Abstract: To reduce the carbon dioxide emission into the
atmosphere, adsorption is believed to be one of the most attractive
methods for post-combustion treatment of flue gas. In this work,
activated carbon (AC) was modified by polyethylenimine (PEI) via
impregnation in order to enhance CO2 adsorption capacity. The
adsorbents were produced at 0.04, 0.16, 0.22, 0.25, and 0.28 wt%
PEI/AC. The adsorption was carried out at a temperature range from
30 °C to 75 °C and five different gas pressures up to 1 atm. TG-DTA,
FT-IR, UV-visible spectrometer, and BET were used to characterize
the adsorbents. Effects of PEI loading on the AC for the CO2
adsorption were investigated. Effectiveness of the adsorbents on the
CO2 adsorption including CO2 adsorption capacity and adsorption
temperature was also investigated. Adsorption capacities of CO2 were
enhanced with the increase in the amount of PEI from 0.04 to 0.22
wt% PEI before the capacities decreased onwards from0.25 wt% PEI
at 30 °C. The 0.22 wt% PEI/AC showed higher adsorption capacity
than the AC for adsorption at 50 °C to 75 °C.
Abstract: Due to the environmental and price issues of current
energy crisis, scientists and technologists around the globe are
intensively searching for new environmentally less-impact form of
clean energy that will reduce the high dependency on fossil fuel.
Particularly hydrogen can be produced from biomass via thermochemical
processes including pyrolysis and gasification due to the
economic advantage and can be further enhanced through in-situ
carbon dioxide removal using calcium oxide. This work focuses on
the synthesis and development of the flowsheet for the enhanced
biomass gasification process in PETRONAS-s iCON process
simulation software. This hydrogen prediction model is conducted at
operating temperature between 600 to 1000oC at atmospheric
pressure. Effects of temperature, steam-to-biomass ratio and
adsorbent-to-biomass ratio were studied and 0.85 mol fraction of
hydrogen is predicted in the product gas. Comparisons of the results
are also made with experimental data from literature. The
preliminary economic potential of developed system is RM 12.57 x
106 which equivalent to USD 3.77 x 106 annually shows economic
viability of this process.
Abstract: This paper presents the effects of migration at the
urban sites with an integrated model under the sustainable local
development policies for the conservation and revitalization of the
site areas as a case at Reyhan heritage site in Bursa. It is known as
the “City of immigrants" because of its richness of cultural plurality.
The city has always regarded the dynamic impact of immigration as a
positive contribution. As a result of this situation, the city created the
earliest urbanization practices: being the first capital city of the
Ottoman Empire. Bursa created the first modern movement practices
and set the first Organized Industrial Zone. The most important aim
of the study is to be offer a model for the similar areas with the
context of conservation and revitalization of the historical areas,
subjected to the local integrated sustainable development policies of
local goverments.
Abstract: Macrobenthos distribution along the coastal waters of
Penang National Park was studid to estimate the effect of different
environmental parameters at three stations, during six sampling
months, from June 2010 to April 2011. The aim of this survey was to
investigate different environment stress over soft bottom polychaete
community along Teluk Ketapang and Pantai Acheh (Penang
National Park) over a year period. Variations in the polychaete
community were evaluated using univariate and multivariate
methods. A total of 604 individuals were examined which was
grouped into 23 families. Family Nereidae was the most abundant
(22.68%), followed by Spionidae (22.02%), Hesionidae (12.58%),
Nephtylidae (9.27%) and Orbiniidae (8.61%). It is noticeable that
good results can only be obtained on the basis of good taxonomic
resolution. The maximum Shannon-Wiener diversity (H'=2.16) was
recorded at distance 200m and 1200m (August 2010) in Teluk
Ketapang and lowest value of diversity was found at distance 1200m
(December 2010) in Teluk Ketapang.
Abstract: Fixed-bed slow pyrolysis experiments of rice husk
have been conducted to determine the effect of pyrolysis
temperature, heating rate, particle size and reactor length on the
pyrolysis product yields. Pyrolysis experiments were performed at
pyrolysis temperature between 400 and 600°C with a constant
heating rate of 60°C/min and particle sizes of 0.60-1.18 mm. The
optimum process conditions for maximum liquid yield from the rice
husk pyrolysis in a fixed bed reactor were also identified. The highest
liquid yield was obtained at a pyrolysis temperature of 500°C,
particle size of
1.18-1.80 mm, with a heating rate of 60°C/min in a 300 mm length
reactor. The obtained yield of, liquid, gas and solid were found be in
the range of 22.57-31.78 %, 27.75-42.26 % and 34.17-42.52 % (all
weight basics) respectively at different pyrolysis conditions. The
results indicate that the effects of pyrolysis temperature and particle
size on the pyrolysis yield are more significant than that of heating
rate and reactor length. The functional groups and chemical
compositions present in the liquid obtained at optimum conditions
were identified by Fourier Transform-Infrared (FT-IR) spectroscopy
and Gas Chromatography/ Mass Spectroscopy (GC/MS) analysis
respectively.
Abstract: Steel corrosion in concrete is considered as a main
engineering problems for many countries and lots of expenses has been paid for their repair and maintenance annually. This problem
may occur in all engineering structures whether in coastal and offshore or other areas. Hence, concrete structures should be able to
withstand corrosion factors existing in water or soil. Reinforcing
steel corrosion enhancement can be measured by use of concrete
electrical resistance; and maintaining high electric resistivity in concrete is necessary for steel corrosion prevention. Lots of studies
devoted to different aspects of the subjects worldwide. In this paper, an evaluation of the effects of W/C ratio, cementitious materials, and
percent increase in silica fume were investigated on electric resistivity of high strength concrete. To do that, sixteen mix design
with one aggregate grading was planned. Five of them had varying amount of W/C ratio and other eleven mixes was prepared with
constant W/C ratio but different amount of cementitious materials.
Silica fume and super plasticizer were used with different proportions
in all specimens. Specimens were tested after moist curing for 28 days. A total of 80 cube specimens (50 mm) were tested for concrete
electrical resistance. Results show that concrete electric resistivity can be increased with increasing amount of cementitious materials
and silica fume.
Abstract: A number of routing algorithms based on learning
automata technique have been proposed for communication
networks. How ever, there has been little work on the effects of
variation of graph scarcity on the performance of these algorithms. In
this paper, a comprehensive study is launched to investigate the
performance of LASPA, the first learning automata based solution to
the dynamic shortest path routing, across different graph structures
with varying scarcities. The sensitivity of three main performance
parameters of the algorithm, being average number of processed
nodes, scanned edges and average time per update, to variation in
graph scarcity is reported. Simulation results indicate that the LASPA
algorithm can adapt well to the scarcity variation in graph structure
and gives much better outputs than the existing dynamic and fixed
algorithms in terms of performance criteria.
Abstract: This research investigates the effects of the opening
shape and location on the structural behavior of reinforced concrete
deep beam with openings, while keeping the opening size unchanged.
The software ANSYS 12.1 is used to handle the nonlinear finite
element analysis. The ultimate strength of reinforced concrete deep
beam with opening obtained by ANSYS 12.1 shows fair agreement
with the experimental results, with a difference of no more than 20%. The present work concludes that the opening location has much more effect on the structural strength than the opening shape. It was
concluded that placing the openings near the upper corners of the
deep beam may double the strength, and the use of a rectangular
narrow opening, with the long sides in the horizontal direction, can save up to 40% of structural strength of the deep beam.
Abstract: Irradiation is considered one of the most efficient technological processes for the reduction of microorganisms in food. It can be used to improve the safety of food products, and to extend their shelf lives. The aim of this study was to evaluate the effects of gamma irradiation for improvement of saffron shelf life. Samples were treated with 0 (none irradiated), 1.0, 2.0, 3.0 and 4.0 kGy of gamma irradiation and held for 2 months. The control and irradiated samples were underwent microbial analysis, chemical characteristics and sensory evaluation at 30 days intervals. Microbial analysis indicated that irradiation had a significant effect (P < 0.05) on the reduction of microbial loads. There was no significant difference in sensory quality and chemical characteristics during storage in saffron.
Abstract: Knee joint forces are available by in vivo measurement
using an instrumented knee prosthesis for small to moderate knee
flexion but not for high flexion yet. We created a 2D mathematical
model of the lower limb incorporating several new features such as a
patello-femoral mechanism, a thigh-calf contact at high knee flexion
and co-contracting muscles' force ratio, then used it to determine knee
joint forces arising from high knee flexions in four kneeling
conditions: rising with legs in parallel, with one foot forward, with or
without arm use. With arms used, the maximum values of knee joint
force decreased to about 60% of those with arms not used. When rising
with one foot forward, if arms are not used, the forward leg sustains a
force as large as that sustained when rising with legs parallel.
Abstract: Semiconductor materials with coatings have a wide range of applications in MEMS and NEMS. This work uses transfermatrix method for calculating the radiative properties. Dopped silicon is used and the coherent formulation is applied. The Drude model for the optical constants of doped silicon is employed. Results showed that for the visible wavelengths, more emittance occurs in greater concentrations and the reflectance decreases as the concentration increases. In these wavelengths, transmittance is negligible. Donars and acceptors act similar in visible wavelengths. The effect of wave interference can be understood by plotting the spectral properties such as reflectance or transmittance of a thin dielectric film versus the film thickness and analyzing the oscillations of properties due to constructive and destructive interferences. But this effect has not been shown at visible wavelengths. At room temperature, the scattering process is dominated by lattice scattering for lightly doped silicon, and the impurity scattering becomes important for heavily doped silicon when the dopant concentration exceeds1018cm-3 .
Abstract: Radial flow reactor was focused for large scale
methanol synthesis and in which the heat transfer type was cross-flow.
The effects of operating conditions including the reactor inlet air
temperature, the heating pipe temperature and the air flow rate on the
cross-flow heat transfer was investigated and the results showed that
the temperature profile of the area in front of the heating pipe was
slightly affected by all the operating conditions. The main area whose
temperature profile was influenced was the area behind the heating
pipe. The heat transfer direction according to the air flow directions. In
order to provide the basis for radial flow reactor design calculation, the
dimensionless number group method was used for data fitting of the
bed effective thermal conductivity and the wall heat transfer
coefficient which was calculated by the mathematical model with the
product of Reynolds number and Prandtl number. The comparison of
experimental data and calculated value showed that the calculated
value fit the experimental data very well and the formulas could be
used for reactor designing calculation.
Abstract: Contamination of aromatic compounds in water can
cause severe long-lasting effects not only for biotic organism but also
on human health. Several alternative technologies for remediation of
polluted water have been attempted. One of these is adsorption
process of aromatic compounds by using organic modified clay
mineral. Porous structure of clay is potential properties for molecular
adsorptivity and it can be increased by immobilizing hydrophobic
structure to attract organic compounds. In this work natural
montmorillonite were modified with cetyltrimethylammonium
(CTMA+) and was evaluated for use as adsorbents of aromatic
compounds: benzene, toluene, and 2-chloro phenol in its single and
multicomponent solution by ethanol:water solvent. Preparation of
CTMA-montmorillonite was conducted by simple ion exchange
procedure and characterization was conducted by using x-day
diffraction (XRD), Fourier-transform infra red (FTIR) and gas
sorption analysis. The influence of structural modification of
montmorillonite on its adsorption capacity and adsorption affinity of
organic compound were studied. It was shown that adsorptivity of
montmorillonite was increased by modification associated with
arrangements of CTMA+ in the structure even the specific surface
area of modified montmorillonite was lower than raw
montmorillonite. Adsorption rate indicated that material has affinity
to adsorb compound by following order: benzene> toluene > 2-chloro
phenol. The adsorption isotherms of benzene and toluene showed 1st
order adsorption kinetic indicating a partition phenomenon of
compounds between the aqueous and organophilic CTMAmontmorillonite.
Abstract: The pavement constructions on soft and expansive soils are not durable and unable to sustain heavy traffic loading. As a result, pavement failures and settlement problems will occur very often even under light traffic loading due to cyclic and rolling effects. Geotechnical engineers have dwelled deeply into this matter, and adopt various methods to improve the engineering characteristics of soft fine-grained soils and expansive soils. The problematic soils are either replaced by good and better quality material or treated by using chemical stabilization with various binding materials. Increased the strength and durability are also the part of the sustainability drive to reduce the environment footprint of the built environment by the efficient use of resources and waste recycle materials. This paper presents a series of laboratory tests and evaluates the effect of cement and fly ash on the strength and drainage characteristics of soil in Miri. The tests were performed at different percentages of cement and fly ash by dry weight of soil. Additional tests were also performed on soils treated with the combinations of fly ash with cement and lime. The results of this study indicate an increase in unconfined compression strength and a decrease in hydraulic conductivity of the treated soil.
Abstract: Seismic design may require non-conventional
concept, due to the fact that the stiffness and layout of the structure
have a great effect on the overall structural behaviour, on the seismic
load intensity as well as on the internal force distribution. To find an
economical and optimal structural configuration the key issue is the
optimal design of the lateral load resisting system. This paper focuses
on the optimal design of regular, concentric braced frame (CBF)
multi-storey steel building structures. The optimal configurations are
determined by a numerical method using genetic algorithm approach,
developed by the authors. Aim is to find structural configurations
with minimum structural cost. The design constraints of objective
function are assigned in accordance with Eurocode 3 and Eurocode 8
guidelines. In this paper the results are presented for various building
geometries, different seismic intensities, and levels of energy
dissipation.
Abstract: The primary cause of Total Hip Replacement (THR)
failure for younger patients is aseptic loosening. This complication is
twice more likely to happen in acetabular cup than in femoral stem.
Excessive micromotion between bone and implant will cause
loosening and it depends in patient activities, age and bone. In this
project, the effects of different metal back design of press fit on
osseointegration of the acetabular cup are carried out. Commercial
acetabular cup designs, namely Spiked, Superfix and Quadrafix are
modelled and analyzed using commercial finite element software.
The diameter of acetabular cup is based on the diameter of acetabular
rim to make sure the component fit to the acetabular cavity. A new
design of acetabular cup are proposed and analyzed to get better
osseointegration between the bones and implant interface. Results
shows that the proposed acetabular cup designs are more stable
compared to other designs with respect to stress and displacement
aspects.
Abstract: The purpose of this study was to explore the complex
flow structure a novel active-type micromixer that based on concept of
Wankle-type rotor. The characteristics of this micromixer are two
folds; a rapid mixing of reagents in a limited space due to the
generation of multiple vortices and a graduate increment in dynamic
pressure as the mixed reagents is delivered to the output ports.
Present micro-mixer is consisted of a rotor with shape of triangle
column, a blending chamber and several inlet and outlet ports. The
geometry of blending chamber is designed to make the rotor can be
freely internal rotated with a constant eccentricity ratio. When the
shape of the blending chamber and the rotor are fixed, the effects of
rotating speed of rotor and the relative locations of ports on the mixing
efficiency are numerical studied. The governing equations are
unsteady, two-dimensional incompressible Navier-Stokes equation
and the working fluid is the water. The species concentration equation
is also solved to reveal the mass transfer process of reagents in various
regions then to evaluate the mixing efficiency.
The dynamic mesh technique was implemented to model the
dynamic volume shrinkage and expansion of three individual
sub-regions of blending chamber when the rotor conducted a complete
rotating cycle. Six types of ports configuration on the mixing
efficiency are considered in a range of Reynolds number from 10 to
300. The rapid mixing process was accomplished with the multiple
vortex structures within a tiny space due to the equilibrium of shear
force, viscous force and inertial force. Results showed that the highest
mixing efficiency could be attained in the following conditions: two
inlet and two outlet ports configuration, that is an included angle of 60
degrees between two inlets and an included angle of 120 degrees
between inlet and outlet ports when Re=10.
Abstract: The selection of parents and breeding strategies for
the successful maize hybrid production will be facilitated by
heterotic groupings of parental lines and determination of combining
abilities of them. Fourteen maize inbred lines, used in maize breeding
programs in Iran, were crossed in a diallel mating design. The 91 F1
hybrids and the 14 parental lines were studied during two years at
four locations of Iran for investigation of combining ability of
gentypes for grain yield and to determine heterotic patterns among
germplasm sources, using both, the Griffing-s method and the biplot
approach for diallel analysis. The graphical representation offered by
biplot analysis allowed a rapid and effective overview of general
combining ability (GCA) and specific combining ability (SCA)
effects of the inbred lines, their performance in crosses, as well as
grouping patterns of similar genotypes. GCA and SCA effects were
significant for grain yield (GY). Based on significant positive GCA
effects, the lines derived from LSC could be used as parent in crosses
to increase GY. The maximum best- parent heterosis values and
highest SCA effects resulted from crosses B73 × MO17 and A679 ×
MO17 for GY. The best heterotic patterns were LSC × RYD, which
would be potentially useful in maize breeding programs to obtain
high-yielding hybrids in the same climate of Iran.
Abstract: In this paper, we propose a Perceptually Optimized Embedded ZeroTree Image Coder (POEZIC) that introduces a perceptual weighting to wavelet transform coefficients prior to control SPIHT encoding algorithm in order to reach a targeted bit rate with a perceptual quality improvement with respect to the coding quality obtained using the SPIHT algorithm only. The paper also, introduces a new objective quality metric based on a Psychovisual model that integrates the properties of the HVS that plays an important role in our POEZIC quality assessment. Our POEZIC coder is based on a vision model that incorporates various masking effects of human visual system HVS perception. Thus, our coder weights the wavelet coefficients based on that model and attempts to increase the perceptual quality for a given bit rate and observation distance. The perceptual weights for all wavelet subbands are computed based on 1) luminance masking and Contrast masking, 2) the contrast sensitivity function CSF to achieve the perceptual decomposition weighting, 3) the Wavelet Error Sensitivity WES used to reduce the perceptual quantization errors. The new perceptually optimized codec has the same complexity as the original SPIHT techniques. However, the experiments results show that our coder demonstrates very good performance in terms of quality measurement.
Abstract: Bones are dynamic and responsive organs, they
regulate their strength and mass according to the loads which they are subjected. Because, the Wnt/β-catenin pathway has profound
effects on the regulation of bone mass, we hypothesized that mechanical loading of bone cells stimulates Wnt/β-catenin signaling, which results in the generation of new bone mass.
Mechanical loading triggers the secretion of the Wnt molecule, which after binding to transmembrane proteins, causes GSK-3β (Glycogen synthase kinase 3 beta) to cease the phosphorylation of β-catenin. β-catenin accumulation in the cytoplasm, followed by its
transport into the nucleus, binding to transcription factors (TCF/LEF)
that initiate transcription of genes related to bone formation. To test this hypothesis, we used TOPGAL (Tcf Optimal Promoter
β-galactosidase) mice in an experiment in which cyclic loads were
applied to the forearm. TOPGAL mice are reporters for cells effected
by the Wnt/β-catenin signaling pathway. TOPGAL mice are genetically engineered mice in which transcriptional activation of β-
catenin, results in the production of an enzyme, β-galactosidase. The
presence of this enzyme allows us to localize transcriptional
activation of β-catenin to individual cells, thereby, allowing us to quantify the effects that mechanical loading has on the Wnt/β-catenin pathway and new bone formation. The ulnae of loaded TOPGAL
mice were excised and transverse slices along different parts of the
ulnar shaft were assayed for the presence of β-galactosidase.
Our results indicate that loading increases β-catenin transcriptional
activity in regions where this pathway is already primed (i.e. where basal activity is already higher) in a load magnitude dependent
manner. Further experiments are needed to determine the temporal and spatial activation of this signaling in relation to bone formation.