Abstract: This research provides a systematic way to study and
better understand double nano-tubular structure of alunina (Al2O3) and
titania (TiO2). The TiO2 NT was prepared by immersing Al2O3
template in 0.02 M titanium fluoride (TiF4) solution (pH=3) at 25 °C
for 120 min, followed by annealing at 450 °C for 1 h to obtain anatase
TiO2 NT in the Al2O3 template. Large-scale development of film for
nanotube-based CO2 capture and conversion can potentially result in
more efficient energy harvesting. In addition, the production process
will be relatively environmentally friendly. The knowledge generated
by this research will significantly advance research in the area of
Al2O3, TiO2, CaO, and Ca2O3 nano-structure film fabrication and
applications for CO2 capture and conversion. This green energy source
will potentially reduce reliance on carbon-based energy resources and
increase interest in science and engineering careers.
Abstract: TiO2 particles have been added in molten aluminium to result in aluminium based cast Al/Al3Ti-Al2O3 composite, which has been added then to molten magnesium to synthesize magnesium based cast Mg-Al/Al3Ti-Al2O3 composite. The nominal compositions in terms of Mg, Al, and TiO2 contents in the magnesium based composites are Mg-9Al-0.6TiO2, Mg-9Al-0.8TiO2, Mg-9Al-1.0TiO2 and Mg-9Al-1.2TiO2 designated respectively as MA6T, MA8T, MA10T and MA12T. The microstructure of the cast magnesium based composite shows grayish rods of intermetallics Al3Ti, inherited from aluminium based composite but these rods, on hot forging, breaks into smaller lengths decreasing the average aspect ratio (length to diameter) from 7.5 to 3.0. There are also cavities in between the broken segments of rods. β-phase in cast microstructure, Mg17Al12, dissolves during heating prior to forging and re-precipitates as relatively finer particles on cooling. The amount of β-phase also decreases on forging as segregation is removed. In both the cast and forged composite, the Brinell hardness increases rapidly with increasing addition of TiO2 but the hardness is higher in forged composites by about 80 BHN. With addition of higher level of TiO2 in magnesium based cast composite, yield strength decreases progressively but there is marginal increase in yield strength over that of the cast Mg-9 wt. pct. Al, designated as MA alloy. But the ultimate tensile strength (UTS) in the cast composites decreases with the increasing particle content indicating possibly an early initiation of crack in the brittle inter-dendritic region and their easy propagation through the interfaces of the particles. In forged composites, there is a significant improvement in both yield strength and UTS with increasing TiO2 addition and also, over those observed in their cast counterpart, but at higher addition it decreases. It may also be noted that as in forged MA alloy, incomplete recovery of forging strain increases the strength of the matrix in the composites and the ductility decreases both in the forged alloy and the composites. Initiation fracture toughness, JIC, decreases drastically in cast composites compared to that in MA alloy due to the presence of intermetallic Al3Ti and Al2O3 particles in the composite. There is drastic reduction of JIC on forging both in the alloy and the composites, possibly due to incomplete recovery of forging strain in both as well as breaking of Al3Ti rods and the voids between the broken segments of Al3Ti rods in composites. The ratio of tearing modulus to elastic modulus in cast composites show higher ratio, which increases with the increasing TiO2 addition. The ratio decreases comparatively more on forging of cast MA alloy than those in forged composites.
Abstract: Chemical stabilization is a technique commonly used
to improve the expansive soil properties. In this regard, an attempt
has been made to evaluate the influence of Calcium Chloride (CaCl2)
stabilizer on the engineering properties of expansive soil. A series of
laboratory experiments including consistency limits, free swell,
compaction, and shear strength tests were performed to investigate
the effect of CaCl2 additive with various percentages 0%, 2%, 5%,
10% and 15% for improving expansive soil. The results obtained
shows that the increase in the percentage of CaCl2decreased the
liquid limit and plasticity index leading to significant reduction in the
free swell index. This, in turn, increased the maximum dry density
and decreased the optimum moisture content which results in greater
strength. The unconfined compressive strength of soil stabilized with
5% CaCl2 increased approximately by 50% as compared to virgin
soil. It can be concluded that CaCl2 had shown promising influence
on the strength and swelling properties of expansive soil, thereby
giving an advantage in improving problematic expansive soil.
Abstract: Al2(HPO4)3 was easily prepared and used as a solid
acid in acetalization of carbonyl compounds at room temperature and
under solvent-free conditions. The protection was done in short
reaction times and in good to high isolated yields. The cheapness and
availability of this reagent with easy procedure and work-up make
this method attractive for the organic synthesis.
Abstract: We present a new subband adaptive filter (R-SAF)
which is robust against impulsive noise in system identification. To
address the vulnerability of adaptive filters based on the L2-norm
optimization criterion against impulsive noise, the R-SAF comes from
the L1-norm optimization criterion with a constraint on the energy
of the weight update. Minimizing L1-norm of the a posteriori error
in each subband with a constraint on minimum disturbance gives
rise to the robustness against the impulsive noise and the capable
convergence performance. Experimental results clearly demonstrate
that the proposed R-SAF outperforms the classical adaptive filtering
algorithms when impulsive noise as well as background noise exist.
Abstract: Approximately 10,000 different types of dyes and
pigments are being used in various industrial applications yearly,
which include the textile and printing industries. However, these dyes
are difficult to degrade naturally once they enter the aquatic system.
Their high persistency in natural environment poses a potential health
hazard to all form of life. Hence, there is a need for alternative dye
removal strategy in the environment via bioremediation. In this study,
fungi laccase is investigated via commercial agar dyes plates and
submerged fermentation to explore the application of fungi laccase in
textile dye wastewater treatment. Two locally isolated basidiomycetes
were screened for laccase activity using media added with commercial
dyes such as 2, 2-azino-bis (3-ethylbenzothiazoline-6-sulfonic acid
(ABTS), guaiacol and Remazol Brillant Blue R (RBBR). Isolate TBB3
(1.70±0.06) and EL2 (1.78±0.08) gave the highest results for ABTS
plates with the appearance of greenish halo on around the isolates.
Submerged fermentation performed on Isolate TBB3 with the
productivity 3.9067 U/ml/day, whereas the laccase activity for Isolate
EL2 was much lower (0.2097 U/ml/day). As isolate TBB3 showed
higher laccase production, it was subjected to molecular
characterization by DNA isolation, PCR amplification and sequencing
of ITS region of nuclear ribosomal DNA. After being compared with
other sequences in National Center for Biotechnology Information
(NCBI database), isolate TBB3 is probably from species Trametes
hirsutei. Further research work can be performed on this isolate by
upscale the production of laccase in order to meet the demands of the
requirement for higher enzyme titer for the bioremediation of textile
dyes.
Abstract: The most crucial aspect that is closely related to vocabulary and the one that needs to be emphasized and investigated more than it has been up until now, is the ability to combine words that co-occur frequently in the language. Pedagogically, collocation is one of the error-provoking aspects in foreign language learning. This is indicative of the dire need to provide L2 learners with tools to help them improve their collocational knowledge. This paper pinpoints the role that collocations play in the English language. Furthermore, it presents pedagogical implications for ESL/EFL learners.
Abstract: Unsteady flow and heat transfer from a circular
cylinder in cross-flow is studied numerically. The governing
equations are solved by using finite volume method. Reynolds
number varies in range of 50 to 200; in this range flow is considered
to be laminar and unsteady. Al2O3 nanoparticle with volume fraction
in range of 5% to 20% is added to pure water. Effects of adding
nanoparticle to pure water on lift and drag coefficient and Nusselt
number is presented. Addition of Al2O3 has inconsiderable effect on
the value of drags and lift coefficient. However, it has significant
effect on heat transfer; results show that heat transfer of Al2O3
nanofluid is about 9% to 36% higher than pure water.
Abstract: Here, we have shown the reaction of [Cr(ArN(CH2)3NAr)2Cl2] (1) where (Ar = 2,6-Pri
2C6H3) and in presence of NaCp (2) (Cp= C5H5 = cyclopentadien), with a center
coordination η5 interaction between Cp as co-ligand and chromium
metal center, for optimization we used density functional theory
(DFT), under methods, explicitly including electrons correlations, for
the final calculations as MB3LYP (Becke) (Lee–Yang–Parr) level of
theory we used to obtain more exact results. This complex was
calculated as electronic energy for molecular system, because the
calculation accounting all electrons correlations interactions. The
optimised of [Cr(ArN(CH2)3NAr)2(η5-Cp)] (Ar = 2,6-Pri2C6H3 and Cp = C5H5) was found to be thermally stable. By using Dewar-Chatt-Duncanson model, as a basis of the molecular orbital (MO) analysis
and showed the highest occupied molecular orbital (HOMO) and
lowest occupied molecular orbital LUMO.
Abstract: The health care must be a right for people around the
world, but in order to guarantee the access to all, it is necessary to
overcome geographical barriers. Telemedicine take advantage of
Information Communication Technologies to deploy health care
services around the world. To achieve those goals, it is necessary to
use existing last mile solution to create access for home users, which
is why is necessary to establish the channel characteristics for those
kinds of services. This paper presents an analysis of network
performance of last mile solution for the use of IPTV broadcasting
with the application of streaming for telemedicine apps.
Abstract: In this numerical study, effects of using Al2O3-water
nanofluid on the rate of heat transfer have been investigated. Physical
model is a square enclosure with insulated top and bottom horizontal
walls, while the vertical walls are kept at different constant
temperatures. Two appropriate models are used to evaluate the
viscosity and thermal conductivity of nanofluid. The governing
stream-vorticity equations are solved using a second order central
finite difference scheme, coupled to the conservation of mass and
energy. The study has been carried out for the nanoparticle diameter
30, 60 and 90 nm and the solid volume fraction 0 to 0.04. Results are
presented by average Nusselt number and normalized Nusselt number
in different range of φ and D for mixed convection dominated
regime. It is found that different heat transfer rate is predicted when
the effect of nanoparticle diameter is taken into account.
Abstract: Rice Husk (RH) is the major byproduct in the
processing of paddy rice. The management of this waste has become
a big challenge to some of the rice producers, some of these wastes
are left in open dumps while some are burn in the open space, and
these two actions have been contributing to environmental pollution.
This study evaluates an alternative waste management of this
agricultural product for use as a civil engineering material. The RH
was burn in a controlled environment to form Rice Husk Ash (RHA).
The RHA was mix with lateritic clay at 0, 2, 4, 6, 8, and 10%
proportion by weight. Chemical test was conducted on the open burn
and controlled burn RHA with the lateritic clay. Physical test such as
particle size distribution, Atterberg limits test, and density test were
carried out on the mix material. The chemical composition obtained
for the RHA showed that the total percentage compositions of Fe2O3,
SiO2 and Al2O3 were found to be above 70% (class “F” pozzolan)
which qualifies it as a very good pozzolan. The coefficient of
uniformity (Cu) was 8 and coefficient of curvature (Cc) was 2 for the
soil sample. The Plasticity Index (PI) for the 0, 2, 4, 6, 8. 10% was
21.0, 18.8, 16.7, 14.4, 12.4 and 10.7 respectively. The work
concluded that RHA can be effectively used in hydraulic barriers and
as a stabilizing agent in soil stabilization.
Abstract: Ceramic obtained on the base of aluminum oxide has
wide application range, because it has unique properties, for example,
wear-resistance, dielectric characteristics, and exploitation ability at
high temperatures and in corrosive atmosphere. Low temperature
synthesis of α-Al2O3 is energo-economical process and it is topical
for developing technologies of corundum ceramics fabrication. In the present work possibilities of low temperature transformation
of oxyhydroxides in α-Al2O3, during the presence of small amount of
rare–earth elements compounds (also Th, Re), have been discussed.
Aluminum unstable oxyhydroxides have been obtained by hydrolysis
of aluminium isopropoxide, nitrates, sulphate, and chloride in
alkaline environment at 80-90ºC temperatures. β-Al(OH)3 has been
received from aluminum powder by ultrasonic development. Drying
of oxyhydroxide sol has been conducted with presence of various
types seeds, which amount reaches 0,1-0,2% (mas). Neodymium,
holmium, thorium, lanthanum, cerium, gadolinium, disprosium
nitrates and rhenium carbonyls have been used as seeds and they
have been added to the sol specimens in amount of 0.1-0.2% (mas)
calculated on metals. Annealing of obtained gels is carried out at 70–
1100ºC for 2 hrs. The same specimen transforms in α-Al2O3 at
1100ºC. At this temperature in case of presence of lanthanum and
gadolinium transformation takes place by 70-85%. In case of
presence of thorium stabilization of γ-and θ-phases takes place. It is
established, that thorium causes inhibition of α-phase generation at
1100ºC, and at the time when in all other doped specimens α-phase is
generated at lower temperatures (1000-1050ºC). Synthesis of various
type compounds and simultaneous consolidation has developed in the
furnace of OXY-GON. Composite materials containing oxide and
non-oxide components close to theoretical data have been obtained in
this furnace respectively. During the work the following devices have
been used: X-ray diffractometer DRON-3M (Cu-Kα, Ni filter,
2º/min), High temperature vacuum furnace OXY-GON, electronic
scanning microscopes Nikon ECLIPSE LV 150, NMM-800TRF,
planetary mill Pulverisette 7 premium line, SHIMADZU Dynamic
Ultra Micro Hardness Tester, DUH-211S, Analysette 12 Dyna sizer.
Abstract: Thermal enhancement of a single mini channel in
Proton Exchange Membrane Fuel Cell (PEMFC) cooling plate is
numerically investigated. In this study, low concentration of Al2O3 in
Water - Ethylene Glycol mixtures is used as coolant in single channel
of carbon graphite plate to mimic the mini channels in PEMFC
cooling plate. A steady and incompressible flow with constant heat
flux is assumed in the channel of 1mm x 5mm x 100mm. Nano
particle of Al2O3 used ranges from 0.1, 0.3 and 0.5 vol %
concentration and then dispersed in 60:40 (water: Ethylene Glycol)
mixture. The effect of different flow rates to fluid flow and heat
transfer enhancement in Re number range of 20 to 140 was observed.
The result showed that heat transfer coefficient was improved by
18.11%, 9.86% and 5.37% for 0.5, 0.3 and 0.1 vol. % Al2O3 in 60:40
(water: EG) as compared to base fluid of 60:40 (water: EG). It is also
showed that the higher vol. % concentration of Al2O3 performed
better in term of thermal enhancement but at the expense of higher
pumping power required due to increase in pressure drop
experienced. Maximum additional pumping power of 0.0012W was
required for 0.5 vol % Al2O3 in 60:40 (water: EG) at Re number 140.
Abstract: This paper reports the viability of developing Zn-27Al
alloy matrix hybrid composites reinforced with alumina, graphite and
fly ash (solid waste bye product of coal in thermal power plants).
This research work was aimed at developing low cost-high
performance Zn-27Al matrix composite with low density. Alumina
particulates (Al2O3), graphite added with 0, 2, 3, 4 and 5 wt% fly ash
were utilized to prepare 10wt% reinforcing phase with Zn-27Al alloy
as matrix using two-step stir casting method. Density measurement,
estimated percentage porosity, tensile testing, micro hardness
measurement and optical microscopy were used to assess the
performance of the composites produced. The results show that the
hardness, ultimate tensile strength, and percent elongation of the
hybrid composites decrease with increase in fly ash content. The
maximum decrease in hardness and ultimate tensile strength of
13.72% and 15.25% respectively were observed for composite grade
containing 5wt% fly ash. The percentage elongation of composite
sample without fly ash is 8.9% which is comparable with that of the
sample containing 2wt% fly ash with percentage elongation of 8.8%.
The fracture toughness of the fly ash containing composites was
however superior to those of composites without fly ash with 5wt%
fly ash containing composite exhibiting the highest fracture
toughness. The results show that fly ash can be utilized as
complementary reinforcement in ZA-27 alloy matrix composite to
reduce cost.
Abstract: This paper aims to study the heat transfer and fluid
flow characteristics of nanofluids used in spray cooling systems. The
effect of spray height, type of nanofluids and concentration of
nanofluids are numerically investigated. Five different nanofluids
such as AgH2O, Al2O3, CuO, SiO2 and TiO2 with volume fraction
range of 0.5% to 2.5% are used. The results revealed that the heat
transfer performance decreases as spray height increases. It is found
that TiO2 has the highest transfer coefficient among other nanofluids.
In dilute spray conditions, low concentration of nanofluids is
observed to be more effective in heat removal in a spray cooling
system.
Abstract: The microstrip antennas area has seen some inventive
work in recent years and is now one of the most dynamic fields of
antenna theory. A novel and simple wideband monopole antenna is
presented printed on a single dielectric substrate which is fed by a 50
ohm microstrip line having a low-profile antenna structure with two
parallel s-shaped meandered line of same size. This antenna is fed by
a coaxial feeding tube. In this research, S–form microstrip patch antenna is designed from
measuring the prototypes of the proposed antenna one available
bands with 10db return loss bandwidths of about GPS application
(GPS L2 1490 MHz) and covering the 1400 to 1580 MHz frequency
band at 1.5 GHz, the simulated results for main parameters such as
return loss, impedance bandwidth, radiation patterns, and gains are
also discussed herein. The modeling study shows that such antennas,
in simplicity design and supply, can satisfy GPS application. Two
parallel slots are incorporated to disturb the surface flow path,
introducing local inductive effect. This antenna is fed by a coaxial
feeding tube.
Abstract: In this study, a multi objective optimization for end
milling of Al 6061 alloy has been presented to provide better
surface quality and higher Material Removal Rate (MRR). The input
parameters considered for the analysis are spindle speed, depth of cut
and feed. The experiments were planned as per Taguchis design of
experiment, with L27 orthogonal array. The Grey Relational Analysis
(GRA) has been used for transforming multiple quality responses
into a single response and the weights of the each performance
characteristics are determined by employing the Principal Component
Analysis (PCA), so that their relative importance can be properly and
objectively described. The results reveal that Taguchi based G-PCA
can effectively acquire the optimal combination of cutting parameters.
Abstract: In the present study, the properties of Al-Al2O3
nanocomposite hollow sphere structures were investigated. For this
reason, the Al-based nanocomposite hollow spheres with different
amounts of nano-alumina reinforcement (0-10wt %) and different
ratio of thickness to diameter (t/D: 0.06-0.3) were prepared via a
powder metallurgy method. Then, the effect of mentioned parameters
was studied on physical and quasi static mechanical properties of
their related prepared structures (open/closed cell) such as density,
hardness, strength, and energy absorption. It was found that, as the
t/D ratio increases the relative density, compressive strength and
energy absorption increase. The highest values of strength and energy
absorption were obtained from the specimen with 5 wt. % of
nanoparticle reinforcement, t/D of 0.3 (t=1 mm, D=400μm) as 22.88
MPa and 13.24 MJ/m3, respectively. The moderate specific strength
of prepared composites in the present study showed the good
consistency with the properties of others low carbon steel composite
with similar structure.
Abstract: A bauxite ore can be utilized in Bayer Process, if the
mass ratio of Al2O3 to SiO2 is greater than 10. Otherwise, its FexOy
and SiO2 content should be removed. On the other hand, removal of
TiO2 from the bauxite ore would be beneficial because of both
lowering the red mud residue and obtaining a valuable raw material
containing TiO2 mineral. In this study, the low grade diasporic
bauxite ore of Yalvaç, Isparta, Turkey was roasted under reducing
atmosphere and subjected to magnetic separation. According to the
experimental results, 800°C for reduction temperature and 20000
Gauss of magnetic intensity were found to be the optimum
parameters for removal of iron oxide and rutile from the nonmagnetic
ore. On the other hand, 600°C and 5000 Gauss were
determined to be the optimum parameters for removal of silica from
the non-magnetic ore.