Abstract: An attempt has been made to beneficiate the Indian
coking coal fines by a combination of Spiral, flotation and Oleo
Flotation processes. Beneficiation studies were also carried out on -
0.5mm coal fines using flotation and oleo flotation by splitting at size
0.063mm.Size fraction of 0.5mm-0.063mm and -0.063mm size were
treated in flotation and Oleo flotation respectively. The washability
studies on the fraction 3-0.5 mm indicated that good separation may
be achieved when it is fed in a spiral. Combined product of Spiral,
Flotation and Oleo Flotation has given a significant yield at
acceptable ash%. Studies were also conducted to see the dewatering
of combined product by batch type centrifuge. It may further be
suggested that combination of different processes may be used to
treat the -3 mm fraction in an integrated manner to achieve the yield
at the desired ash level. The treatment of the 3/1 mm -0.5 mm size
fraction by spiral,-0.5-0.63 mm by conventional froth flotation and -
0.063 fractions by oleo flotation may provide a complete solution of
beneficiation and dewatering of coal fines, and can effectively
address the environmental problems caused by coal fines.
Abstract: Macrophomina phaseolina is a devastating soil-borne
fungal plant pathogen that causes charcoal rot disease in many
economically important crops worldwide. So far, no registered
fungicide is available against this plant pathogen. This study was
planned to examine the antifungal activity of an allelopathic grass
Cenchrus pennisetiformis (Hochst. & Steud.) Wipff. for the
management of M. phaseolina isolated from cowpea [Vigna
unguiculata (L.) Walp.] plants suffering from charcoal rot disease.
Different parts of the plants viz. inflorescence, shoot and root were
extracted in methanol. Laboratory bioassays were carried out using
different concentrations (0, 0.5, 1.0, …, 3.0 g mL-1) of methanolic
extracts of the test allelopathic grass species to assess the antifungal
activity against the pathogen. In general, extracts of all parts of the
grass exhibited antifungal activity. All the concentrations of
methanolic extracts of shoot and root significantly reduced fungal
biomass by 20–73% and 40–80%, respectively. Methanolic shoot
extract was fractionated using n-hexane, chloroform, ethyl acetate
and n-butanol. Different concentrations of these fractions (3.125,
6.25, …, 200 mg mL-1) were analyzed for their antifungal activity.
All the concentrations of n-hexane fraction significantly reduced
fungal biomass by 15–96% over corresponding control treatments.
Higher concentrations (12.5–200 mg mL-1) of chloroform, ethyl
acetate and n-butanol also reduced the fungal biomass significantly
by 29–100%, 46–100% and 24–100%, respectively.
Abstract: Air conditioning is mainly to be used as human
comfort medium. It has been use more often in country in which the
daily temperatures are high. In scientific, air conditioning is defined
as a process of controlling the moisture, cooling, heating and cleaning
air. Without proper estimation of cooling load, big amount of waste
energy been used because of unsuitable of air conditioning system are
not considering to overcoming heat gains from surrounding. This is
due to the size of the room is too big and the air conditioning has to
use more energy to cool the room and the air conditioning is too
small for the room. The studies are basically to develop a program to
calculate cooling load. Through this study it is easy to calculate
cooling load estimation. Furthermore it-s help to compare the cooling
load estimation by hourly and yearly. Base on the last study that been
done, the developed software are not user-friendly. For individual
without proper knowledge of calculating cooling load estimation
might be problem. Easy excess and user-friendly should be the main
objective to design something. This program will allow cooling load
able be estimate by any users rather than estimation by using rule of
thumb. Several of limitation of case study is judged to sure it-s
meeting to Malaysia building specification. Finally validation is done
by comparison manual calculation and by developed program.
Abstract: This study presents a simulation model for converting coal to methanol, based on gasification technology with the commercial chemical process simulator, Pro/II® V8.1.1. The methanol plant consists of air separation unit (ASU), gasification unit, gas clean-up unit, and methanol synthetic unit. The clean syngas is produced with the first three operating units, and the model has been verified with the reference data from United States Environment Protection Agency. The liquid phase methanol (LPMEOHTM) process is adopted in the methanol synthetic unit. Clean syngas goes through gas handing section to reach the reaction requirement, reactor loop/catalyst to generate methanol, and methanol distillation to get desired purity over 99.9 wt%. The ratio of the total energy combined with methanol and dimethyl ether to that of feed coal is 78.5% (gross efficiency). The net efficiency is 64.2% with the internal power consumption taken into account, based on the assumption that the efficiency of electricity generation is 40%.
Abstract: A mathematical model based on a mass and energy
balance for the combustion in a cement rotary kiln was developed.
The model was used to investigate the impact of replacing about
45 % of the primary coal energy by different alternative fuels.
Refuse derived fuel, waste wood, solid hazardous waste and liquid
hazardous waste were used in the modeling. The results showed that
in order to keep the kiln temperature unchanged, and thereby
maintain the required clinker quality, the production capacity had to
be reduced by 1-15 %, depending on the fuel type. The reason for the
reduction is increased exhaust gas flow rates caused by the fuel
characteristics. The model, which has been successfully validated in a
full-scale experiment, was also used to show that the negative impact
on the production capacity can be avoided if a relatively small part of
the combustion air is replaced by pure oxygen.
Abstract: Bubble columns have a variety of applications in
absorption, bio-reactions, catalytic slurry reactions, and coal
liquefaction; because they are simple to operate, provide good heat
and mass transfer, having less operational cost. The use of
Computational Fluid Dynamics (CFD) for bubble column becomes
important, since it can describe the fluid hydrodynamics on both local
and global scale. Euler- Euler two-phase fluid model has been used to
simulate two-phase (air and water) transient up-flow in bubble
column (15cm diameter) using FLUENT6.3. These simulations and
experiments were operated over a range of superficial gas velocities
in the bubbly flow and churn turbulent regime (1 to16 cm/s) at
ambient conditions. Liquid velocity was varied from 0 to 16cm/s. The
turbulence in the liquid phase is described using the standard k-ε
model. The interactions between the two phases are described
through drag coefficient formulations (Schiller Neumann). The
objectives are to validate CFD simulations with experimental data,
and to obtain grid-independent numerical solutions. Quantitatively
good agreements are obtained between experimental data for hold-up
and simulation values. Axial liquid velocity profiles and gas holdup
profiles were also obtained for the simulation.
Abstract: Benchmarking cleaner production performance is an
effective way of pollution control and emission reduction in coal-fired
power industry. A benchmarking method using two-stage
super-efficiency data envelopment analysis for coal-fired power plants
is proposed – firstly, to improve the cleaner production performance of
DEA-inefficient or weakly DEA-efficient plants, then to select the
benchmark from performance-improved power plants. An empirical
study is carried out with the survey data of 24 coal-fired power plants.
The result shows that in the first stage the performance of 16 plants is
DEA-efficient and that of 8 plants is relatively inefficient. The target
values for improving DEA-inefficient plants are acquired by
projection analysis. The efficient performance of 24 power plants and
the benchmarking plant is achieved in the second stage. The two-stage
benchmarking method is practical to select the optimal benchmark in
the cleaner production of coal-fired power industry and will
continuously improve plants- cleaner production performance.
Abstract: Generation of electricity from coal has increased over
the years in the United States and around the world. Burning of coal
results in annual production of upwards of 100 millions tons (United
States only) of coal combustion products (CCPs). Only about a third
of these products are being used to create new products while the
remainder goes to landfills. Application of CCPs mixed with
composted organic materials onto soil can improve the soil-s
physico-chemical conditions and provide essential plant nutritients.
Our objective was to create plant growth media utilizing CCPs and
compost in way which maximizes the use of these products and, at
the same time, maintain good plant growth. Media were formulated
by adding composted organic matter (COM) to CCPs at ratios
ranging from 2:8 to 8:2 (v/v). The quality of these media was
evaluated by measuring their physical and chemical properties and
their effect on plant growth. We tested the media by 1) measuring
their physical and chemical properties and 2) the growth of three
plant species in the experimental media: wheat (Triticum sativum),
tomato (Lycopersicum esculentum) and marigold (Tagetes patula).
We achieved significantly (p < 0.001) higher growth (7-130%) in the
experimental media containing CCPs compared to a commercial mix.
The experimental media supplied adequate plant nutrition as no
fertilization was provided during the experiment. Based on the
results, we recommend the use of CCPs and composts for the
creation of plant growth media.
Abstract: The economic and stable operation was affected
seriously by coal quality disturbance for power plants. Based on model
analysis, influence of the disturbance can be considered as gain change
of control system. Power capability coefficient of coal was
constructed to inhibit it. Accuracy of the coefficient was verified by
operating data. Then coal quality disturbance free system based on
gain scheduling was designed for coordinated control system.
Simulation showed that, the strategy improved control quality
obviously, and inhibited the coal quality disturbance.
Abstract: Liquid-liquid extraction is a process using two immiscible
liquids to extract compounds from one phase without high
temperature requirement. Mostly, the technical implementation of
this process is carried out in mixer-settlers or extraction columns. In
real chemical processes, chemicals may have high viscosity and
contain impurities. These impurities may change the settling behavior
of the process without measurably changing the physical properties
of the phases. In the current study, the settling behavior and the affected
parameters in a high-viscosity system were observed. Batchsettling
experiments were performed to experimentally quantify the
settling behavior and the mixer-settler model of Henschke [1] was
used to evaluate the behavior of the toluene + water system. The
viscosity of the system was increased by adding polyethylene glycol
4000 to the aqueous phase. NaCl and Na2SO4 were used to study the
influence of electrolytes. The results from this study show that increasing
the viscosity of water has a higher influence on the settling
behavior in comparison to the effects of the electrolytes. It can be
seen from the experiments that at high salt concentrations, there was
no effect on the settling behavior.
Abstract: Coal fly ash (CFA) generated by coal-based thermal
power plants is mainly composed of some oxides having high
crystallinity, like quartz and mullite. In this study, the effect of CFA
crystallinity toward lead adsorption capacity was investigated. To get
solid with various crystallinity, the solution of sodium hydroxide
(NaOH) of 1-7 M was used to treat CFA at various temperature and
reflux time. Furthermore, to evaluate the effect of NaOH-treated CFA
with respect to adsorption capacity, the treated CFA were examine as
adsorbent for removing lead in the solution. The result shows that
using NaOH to treat CFA causes crystallinity of quartz and mullite
decrease. At higher NaOH concentration (>3M), in addition the
damage of quartz and mullite crystallinity is followed by crystal
formation called hydroxysodalite. The lower crystalllinity, the higher
adsorption capacity.
Abstract: There is wide range of scientific workflow systems
today, each one designed to resolve problems at a specific level. In
large collaborative projects, it is often necessary to recognize the
heterogeneous workflow systems already in use by various partners
and any potential collaboration between these systems requires
workflow interoperability. Publish/Subscribe Scientific Workflow
Interoperability Framework (PS-SWIF) approach was proposed to
achieve workflow interoperability among workflow systems. This
paper evaluates the PS-SWIF approach and its system to achieve
workflow interoperability using Web Services with asynchronous
notification messages represented by WS-Eventing standard. This
experiment covers different types of communication models provided
by Workflow Management Coalition (WfMC). These models are:
Chained processes, Nested synchronous sub-processes, Event
synchronous sub-processes, and Nested sub-processes
(Polling/Deferred Synchronous). Also, this experiment shows the
flexibility and simplicity of the PS-SWIF approach when applied to a
variety of workflow systems (Triana, Taverna, Kepler) in local and
remote environments.
Abstract: Modes of occurrence of Pb, As, Cr, Co, Cu, and Ni in bituminous coal and lignite were determined by means of sequential extraction using NH4OAc, HCl, HF and HNO3 extraction solutions. Elemental affinities obtained were then evaluated in relation to volatility of these elements during the combustion of these coals in two circulating fluidised-bed power stations. It was found out that higher percentage of the elements bound in silicates brought about lower volatility, while higher elemental proportion with monosulphides association (or bound as exchangeable ion) resulted in higher volatility. The only exception was the behavior of arsenic, whose volatility depended on amount of limestone added during the combustion process (as desulphurisation additive) rather than to its association in coal.
Abstract: This work was to study batch biosorption of Pb(II)
ions from aqueous solution by Luffa charcoal. The effect of operating
parameters such as adsorption contact time, initial pH solution and
different initial Pb(II) concentration on the sorption of Pb(II) were
investigated. The results showed that the adsorption of Pb(II) ions
was initially rapid and the equilibrium time was 10 h. Adsorption
kinetics of Pb(II) ions onto Luffa charcoal could be best described by
the pseudo-second order model. At pH 5.0 was favorable for the
adsorption and removal of Pb(II) ions. Freundlich adsorption
isotherm model was better fitted for the adsorption of Pb(II) ions than
Langmuir and Timkin isotherms, respectively. The highest monolayer
adsorption capacity obtained from Langmuir isotherm model was
51.02 mg/g. This study demonstrated that Luffa charcoal could be
used for the removal of Pb(II) ions in water treatment.
Abstract: This paper presents the stabilization potential of Class
F pond ash (PA) from a coal fired thermal power station on tropical
peat soil. Peat or highly organic soils are well known for their high
compressibility, natural moisture content, low shear strength and
long-term settlement. This study investigates the effect of different
amount (i.e., 5, 10, 15 and 20%) of PA on peat soil, collected from
Sarawak, Malaysia, mainly compaction and unconfined compressive
strength (UCS) properties. The amounts of PA added to the peat soil
sample as percentage of the dry peat soil mass. With the increase in
PA content, the maximum dry density (MDD) of peat soil increases,
while the optimum moisture content (OMC) decreases. The UCS
value of the peat soils increases significantly with the increase of PA
content and also with curing periods. This improvement on
compressive strength of tropical peat soils indicates that PA has the
potential to be used as a stabilizer for tropical peat soil. Also, the use
of PA in soil stabilization helps in reducing the pond volume and
achieving environment friendly as well as a sustainable development
of natural resources.
Abstract: This paper presents a conceptual model of agreement
options on negotiation support for civil engineering decision. The
negotiation support facilitates the solving of group choice decision
making problems in civil engineering decision to reduce the impact
of mud volcano disaster in Sidoarjo, Indonesia. The approach based
on application of analytical hierarchy process (AHP) method for
multi criteria decision on three level of decision hierarchy.
Decisions for reducing impact is very complicated since many
parties involved in a critical time. Where a number of stakeholders
are involved in choosing a single alternative from a set of solution
alternatives, there are different concern caused by differing
stakeholder preferences, experiences, and background. Therefore, a
group choice decision support is required to enable each stakeholder
to evaluate and rank the solution alternatives before engaging into
negotiation with the other stakeholders. Such civil engineering
solutions as alternatives are referred to as agreement options that are
determined by identifying the possible stakeholder choice, followed
by determining the optimal solution for each group of stakeholder.
Determination of the optimal solution is based on a game theory
model of n-person general sum game with complete information that
involves forming coalitions among stakeholders.
Abstract: A research study was conducted with an objective to propose a collaborative business strategy of a oil and gas trading company, representing PPT Energy Trading Co., Ltd., with its shareholder, especially electricity and power supply companies for LNG Form of Coal Bed Methane in B2B Transaction. Collaborative business strategy is a strategy to collaborate with other organizations due to have future benefits in both parties, or achieve the business objective through the collaboration of business, its strategy and partners. A structured interview was established to collect the required primary data from the company. Not only interview, but also company’s business plan and annual report were collected and analyzed for the company’s current condition. As the result, this research shows a recommendation to propose a new collaborative strategy with limiting its target market, diversifying product, conducting new business model, and considering other stakeholders.
Abstract: Restoration research has become important on principle recently in Czech Republic. The reason is simple. More than 70 % of mined brown coal comes from the North Bohemian Basin these days. Open cast brown coal mining has lead to large damage on the landscape. Reclamation of phytotoxic areas is one of the serious problems in the North Bohemian Basin. It mainly concerns the areas with the occurrence of overburden rocks from the coal bed enriched with coal. The presented paper includes the characteristics of the important phytotoxic areas and the methodology of their reclamation. The results are documented with the long term monitoring of physical, mineralogical, chemical and pedological parameters of rocks in the testing areas.
Abstract: There are many sources trough which the soil get
enriched and contaminated with REEs. The determination of REEs in
environmental samples has been limited because of the lack of
sensitive analytical techniques. Soil samples were collected from
four sites including open cast coal mine, natural coal burning, coal
washery and control in the coal field located in Dhanbad, India.
Total concentrations of rare earth elements (REEs) were determined
using the inductively coupled plasma atomic absorption spectrometry
in order to assess enrichment status in the coal field. Results showed
that the mean concentrations of La, Pr, Eu, Tb, Ho, and Tm in open
cast mine and natural coal burning sites were elevated compared to
the reference concentrations, while Ce, Nd, Sm, and Gd were
elevated in coal washery site. When compared to reference soil,
heavy REEs (HREEs) were enriched in open cast mines and natural
coal burning affected soils, however, the HREEs were depleted in the
coal washery sites. But, the Chondrite-normalization diagram showed
significant enrichment for light REEs (LREEs) in all the soils. High
concentration of Pr, Eu, Tb, Ho, Tm, and Lu in coal mining and coal
burning sites may pose human health risks. Factor analysis showed
that distribution and relative abundance of REEs of the coal washery
site is comparable with the control. Eventually washing or cleaning
of coal could significantly decrease the emission of REEs from coal
into the environment.
Abstract: The prospective analysis is presented as an important tool to identify the most relevant opportunities and needs in research and development from planned interventions in innovation systems. This study chose Phyllanthus niruri, known as "stone break" to describe the knowledge about the specie, by using biotechnological forecasting through the software Vantage Point. It can be seen a considerable increase in studies on Phyllanthus niruri in recent years and that there are patents about this plant since twenty-five years ago. India was the country that most carried out research on the specie, showing interest, mainly in studies of hepatoprotection, antioxidant and anti-cancer activities. Brazil is in the second place, with special interest for anti-tumor studies. Given the identification of the Brazilian groups that exploit the species it is possible to mediate partnerships and cooperation aiming to help on the implementing of the Program of Herbal medicines (phytotherapics) in Brazil.