Abstract: The hydrogen peroxide treatment was able to
remediate chlorophenols, polycyclic aromatic hydrocarbons, diesel
and transformer oil contaminated soil. Chemical treatment of
contaminants adsorbed in peat resulted in lower contaminants-
removal and required higher addition of chemicals than the treatment
of contaminants in sand. The hydrogen peroxide treatment was found
to be feasible for soil remediation at natural soil pH. Contaminants in
soil could degrade with the addition of hydrogen peroxide only
indicating the ability of transition metals ions and minerals of these
metals presented in soil to catalyse the reaction of hydrogen peroxide
decomposition.
Abstract: Transesterification of candlenut (aleurites moluccana)
oil with methanol using potassium hydroxide as catalyst was
studied. The objective of the present investigation was to produce
the methyl ester for use as biodiesel. The operation variables
employed were methanol to oil molar ratio (3:1 – 9:1), catalyst
concentration (0.50 – 1.5 %) and temperature (303 – 343K). Oil
volume of 150 mL, reaction time of 75 min were fixed as common
parameters in all the experiments. The concentration of methyl ester
was evaluated by mass balance of free glycerol formed which was
analyzed by using periodic acid. The optimal triglyceride conversion
was attained by using methanol to oil ratio of 6:1, potassium
hydroxide as catalyst was of 1%, at room temperature. Methyl ester
formed was characterized by its density, viscosity, cloud and pour
points. The biodiesel properties had properties similar to those of
diesel oil, except for the viscosity that was higher.
Abstract: Biodiesel production with used frying by
transesterification reaction with methanol, using a commercial
kaolinite thermally-activated solid acid catalyst was investigated.
The surface area, the average pore diameter and pore volume of the
kaolinite catalyst were 10 m2/g, 13.0 nm and 30 mm3/g, respectively.
The optimal conditions for the transesterification reaction were
determined to be oil/methanol, in a molar ratio 1:31, temperature 160
ºC and catalyst concentration of 3% (w/w). The yield of fatty acids
methyl esters (FAME) was 92.4% after 2 h of reaction. This method
of preparation of biodiesel can be a positive alternative for utilizing
used frying corn oil for feedstock of biodiesel combined with the
inexpensive catalyst.
Abstract: Hydrogenated biodiesel is one of the most promising
renewable fuels. It has many advantages over conventional biodiesel,
including higher cetane number, higher heating value, lower
viscosity, and lower corrosiveness due to its absence of oxygen.
From previous work, Pd/TiO2 gave high conversion and selectivity in
hydrogenated biodiesel. In this work, the effect of biomass feedstocks
(i.e. beef fat, chicken fat, pork fat, and jatropha oil) on the production
of hydrogenated biodiesel over Pd/TiO2 has been studied. Biomass
feedstocks were analyzed by ICP-OES (inductively coupled plasma
optical emission spectrometry) to identify the content of impurities
(i.e. P, K, Ca, Na, and Mg). The deoxygenation catalyst, Pd/TiO2,
was prepared by incipient wetness impregnation (IWI) and tested in a
continuous flow packed-bed reactor at 500 psig, 325°C, H2/feed
molar ratio of 30, and LHSV of 4 h-1 for its catalytic activity and
selectivity in hydrodeoxygenation. All feedstocks gave high
selectivity in diesel specification range hydrocarbons and the main
hydrocarbons were n-pentadecane (n-C15) and n-heptadecane (n-
C17), resulting from the decarbonylation/decarboxylation reaction.
Intermediates such as oleic acid, stearic acid, palmitic acid, and esters
were also detected in minor amount. The conversion of triglycerides
in jatropha oil is higher than those of chicken fat, pork fat, and beef
fat, respectively. The higher concentration of metal impurities in
feedstock, the lower conversion of feedstock.
Abstract: Monoculture and mixed cultures of microalgae and
the oleaginous yeast for microbial oil productions were investigated
using sugarcane juice as carbon substrate. The monoculture of yeast
Torulaspora maleeae Y30, Torulaspora globosa YU5/2 grew faster
than that of microalgae Chlorella sp. KKU-S2. In monoculture of T.
maleeae Y30, a biomass of 8.267g/L with lipid yield of 0.920g/L
were obtained, while 8.333g/L of biomass with lipid yield of
1.141g/L were obtained for monoculture of T. globosa YU5/2. A
biomass of 1.933g/L with lipid yield of 0.052g/L was found for
monoculture of Chlorella sp. KKU-S2. The biomass concentration in
the mixed culture of the oleaginous yeast with microalgae increased
faster and was higher compared with that in the monocultures. A
biomass of 8.733g/L with lipid yield of 1.564g/L was obtained for a
mixed culture of T. maleeae Y30 with Chlorella sp. KKU-S2, while
8.010g/L of biomass with lipid yield of 2.424g/L was found for
mixed culture of T. globosa YU5/2 with Chlorella sp. KKU-S2.
Maximum cell yield coefficient (YX/S, g/L) was found of 0.323 in
monoculture of Chlorella sp. KKU-S2 but low level of both specific
yield of lipid (YP/X, g lipid/g cells) of 0.027 and volumetric lipid
production rate (QP, g/L/d) of 0.003 were observed. While, maximum
YP/X (0.303), QP (0.105) and maximum process product yield (YP/S,
0.061) were obtained in mixed culture of T. globosa YU5/2 with
Chlorella sp. KKU-S2. The results obtained from the study shows
that mixed culture of yeast with microalgae is a desirable cultivation
process for microbial oil production.
Abstract: The mixture formation prior to the ignition process
plays as a key element in the diesel combustion. Parametric studies of
mixture formation and ignition process in various injection parameter
has received considerable attention in potential for reducing
emissions. Purpose of this study is to clarify the effects of injection
pressure on mixture formation and ignition especially during ignition
delay period, which have to be significantly influences throughout the
combustion process and exhaust emissions. This study investigated
the effects of injection pressure on diesel combustion fundamentally
using rapid compression machine. The detail behavior of mixture
formation during ignition delay period was investigated using the
schlieren photography system with a high speed camera. This method
can capture spray evaporation, spray interference, mixture formation
and flame development clearly with real images. Ignition process and
flame development were investigated by direct photography method
using a light sensitive high-speed color digital video camera. The
injection pressure and air motion are important variable that strongly
affect to the fuel evaporation, endothermic and prolysis process
during ignition delay. An increased injection pressure makes spray tip
penetration longer and promotes a greater amount of fuel-air mixing
occurs during ignition delay. A greater quantity of fuel prepared
during ignition delay period thus predominantly promotes more rapid
heat release.
Abstract: A long-term campaign for monitoring the
concentration of atmospheric Particulate Matter (PM) was conducted
at multiple sites located in the center and suburbs of the Tokyo
Metropolitan Area in Japan. The concentration of fine PM has shown a
declining trend over the last two decades. A positive matrix
factorization model elucidated that the contribution of combustion
sources was drastically reduced. In Japan, the regulations on vehicle
exhaust emissions were phased in and gradually tightened over the last
two decades, which has triggered a notable reduction in PM emissions
from automobiles and has contributed to the mitigation of the problem
of fine PM pollution.
Abstract: Compared to oil production from microorganisms, little work has been performed for mixed culture of microalgae and yeast. In this article it is aimed to show high oil accumulation potential of mixed culture of microalgae Chlorella sp. KKU-S2 and oleaginous yeast Torulaspora maleeae Y30 using sugarcane molasses as substrate. The monoculture of T. maleeae Y30 grew faster than that of microalgae Chlorella sp. KKU-S2. In monoculture of yeast, a biomass of 6.4g/L with specific growth rate (m) of 0.265 (1/d) and lipid yield of 0.466g/L were obtained, while 2.53g/L of biomass with m of 0.133 (1/d) and lipid yield of 0.132g/L were obtained for monoculture of Chlorella sp. KKU-S2. The biomass concentration in the mixed culture of T. maleeae Y30 with Chlorella sp. KKU-S2 increased faster and was higher compared with that in the monoculture and mixed culture of microalgae. In mixed culture of microalgae Chlorella sp. KKU-S2 and C. vulgaris TISTR8580, a biomass of 3.47g/L and lipid yield of 0.123 g/L were obtained. In mixed culture of T. maleeae Y30 with Chlorella sp. KKU-S2, a maximum biomass of 7.33 g/L and lipid yield of 0.808g/L were obtained. Maximum cell yield coefficient (YX/S, 0.229g/L), specific yield of lipid (YP/X, 0.11g lipid/g cells) and volumetric lipid production rate (QP, 0.115 g/L/d) were obtained in mixed culture of yeast and microalgae. Clearly, T. maleeae Y30 and Chlorella sp. KKU-S2 use sugarcane molasses as organic nutrients efficiently in mixed culture under mixotrophic growth. The biomass productivity and lipid yield are notably enhanced in comparison with monoculture.
Abstract: The rapidly increasing costs of power line extensions
and fossil fuel, combined with the desire to reduce carbon dioxide
emissions pushed the development of hybrid power system suited for
remote locations, the purpose in mind being that of autonomous local
power systems. The paper presents the suggested solution for a “high
penetration" hybrid power system, it being determined by the
location of the settlement and its “zero policy" on carbon dioxide
emissions. The paper focuses on the technical solution and the power
flow management algorithm of the system, taking into consideration
local conditions of development.
Abstract: The conventional production of biodiesel from crude
palm oil which contains large amounts of free fatty acids in the
presence of a homogeneous base catalyst confronts the problems of
soap formation and very low yield of biodiesel. To overcome these
problems, free fatty acids must be esterified to their esters in the
presence of an acid catalyst prior to alkaline-catalyzed
transesterification. Sulfated metal oxides are a promising group of
catalysts due to their very high acidity. In this research, aluminadoped
sulfated tin oxide (SO4
2-/Al2O3-SnO2) catalysts were prepared
and used for esterification of free fatty acids in crude palm oil in a
batch reactor. The SO4
2-/Al2O3-SnO2 catalysts were prepared from
different Al precursors. The results showed that different Al
precursors gave different activities of the SO4
2-/Al2O3-SnO2 catalysts.
The esterification of free fatty acids in crude palm oil with methanol
in the presence of SO4
2-/Al2O3-SnO2 catalysts followed first-order
kinetics.
Abstract: The increased use of biodiesel implies variations on both greenhouse gases and air pollutant emissions. Some studies point out that the use of biodiesel blends on diesel can help in controlling air pollution and promote a reduction of CO2 emissions. Reductions on PM, SO2, VOC and CO emissions are also expected, however NOx emissions may increase, which may potentiate O3 formation. This work aims to assess the impact of the biodiesel use on air quality, through a numerical modeling study, taking the Northern region of Portugal as a case study. The emission scenarios are focused on 2008 (baseline year) and 2020 (target year of Renewable Energy Directive-RED) and on three biodiesel blends (B0, B10 and B20). In a general way the use of biodiesel by 2020 will reduce the CO2 and air pollutants emissions in the Northern Portugal, improving air quality. However it will be in a very small extension.
Abstract: Transesterified vegetable oils (biodiesel) are promising alternative fuel for diesel engines. Used vegetable oils are disposed from restaurants in large quantities. But higher viscosity restricts their direct use in diesel engines. In this study, used cooking oil was dehydrated and then transesterified using an alkaline catalyst. The combustion, performance and emission characteristics of Used Cooking oil Methyl Ester (UCME) and its blends with diesel oil are analysed in a direct injection C.I. engine. The fuel properties and the combustion characteristics of UCME are found to be similar to those of diesel. A minor decrease in thermal efficiency with significant improvement in reduction of particulates, carbon monoxide and unburnt hydrocarbons is observed compared to diesel. The use of transesterified used cooking oil and its blends as fuel for diesel engines will reduce dependence on fossil fuels and also decrease considerably the environmental pollution.
Abstract: The Bangalore City is facing the acute problem of
pollution in the atmosphere due to the heavy increase in the traffic
and developmental activities in recent years. The present study is an
attempt in the direction to assess trend of the ambient air quality
status of three stations, viz., AMCO Batteries Factory, Mysore Road,
GRAPHITE INDIA FACTORY, KHB Industrial Area, Whitefield
and Ananda Rao Circle, Gandhinagar with respect to some of the
major criteria pollutants such as Total Suspended particular matter
(SPM), Oxides of nitrogen (NOx), and Oxides of sulphur (SO2). The
sites are representative of various kinds of growths viz., commercial,
residential and industrial, prevailing in Bangalore, which are
contributing to air pollution. The concentration of Sulphur Dioxide
(SO2) at all locations showed a falling trend due to use of refined
petrol and diesel in the recent years. The concentration of Oxides of
nitrogen (NOx) showed an increasing trend but was within the
permissible limits. The concentration of the Suspended particular
matter (SPM) showed the mixed trend. The correlation between
model and observed values is found to vary from 0.4 to 0.7 for SO2,
0.45 to 0.65 for NOx and 0.4 to 0.6 for SPM. About 80% of data is
observed to fall within the error band of ±50%. Forecast test for the
best fit models showed the same trend as actual values in most of the
cases. However, the deviation observed in few cases could be
attributed to change in quality of petro products, increase in the
volume of traffic, introduction of LPG as fuel in many types of
automobiles, poor condition of roads, prevailing meteorological
conditions, etc.
Abstract: The increased number of automobiles in recent years
has resulted in great demand for fossil fuel. This has led to the
development of automobile by using alternative fuels which include
gaseous fuels, biofuels and vegetables oils as fuel. Energy from
biomass and more specific bio-diesel is one of the opportunities that
could cover the future demand of fossil fuel shortage. Biomass in the
form of cashew nut shell represents a new energy source and
abundant source of energy in India. The bio-fuel is derived from
cashew nut shell oil and its blend with diesel are promising
alternative fuel for diesel engine. In this work the pyrolysis Cashew
Nut Shell Liquid (CNSL)-Diesel Blends (CDB) was used to run the
Direct Injection (DI) diesel engine. The experiments were conducted
with various blends of CNSL and Diesel namely B20, B40, B60, B80
and B100. The results are compared with neat diesel operation. The
brake thermal efficiency was decreased for blends of CNSL and
Diesel except the lower blends of B20. The brake thermal efficiency
of B20 is nearly closer to that of diesel fuel. Also the emission level
of the all CNSL and Diesel blends was increased compared to neat
diesel. The higher viscosity and lower volatility of CNSL leads to
poor mixture formation and hence lower brake thermal efficiency and
higher emission levels. The higher emission level can be reduced by
adding suitable additives and oxygenates with CNSL and Diesel
blends.
Abstract: In this study, we developed a model to predict the
temperature and the pressure variation in an internal combustion
engine operated in HCCI (Homogeneous charge compression ignition)
mode. HCCI operation begins from aspirating of homogeneous charge
mixture through intake valve like SI (Spark ignition) engine and the
premixed charge is compressed until temperature and pressure of
mixture reach autoignition point like diesel engine. Combustion phase
was described by double-Wiebe function. The single zone model
coupled with an double-Wiebe function were performed to simulated
pressure and temperature between the period of IVC (Inlet valve close)
and EVO (Exhaust valve open). Mixture gas properties were
implemented using STANJAN and transfer the results to main model.
The model has considered the engine geometry and enables varying in
fuelling, equivalence ratio, manifold temperature and pressure. The
results were compared with the experiment and showed good
correlation with respect to combustion phasing, pressure rise, peak
pressure and temperature. This model could be adapted and use to
control start of combustion for HCCI engine.
Abstract: The present study conducted experimental investigation on combustion and emission characteristics of compression ignition engine using diesel as pilot fuel and methane, hydrogen and methane/hydrogen mixture as gaseous fuels at 1800 rev min-1. The effect of gaseous fuel on peak cylinder pressure and heat release is modest at low to medium loads. At high load, the high combustion temperature and high quantity of pilot fuel contribute to better combustion efficiency for all kinds of gaseous fuels and increases the peak cylinder pressure. Enrichment of hydrogen in methane gradually increases the peak cylinder pressure. The brake thermal efficiency increases with higher hydrogen fraction at lower loads. Hydrogen addition in methane contributed to a proportional reduction of CO/CO2/HC emission without penalty of NOx. For particulate emission, methane and hydrogen, could both suppress the particle emission. 30% hydrogen fraction in methane is observed to be best in reducing the particulate emission.
Abstract: Nano MgO has been synthesized by hydration and
dehydration method by modifies the commercial MgO. The prepared
MgO had been investigated as a heterogeneous base catalyst for
transesterification process for biodiesel production using palm oil.
TGA, FT-IR and XRD results obtained from this study lie each other
and proved in the formation of nano MgO from decomposition of
Mg(OH)2. This study proved that the prepared nano MgO was a
better base transesterification catalyst compared to commercial MgO.
The nano MgO calcined at 600ºC had gives the highest conversion of
51.3% of palm oil to biodiesel.
Abstract: The combustion of liquid fuel in the porous burner
(PB) was experimented to investigate evaporation mechanism and
combustion behavior. The diesel oil was used as fuel and the pebbles
carefully chosen in the same size like the solid sphere homogeneously
was adopted as the porous media. Two structures of the liquid porous
burner, i.e. the PB without and with installation of porous emitter
(PE), were performed. PE was installed by lower than PB with
distance of 20 cm. The pebbles having porosity (φ) of 0.45 and 0.52
were, respectively, used in PB and PE. The fuel was supplied dropwise
from the top through the PB and the combustion was occurred between
PB and PE. Axial profiles of temperature along the burner length were
measured to clarify the evaporation and combustion phenomena. The
pollutant emission characteristics were monitored at the burner exit.
From the experiment, it was found that the temperature profiles of both
structures decreased with the three ways swirling air flows (QA)
increasing. On the other hand, the temperature profiles increased with
fuel heat input (QF). Obviously, the profile of the porous burner
installed with PE was higher than that of the porous burner without
PE
Abstract: Homogeneous Charge Compression (HCCI) Ignition technology has been around for a long time, but has recently received renewed attention and enthusiasm. This paper deals with experimental investigations of HCCI engine using hydrous methanol as a primary fuel and Dimethyl Ether (DME) as an ignition improver. A regular diesel engine has been modified to work as HCCI engine for this investigation. The hydrous methanol is inducted and DME is injected into a single cylinder engine. Hence, hydrous methanol is used with 15% water content in HCCI engine and its performance and emission behavior is documented. The auto-ignition of Methanol is enabled by DME. The quantity of DME varies with respect to the load. In this study, the experiments are conducted independently and the effect of the hydrous methanol on the engine operating limit, heat release rate and exhaust emissions at different load conditions are investigated. The investigation also proves that the Hydrous Methanol with DME operation reduces the oxides of Nitrogen and smoke to an extreme low level which is not possible by the direct injection CI engine. Therefore, it is beneficial to use hydrous methanol-DME HCCI mode while using hydrous methanol in internal Combustion Engines.
Abstract: Batch fermentation of 5, 10 and 25 g/L biodiesel
derived crude glycerol was carried out at 30, 37 and 450C by
Clostridium pasteurianum cells immobilized on silica. Maximum
yield of 1,3-propanediol (PDO) (0.60 mol/mol), and ethanol (0.26
mol/mol) were obtained from 10 g/L crude glycerol at 30 and 370C
respectively. Maximum yield of butanol (0.28 mol/mol substrate
added) was obtained at 370C with 25 g/L substrate. None of the three
products were detected at 45oC even after 10 days of fermentation.
Only traces of ethanol (0.01 mol/mol) were detected at 450C with 5
g/L substrate. The results obtained for 25 g/L substrate utilization
were fitted in first order rate equation to obtain the values of rate
constant at three different temperatures for bioconversion of glycerol.
First order rate constants for bioconversion of glycerol at 30, 37 and
45oC were found to be 0.198, 0.294 and 0.029/day respectively.
Activation energy (Ea) for crude glycerol bioconversion was
calculated to be 57.62 kcal/mol.