Abstract: Bio-based carbon nanotubes (CNTs) have received considerable research attention due to their comparative advantages of high level stability, simplistic use, low toxicity and overall environmental friendliness. New potentials for improvement in heat transfer applications are presented due to their high aspect ratio, high thermal conductivity and special surface area. Phonons have been identified as being responsible for thermal conductivities in carbon nanotubes. Therefore, understanding the mechanism of heat conduction in CNTs involves investigating the difference between the varieties of phonon modes and knowing the kinds of phonon modes that play the dominant role. In this review, a reference to a different number of studies is made and in addition, the role of phonon relaxation rate mainly controlled by boundary scattering and three-phonon Umklapp scattering process was investigated. Results show that the phonon modes are sensitive to a number of nanotube conditions such as: diameter, length, temperature, defects and axial strain. At a low temperature (
Abstract: Pectinatella magnifica (Leidy, 1851) is an invasive freshwater animal that lives in colonies. A colony of Pectinatella magnifica (a gelatinous blob) can be up to several feet in diameter large and under favorable conditions it exhibits an extreme growth rate. Recently European countries around rivers of Elbe, Oder, Danube, Rhine and Vltava have confirmed invasion of Pectinatella magnifica, including freshwater reservoirs in South Bohemia (Czech Republic). Our project (Czech Science Foundation, GAČR P503/12/0337) is focused onto biology and chemistry of Pectinatella magnifica. We monitor the organism occurrence in selected South Bohemia ponds and sandpits during the last years, collecting information about physical properties of surrounding water, and sampling the colonies for various analyses (classification, maps of secondary metabolites, toxicity tests). Because the gelatinous matrix is during the colony lifetime also a host for algae, bacteria and cyanobacteria (co-habitants), in this contribution, we also applied a high performance liquid chromatography (HPLC) method for determination of potentially present cyanobacterial toxins (microcystin-LR, microcystin-RR, nodularin). Results from the last 3-year monitoring show that these toxins are under limit of detection (LOD), so that they do not represent a danger yet. The final goal of our study is to assess toxicity risks related to fresh water resources invaded by Pectinatella magnifica, and to understand the process of invasion, which can enable to control it.
Abstract: Hybrid propulsion combines beneficial properties of both solid and liquid rockets, such as multiple restarts, throttability as well as simplicity and reduced costs. A nitrous oxide (N2O)/paraffin-based hybrid rocket engine demonstrator is currently under development at the Italian Aerospace Research Center (CIRA) within the national research program HYPROB, funded by the Italian Ministry of Research. Nitrous oxide belongs to the class of self-pressurizing propellants that exhibit a high vapor pressure at standard ambient temperature. This peculiar feature makes those fluids very attractive for space rocket applications because it avoids the use of complex pressurization systems, leading to great benefits in terms of weight savings and reliability. To avoid feed-system-coupled instabilities, the phase change is required to occur through the injectors. In this regard, the oxidizer is stored in liquid condition while target chamber pressures are designed to lie below vapor pressure. The consequent cavitation and flash vaporization constitute a remarkably complex phenomenology that arises great modelling challenges. Thus, it is clear that the design of the injection system is fundamental for the full exploitation of hybrid rocket engine throttability. The Analytical Hierarchy Process has been used to select the injection architecture as best compromise among different design criteria such as functionality, technology innovation and cost. The impossibility to use engineering simplified relations for the dimensioning of the injectors led to the needs of applying a numerical approach based on OpenFOAM®. The numerical tool has been validated with selected experimental data from literature. Quantitative, as well as qualitative comparisons are performed in terms of mass flow rate and pressure drop across the injector for several operating conditions. The results show satisfactory agreement with the experimental data. Modeling assumptions, together with their impact on numerical predictions are discussed in the paper. Once assessed the reliability of the numerical tool, the injection plate has been designed and sized to guarantee the required amount of oxidizer in the combustion chamber and therefore to assure high combustion efficiency. To this purpose, the plate has been designed with multiple injectors whose number and diameter have been selected in order to reach the requested mass flow rate for the two operating conditions of maximum and minimum thrust. The overall design has been finally verified through three-dimensional computations in cavitating non-reacting conditions and it has been verified that the proposed design solution is able to guarantee the requested values of mass flow rates.
Abstract: In this paper, triangular lattice index-guiding photonic crystal fibers (PCFs) are synthesized to compensate the chromatic dispersion of a single mode fiber (SMF-28) for an 80 km optical link operating at 1.55 µm, by using the directed tabu search algorithm. Hole-to-hole distance, circular air-hole diameter, solid-core diameter, ring number and PCF length parameters are optimized for this purpose. Three Synthesized PCFs with different physical parameters are compared in terms of their objective functions values, residual dispersions and compensation ratios.
Abstract: Automotive designers have been trying to use dimples to reduce drag in vehicles. In this work, a car model has been applied with dimple surface with a parameter called dimple ratio DR, the ratio between the depths of the half dimple over the print diameter of the dimple, has been introduced and numerically simulated via k-ε turbulence model to study the aerodynamics performance with the increasing depth of the dimples The Ahmed body car model with 25 degree slant angle is simulated with the DR of 0.05, 0.2, 0.3 0.4 and 0.5 at Reynolds number of 176387 based on the frontal area of the car model. The geometry of dimple changes the kinematics and dynamics of flow. Complex interaction between the turbulent fluctuating flow and the mean flow escalates the turbulence quantities. The maximum level of turbulent kinetic energy occurs at DR = 0.4. It can be concluded that the dimples have generated extra turbulence energy at the surface and as a result, the application of dimples manages to reduce the drag coefficient of the car model compared to the model with smooth surface.
Abstract: Wetting efficiency of microstructures or nanostructures patterned on Si wafers is a real challenge in integrated circuits manufacturing. In fact, bad or non-uniform wetting during wet processes limits chemical reactions and can lead to non-complete etching or cleaning inside the patterns and device defectivity. This issue is more and more important with the transistors size shrinkage and concerns mainly high aspect ratio structures. Deep Trench Isolation (DTI) structures enabling pixels’ isolation in imaging devices are subject to this phenomenon. While low-frequency acoustic reflectometry principle is a well-known method for Non Destructive Test applications, we have recently shown that it is also well suited for nanostructures wetting characterization in a higher frequency range. In this paper, we present a high-frequency acoustic reflectometry characterization of DTI wetting through a confrontation of both experimental and modeling results. The acoustic method proposed is based on the evaluation of the reflection of a longitudinal acoustic wave generated by a 100 µm diameter ZnO piezoelectric transducer sputtered on the silicon wafer backside using MEMS technologies. The transducers have been fabricated to work at 5 GHz corresponding to a wavelength of 1.7 µm in silicon. The DTI studied structures, manufactured on the wafer frontside, are crossing trenches of 200 nm wide and 4 µm deep (aspect ratio of 20) etched into a Si wafer frontside. In that case, the acoustic signal reflection occurs at the bottom and at the top of the DTI enabling its characterization by monitoring the electrical reflection coefficient of the transducer. A Finite Difference Time Domain (FDTD) model has been developed to predict the behavior of the emitted wave. The model shows that the separation of the reflected echoes (top and bottom of the DTI) from different acoustic modes is possible at 5 Ghz. A good correspondence between experimental and theoretical signals is observed. The model enables the identification of the different acoustic modes. The evaluation of DTI wetting is then performed by focusing on the first reflected echo obtained through the reflection at Si bottom interface, where wetting efficiency is crucial. The reflection coefficient is measured with different water / ethanol mixtures (tunable surface tension) deposited on the wafer frontside. Two cases are studied: with and without PFTS hydrophobic treatment. In the untreated surface case, acoustic reflection coefficient values with water show that liquid imbibition is partial. In the treated surface case, the acoustic reflection is total with water (no liquid in DTI). The impalement of the liquid occurs for a specific surface tension but it is still partial for pure ethanol. DTI bottom shape and local pattern collapse of the trenches can explain these incomplete wetting phenomena. This high-frequency acoustic method sensitivity coupled with a FDTD propagative model thus enables the local determination of the wetting state of a liquid on real structures. Partial wetting states for non-hydrophobic surfaces or low surface tension liquids are then detectable with this method.
Abstract: This paper presents the data of a series of two-dimensional Discrete Element Method (DEM) simulations of a large-diameter rigid monopile subjected to cyclic loading under a high gravitational force. At present, monopile foundations are widely used to support the tall and heavy wind turbines, which are also subjected to significant from wind and wave actions. A safe design must address issues such as rotations and changes in soil stiffness subject to these loadings conditions. Design guidance on the issue is limited, so are the availability of laboratory and field test data. The interpretation of these results in sand, such as the relation between loading and displacement, relies mainly on empirical correlations to pile properties. Regarding numerical models, most data from Finite Element Method (FEM) can be found. They are not comprehensive, and most of the FEM results are sensitive to input parameters. The micro scale behaviour could change the mechanism of the soil-structure interaction. A DEM model was used in this paper to study the cyclic lateral loads behaviour. A non-dimensional framework is presented and applied to interpret the simulation results. The DEM data compares well with various set of published experimental centrifuge model test data in terms of lateral deflection. The accumulated permanent pile lateral displacements induced by the cyclic lateral loads were found to be dependent on the characteristics of the applied cyclic load, such as the extent of the loading magnitudes and directions.
Abstract: The discharge of dye in industrial effluents is of great concern because their presence and accumulation have a toxic or carcinogenic effect on living species. The removal of such compounds at such low levels is a difficult problem. The adsorption process is an effective and attractive proposition for the treatment of dye contaminated wastewater. Activated carbon adsorption in fixed beds is a very common technology in the treatment of water and especially in processes of decolouration. However, it is expensive and the powdered one is difficult to be separated from aquatic system when it becomes exhausted or the effluent reaches the maximum allowable discharge level. The regeneration of exhausted activated carbon by chemical and thermal procedure is also expensive and results in loss of the sorbent. The focus of this research was to evaluate the adsorption potential of the raw clay in removing rhodamine B from aqueous solutions using a laboratory fixed-bed column. The continuous sorption process was conducted in this study in order to simulate industrial conditions. The effect of process parameters, such as inlet flow rate, adsorbent bed height, and initial adsorbate concentration on the shape of breakthrough curves was investigated. A glass column with an internal diameter of 1.5 cm and height of 30 cm was used as a fixed-bed column. The pH of feed solution was set at 8.5. Experiments were carried out at different bed heights (5 - 20 cm), influent flow rates (1.6- 8 mL/min) and influent rhodamine B concentrations (20 - 80 mg/L). The obtained results showed that the adsorption capacity increases with the bed depth and the initial concentration and it decreases at higher flow rate. The column regeneration was possible for four adsorption–desorption cycles. The clay column study states the value of the excellent adsorption capacity for the removal of rhodamine B from aqueous solution. Uptake of rhodamine B through a fixed-bed column was dependent on the bed depth, influent rhodamine B concentration, and flow rate.
Abstract: In this paper, shear behavior of reconstituted clay reinforced with varying diameter of sand compaction piles with area replacement-ratio (as) of 6.25, 10.24, 16, 20.25 and 64% in 100mm diameter and 200mm long clay specimens is modeled using consolidated drained and undrained triaxial tests under different confining pressures ranging from 50kPa to 575kPa. The test results show that the stress-strain behavior of the clay was highly influenced by the presence of SCP. The insertion of SCPs into soft clay has shown to have a positive effect on the load carrying capacity of the clay, resulting in a composite soil mass that has greater shear strength and improved stiffness compared to the unreinforced clay due to increased reinforcement area ratio. In addition, SCP also acts as vertical drain in the clay thus accelerating the dissipation of excess pore water pressures that are generated during loading by shortening the drainage path and activating radial drainage, thereby reducing post-construction settlement. Thus, sand compaction piles currently stand as one of the most viable and practical techniques for improving the mechanical properties of soft clays.
Abstract: In the process of recovering oil in weak sandstone formations, the strength of sandstones around the wellbore is weakened due to the increase of effective stress/load from the completion activities around the cavity. The weakened and de-bonded sandstone may be eroded away by the produced fluid, which is termed sand production. It is one of the major trending subjects in the petroleum industry because of its significant negative impacts, as well as some observed positive impacts. For efficient sand management therefore, there has been need for a reliable study tool to understand the mechanism of sanding. One method of studying sand production is the use of the widely recognized Discrete Element Method (DEM), Particle Flow Code (PFC3D) which represents sands as granular individual elements bonded together at contact points. However, there is limited knowledge of the particle-scale behavior of the weak sandstone, and the parameters that affect sanding. This paper aims to investigate the reliability of using PFC3D and a simple Darcy flow in understanding the sand production behavior of a weak sandstone. An isotropic tri-axial test on a weak oil sandstone sample was first simulated at a confining stress of 1MPa to calibrate and validate the parallel bond models of PFC3D using a 10m height and 10m diameter solid cylindrical model. The effect of the confining stress on the number of bonds failure was studied using this cylindrical model. With the calibrated data and sample material properties obtained from the tri-axial test, simulations without and with fluid flow were carried out to check on the effect of Darcy flow on bonds failure using the same model geometry. The fluid flow network comprised of every four particles connected with tetrahedral flow pipes with a central pore or flow domain. Parametric studies included the effects of confining stress, and fluid pressure; as well as validating flow rate – permeability relationship to verify Darcy’s fluid flow law. The effect of model size scaling on sanding was also investigated using 4m height, 2m diameter model. The parallel bond model successfully calibrated the sample’s strength of 4.4MPa, showing a sharp peak strength before strain-softening, similar to the behavior of real cemented sandstones. There seems to be an exponential increasing relationship for the bigger model, but a curvilinear shape for the smaller model. The presence of the Darcy flow induced tensile forces and increased the number of broken bonds. For the parametric studies, flow rate has a linear relationship with permeability at constant pressure head. The higher the fluid flow pressure, the higher the number of broken bonds/sanding. The DEM PFC3D is a promising tool to studying the micromechanical behavior of cemented sandstones.
Abstract: To increase the temperature contrast in thermal
images, the characteristics of the electrical conductivity and thermal
imaging modalities can be combined. In this experimental study, it is
objected to observe whether the temperature contrast created by the
tumor tissue can be improved just due to the current application
within medical safety limits. Various thermal breast phantoms are
developed to simulate the female breast tissue. In vitro experiments
are implemented using a thermal infrared camera in a controlled
manner. Since experiments are implemented in vitro, there is no
metabolic heat generation and blood perfusion. Only the effects and
results of the electrical stimulation are investigated. Experimental
study is implemented with two-dimensional models. Temperature
contrasts due to the tumor tissues are obtained. Cancerous tissue is
determined using the difference and ratio of healthy and tumor
images. 1 cm diameter single tumor tissue causes almost 40 °mC
temperature contrast on the thermal-breast phantom. Electrode
artifacts are reduced by taking the difference and ratio of background
(healthy) and tumor images. Ratio of healthy and tumor images show
that temperature contrast is increased by the current application.
Abstract: Interaction between mixing and crystallization is often
ignored despite the fact that it affects almost every aspect of the
operation including nucleation, growth, and maintenance of the
crystal slurry. This is especially pronounced in multiple impeller
systems where flow complexity is increased. By choosing proper
mixing parameters, what closely depends on the knowledge of the
hydrodynamics in a mixing vessel, the process of batch cooling
crystallization may considerably be improved. The values that render
useful information when making this choice are mixing time and
power consumption. The predominant motivation for this work was
to investigate the extent to which radial dual impeller configuration
influences mixing time, power consumption and consequently the
values of metastable zone width and nucleation rate. In this research,
crystallization of borax was conducted in a 15 dm3 baffled batch
cooling crystallizer with an aspect ratio (H/T) of 1.3. Mixing was
performed using two straight blade turbines (4-SBT) mounted on the
same shaft that generated radial fluid flow. Experiments were
conducted at different values of N/NJS ratio (impeller speed/
minimum impeller speed for complete suspension), D/T ratio
(impeller diameter/crystallizer diameter), c/D ratio (lower impeller
off-bottom clearance/impeller diameter), and s/D ratio (spacing
between impellers/impeller diameter). Mother liquor was saturated at
30°C and was cooled at the rate of 6°C/h. Its concentration was
monitored in line by Na-ion selective electrode. From the values of
supersaturation that was monitored continuously over process time, it
was possible to determine the metastable zone width and
subsequently the nucleation rate using the Mersmann’s nucleation
criterion. For all applied dual impeller configurations, the mixing
time was determined by potentiometric method using a pulse
technique, while the power consumption was determined using a
torque meter produced by Himmelstein & Co. Results obtained in
this investigation show that dual impeller configuration significantly
influences the values of mixing time, power consumption as well as
the metastable zone width and nucleation rate. A special attention
should be addressed to the impeller spacing considering the flow
interaction that could be more or less pronounced depending on the
spacing value.
Abstract: This paper presents the performance characteristics of
Darrieus-type vertical axis wind turbine (VAWT) with NACA airfoil
blades. The performance of Darrieus-type VAWT can be
characterized by torque and power. There are various parameters
affecting the performance such as chord length, helical angle, pitch
angle and rotor diameter. To estimate the optimum shape of Darrieustype
wind turbine in accordance with various design parameters, we
examined aerodynamic characteristics and separated flow occurring
in the vicinity of blade, interaction between flow and blade, and
torque and power characteristics derived from it. For flow analysis,
flow variations were investigated based on the unsteady RANS
(Reynolds-averaged Navier-Stokes) equation. Sliding mesh algorithm
was employed in order to consider rotational effect of blade. To
obtain more realistic results we conducted experiment and numerical
analysis at the same time for three-dimensional shape. In addition,
several parameters (chord length, rotor diameter, pitch angle, and
helical angle) were considered to find out optimum shape design and
characteristics of interaction with ambient flow. Since the NACA
airfoil used in this study showed significant changes in magnitude of
lift and drag depending on an angle of attack, the rotor with low drag,
long cord length and short diameter shows high power coefficient in
low tip speed ratio (TSR) range. On the contrary, in high TSR range,
drag becomes high. Hence, the short-chord and long-diameter rotor
produces high power coefficient. When a pitch angle at which airfoil
directs toward inside equals to -2° and helical angle equals to 0°,
Darrieus-type VAWT generates maximum power.
Abstract: The present study investigates the effectiveness of
newly designed clayey pellets (fired clay pellets diameter sizes of 5
and 8 mm, and unfired clay pellets with the diameter size of 15 mm)
as the beds in the column adsorption process. The adsorption
experiments in the batch mode were performed before the column
experiment with the purpose to determine the order of adsorbent
package in the column which was to be designed in the investigation.
The column experiment was performed by using a known mass of the
clayey beds and the volume of the waste printing developer, which
was purified. The column was filled in the following order: fired clay
pellets of the diameter size of 5 mm, fired clay pellets of the diameter
size of 8 mm, and unfired clay pellets of the diameter size of 15 mm.
The selected order of the adsorbents showed a high removal
efficiency for zinc (97.8%) and copper (81.5%) ions. These
efficiencies were better than those in the case of the already existing
mode adsorption. The obtained experimental data present a good
basis for the selection of an appropriate column fill, but further
testing is necessary in order to obtain more accurate results.
Abstract: Nanofibers are defined as fibers with diameters less
than 100 nanometers. In this study, behaviours of activated carbon
nanofiber (ACNF), carbon nanofiber (CNF), polyacrylonitrile/ carbon
nanotube (PAN/CNT), polyvinyl alcohol/nanosilver (PVA/Ag) in
proton exchange membrane (PEM) fuel cells are investigated
experimentally. This material was used as gas diffusion layer (GDL)
in PEM fuel cells. In this study, the electrical conductivities of
nanofiber and nanofiber/nanoparticles have been studied to
understand their effects on PEM fuel cell performance. According to
the experimental results, the maximum electrical conductivity
performance of the fuel cell with nanofiber was found to be at
PVA/Ag (at UConn condition). The electrical conductivities of CNF,
ACNF, PAN/CNT are lower for PEM. The resistance of cell with
PVA/Ag is lower than the resistance of cell with PAN/CNT, ACNF,
CNF.
Abstract: This article developed an ion thruster optic system
sputter erosion depth numerical 3D model by IFE-PIC (Immersed
Finite Element-Particle-in-Cell) and Mont Carlo method, and
calculated the downstream surface sputter erosion rate of accelerator
grid; compared with LIPS-200 life test data. The results of the
numerical model are in reasonable agreement with the measured data.
Finally, we predicted the lifetime of the 20cm diameter ion thruster via
the erosion data obtained with the model. The ultimate result
demonstrated that under normal operating condition, the erosion rate
of the grooves wears on the downstream surface of the accelerator grid
is 34.6μm⁄1000h, which means the conservative lifetime until
structural failure occurring on the accelerator grid is 11500 hours.
Abstract: Highly stable and homogeneously dispersed amino
acid coated silver nanoparticles (ANP) of ≈ 10 nm diameter, ranging
from 420 to 430 nm are prepared on AgNO3 solution addition to gum
of Azadirachta indica solution at 373.15 K. The amino acids were
selected based on their polarity. The synthesized nanoparticles were
characterized by UV-Vis, FTIR spectroscopy, HR-TEM, XRD, SEM
and 1H-NMR. The coated nanoparticles were used as catalyst for the
reduction of methylene blue dye in presence of Sn(II) in aqueous,
anionic and cationic micellar media. The rate of reduction of dye was
determined by measuring the absorbance at 660 nm,
spectrophotometrically and followed the order: Kcationic > Kanionic >
Kwater. After 12 min and in absence of the ANP, only 2%, 3% and 6%
of the dye reduction was completed in aqueous, anionic and cationic
micellar media respectively while, in presence of ANP coated by
polar neutral amino acid with non-polar -R group, the reduction
completed to 84%, 95% and 98% respectively. The ANP coated with
polar neutral amino acid having non-polar -R group, increased the
rate of reduction of the dye by 94, 3205 and 6370 folds in aqueous,
anionic and cationic micellar media respectively. Also, the rate of
reduction of the dye increased by three folds when the micellar media
was changed from anionic to cationic when the ANP is coated by a
polar neutral amino acid having a non-polar -R group.
Abstract: This study investigated the effects of thermal
treatment on Tualang honey sample in terms of honey colour and
heat-induced small metabolites. The heating process was carried out
in a temperature controlled water batch at 90oC for 4 hours. The
honey samples were put in cylinder tubes with the dimension of 1 cm
diameter and 10 cm length for homogenous heat transfer. The results
found that the thermal treatment produced not only
hydroxylmethylfurfural, but also other harmful substances such as
phthalic anhydride and radiolytic byproducts. The degradation of
honey protein was due to the detection of free amino acids such as
cysteine and phenylalanine in heat-treated honey samples. Sugar
dehydration was also occurred because fragmented di-galactose was
identified based on the presence of characteristic ions in the mass
fragmentation pattern. The honey colour was found getting darker as
the heating duration was increased up to 4 hours. Approximately, 60
mm PFund of increment was noticed for the honey colour with the
colour change rate of 14.8 mm PFund per hour. Based on the
principal component analysis, the score plot clearly shows that the
chemical profile of Tualang honey was significantly altered after 2
hours of heating at 90oC.
Abstract: A three-dimensional numerical simulation of flow
through mini and microchannels with designed roughness is
conducted here. The effect of the roughness height (surface
roughness), geometry, Reynolds number on the friction factor, and
Nusselt number is investigated. The study is carried out by
employing CFD software, CFX. Our work focuses on a water flow
inside a circular mini-channel of 1 mm and microchannels of 500 and
100 m in diameter. The speed entry varies from 0.1 m/s to 20 m/s.
The general trend can be observed that bigger sizes of roughness
element lead to higher flow resistance. It is found that the friction
factor increases in a nonlinear fashion with the increase in obstruction
height. Particularly, the effect of roughness can no longer be ignored
at relative roughness height higher than 3%. A significant increase in
Poiseuille number is detected for all configurations considered. The
same observation can be done for Nusselt number. The transition
zone between laminar and turbulent flow depends on the channel
diameter.
Abstract: Production fluids are transported from the platform to
tankers or process facilities through transfer pipelines. Water being
one of the heavier phases tends to settle at the bottom of pipelines
especially at low flow velocities and this has adverse consequences
for pipeline integrity. On restart after a shutdown, this could result in
corrosion and issues for process equipment, thus the need to have the
heavier liquid dispersed into the flowing lighter fluid. This study
looked at the flow regime of low water cut and low flow velocity oil
and water flow using conductive film thickness probes in a large
diameter 4-inch pipe to obtain oil and water interface height and the
interface structural velocity. A wide range of 0.1–1.0 m/s oil and
water mixture velocities was investigated for 0.5–5% water cut. Two
fluid model predictions were used to compare with the experimental
results.