found equal to 158.73mg/g and 91.74 mg/g by Langmuir model.
The values of the mean free energy determined with the D-R equation
showed that adsorption process is a physiosorption process. The
thermodynamic parameters Gibbs free energy (ΔG°), enthalpy (ΔH°),
and entropy (ΔS°) changes were also calculated, and the values
indicated that the biosorption process was exothermic and
spontaneous. Experiment data were also used to study biosorption
kinetics using pseudo-first-order and pseudo-second-order kinetic
models. Kinetic parameters, rate constants, equilibrium sorption
capacities and related correlation coefficients were calculated and
discussed. The results showed that the biosorption processes of both
metal ions followed well pseudo-second-order kinetics.
Abstract: Structural behavior of ring stiffened thick walled
cylinders made of functionally graded materials (FGMs) is
investigated in this paper. Functionally graded materials are inhomogeneous composites which are usually made from a mixture
of metal and ceramic. The gradient compositional variation of the
constituents from one surface to the other provides an elegant solution to the problem of high transverse shear stresses that are
induced when two dissimilar materials with large differences in material properties are bonded. FGM formation of the cylinder is
modeled by power-law exponent and the variation of characteristics is supposed to be in radial direction.
A finite element formulation is derived for the analysis. According to the property variation of the constituent materials in the radial
direction of the wall, it is not convenient to use conventional elements to model and analyze the structure of the stiffened FGM
cylinders. In this paper a new cylindrical super-element is used to model the finite element formulation and analyze the static and
modal behavior of stiffened FGM thick walled cylinders. By using
this super-element the number of elements, which are needed for
modeling, will reduce significantly and the process time is less in comparison with conventional finite element formulations. Results for static and modal analysis are evaluated and verified by
comparison to finite element formulation with conventional
elements. Comparison indicates a good conformity between results.
Abstract: A new chelating resin is prepared by coupling Amberlite XAD-4 with 1-amino-2-naphthole through an azo spacer. The resulting sorbent has been characterized by FT-IR, elemental analysis and thermogravimetric analysis (TGA) and studied for preconcentrating of Fe (II) using flame atomic absorption spectrometry (FAAS) for metal monitoring. The optimum pH value for sorption of the iron ions was 6.5. The resin was subjected to evaluation through batch binding of mentioned metal ion. Quantitative desorption occurs instantaneously with 0.5 M HNO3. The sorption capacity was found 4.1 mmol.g-1 of resin for Fe (II) in the aqueous solution. The chelating resin can be reused for 10 cycles of sorption-desorption without any significant change in sorption capacity. A recovery of 97% was obtained the metal ions with 0.5 M HNO3 as eluting agent. The method was applied for metal ions determination from industrial waste water sample.
Abstract: Arc welding creates a weld pool to realize continuity between pieces of assembly. The thermal history of the weld is dependent on heat transfer and fluid flow in the weld pool. The metallurgical transformation during welding and cooling are modeled in the literature only at solid state neglecting the fluid flow. In the present paper we associate a heat transfer – fluid flow and metallurgical model for the 16MnD5 steel. The metallurgical transformation model is based on Leblond model for the diffusion kinetics and on the Koistinen-Marburger equation for Marteniste transformation. The predicted thermal history and metallurgical transformations are compared to a simulation without fluid phase. This comparison shows the great importance of the fluid flow modeling.
Abstract: To improve the material characteristics of single- and
poly-crystals of pure copper, the respective relationships between crystallographic orientations and microstructures, and the bending and mechanical properties were examined. And texture distribution is also
analyzed. A grain refinement procedure was performed to obtain a
grained structure. Furthermore, some analytical results related to
crystal direction maps, inverse pole figures, and textures were obtained from SEM-EBSD analyses. Results showed that these
grained metallic materials have peculiar springback characteristics with various bending angles.
Abstract: Recently, the advanced technologies that offer high
precision product, relative easy, economical process and also rapid
production are needed to realize the high demand of ultra precision
micro part. In our research, micromanufacturing based on soft
lithography and nanopowder injection molding was investigated. The
silicone metal pattern with ultra thick and high aspect ratio succeeds to
fabricate Polydimethylsiloxane (PDMS) micro mold. The process
followed by nanopowder injection molding (PIM) by a simple vacuum
hot press. The 17-4ph nanopowder with diameter of 100 nm, succeed
to be injected and it forms green sample microbearing with thickness,
microchannel and aspect ratio is 700μm, 60μm and 12, respectively.
Sintering process was done in 1200 C for 2 hours and heating rate
0.83oC/min. Since low powder load (45% PL) was applied to achieve
green sample fabrication, ~15% shrinkage happen in the 86% relative
density. Several improvements should be done to produce high
accuracy and full density sintered part.
Abstract: Petrology and geochemical characteristics of granitic
rocks from South Sulawesi, especially from Polewaliand Masamba
area are presented in order to elucidate their origin of magma and
geodynamic setting. The granitic rocks in these areas are dominated by
granodiorite and granite in composition. Quartz, K-feldspar and
plagioclase occur as major phases with hornblende and biotite as
major ferromagnesian minerals. All of the samples were plotted in
calc-alkaline field, show metaluminous affinity and typical of I-type
granitic rock. Harker diagram indicates that granitic rocks experienced
fractional crystallization during magmatic evolution. Both groups
displayed an extreme enrichment of LILE, LREE and a slight negative
Eu anomaly which resemble upper continental crust affinity. They
were produced from partial melting of upper continental crust and
have close relationship of sources composition within a suite. The
geochemical characteristics explained the arc related subduction
environment which later give an evidence of continent-continent
collision between Australia-derived microcontinent and Sundalandto
form continental arc environment.
Abstract: Over a million tonnes of cigarette butts (CBs) are produced worldwide annually. These CBs accumulate in the environment due to the poor biodegradability of the cellulose acetate filters and pose a serious environmental risk. This paper presents some of the results from a continuing study on recycling CBs into fired clay bricks. Properties including compressive strength, flexural strength, density, water absorption and thermal conductivity of fired clay bricks are reported and discussed. Furthermore, leaching of heavy metals from the manufactured clay bricks was tested. The results show that the density of fired bricks was reduced by about 8 – 30 %, depending on the percentage of CBs incorporated into the raw materials. The compressive strength of bricks tested was 12.57, 5.22 and 3.00 MPa for 2.5, 5.0 and 10 % CB content respectively. Water absorption and initial rate of absorption values increased as density, and hence porosity, of bricks decreased with increasing CB volume. The leaching test results revealed trace amounts of heavy metals.
Abstract: Rapid Prototyping (RP) is a technology that produces models and prototype parts from 3D CAD model data, CT/MRI scan data, and model data created from 3D object digitizing systems. There are several RP process like Stereolithography (SLA), Solid Ground Curing (SGC), Selective Laser Sintering (SLS), Fused Deposition Modeling (FDM), 3D Printing (3DP) among them SLS and FDM RP processes are used to fabricate pattern of custom cranial implant. RP technology is useful in engineering and biomedical application. This is helpful in engineering for product design, tooling and manufacture etc. RP biomedical applications are design and development of medical devices, instruments, prosthetics and implantation; it is also helpful in planning complex surgical operation. The traditional approach limits the full appreciation of various bony structure movements and therefore the custom implants produced are difficult to measure the anatomy of parts and analyze the changes in facial appearances accurately. Cranioplasty surgery is a surgical correction of a defect in cranial bone by implanting a metal or plastic replacement to restore the missing part. This paper aims to do a comparative study on the dimensional error of CAD and SLS RP Models for reconstruction of cranial defect by comparing the virtual CAD with the physical RP model of a cranial defect.
Abstract: The article deals with technical support of intracranial single unit activity measurement. The parameters of the whole measuring set were tested in order to assure the optimal conditions of extracellular single-unit recording. Metal microelectrodes for measuring the single-unit were tested during animal experiments. From signals recorded during these experiments, requirements for the measuring set parameters were defined. The impedance parameters of the metal microelectrodes were measured. The frequency-gain and autonomous noise properties of preamplifier and amplifier were verified. The measurement and the description of the extracellular single unit activity could help in prognoses of brain tissue damage recovery.
Abstract: Two short sediment cores collected from mangrove
areas of Manori and Thane creeks along Mumbai coast were analysed
for sediment composition and metals (Fe, Mn, Cu, Pb, Co, Ni, Zn, Cr
and V). The statistical analysis of Pearson correlation matrix proved
that there is a significant relationship between metal concentration
and finer grain size in Manori creek while poor correlation was
observed in Thane creek. Based on the enrichment factor, the present
metal to background metal ratios clearly reflected maximum
enrichment of Cu and Pb in Manori creek and Mn in Thane creek.
Geoaccumulation index calculated indicate that the study area is
unpolluted with respect to Fe, Mn, Co, Ni, Zn and Cr in both the
cores while moderately polluted with Cu and Pb in Manori creek.
Based on contamination degree, both the core sediments were found
to be considerably contaminated with metals.
Abstract: A finite element analysis (FEA) computer software HyperWorks is utilized in re-designing an automotive component to reduce its mass. Reduction of components mass contributes towards environmental sustainability by saving world-s valuable metal resources and by reducing carbon emission through improved overall vehicle fuel efficiency. A shape optimization analysis was performed on a rear spindle component. Pre-processing and solving procedures were performed using HyperMesh and RADIOSS respectively. Shape variables were defined using HyperMorph. Then optimization solver OptiStruct was utilized with fatigue life set as a design constraint. Since Stress-Number of Cycle (S-N) theory deals with uni-axial stress, the Signed von Misses stress on the component was used for looking up damage on S-N curve, and Gerber criterion for mean stress corrections. The optimization analysis resulted in mass reduction of 24% of the original mass. The study proved that the adopted approach has high potential use for environmental sustainability.
Abstract: In this paper an attempt has been made to correlate the usefulness of electrodes made through powder metallurgy (PM) in comparison with conventional copper electrode during electric discharge machining. Experimental results are presented on electric discharge machining of AISI D2 steel in kerosene with copper tungsten (30% Cu and 70% W) tool electrode made through powder metallurgy (PM) technique and Cu electrode. An L18 (21 37) orthogonal array of Taguchi methodology was used to identify the effect of process input factors (viz. current, duty cycle and flushing pressure) on the output factors {viz. material removal rate (MRR) and surface roughness (SR)}. It was found that CuW electrode (made through PM) gives high surface finish where as the Cu electrode is better for higher material removal rate.