Abstract: In the present research, whole meal barley flour
(WBF) was supplemented with gelatinized corn flour (GCF) in 0 and
30%. Whole meal wheat flour (WWF) was mixed with defatted rice
bran (DRB) to produce 0, 20, 25, and 30% replacement levels.
Rheological properties of dough were studied. Thermal properties
and starch crystallinity of flours were evaluated. Flat bread, balady
bread and pie were prepared from the different flour blends. The
different bakeries were sensory evaluated. Color of raw materials and
crust of bakery products were determined. Nutrients contents of raw
flours and food products were assessed. Results showed that addition
of GCF to WBF increased the viscosity and falling number of the
produced dough. Water absorption, dough development time and
dough stability increased with increasing the level of DRB in dough
while, weakening and mixing tolerance index decreased.
Extensibility and energy decreased, while, resistance to extension
increased as DRB level increased. Gelatinized temperature of WWF,
WBF, GCF, and DRB were 13.26, 35.09, 28.33, and 39.63,
respectively. Starch crystallinity was affected when DRB was added
to WWF. The highest protein content was present in balady bread
made from 70% WWF and 30% DRB. The highest calcium,
phosphorus, and potassium levels were present in products made
from 100% WBF. Sensory attributes of the products were slightly
affected by adding DRB and GCF. Conclusion: Addition of DRB or
GCF to WWF or WBF, respectively affect the physical, chemical,
rheological and sensory properties of balady bread, flat bread, and pie
while improved their nutritive values.
Abstract: This paper describes the development of new class of
epoxy based rice husk filled jute reinforced composites. Rice husk
flour is added in 0%, 1%, 3%, 5% by weight. Epoxy resin and
triethylenetetramine (T.E.T.A) is used as matrix and hardener
respectively. It investigates the mechanical properties of the
composites and a comparison is done for monolithic jute composite
and the filled ones. The specimens are prepared according to the
ASTM standards and experimentation is carried out using INSTRON
8801. The result shows that with the increase of filler percentage the
tensile properties increases but compressive and flexural properties
decreases.
Abstract: Geopolymer composites reinforced with flax fabrics
and nanoclay are fabricated and studied for physical and mechanical
properties using X-Ray Diffraction (XRD), Fourier Transform
Infrared Spectroscopy (FTIR), and Scanning Electron Microscope
(SEM). Nanoclay platelets at a weight of 1.0%, 2.0%, and 3.0% were
added to geopolymer pastes. Nanoclay at 2.0 wt.% was found to
improve density and decrease porosity while improving flexural
strength and post-peak toughness. A microstructural analysis
indicated that nanoclay behaves as filler and as an activator
supporting geopolymeric reaction while producing a higher content
geopolymer gel improving the microstructure of binders. The process
enhances adhesion between the geopolymer matrix and flax fibres.
Abstract: Polylactic acid (PLA) is the most commercially
available bio-based and biodegradable plastic at present. PLA has
been used in plastic related industries including single-used
containers, disposable and environmentally friendly packaging owing
to its renewability, compostability, biodegradability, and safety.
Although PLA demonstrates reasonably good optical, physical,
mechanical and barrier properties comparable to the existing
petroleum-based plastics, its brittleness and mold shrinkage as well as
its price are the points to be concerned for the production of rigid and
semi-rigid packaging. Blending PLA with other bio-based polymers
including thermoplastic starch (TPS) is an alternative not only to
achieve a complete bio-based plastic, but also to reduce the
brittleness, shrinkage during molding and production cost of the
PLA-based products. TPS is a material produced mainly from starch
which is cheap, renewable, biodegradable, compostable, and nontoxic.
It is commonly prepared by a plasticization of starch under
applying heat and shear force. Although glycerol has been reported as
one of the most plasticizers used for preparing TPS, its migration
caused the surface stickiness of the TPS products. In some cases,
mixed plasticizers or natural fibers have been applied to impede the
retrogradation of starch or reduce the migration of glycerol. The
introduction of fibers into TPS-based materials could reinforce the
polymer matrix as well. Therefore, the objective of the present
research is to study the effect of starch type (i.e. native starch and
phosphate starch), plasticizer type (i.e. glycerol and xylitol with a
weight ratio of glycerol to xylitol of 100:0, 75:25, 50:50, 25:75 and
0:100) and fiber content (i.e. in the range of 1-25 %wt) on properties
of PLA/TPS blend and composite. PLA/TPS blends and composites
were prepared using a twin-screw extruder and then converted into
dumbbell-shaped specimens using an injection molding machine. The
PLA/TPS blends prepared by using phosphate starch showed higher
tensile strength and stiffness than the blends prepared by using native
one. In contrast, the blends from native starch exhibited higher
extensibility and heat distortion temperature (HDT) than those from
the modified starch. Increasing xylitol content resulted in enhanced
tensile strength, stiffness and water resistance, but decreased
extensibility and HDT of the PLA/TPS blend. Tensile properties and
hydrophobicity of the blend could be improved by incorporating
silane treated-jute fibers.
Abstract: The development of composite materials and the
related design and manufacturing technologies is one of the most
important advances in the history of materials. Composites are
multifunctional materials having unprecedented mechanical and
physical properties that can be tailored to meet the requirements of a
particular application. Some composites also exhibit great resistance
to high-temperature corrosion, oxidation, and wear. Polymers are
widely used indoors and outdoors, therefore they are exposed to a
chemical environment which may include atmospheric oxygen, acidic
fumes, acidic rain, moisture heat and thermal shock, ultra-violet light,
high energy radiation, etc. Different polymers are affected differently
by these factors even though the amorphous polymers are more
sensitive. Ageing is also important and it is defined as the process of
deterioration of engineering materials resulting from the combined
effects of atmospheric radiation, heat, oxygen, water, microorganisms
and other atmospheric factors.
Abstract: Carbon Fiber Reinforced Plastics (CFRPs) are widely
used for advanced applications, in particular in aerospace, automotive
and wind energy industries. Once cured to near net shape, CFRP
parts need several finishing operations such as trimming, milling or
drilling in order to accommodate fastening hardware and meeting the
final dimensions. The present research aims to study the effect of the
cutting temperature in trimming on the mechanical strength of high
performance CFRP laminates used for aeronautics applications. The
cutting temperature is of great importance when dealing with
trimming of CFRP. Temperatures higher than the glass-transition
temperature (Tg) of the resin matrix are highly undesirable: they
cause degradation of the matrix in the trimmed edges area, which can
severely affect the mechanical performance of the entire component.
In this study, a 9.50mm diameter CVD diamond coated carbide tool
with six flutes was used to trim 24-plies CFRP laminates. A
300m/min cutting speed and 1140mm/min feed rate were used in the
experiments. The tool was heated prior to trimming using a
blowtorch, for temperatures ranging from 20°C to 300°C. The
temperature at the cutting edge was measured using embedded KType
thermocouples. Samples trimmed for different cutting
temperatures, below and above Tg, were mechanically tested using
three-points bending short-beam loading configurations. New cutting
tools as well as worn cutting tools were utilized for the experiments.
The experiments with the new tools could not prove any correlation
between the length of cut, the cutting temperature and the mechanical
performance. Thus mechanical strength was constant, regardless of
the cutting temperature. However, for worn tools, producing a cutting
temperature rising up to 450°C, thermal damage of the resin was
observed. The mechanical tests showed a reduced mean resistance in
short beam configuration, while the resistance in three point bending
decreases with increase of the cutting temperature.
Abstract: In the present study we have investigated axial
buckling characteristics of nanocomposite beams reinforced by
single-walled carbon nanotubes (SWCNTs). Various types of beam
theories including Euler-Bernoulli beam theory, Timoshenko beam
theory and Reddy beam theory were used to analyze the buckling
behavior of carbon nanotube-reinforced composite beams.
Generalized differential quadrature (GDQ) method was utilized to
discretize the governing differential equations along with four
commonly used boundary conditions. The material properties of the
nanocomposite beams were obtained using molecular dynamic (MD)
simulation corresponding to both short-(10,10) SWCNT and long-
(10,10) SWCNT composites which were embedded by amorphous
polyethylene matrix. Then the results obtained directly from MD
simulations were matched with those calculated by the mixture rule
to extract appropriate values of carbon nanotube efficiency
parameters accounting for the scale-dependent material properties.
The selected numerical results were presented to indicate the
influences of nanotube volume fractions and end supports on the
critical axial buckling loads of nanocomposite beams relevant to
long- and short-nanotube composites.
Abstract: Carbon nanotubes (CNTs) are known for having high elastic properties with high surface area that promote them as good candidates for reinforcing polymeric matrices. In composite materials, CNTs lack chemical bonding with the surrounding matrix which decreases the possibility of better stress transfer between the components. In this work, a chemical treatment for activating the surface of the multi-wall carbon nanotubes (MWCNT) was applied and the effect of this functionalization on the elastic properties of the epoxy nanocomposites was studied. Functional amino-groups were added to the surface of the CNTs and it was evaluated to be about 34% of the total weight of the CNTs. Elastic modulus was found to increase by about 40% of the neat epoxy resin at CNTs’ weight fraction of 0.5%. The elastic modulus was found to decrease after reaching a certain concentration of CNTs which was found to be 1% wt. The scanning electron microscopic pictures showed the effect of the CNTs on the crack propagation through the sample by forming stress concentrated spots at the nanocomposite samples.
Abstract: This paper reports the viability of developing Zn-27Al
alloy matrix hybrid composites reinforced with alumina, graphite and
fly ash (solid waste bye product of coal in thermal power plants).
This research work was aimed at developing low cost-high
performance Zn-27Al matrix composite with low density. Alumina
particulates (Al2O3), graphite added with 0, 2, 3, 4 and 5 wt% fly ash
were utilized to prepare 10wt% reinforcing phase with Zn-27Al alloy
as matrix using two-step stir casting method. Density measurement,
estimated percentage porosity, tensile testing, micro hardness
measurement and optical microscopy were used to assess the
performance of the composites produced. The results show that the
hardness, ultimate tensile strength, and percent elongation of the
hybrid composites decrease with increase in fly ash content. The
maximum decrease in hardness and ultimate tensile strength of
13.72% and 15.25% respectively were observed for composite grade
containing 5wt% fly ash. The percentage elongation of composite
sample without fly ash is 8.9% which is comparable with that of the
sample containing 2wt% fly ash with percentage elongation of 8.8%.
The fracture toughness of the fly ash containing composites was
however superior to those of composites without fly ash with 5wt%
fly ash containing composite exhibiting the highest fracture
toughness. The results show that fly ash can be utilized as
complementary reinforcement in ZA-27 alloy matrix composite to
reduce cost.
Abstract: Natural fibers are used in polymer composites to
improve mechanical properties to replace inorganic reinforcing
agents produced by non-renewable resources. The present study
investigates the tensile and flexural behaviors of palm fibers-high
density polyethylene (HDPE) composite as a function of volume
fraction. The surface of the fibers was treated by mercerization
treatments to improve the wetting behavior of the apolar HDPE. The
treatment characterization was obtained by scanning electron
microscopy, X-Ray diffraction and infrared spectroscopy. Results
evidences that a good adhesion interfacial between fibers-matrix
caused an increase strength and modulus flexural as well as tensile
strength in the modified fibers/HDPE composites when compared to
the pure HDPE and untreated fibers reinforced composites.
Abstract: The seriously damaged structures during earthquakes
show the need and importance of design of reinforced concrete
structures with high ductility. Reinforced concrete beam-column
joints have an important function in all structures. Under seismic
excitation, the beam column joint region is subjected to horizontal
and vertical shear forces whose magnitude is many times higher than
the adjacent beam and column. Strength and ductility of structures
depends mainly on proper detailing of the reinforcement in beamcolumn
joints and the old structures were found ductility deficient.
DSP materials are obtained by using high quantities of super
plasticizers and high volumes of micro silica. In the case of High
Performance Densified Small Particle Concrete (HPDSPC), since
concrete is dense even at the micro-structure level, tensile strain
would be much higher than that of the conventional SFRC, SIFCON
& SIMCON. This in turn will improve cracking behaviour, ductility
and energy absorption capacity of composites in addition to
durability. The fine fibers used in our mix are 0.3mm diameter and 10
mm which can be easily placed with high percentage. These fibers
easily transfer stresses and act as a composite concrete unit to take up
extremely high loads with high compressive strength. HPDSPC
placed in the beam column joints helps in safety of human life due to
prolonged failure.
Abstract: Chitosan polyacrylic acid composite membranes were
prepared by a bulk polymerization method in presence of N, N'-
methylene bisacrylamide (crosslinker) and ammonium persulphate as
initiator. Membranes prepared from this copolymer in presence and
absence of Ag nanoparticles were characterized by measuring
mechanical and physical properties, water up-take and antibacterial
properties. The results obtained indicated that the prepared
membranes have antibacterial properties which increase with adding
Ag nanoparticles.
Abstract: Work presented is interested in the characterization of
the quasistatic mechanical properties and in fatigue of a composite
laminated in jute/epoxy. The natural fibers offer promising prospects
thanks to their interesting specific properties, because of their low
density, but also with their bio-deterioration. Several scientific
studies highlighted the good mechanical resistance of the vegetable
fiber composites reinforced, even after several recycling. Because of
the environmental standards that become increasingly severe, one
attends the emergence of eco-materials at the base of natural fibers
such as flax, bamboo, hemp, sisal, jute. The fatigue tests on
elementary vegetable fibers show an increase of about 60% of the
rigidity of elementary fibers of hemp subjected to cyclic loadings. In
this study, the test-tubes manufactured by the method infusion have
sequences of stacking of 0/90° and ± 45° for the shearing and tensile
tests. The quasistatic tests reveal a variability of the mechanical
properties of about 8%. The tensile fatigue tests were carried out for
levels of constraints equivalent to half of the ultimate values of the
composite. Once the fatigue tests carried out for well-defined values
of cycles, a series of static tests of traction type highlights the
influence of the number of cycles on the quasi-static mechanical
behavior of the laminate jute/epoxy.
Abstract: In the present study, the properties of Al-Al2O3
nanocomposite hollow sphere structures were investigated. For this
reason, the Al-based nanocomposite hollow spheres with different
amounts of nano-alumina reinforcement (0-10wt %) and different
ratio of thickness to diameter (t/D: 0.06-0.3) were prepared via a
powder metallurgy method. Then, the effect of mentioned parameters
was studied on physical and quasi static mechanical properties of
their related prepared structures (open/closed cell) such as density,
hardness, strength, and energy absorption. It was found that, as the
t/D ratio increases the relative density, compressive strength and
energy absorption increase. The highest values of strength and energy
absorption were obtained from the specimen with 5 wt. % of
nanoparticle reinforcement, t/D of 0.3 (t=1 mm, D=400μm) as 22.88
MPa and 13.24 MJ/m3, respectively. The moderate specific strength
of prepared composites in the present study showed the good
consistency with the properties of others low carbon steel composite
with similar structure.
Abstract: Polyaniline is an indispensible component in lightemitting
devices (LEDs), televisions, cellular telephones, automotive,
corrosion-resistant coatings, actuators etc. The electrical conductivity
properties was found be increased by introduction of metal nano
particles. In the present study, an attempt has been made to utilize
platinum nano particles to achieve the improved electrical properties.
Polyaniline and Pt-polyaniline composite are synthesized by
electrochemical routes. X-ray diffractometer confirms the amorphous
nature of polyaniline. The Bragg’s diffraction peaks correspond to
platinum nanoparticles in Pt-polyaniline composite and
thermogravimetric analyzer indicates its decomposition at certain
temperature. The Scanning Electron Micrographs of colloidal
platinum nanoparticles were spherical, uniform shape in the
composite. The current-voltage (I-V) characteristics of the PANI and
composites were also studied which indicate a significant decreasing
resistivity than PANI-Platinum after introduction of pt nanoparticles
in the matrix of polyaniline (PANI).
Abstract: Typical load-bearing biological materials like bone,
mineralized tendon and shell, are biocomposites made from both
organic (collagen) and inorganic (biomineral) materials. This
amazing class of materials with intrinsic internally designed
hierarchical structures show superior mechanical properties with
regard to their weak components from which they are formed.
Extensive investigations concentrating on static loading conditions
have been done to study the biological materials failure. However,
most of the damage and failure mechanisms in load-bearing
biological materials will occur whenever their structures are exposed
to dynamic loading conditions. The main question needed to be
answered here is: What is the relation between the layout and
architecture of the load-bearing biological materials and their
dynamic behavior? In this work, a staggered model has been
developed based on the structure of natural materials at nanoscale and
Finite Element Analysis (FEA) has been used to study the dynamic
behavior of the structure of load-bearing biological materials to
answer why the staggered arrangement has been selected by nature to
make the nanocomposite structure of most of the biological materials.
The results showed that the staggered structures will efficiently
attenuate the stress wave rather than the layered structure.
Furthermore, such staggered architecture is effectively in charge of
utilizing the capacity of the biostructure to resist both normal and
shear loads. In this work, the geometrical parameters of the model
like the thickness and aspect ratio of the mineral inclusions selected
from the typical range of the experimentally observed feature sizes
and layout dimensions of the biological materials such as bone and
mineralized tendon. Furthermore, the numerical results validated with
existing theoretical solutions. Findings of the present work emphasize
on the significant effects of dynamic behavior on the natural
evolution of load-bearing biological materials and can help scientists
to design bioinspired materials in the laboratories.
Abstract: This work presents an improved single fiber pull-out
test for fiber/matrix interface characterization. This test has been
used to study the Inter-Facial Shear Strength ‘IFSS’ of hemp fibers
reinforced polypropylene (PP). For this aim, the fiber diameter
has been carefully measured using a tomography inspired method.
The fiber section contour can then be approximated by a circle
or a polygon. The results show that the IFSS is overestimated if
the circular approximation is used. The Influence of the molding
temperature on the IFSS has also been studied. We find that a molding
temperature of 183◦C leads to better interfacial properties. Above or
below this temperature the interface strength is reduced.
Abstract: Superabsorbent polymers received much attention and
are used in many fields because of their superior characters to
traditional absorbents, e.g., sponge and cotton. So, it is very
important but challenging to prepare highly and fast-swelling
superabsorbents. A reliable, efficient and low-cost technique for
removing heavy metal ions from wastewater is the adsorption using
bio-adsorbents obtained from biological materials, such as
polysaccharides-based hydrogels superabsorbents. In this study, novel multi-functional superabsorbent composites
type semi-interpenetrating polymer networks (Semi-IPNs) were
prepared via graft polymerization of acrylamide onto chitosan
backbone in presence of gelatin, CTS-g-PAAm/Ge, using potassium
persulfate and N,N’-methylene bisacrylamide as initiator and
crosslinker, respectively. These hydrogels were also partially
hydrolyzed to achieve superabsorbents with ampholytic properties
and uppermost swelling capacity. The formation of the grafted
network was evidenced by Fourier Transform Infrared Spectroscopy
(ATR-FTIR) and Thermogravimetric Analysis (TGA). The porous
structures were observed by Scanning Electron Microscope (SEM).
From TGA analysis, it was concluded that the incorporation of the Ge
in the CTS-g-PAAm network has marginally affected its thermal
stability. The effect of gelatin content on the swelling capacities of
these superabsorbent composites was examined in various media
(distilled water, saline and pH-solutions). The water absorbency was
enhanced by adding Ge in the network, where the optimum value was
reached at 2 wt. % of Ge. Their hydrolysis has not only greatly
optimized their absorption capacity but also improved the swelling
kinetic.These materials have also showed reswelling ability. We
believe that these super-absorbing materials would be very effective
for the adsorption of harmful metal ions from wastewater.
Abstract: In present global scenario, aluminum alloys are
coining the attention of many innovators as competing structural
materials for automotive and space applications. Comparing to other
challenging alloys, especially, 7xxx series aluminum alloys have
been studied seriously because of benefits such as moderate strength;
better deforming characteristics and affordable cost. It is expected
that substitution of aluminum alloys for steels will result in great
improvements in energy economy, durability and recyclability.
However, it is necessary to improve the strength and the formability
levels at low temperatures in aluminum alloys for still better
applications. Aluminum–Zinc–Magnesium with or without other
wetting agent denoted as 7XXX series alloys are medium strength
heat treatable alloys. In addition to Zn, Mg as major alloying
additions, Cu, Mn and Si are the other solute elements which
contribute for the improvement in mechanical properties by suitable
heat treatment process. Subjecting to suitable treatments like age
hardening or cold deformation assisted heat treatments; known as low
temperature thermomechanical treatments (LTMT) the challenging
properties might be incorporated. T6 is the age hardening or
precipitation hardening process with artificial aging cycle whereas T8
comprises of LTMT treatment aged artificially with X% cold
deformation. When the cold deformation is provided after solution
treatment, there is increase in hardness related properties such as
wear resistance, yield and ultimate strength, toughness with the
expense of ductility. During precipitation hardening both hardness
and strength of the samples are increasing. The hardness value may
further improve when room temperature deformation is positively
supported with age hardening known as thermomechanical treatment.
It is intended to perform heat treatment and evaluate hardness, tensile
strength, wear resistance and distribution pattern of reinforcement in
the matrix. 2 to 2.5 and 3 to 3.5 times increase in hardness is reported
in age hardening and LTMT treatments respectively as compared to
as-cast composite. There was better distribution of reinforcements in
the matrix, nearly two fold increase in strength levels and up to 5
times increase in wear resistance are also observed in the present
study.
Abstract: It is a major challenge to build a bridge superstructure
that has long-term durability and low maintenance requirements. A
solution to this challenge may be to use new materials or to
implement new structural systems. Fiber Reinforced Polymer (FRP)
composites have continued to play an important role in solving some
of persistent problems in infrastructure applications because of its
high specific strength, light weight, and durability. In this study, the
concept of the hybrid FRP-concrete structural systems is applied to a
bridge superstructure. The hybrid FRP-concrete bridge superstructure
is intended to have durable, structurally sound, and cost effective
hybrid system that will take full advantage of the inherent properties
of both FRP materials and concrete. In this study, two hybrid FRP-concrete
bridge systems were investigated. The first system consists
of trapezoidal cell units forming a bridge superstructure. The second
one is formed by arch cells. The two systems rely on using cellular
components to form the core of the bridge superstructure, and an
outer shell to warp around those cells to form the integral unit of the
bridge. Both systems were investigated analytically by using finite
element (FE) analysis. From the rigorous FE studies, it was
concluded that first system is more efficient than the second.