Abstract: The present work relates to the corrosivity of distillery effluent and corrosion performance of mild steel and stainless steels SS304L, SS316L, and 2205. The report presents the results and conclusions drawn on the basis of (i) electrochemical polarization tests performed in distillery effluent and laboratory prepared solutions having composition similar to that of the effluent (ii) the surface examination by scanning electron microscope (SEM) of the corroded steel samples. It is observed that pH and presence of chloride, phosphate, calcium, nitrite and nitrate in distillery effluent enhance corrosion, whereas presence of sulphate and potassium inhibits corrosion. Among the materials tested, mild steel is observed to experience maximum corrosion followed by stainless steels SS304L, SS316L, and 2205.
Abstract: A geoelectric survey was carried out in some parts of
Angwan Gwari, an outskirt of Lapai Local Government Area on
Niger State which belongs to the Nigerian Basement Complex, with
the aim of evaluating the soil corrosivity, aquifer transmissivity and
protective capacity of the area from which aquifer characterisation
was made. The G41 Resistivity Meter was employed to obtain fifteen
Schlumberger Vertical Electrical Sounding data along profiles in a
square grid network. The data were processed using interpex 1-D
sounding inversion software, which gives vertical electrical sounding
curves with layered model comprising of the apparent resistivities,
overburden thicknesses, and depth. This information was used to
evaluate longitudinal conductance and transmissivities of the layers.
The results show generally low resistivities across the survey area
and an average longitudinal conductance variation from
0.0237Siemens in VES 6 to 0.1261Siemens in VES 15 with almost
the entire area giving values less than 1.0 Siemens. The average
transmissivity values range from 96.45 Ω.m2 in VES 4 to 299070
Ω.m2 in VES 1. All but VES 4 and VES14 had an average
overburden greater than 400 Ω.m2, these results suggest that the
aquifers are highly permeable to fluid movement within, leading to
the possibility of enhanced migration and circulation of contaminants
in the groundwater system and that the area is generally corrosive.
Abstract: The removal of hydrogen sulphide is required for reasons of health, odour problems, safety and corrosivity problems. The means of removing hydrogen sulphide mainly depend on its concentration and kind of medium to be purified. The paper deals with a method of hydrogen sulphide removal from the air by its catalytic oxidation to elemental sulphur with the use of Fe-EDTA complex. The possibility of obtaining fibrous filtering materials able to remove small concentrations of H2S from the air were described. The base of these materials is fibrous ion exchanger with Fe(III)- EDTA complex immobilized on their functional groups. The complex of trivalent iron converts hydrogen sulphide to elemental sulphur. Bivalent iron formed in the reaction is oxidized by the atmospheric oxygen, so complex of trivalent iron is continuously regenerated and the overall process can be accounted as pseudocatalytic. In the present paper properties of several fibrous catalysts based on ion exchangers with different chemical nature (weak acid,weak base and strong base) were described. It was shown that the main parameters affecting the process of catalytic oxidation are:concentration of hydrogen sulphide in the air, relative humidity of the purified air, the process time and the content of Fe-EDTA complex in the fibres. The data presented show that the filtering layers with anion exchange package are much more active in the catalytic processes of hydrogen sulphide removal than cation exchanger and inert materials. In the addition to the nature of the fibres relative air humidity is a critical factor determining efficiency of the material in the air purification from H2S. It was proved that the most promising carrier of the Fe-EDTA catalyst for hydrogen sulphide oxidation are Fiban A-6 and Fiban AK-22 fibres.
Abstract: Sarkhoon gas plant, located in south of Iran, has been installed to removal H2S contained in a high pressure natural gas stream. The solvent used for the H2S removal from gaseous stream is 34% by weight (wt%) Di-ethanol amine (DEA) solutions. Due to increasing concentration of heat stable salt (HSS) in solvent, corrosivity of amine solution had been increased. Reports indicated that there was corrosion on the shell of regeneration column. Because source formation of HSS was unknown, we decided to control the amount of HSS at the limit less than 3% wt amine solvent. Therefore, two small columns were filled by strong anionic base and carbon active, and then polluted amine was passed through beds. Finally a temporary amine recovery package on industrial scale was made based on laboratory’s results. From economical point of view we could save $700000 beside corrosion occurrence of the stripping column has been vigorously decreased.