Abstract: E-glass-epoxy laminated composites having different fiber volume fractions (40, 50, 60 and 70) were fabricated with and without the addition of nanoclay. Flexural strength and tensile strength of the composite laminates were determined. It was observed that, with increasing the fiber volume fraction (Vf) of fiber from 40 to 60, the ability of nanoclay to enhance the tensile and flexural strength of E-glass-epoxy composites decreases significantly. At 70Vf, the tensile and flexural strength of the nanoclay reinforced E-glass-epoxy were found to be lowest when compared to the E-glass-epoxy composite made without the addition of nanoclay. Based on the obtained data and microstructure of the tested samples, plausible mechanism for the observed trends has been proposed. The enhanced mechanical properties for nanoclay reinforced E-glass-epoxy composites for 40-60 Vf, due to higher interface toughness coupled with strong interfilament bonding may have ensured the homogeneous load distribution across all the glass fibers. Results in the decrease in mechanical properties at 70Vf, may be due to the inability of the matrix to bind the nanoclay and glass-fibers.
Abstract: Promotion of the Fiber Reinforced Concrete (FRC) as a construction material for civil engineering projects has invoked numerous researchers to investigate their mechanical behavior. Even though there is satisfactory information about the effects of fiber type and length, concrete mixture, casting type and other variables on the strength and deformability parameters of FRC, the numerical modeling of such materials still needs research attention. The focus of this study is to investigate the feasibility of Concrete Damaged Plasticity (CDP) model in prediction of Macro-synthetic FRC structures behavior. CDP model requires the tensile behavior of concrete to be well characterized. For this purpose, a series of uniaxial direct tension and four point bending tests were conducted on the notched specimens to define bilinear tension softening (post-peak tension stress-strain) behavior. With these parameters obtained, the flexural behavior of macro-synthetic FRC beams were modeled and the results showed a good agreement with the experimental measurements.
Abstract: This paper investigates the application of metallic
coatings on high fiber volume fraction carbon/epoxy polymer matrix
composites. For the grip of the metallic layer, a method of modifying
the surface of the composite by introducing a mixture of copper and
steel powder (filler powders) which can reduce the impact of thermal
spray particles. The powder was introduced to the surface at the time
of the forming. Arc spray was used to project the zinc coating layer.
The substrate was grit blasted to avoid poor adherence. The porosity, microstructure, and morphology of layers are
characterized by optical microscopy, SEM and image analysis. The
samples were studied also in terms of hardness and erosion resistance.
This investigation did not reveal any visible evidence damage to the
substrates. The hardness of zinc layer was about 25.94 MPa and the
porosity was around (∼6.70%). The erosion test showed that the zinc
coating improves the resistance to erosion. Based on the results
obtained, we can conclude that thermal spraying allows the production
of protective coating on PMC. Zinc coating has been identified as a
compatible material with the substrate. The filler powders layer
protects the substrate from the impact of hot particles and allows
avoiding the rupture of brittle carbon fibers.
Abstract: Nanofibers are defined as fibers with diameters less
than 100 nanometers. In this study, behaviours of activated carbon
nanofiber (ACNF), carbon nanofiber (CNF), polyacrylonitrile/ carbon
nanotube (PAN/CNT), polyvinyl alcohol/nanosilver (PVA/Ag) in
proton exchange membrane (PEM) fuel cells are investigated
experimentally. This material was used as gas diffusion layer (GDL)
in PEM fuel cells. In this study, the electrical conductivities of
nanofiber and nanofiber/nanoparticles have been studied to
understand their effects on PEM fuel cell performance. According to
the experimental results, the maximum electrical conductivity
performance of the fuel cell with nanofiber was found to be at
PVA/Ag (at UConn condition). The electrical conductivities of CNF,
ACNF, PAN/CNT are lower for PEM. The resistance of cell with
PVA/Ag is lower than the resistance of cell with PAN/CNT, ACNF,
CNF.
Abstract: Earth structures constructed of marine clay soils have
tendency to crack. In order to improve the flexural strength and
brittleness, a technique of mixing short fibers is introduced to the soil
lime mixture. Coir fiber was used in this study as reinforcing
elements. An experimental investigation consisting primarily of
flexural tensile tests was conducted to examine the influence of coir
fibers on the flexural behaviour of the reinforced soils. The test
results that the coir fibers were effective in improving the flexural
strength and Young’s modulus of all soils examined and ductility
after peak strength for reinforced marine clay soil treated by lime. 5%
lime treated soil and 1% coir fiber reinforced soil specimens’
demonstrated good strength and durability when submerged in water
and retained 45% of their air-cured strengths.
Abstract: Despite the wide spread use of synthetic dyes, natural
dyes are still exploited and used to enhance its inherent aesthetic
qualities as a major material for beautification of the body. Centuries
before the discovery of synthetic dyes, natural dyes were the only
source of dye open to mankind. Dyes are extracted from plant -
leaves, roots and barks, insect secretions, and minerals. However,
research findings have made it clear that of all, plants- leaves, roots,
barks or flowers are the most explored and exploited in which henna
(Lawsonia innermis L.) is one of those plants. Experiment has also
shown that henna is used in body painting in conjunction with an
alkaline (Ammonium Sulphate) as a fixing agent. This of course
gives a clue that if colour derived from henna is properly
investigated, it may not only be used for body decoration but
possibly, may have affinity to fiber substrate. This paper investigates
the dyeing potentials – dye ability and fastness qualities of henna dye
extracts on cotton and linen fibers using mordants like ammonium
sulphate and other alkalis (hydrosulphate and caustic soda, potash,
common salt, potassium alum). Hot and cold water and ethanol
solvent were used in the extraction of the dye to investigate the most
effective method, dye ability, and fastness qualities of these extracts
under room temperature. The results of the experiment show that
cotton have a high rate of dye intake than other fiber. On a similar
note, the colours obtained depend most on the solvent used. In
conclusion, hot water extraction appears more effective. While the
colours obtained from ethanol and both cold hot methods of
extraction range from light to dark yellow, light green to army green
and to some extent shades of brown hues.
Abstract: Lightweight and efficient structures have the aim to
enhance the efficiency of the components in various industries.
Toward this end, composites are one of the most widely used
materials because of durability, high strength and modulus, and low
weight. One type of the advanced composites is grid-stiffened
composite (GSC) structures, which have been extensively considered
in aerospace, automotive, and aircraft industries. They are one of the
top candidates for replacing some of the traditional components,
which are used here. Although there are a good number of published
surveys on the design aspects and fabrication of GSC structures, little
systematic work has been reported on their material modification to
improve their properties, to our knowledge. Matrix modification
using nanoparticles is an effective method to enhance the flexural
properties of the fibrous composites. In the present study, a silanecoupling
agent (3-glycidoxypropyltrimethoxysilane/3-GPTS) was
introduced onto the silica (SiO2) nanoparticle surface and its effects
on the three-point flexural response of isogrid E-glass/epoxy
composites were assessed. Based on the Fourier Transform Infrared
Spectrometer (FTIR) spectra, it was inferred that the 3-GPTS
coupling agent was successfully grafted onto the surface of SiO2
nanoparticles after modification. Flexural test revealed an
improvement of 16%, 14%, and 36% in stiffness, maximum load and
energy absorption of the isogrid specimen filled with 3 wt.% 3-
GPTS/SiO2 compared to the neat one. It would be worth mentioning
that in these structures, considerable energy absorption was observed
after the primary failure related to the load peak. In addition, 3-
GPTMS functionalization had a positive effect on the flexural
behavior of the multiscale isogrid composites. In conclusion, this
study suggests that the addition of modified silica nanoparticles is a
promising method to improve the flexural properties of the gridstiffened
fibrous composite structures.
Abstract: A number of studies have been conducted recently to
investigate the influence of randomly oriented fibers on some
engineering properties of cohesive and cohesionless soils. However,
few studies have been carried out on freezing-thawing behavior of
fine-grained soils modified with discrete fiber inclusions and additive
materials. This experimental study was performed to investigate the
effect of randomly distributed polypropylene fibers (PP) and some
additive materials [e.g.., borogypsum (BG), fly ash (FA) and cement
(C)] on freezing-thawing durability (mass losses) of a fine-grained
soil for 6, 12, and 18 cycles. The Taguchi method was applied to the
experiments and a standard L9 orthogonal array (OA) with four
factors and three levels were chosen. A series of freezing-thawing
tests were conducted on each specimen. 0-20% BG, 0-20% FA, 0-
0.25% PP and 0-3% of C by total dry weight of mixture were used in
the preparation of specimens. Experimental results showed that the
most effective materials for the freezing-thawing durability (mass
losses) of the samples were borogypsum and fly ash. The values of
mass losses for 6, 12 and 18 cycles in optimum conditions were
16.1%, 5.1% and 3.6%, respectively.
Abstract: In this study, the time-dependent behavior of damaged
reinforced concrete shear wall structures strengthened with composite
plates having variable fibers spacing was investigated to analyze their
seismic response. In the analytical formulation, the adherent and the
adhesive layers are all modeled as shear walls, using the mixed Finite
Element Method (FEM). The anisotropic damage model is adopted to
describe the damage extent of the Reinforced Concrete shear walls.
The phenomenon of creep and shrinkage of concrete has been
determined by Eurocode 2. Large earthquakes recorded in Algeria
(El-Asnam and Boumerdes) have been tested to demonstrate the
accuracy of the proposed method. Numerical results are obtained for non-uniform distributions of
carbon fibers in epoxy matrices. The effects of damage extent and the
delay mechanism creep and shrinkage of concrete are highlighted.
Prospects are being studied.
Abstract: The purpose of this study is to propose an effective method to improve frictional coefficient between shoe rubber soles with added glass fibers and the surfaces of icy and snowy road in order to prevent slip-and-fall accidents by the users. The additional fibers into the rubber were uniformly tilted to the perpendicular direction of the frictional surface, where tilting angles were -60, -30, +30, +60, 90 degrees and 0 (as normal specimen), respectively. It was found that parallel arraignment was effective to improve the frictional coefficient when glass fibers were embedded in the shoe rubber, while perpendicular to normal direction of the embedded glass fibers on the shoe surface was also effective to do that once after they were exposed from the shoe rubber with its abrasion. These improvements were explained by the increase of stiffness against the shear deformation of the rubber at critical frictional state and adequate scratching of fibers when fibers were protruded in perpendicular to frictional direction, respectively. Most effective angle of tilting of frictional coefficient between rubber specimens and a stone was perpendicular (= 0 degree) to frictional direction. Combinative modified rubber specimen having 2 layers was fabricated where tilting angle of protruded fibers was 0 degree near the contact surface and tilting angle of embedded fibers was 90 degrees near back surface in thickness direction to further improve the frictional coefficient. Current study suggested that effective arraignments in tilting angle of the added fibers should be applied in designing rubber shoe soles to keep the safeties for users in regions of cold climates.
Abstract: Diets high in processed foods have been found to lack
essential micro-nutrients for optimum human development and
overall health. Some micro-nutrients such as copper (Cu) have been
found to enhance the inflammatory response through its oxidative
functions, thereby having a role in cardiovascular disease, metabolic
syndrome, diabetes and related complications. This research study
was designed to determine if food crops could be bio-fortified with
micro-nutrients by growing sprouts on mineral fortified fiber mats. In
the feasibility study described in this contribution, recycled cellulose
fibers and clay, saturated with either micro-nutrient copper ions or
copper nanoparticles, were converted to a novel mineral-cellulose
fiber carrier of essential micro-nutrient and of antimicrobial
properties. Seeds of Medicago sativa (alfalfa), purchased from a
commercial, organic supplier were germinated on engineered
cellulose fiber mats. After the appearance of the first leaves, the
sprouts were dehydrated and analyzed for Cu content. Nutrient
analysis showed ~2 increase in Cu of the sprouts grown on the fiber
mats with copper particles, and ~4 increase on mats with ionic copper
as compared to the control samples. This study illustrates the
potential for the use of engineered mats as a viable way to increase
the micro-nutrient composition of locally-grown food crops and the
need for additional research to determine the uptake, nutritional
implications and risks of micro-nutrient bio-fortification.
Abstract: Novel wind-lens turbine designs can augment power
output. Vacuum-Assisted Resin Transfer Molding (VARTM) is used
to form large and complex structures from a Carbon Fiber Reinforced
Polymer (CFRP) composite. Typically, wind-lens turbine structures
are fabricated in segments, and then bonded to form the final structure.
This paper introduces five new adhesive joints, divided into two
groups: one is constructed between dry carbon and CFRP fabrics, and
the other is constructed with two dry carbon fibers. All joints and
CFRP fabrics were made in our laboratory using VARTM
manufacturing techniques. Specimens were prepared for tensile testing
to measure joint performance. The results showed that the second
group of joints achieved a higher tensile strength than the first group.
On the other hand, the tensile fracture behavior of the two groups
showed the same pattern of crack originating near the joint ends
followed by crack propagation until fracture.
Abstract: Background: To compare the thinning patterns of the
ganglion cell-inner plexiform layer (GCIPL) and peripapillary retinal
nerve fiber layer (pRNFL) as measured using Cirrus high-definition
optical coherence tomography (HD-OCT) in patients with visual field
(VF) defects that respect the vertical meridian. Methods: Twenty eyes of eleven patients with VF defects that
respect the vertical meridian were enrolled retrospectively. The
thicknesses of the macular GCIPL and pRNFL were measured using
Cirrus HD-OCT. The 5% and 1% thinning area index (TAI) was
calculated as the proportion of abnormally thin sectors at the 5% and
1% probability level within the area corresponding to the affected VF.
The 5% and 1% TAI were compared between the GCIPL and pRNFL
measurements. Results: The color-coded GCIPL deviation map showed a
characteristic vertical thinning pattern of the GCIPL, which is also
seen in the VF of patients with brain lesions. The 5% and 1% TAI
were significantly higher in the GCIPL measurements than in the
pRNFL measurements (all P < 0.01). Conclusions: Macular GCIPL analysis clearly visualized a
characteristic topographic pattern of retinal ganglion cell (RGC) loss
in patients with VF defects that respect the vertical meridian, unlike
pRNFL measurements. Macular GCIPL measurements provide more
valuable information than pRNFL measurements for detecting the
loss of RGCs in patients with retrograde degeneration of the optic
nerve fibers.
Abstract: Polylactic acid (PLA) is the most commercially
available bio-based and biodegradable plastic at present. PLA has
been used in plastic related industries including single-used
containers, disposable and environmentally friendly packaging owing
to its renewability, compostability, biodegradability, and safety.
Although PLA demonstrates reasonably good optical, physical,
mechanical and barrier properties comparable to the existing
petroleum-based plastics, its brittleness and mold shrinkage as well as
its price are the points to be concerned for the production of rigid and
semi-rigid packaging. Blending PLA with other bio-based polymers
including thermoplastic starch (TPS) is an alternative not only to
achieve a complete bio-based plastic, but also to reduce the
brittleness, shrinkage during molding and production cost of the
PLA-based products. TPS is a material produced mainly from starch
which is cheap, renewable, biodegradable, compostable, and nontoxic.
It is commonly prepared by a plasticization of starch under
applying heat and shear force. Although glycerol has been reported as
one of the most plasticizers used for preparing TPS, its migration
caused the surface stickiness of the TPS products. In some cases,
mixed plasticizers or natural fibers have been applied to impede the
retrogradation of starch or reduce the migration of glycerol. The
introduction of fibers into TPS-based materials could reinforce the
polymer matrix as well. Therefore, the objective of the present
research is to study the effect of starch type (i.e. native starch and
phosphate starch), plasticizer type (i.e. glycerol and xylitol with a
weight ratio of glycerol to xylitol of 100:0, 75:25, 50:50, 25:75 and
0:100) and fiber content (i.e. in the range of 1-25 %wt) on properties
of PLA/TPS blend and composite. PLA/TPS blends and composites
were prepared using a twin-screw extruder and then converted into
dumbbell-shaped specimens using an injection molding machine. The
PLA/TPS blends prepared by using phosphate starch showed higher
tensile strength and stiffness than the blends prepared by using native
one. In contrast, the blends from native starch exhibited higher
extensibility and heat distortion temperature (HDT) than those from
the modified starch. Increasing xylitol content resulted in enhanced
tensile strength, stiffness and water resistance, but decreased
extensibility and HDT of the PLA/TPS blend. Tensile properties and
hydrophobicity of the blend could be improved by incorporating
silane treated-jute fibers.
Abstract: Natural fibers are used in polymer composites to
improve mechanical properties to replace inorganic reinforcing
agents produced by non-renewable resources. The present study
investigates the tensile and flexural behaviors of palm fibers-high
density polyethylene (HDPE) composite as a function of volume
fraction. The surface of the fibers was treated by mercerization
treatments to improve the wetting behavior of the apolar HDPE. The
treatment characterization was obtained by scanning electron
microscopy, X-Ray diffraction and infrared spectroscopy. Results
evidences that a good adhesion interfacial between fibers-matrix
caused an increase strength and modulus flexural as well as tensile
strength in the modified fibers/HDPE composites when compared to
the pure HDPE and untreated fibers reinforced composites.
Abstract: The seriously damaged structures during earthquakes
show the need and importance of design of reinforced concrete
structures with high ductility. Reinforced concrete beam-column
joints have an important function in all structures. Under seismic
excitation, the beam column joint region is subjected to horizontal
and vertical shear forces whose magnitude is many times higher than
the adjacent beam and column. Strength and ductility of structures
depends mainly on proper detailing of the reinforcement in beamcolumn
joints and the old structures were found ductility deficient.
DSP materials are obtained by using high quantities of super
plasticizers and high volumes of micro silica. In the case of High
Performance Densified Small Particle Concrete (HPDSPC), since
concrete is dense even at the micro-structure level, tensile strain
would be much higher than that of the conventional SFRC, SIFCON
& SIMCON. This in turn will improve cracking behaviour, ductility
and energy absorption capacity of composites in addition to
durability. The fine fibers used in our mix are 0.3mm diameter and 10
mm which can be easily placed with high percentage. These fibers
easily transfer stresses and act as a composite concrete unit to take up
extremely high loads with high compressive strength. HPDSPC
placed in the beam column joints helps in safety of human life due to
prolonged failure.
Abstract: The effect of carbon nanofibers (CNFs) on the
electrical properties of Poly(vinylidene fluoride-hexafluoropropylene)
(P(VdF-HFP)) based gel polymer electrolytes has been investigated
in the present work. The length and diameter ranges of CNFs used in
the present work are 5-50 μm and 200-600 nm respectively. The
nanocomposite gel polymer electrolytes have been synthesized by
solution casting technique with varying CNFs content in terms of
weight percentage. Electrochemical impedance analysis demonstrates
that the reinforcement of carbon nanofibers significantly enhances the
ionic conductivity of the polymer electrolyte. The decrease of
crystallinity of P(VdF-HFP) due the addition of CNFs has been
confirmed by X-ray diffraction (XRD). The interaction of CNFs with
various constituents of nanocomposite gel polymer electrolytes has
been assessed by Fourier Transform Infrared (FTIR) spectroscopy.
Moreover CNFs added gel polymer electrolytes offer superior
thermal stability as compared to that of CNFs free electrolytes as
confirmed by Thermogravimetric analysis (TGA).
Abstract: This study intends to show the influence of the
hydrolytic degradation on the properties of the e-PTFE/NOMEX®
membranes used in fire-protective clothing. The modification of
water vapour permeability, morphology and chemical structure was
examined by MOCON Permatran, electron microscopy scanning
(SEM), and ATR-FTIR, respectively. A decrease in permeability to
water vapour of the aged samples was observed following closure of
transpiration pores. Analysis of fiber morphology indicates the
appearance of defects at the fibers surface with the presence of micro
cavities. ATR-FTIR analysis reveals the presence of a new absorption
band attributed to carboxylic acid terminal groups generated during
the amide bond hydrolysis.
Abstract: Natural dyes are gaining interest due their expected
low risk to human health and to the environment. In this study, the
wash fastness of a natural coloring matter from the liquid waste
produced in the steam treatment of eucalyptus wood in textile fabrics
was investigated. Specifically, eucalyptus wood extract was used to
dye cotton, nylon and wool in an exhaust dyeing process without the
addition of the traditional mordanting agents and then submitted to
wash fastness analysis. The resulting dyed fabrics were evaluated for
color fastness. It was found that wash fastness of dyed fabrics was
very good to cotton and excellent to nylon and wool.
Abstract: Concrete is strong in compression however weak in
tension. The tensile strength as well as ductile property of concrete
could be improved by addition of short dispersed fibers. Polyethylene
terephthalate (PET) fiber obtained from hand cutting or mechanical
slitting of plastic sheets generally used as discrete reinforcement in
substitution of steel fiber. PET fiber obtained from the former process
is in the form of straight slit sheet pattern that impart weaker
mechanical bonding behavior in the concrete matrix. To improve the
limitation of straight slit sheet fiber the present study considered two
additional geometry of fiber namely (a) flattened end slit sheet and
(b) deformed slit sheet. The mix for plain concrete was design for a
compressive strength of 25 MPa at 28 days curing time with a watercement
ratio of 0.5. Cylindrical and beam specimens with 0.5% fibers
volume fraction and without fibers were cast to investigate the
influence of geometry on the mechanical properties of concrete. The
performance parameters mainly studied include flexural strength,
splitting tensile strength, compressive strength and ultrasonic pulse
velocity (UPV). Test results show that geometry of fiber has a
marginal effect on the workability of concrete. However, it plays a
significant role in achieving a good compressive and tensile strength
of concrete. Further, significant improvement in term of flexural and
energy dissipation capacity were observed from other fibers as
compared to the straight slit sheet pattern. Also, the inclusion of PET
fiber improved the ability in absorbing energy in the post-cracking
state of the specimen as well as no significant porous structures.