Abstract: Thermo-chemical treatment (TCT) such as pyrolysis
is getting recognized as a valid route for (i) materials and valuable
products and petrochemicals recovery; (ii) waste recycling; and (iii)
elemental characterization. Pyrolysis is also receiving renewed
attention for its operational, economical and environmental
advantages. In this study, samples of polyethylene terephthalate
(PET) and polystyrene (PS) were pyrolysed in a microthermobalance
reactor (using a thermogravimetric-TGA setup). Both
polymers were prepared and conditioned prior to experimentation.
The main objective was to determine the kinetic parameters of the
depolymerization reactions that occur within the thermal degradation
process. Overall kinetic rate constants (ko) and activation energies
(Eo) were determined using the general kinetics theory (GKT)
method previously used by a number of authors. Fitted correlations
were found and validated using the GKT, errors were within ± 5%.
This study represents a fundamental step to pave the way towards the
development of scaling relationship for the investigation of larger
scale reactors relevant to industry.
Abstract: Zeolite A and MCM-41 have extensive applications in basic science, petrochemical science, energy conservation/storage, medicine, chemical sensor, air purification, environmentally benign composite structure and waste remediation. However, the use of zeolite A and MCM-41 in these areas, especially environmental remediation, are restricted due to prohibitive production cost. Efficient recycling of and resource recovery from coal fly ash has been a major topic of current international research interest, aimed at achieving sustainable development of human society from the viewpoints of energy, economy, and environmental strategy. This project reported an original, novel, green and fast methods to produce nano-porous zeolite A and MCM-41 materials from coal fly ash. For zeolite A, this novel production method allows a reduction by half of the total production time while maintaining a high degree of crystallinity of zeolite A which exists in a narrower particle size distribution. For MCM-41, this remarkably green approach, being an environmentally friendly process and reducing generation of toxic waste, can produce pure and long-range ordered MCM-41 materials from coal fly ash. This approach took 24 h at 25 oC to produce 9 g of MCM-41 materials from 30 g of the coal fly ash, which is the shortest time and lowest reaction temperature required to produce pure and ordered MCM-41 materials (having the largest internal surface area) compared to the values reported in the literature. Performance evaluation of the produced zeolite A and MCM-41 materials in wastewater treatment and air pollution control were reported. The residual fly ash was also converted to zeolite Na-P1 which showed good performance in removal of multi-metal ions in wastewater. In wastewater treatment, compared to commercial-grade zeolite A, adsorbents produced from coal fly ash were effective in removing multi heavy metal ions in water and could be an alternative material for treatment of wastewater. In methane emission abatement, the zeolite A (produced from coal fly ash) achieved similar methane removal efficiency compared to the zeolite A prepared from pure chemicals. This report provides the guidance for production of zeolite A and MCM-41 from coal fly ash by a cost-effective approach which opens potential applications of these materials in environmental industry. Finally, environmental and economic aspects of production of zeolite A and MCM-41 from coal fly ash were discussed.
Abstract: This study aimed to evaluate regional soil Borkhar of
the metals Lead has been made. In this field study fires visits to the
regions. The limit of this study located in the East refineries,
petrochemical and power plant to 20 km was selected. The 41 soil
samples from depths of 0 to 10 cm in area and were randomized. Soil
samples were transported to the laboratory and by air was dry and
passed through 2-mil thickness sieve. In the laboratory of physical
and chemical characteristics and concentrations of total absorption
was measured. The results showed that the amount of lead in soil in
many parts of the range higher than the standard limit. Survey maps
show that the lead spatial distribution of the region does not special
pattern.
Abstract: Polyurethane foam (PUF) is formed by a chemical
reaction of polyol and isocyanate. The aim is to understand the
impact of Silicone on synthesizing polyurethane in differentiate
volume of molding. The method used was one step process, which is
simultaneously caried out a blending polyol (petroleum polyol and
soybean polyol), a TDI (2,4):MDI (4,4-) (80:20), a distilled water,
and a silicone. The properties of the material were measured via a
number of parameters, which are polymer density, compressive
strength, and cellular structures. It is found that density of
polyurethane using silicone with volume of molding either 250 ml or
500 ml is lower than without using silicone.
Abstract: This study discusses the effect of uncertainty on
production levels of a petrochemical complex. Uncertainly or
variations in some model parameters, such as prices, supply and
demand of materials, can affect the optimality or the efficiency of any
chemical process. For any petrochemical complex with many plants,
there are many sources of uncertainty and frequent variations which
require more attention. Many optimization approaches are proposed
in the literature to incorporate uncertainty within the model in order
to obtain a robust solution. In this work, a stability analysis approach
is applied to a deterministic LP model of a petrochemical complex
consists of ten plants to investigate the effect of such variations on
the obtained optimal production levels. The proposed approach can
determinate the allowable variation ranges of some parameters,
mainly objective or RHS coefficients, before the system lose its
optimality. Parameters with relatively narrow range of variations, i.e.
stability limits, are classified as sensitive parameters or constraints
that need accurate estimate or intensive monitoring. These stability
limits offer easy-to-use information to the decision maker and help in
understanding the interaction between some model parameters and
deciding when the system need to be re-optimize. The study shows
that maximum production of ethylene and the prices of intermediate
products are the most sensitive factors that affect the stability of the
optimum solution
Abstract: Spent petroleum catalyst from Korean petrochemical
industry contains trace amount of metals such as Ni, V and Mo.
Therefore an attempt was made to recover those trace metal using
bioleaching process. Different leaching parameters such as Fe(II)
concentration, pulp density, pH, temperature and particle size of
spent catalyst particle were studied to evaluate their effects on the
leaching efficiency. All the three metal ions like Ni, V and Mo
followed dual kinetics, i.e., initial faster followed by slower rate. The
percentage of leaching efficiency of Ni and V were higher than Mo.
The leaching process followed a diffusion controlled model and the
product layer was observed to be impervious due to formation of
ammonium jarosite (NH4)Fe3(SO4)2(OH)6. In addition, the lower
leaching efficiency of Mo was observed due to a hydrophobic coating
of elemental sulfur over Mo matrix in the spent catalyst.