Abstract: This paper presents a method of economic factorial analysis of the CO2 emissions based on the extension of the Divisia index to interconnected factors. This approach, contrary to the Kaya identity, considers three main factors of the CO2 emissions: gross domestic product, energy consumption, and population - as equally important, and allows for accounting of all of them simultaneously. The three factors are included into analysis together with their carbon intensities that allows for obtaining a comprehensive picture of the change in the CO2 emissions. A computer program in R-language that is available for free download serves automation of the calculations. A case study of the U.S. carbon dioxide emissions is used as an example.
Abstract: Quercetin and (+)-catechin are metabolites present in Phyllanthus niruri plant, have potential in medicinal uses as anticancer and antioxidant agents. Studies on production of quercetin and (+)-catechin from P. niruri callus culture via in vitro technique were carried out and the results were compared to the intact plant. P. niruri explants were cultured on Murashige and Skoog (MS) solidified media supplemented with several phytohormone combinations for one month. The metabolites were extracted from P. niruri callus and intact plant by using carbon dioxide supercritical fluid extraction (SFE) with ethanol as modifier and solvent extraction techniques. The extracts were analyzed by means of HPLC method. Results showed that P. niruri callus culture was successfully established. The highest content of quercetin (1.72%) was found from P. niruri callus grown in media supplemented with 0.8mg/L kinetin and 0.2mg/L 2,4-dicholophenoxyacetic acid (2,4-D), which was 1.2 fold higher than intact plant. Meanwhile, the highest amounts of (+)-catechin (0.63%) was found from P. niruri callus grown in media with addition of 0.2mg/L 1-naphthalene acetic acid (NAA) and 0.8mg/L 2,4-D. The SFE condition in this study showed better extraction efficiency when higher contents of selected metabolites were found in all SFE extracts compared to the common solvent extracts.
Abstract: Carbon dioxide has been well associated with greenhouse effect, and due to its corrosive nature it is an undesirable compound. A variety of physical-chemical processes are available for the removal of carbon dioxide. Previous attempts in this field have established alkanolamine group has the capability to remove carbon dioxide. So, this study combined the polymeric membrane and alkanolamine solutions to fabricate the amine polymeric membrane (APM) to remove carbon dioxide (CO2). This study entails the effect of three types of amines, monoethanolamine (MEA), diethanolamine (DEA), and methyldiethanolamine (MDEA). The effect of each alkanolamine group on the morphology and performance of polyether sulfone (PES) polymeric membranes was studied. Flat sheet membranes were fabricated by solvent evaporation method by adding polymer and different alkanolamine solutions in the N-Methyl-2-pyrrolidone (NMP) solvent. The final membranes were characterized by using Field Emission Electron Microscope (FESEM), Fourier Transform Infrared (FTIR), and Thermo-Gravimetric Analysis (TGA). The membrane separation performance was studied. The PES-DEA and PES-MDEA membrane has good ability to remove carbon dioxide.
Abstract: Calcium oxide (CaO) as carbon dioxide (CO2)
adsorbent at the elevated temperature has been very well-received
thus far. The CaO can be synthesized from natural calcium carbonate
(CaCO3) sources through the reversible calcination-carbonation
process. In the study, cockle shell has been selected as CaO
precursors. The objectives of the study are to investigate the
performance of calcination and carbonation with respect to different
temperature, heating rate, particle size and the duration time. Overall,
better performance is shown at the calcination temperature of 850oC
for 40 minutes, heating rate of 20oC/min, particle size of < 0.125mm
and the carbonation temperature is at 650oC. The synthesized
materials have been characterized by nitrogen physisorption and
surface morphology analysis. The effectiveness of the synthesized
cockle shell in capturing CO2 (0.72 kg CO2/kg adsorbent) which is
comparable to the commercialized adsorbent (0.60 kg CO2/kg
adsorbent) makes them as the most promising materials for CO2
capture.
Abstract: Any use of energy in industrial productive activities is combined with various environment impacts. Withintransportation,
this fact was not only found among land transport, railways and maritime transport, but also in the air transport industry. An effective climate protection requires strategies and measures for reducing all
greenhouses gas emissions, in particular carbon dioxide, and must
take into account the economic, ecologic and social aspects. It seem simperative now to develop and manufacture environmentally
friendly products and systems, to reduce consumption and use less
resource, and to save energy and power. Today-sproducts could
better serve these requirements taking into account the integration of
a power management system into the electrical power system.This
paper gives an overview of an approach ofpower management with
load prioritization in modernaircraft. Load dimensioning and load
management strategies on current civil aircraft will be presented and
used as a basis for the proposed approach.
Abstract: In this study the enthalpies of dissociation for pure
methane and pure carbon dioxide was calculated using a hydrate
equilibrium data obtained in this study. The enthalpy of dissociation
was determined using Clausius-Clapeyron equation. The results were
compared with the values reported in literature obtained using
various techniques.
Abstract: The development of wearable sensing technologies is a great challenge which is being addressed by the Proetex FP6 project (www.proetex.org). Its main aim is the development of wearable sensors to improve the safety and efficiency of emergency personnel. This will be achieved by continuous, real-time monitoring of vital signs, posture, activity, and external hazards surrounding emergency workers. We report here the development of carbon dioxide (CO2) sensing boot by incorporating commercially available CO2 sensor with a wireless platform into the boot assembly. Carefully selected commercially available sensors have been tested. Some of the key characteristics of the selected sensors are high selectivity and sensitivity, robustness and the power demand. This paper discusses some of the results of CO2 sensor tests and sensor integration with wireless data transmission
Abstract: In industrial scale of Gas to Liquid (GTL) process in
Fischer-Tropsch (FT) synthesis, a part of reactor outlet gases such as
CO2 and CH4 as side reaction products, is usually recycled. In this
study, the influence of CO2 and CH4 on the performance and
selectivity of Co-Ru/Al2O3 catalyst is investigated by injection of
these gases (0-20 vol. % of feed) to the feed stream. The effect of
temperature and feed flow rate, are also inspected. The results show
that low amounts of CO2 in the feed stream, doesn`t change the
catalyst activity significantly but increasing the amount of CO2 (more
than 10 vol. %) cause the CO conversion to decrease and the
selectivity of heavy components to increase. Methane acts as an inert
gas and doesn`t affect the catalyst performance. Increasing feed flow
rate has negative effect on both CO conversion and heavy component
selectivity. By raising the temperature, CO conversion will increase
but there are more volatile components in the product. The effect of
CO2 on the catalyst deactivation is also investigated carefully and a
mechanism is suggested to explain the negative influence of CO2 on
catalyst deactivation.
Abstract: Due to urbanization, trees and plants which covered a great land mass of the earth and are an excellent carbon dioxide (CO2) absorber through photosynthesis are being replaced by several concrete based structures. It is therefore important to have these cement based structures absorb the large volume of carbon dioxide which the trees would have removed from the atmosphere during their useful lifespan. Hence the need for these cement based structures to be designed to serve other useful purposes in addition to shelter. This paper reviews the properties of Sodium carbonate and sugar as admixtures in concrete with respect to improving carbon sequestration in concrete.
Abstract: In recent years, global warming has become a
worldwide problem. The reduction of carbon dioxide emissions is a
top priority for many companies in the manufacturing industry. In the
automobile industry as well, the reduction of carbon dioxide emissions
is one of the most important issues. Technology to reduce the weight
of automotive parts improves the fuel economy of automobiles, and is
an important technology for reducing carbon dioxide. Also, even if
this weight reduction technology is applied to electric automobiles
rather than gasoline automobiles, reducing energy consumption
remains an important issue. Plastic processing of hollow pipes is one
important technology for realizing the weight reduction of automotive
parts. Ohashi et al. [1],[2] present an example of research on pipe
formation in which a process was carried out to enlarge a pipe
diameter using a lost core, achieving the suppression of wall thickness
reduction and greater pipe expansion than hydroforming.
In this study, we investigated a method to increase the wall
thickness of a pipe through pipe compression using planetary rolls.
The establishment of a technology whereby the wall thickness of a
pipe can be controlled without buckling the pipe is an important
technology for the weight reduction of products. Using the finite
element analysis method, we predicted that it would be possible to
increase the compression of an aluminum pipe with a 3mm wall
thickness by approximately 20%, and wall thickness by approximately
20% by pressing the hollow pipe with planetary rolls.
Abstract: Continuous measurements and multivariate methods are applied in researching the effects of energy consumption on indoor air quality (IAQ) in a Finnish one-family house. Measured data used in this study was collected continuously in a house in Kuopio, Eastern Finland, during fourteen months long period. Consumption parameters measured were the consumptions of district heat, electricity and water. Indoor parameters gathered were temperature, relative humidity (RH), the concentrations of carbon dioxide (CO2) and carbon monoxide (CO) and differential air pressure. In this study, self-organizing map (SOM) and Sammon's mapping were applied to resolve the effects of energy consumption on indoor air quality. Namely, the SOM was qualified as a suitable method having a property to summarize the multivariable dependencies into easily observable two-dimensional map. Accompanying that, the Sammon's mapping method was used to cluster pre-processed data to find similarities of the variables, expressing distances and groups in the data. The methods used were able to distinguish 7 different clusters characterizing indoor air quality and energy efficiency in the study house. The results indicate, that the cost implications in euros of heating and electricity energy vary according to the differential pressure, concentration of carbon dioxide, temperature and season.
Abstract: Production of biogas from bakery waste was enhanced
by additional bacterial cell. This study was divided into 2 steps. First
step, grease waste from bakery industry-s grease trap was initially
degraded by Pseudomonas aeruginosa. The concentration of byproduct,
especially glycerol, was determined and found that glycerol
concentration increased from 12.83% to 48.10%. Secondary step, 3
biodigesters were set up in 3 different substrates: non-degraded waste
as substrate in first biodigester, degraded waste as substrate in
secondary biodigester, and degraded waste mixed with swine manure
in ratio 1:1 as substrate in third biodigester. The highest
concentration of biogas was found in third biodigester that was
44.33% of methane and 63.71% of carbon dioxide. The lower
concentration at 24.90% of methane and 18.98% of carbon dioxide
was exhibited in secondary biodigester whereas the lowest was found
in non-degraded waste biodigester. It was demonstrated that the
biogas production was greatly increased with the initial grease waste
degradation by Pseudomonas aeruginosa.
Abstract: Two-phase frictional pressure drop data were
obtained for condensation of carbon dioxide in single horizontal
micro tube of inner diameter ranged from 0.6 mm up to 1.6 mm over
mass flow rates from 2.5*10-5 to 17*10-5 kg/s and vapor qualities
from 0.0 to 1.0. The inlet condensing pressure is changed from 33.5
to 45 bars. The saturation temperature ranged from -1.5 oC up to 10
oC. These data have then been compared against three (two-phase)
frictional pressure drop prediction methods. The first method is by
Muller-Steinhagen and Heck (Muller-Steinhagen H, Heck K. A
simple friction pressure drop correlation for two-phase flow in pipes.
Chem. Eng. Process 1986;20:297–308) and that by Gronnerud R.
Investigation of liquid hold-up, flow-resistance and heat transfer in
circulation type evaporators, part IV: two-phase flow resistance in
boiling refrigerants, Annexe 1972. Then the method used by
FriedelL. Improved friction pressures drop in horizontal and vertical
two-phase pipe flow. European Two-Phase Flow Group Meeting,
Paper E2; 1979 June, Ispra, Italy. The methods are used by M.B Ould
Didi et al (2001) “Prediction of two-phase pressure gradients of
refrigerant in horizontal tubes". Int.J.of Refrigeration 25(2002) 935-
947. The best available method for annular flow was that of Muller-
Steinhagen and Heck. It was observed that the peak in the two-phase
frictional pressure gradient is at high vapor qualities.
Abstract: As the fossil fuels kept on depleting, intense research in developing hydrogen (H2) as the alternative fuel has been done to cater our tremendous demand for fuel. The potential of H2 as the ultimate clean fuel differs with the fossil fuel that releases significant amounts of carbon dioxide (CO2) into the surrounding and leads to the global warming. The experimental work was carried out to study the production of H2 from palm kernel shell steam gasification at different variables such as heating rate, steam to biomass ratio and adsorbent to biomass ratio. Maximum H2 composition which is 61% (volume basis) was obtained at heating rate of 100oCmin-1, steam/biomass of 2:1 ratio, and adsorbent/biomass of 1:1 ratio. The commercial adsorbent had been modified by utilizing the alcoholwater mixture. Characteristics of both adsorbents were investigated and it is concluded that flowability and floodability of modified CaO is significantly improved.
Abstract: The use of neural networks is popular in various
building applications such as prediction of heating load, ventilation
rate and indoor temperature. Significant is, that only few papers deal
with indoor carbon dioxide (CO2) prediction which is a very good
indicator of indoor air quality (IAQ). In this study, a data-driven
modelling method based on multilayer perceptron network for indoor
air carbon dioxide in an apartment building is developed.
Temperature and humidity measurements are used as input variables
to the network. Motivation for this study derives from the following
issues. First, measuring carbon dioxide is expensive and sensors
power consumptions is high and secondly, this leads to short
operating times of battery-powered sensors. The results show that
predicting CO2 concentration based on relative humidity and
temperature measurements, is difficult. Therefore, more additional
information is needed.
Abstract: Experiments were carried out at the Faculty of Food
Technology of Latvia University of Agriculture (LLU). Soft cheese
Kleo produced in Latvia was packed in a biodegradable PLA without
barrierproperties and VC999 BioPack lidding film PLA, coated with
a barrier of pure silicon oxide (SiOx) and in combination with
modified atmosphere (MAP) the influence on the shelf life was
investigated and compared with some conventional (OPP, PE/PA,
PE/OPA and Multibarrier 60) polymer film impact. Modified
atmosphere consisted of carbon dioxide CO2 (E 290) 30% and
nitrogen N2 (E 941) 70%. The analyzable samples were stored at the
temperature of +4.0±0.5 °C up to 32 days- and analyzed before
packaging and in the 0, 5th, 11th, 15th, 18th, 22nd, 25th, 29th and 32nd
day of storage. The shelf life was extended along to 32 days, good
outside appearance and lactic acid aroma was observed.
Abstract: This research studied recycled waste by the Recyclable Material Bank Project of 4 universities in the central region of Thailand for the evaluation of reducing greenhouse gas emissions compared with landfilling activity during July 2012 to June 2013. The results showed that the projects collected total amount of recyclable wastes of about 911,984.80 kilograms. Office paper had the largest amount among these recycled wastes (50.68% of total recycled waste). Groups of recycled waste can be prioritized from high to low according to their amount as paper, plastic, glass, mixed recyclables, and metal, respectively. The project reduced greenhouse gas emissions equivalent to about 2814.969 metric tons of carbon dioxide. The most significant recycled waste that affects the reduction of greenhouse gas emissions is office paper which is 70.16% of total reduced greenhouse gasses emission. According to amount of reduced greenhouse gasses emission, groups of recycled waste can be prioritized from high to low significances as paper, plastic, metals, mixed recyclables, and glass, respectively.
Abstract: The aim of this paper is to compare the effectiveness and electrochemical behavior of typical oilfield corrosion inhibitors with previous oilfield corrosion inhibitors under the same electrochemical techniques to control preferential weld corrosion of X65 pipeline steel in artificial seawater saturated with carbon dioxide at a pressure of one bar. A secondary aim is to investigate the conditions under which current reversal takes place. A flow channel apparatus was used in the laboratory to simulate the actual condition that occurs in marine pipelines. Different samples from the parent metal, the weld metal and the heat affected zone in the pipeline steel were galvanically coupled. The galvanic currents flowing between the weld regions were recorded using zero-resistance ammeters and tested under static and flowing conditions in both inhibited and uninhibited media. The results show that a current reversal took place when 30ppm of both green oilfield inhibitors were present, resulting in accelerated weld corrosion.
Abstract: Carbon dioxide is one of the major green house gases.
It is removed from different streams using amine absorption process.
Sterically hindered amines are suggested as good CO2 absorbers.
Solubility of carbon dioxide (CO2) was measured in aqueous
solutions of 2-Amino-2-methyl-1-propanol (AMP) at temperatures 30
oC, 40 oC and 60 oC. The effect of pressure and temperature was
studied over various concentrations of AMP. It has been found that
pressure has positive effect on CO2 solubility where as solubility
decreased with increasing temperature. Absorption performance of
AMP increased with increasing pressure. Solubility of aqueous AMP
was compared with mo-ethanolamine (MEA) and the absorption
capacity of aqueous solutions of AMP was found to be better.
Abstract: CO2 is the primary anthropogenic greenhouse gas,
accounting for 77% of the human contribution to the greenhouse
effect in 2004. In the recent years, global concentration of CO2 in the
atmosphere is increasing rapidly. CO2 emissions have an impact on
global climate change. Anthropogenic CO2 is emitted primarily from
fossil fuel combustion. Carbon capture and storage (CCS) is one
option for reducing CO2 emissions. There are three major approaches
for CCS: post-combustion capture, pre-combustion capture and
oxyfuel process. Post-combustion capture offers some advantages as
existing combustion technologies can still be used without radical
changes on them.
There are several post combustion gas separation and capture
technologies being investigated, namely; (a) absorption, (b)
cryogenic separation, (c) membrane separation (d) micro algal biofixation
and (e) adsorption. Apart from establishing new techniques,
the exploration of capture materials with high separation performance
and low capital cost are paramount importance. However, the
application of adsorption from either technology, require easily
regenerable and durable adsorbents with a high CO2 adsorption
capacity. It has recently been reported that the cost of the CO2
capture can be reduced by using this technology. In this paper, the
research progress (from experimental results) in adsorbents for CO2
adsorption, storage, and separations were reviewed and future
research directions were suggested as well.