Enthalpies of Dissociation of Pure Methane and Carbon Dioxide Gas Hydrate
In this study the enthalpies of dissociation for pure
methane and pure carbon dioxide was calculated using a hydrate
equilibrium data obtained in this study. The enthalpy of dissociation
was determined using Clausius-Clapeyron equation. The results were
compared with the values reported in literature obtained using
various techniques.
[1] E.G. Hammerschmidt, "Formation of Gas Hydrates in Natural Gas
Transmission Lines”,Ind. Eng. Chem, vol. 26, pp.851-855, 1934
[2] B. Tohidi, , R. W. Burgass, A. Danesh, K. K. Ostergaard, A. C. Todd,
"Improving the accuracy of gas hydrate dissociation point
measurement”, Ann. N. Y. Acad. Sci, vol. 919, pp. 924 – 931, 2000
[3] P. Skovborg, P. Rasmussen, ‘Comments on: hydrate dissociation
enthalpy and guest size”, Fluid Phase Equilib,vol. 96, pp. 223-231 1994
[4] A. Hachikubo, A. Miyamoto, K. Hyakutake, K. Abe, H. Shoji, "Phase
equilibrium studies on gas hydrates formed from various guest
molecules and powder ice”, The fourth International conference on gas
hydrates, Yokohama, Japan, 2002
[5] T. Nakamura, T. Makino, T. Sugahara, K. Ohgaki, "Stability boundaries
of gas hydrates helped by methane-structure-H hydrates of
methylcyclohexane and cis-1,2-dimethylcyclohexane”, Chem. Eng.Sci,
vol. 58, pp. 269-273, 2003
[6] M. Kharrat, D. Dalmazzone, "Experimental determination of stability
conditions of methane hydrate in aqueous calcium chloride solutions
using high pressure differential scanning calorimetry”, J. Chem.
Thermodyn, vol. 35, pp. 1498-1505, 2003
[7] A. H. Mohammadi, R. Anderson, B. Tohidi, "Carbon monoxide
clathrate hydrates: Experimental equilibrium data and thermodynamic
modeling”, ALChE. J, vol. 51, pp. 2825-2833, 2005
[8] D. B. Robinson, B. R. Mehta, "Hydrates in the propane-carbon dioxidewater
system”, J.Can. Petro, vol. 10, pp. 33-35, 1971
[9] K. M. Sabil, G.J. Witkampa, C.J. Peters, "Estimation of enthalpies of
dissociation of simple and mixed carbon dioxide hydrates from phase
equilibrium data”, Fluid Phase Equilib, vol. 290, pp. 109-114, 2010
[10] G. Soave, "Equilibrium Constants from a Modified Redlich–Kwong
Equation of State”, Chem. Eng. Sci, vol. 27, pp. 1197-1203, 1972
[11] J.H. Yoon, Y. Yamamoto, T. Komai, H. Haneda, Rigorous "Approach to
the Prediction of Heat of Dissociation of Gas Hydrates”, Ind. Eng.
Chem. Res, vol. 42, pp. 1111-1114, 2003
[12] G.K. Anderson, "Enthalpy of dissociation and hydration number of
carbon dioxide hydrate from Clapeyron equation”, J. Chem. Thermodyn,
vol. 35, pp.1171-1183, 2003
[13] V.A. Kamath, ‘A Study of Heat Transfer Characteristics during
Dissociation of Gas Hydrates”, in, University of Pittsburgh, 1984.
[14] S.-P. Kang, H. Lee, B.-J Ryu, "Enthalpies of dissociation of clathrate
hydrate of carbon dioxide,nitrogen, (carbon dioxide+ nitrogen), and
carbon dioxide + nitrogen + tetrahydrofuran)”,J. Chem. Thermodyn, vol.
33, pp. 513-521,200.
[15] T. Uchida, A. Takagi, J. Kawabata, S. Mae, T. Hondoh, "Raman
spectroscopic analyses of the growth process of CO2 hydrates”, Energy
Convers. Manage.Vol. 36, pp. 547–550, 1995
[16] Y.P. Handa, Compositions, "Enthalpies of dissociation, and Heat
capacities in the range 85 to 270K for clathrate hydrate of CH4 , C2H6,
C3H8”, J.Chem.Thermo, vol. 18, pp 15, 1986a
[17] R.M. Rueff, E.D. Sloan, "Y.V. F, Heat capacity and Heat of dissociation
of methane hydrates”, AlChE Journal, vol. 34, pp. 1468, 1988
[18] J.S. Lievois, R. Perkins, R.J. Martin, R. Kobayashi, "Development of an
automated, High pressure heat flux calorimeter and its application to
measure the heat of dissociation and hydrate number of methane
hydrate”, Fluid Phase Equilib, vol. 59, pp.73, 1990
[19] J.P. Long, "Gas Hydrate Formation Mechanisim and Kinetic Inhibition”,
in, Colorado School of Mines, 1994.
[20] A. Delahaye, L. Fournaison, S. Marinhas, I. Chatti, J.-P Petitet, D.
Dalmazzone, W. F˜urst, "Effect of THF on Equilibrium Pressure and
Dissociation Enthalpy of CO2 Hydrate Applied to Secondary
Refrigeration”, Ind. Eng. Chem.Res, vol. 45, pp.391-397, 2006.
[1] E.G. Hammerschmidt, "Formation of Gas Hydrates in Natural Gas
Transmission Lines”,Ind. Eng. Chem, vol. 26, pp.851-855, 1934
[2] B. Tohidi, , R. W. Burgass, A. Danesh, K. K. Ostergaard, A. C. Todd,
"Improving the accuracy of gas hydrate dissociation point
measurement”, Ann. N. Y. Acad. Sci, vol. 919, pp. 924 – 931, 2000
[3] P. Skovborg, P. Rasmussen, ‘Comments on: hydrate dissociation
enthalpy and guest size”, Fluid Phase Equilib,vol. 96, pp. 223-231 1994
[4] A. Hachikubo, A. Miyamoto, K. Hyakutake, K. Abe, H. Shoji, "Phase
equilibrium studies on gas hydrates formed from various guest
molecules and powder ice”, The fourth International conference on gas
hydrates, Yokohama, Japan, 2002
[5] T. Nakamura, T. Makino, T. Sugahara, K. Ohgaki, "Stability boundaries
of gas hydrates helped by methane-structure-H hydrates of
methylcyclohexane and cis-1,2-dimethylcyclohexane”, Chem. Eng.Sci,
vol. 58, pp. 269-273, 2003
[6] M. Kharrat, D. Dalmazzone, "Experimental determination of stability
conditions of methane hydrate in aqueous calcium chloride solutions
using high pressure differential scanning calorimetry”, J. Chem.
Thermodyn, vol. 35, pp. 1498-1505, 2003
[7] A. H. Mohammadi, R. Anderson, B. Tohidi, "Carbon monoxide
clathrate hydrates: Experimental equilibrium data and thermodynamic
modeling”, ALChE. J, vol. 51, pp. 2825-2833, 2005
[8] D. B. Robinson, B. R. Mehta, "Hydrates in the propane-carbon dioxidewater
system”, J.Can. Petro, vol. 10, pp. 33-35, 1971
[9] K. M. Sabil, G.J. Witkampa, C.J. Peters, "Estimation of enthalpies of
dissociation of simple and mixed carbon dioxide hydrates from phase
equilibrium data”, Fluid Phase Equilib, vol. 290, pp. 109-114, 2010
[10] G. Soave, "Equilibrium Constants from a Modified Redlich–Kwong
Equation of State”, Chem. Eng. Sci, vol. 27, pp. 1197-1203, 1972
[11] J.H. Yoon, Y. Yamamoto, T. Komai, H. Haneda, Rigorous "Approach to
the Prediction of Heat of Dissociation of Gas Hydrates”, Ind. Eng.
Chem. Res, vol. 42, pp. 1111-1114, 2003
[12] G.K. Anderson, "Enthalpy of dissociation and hydration number of
carbon dioxide hydrate from Clapeyron equation”, J. Chem. Thermodyn,
vol. 35, pp.1171-1183, 2003
[13] V.A. Kamath, ‘A Study of Heat Transfer Characteristics during
Dissociation of Gas Hydrates”, in, University of Pittsburgh, 1984.
[14] S.-P. Kang, H. Lee, B.-J Ryu, "Enthalpies of dissociation of clathrate
hydrate of carbon dioxide,nitrogen, (carbon dioxide+ nitrogen), and
carbon dioxide + nitrogen + tetrahydrofuran)”,J. Chem. Thermodyn, vol.
33, pp. 513-521,200.
[15] T. Uchida, A. Takagi, J. Kawabata, S. Mae, T. Hondoh, "Raman
spectroscopic analyses of the growth process of CO2 hydrates”, Energy
Convers. Manage.Vol. 36, pp. 547–550, 1995
[16] Y.P. Handa, Compositions, "Enthalpies of dissociation, and Heat
capacities in the range 85 to 270K for clathrate hydrate of CH4 , C2H6,
C3H8”, J.Chem.Thermo, vol. 18, pp 15, 1986a
[17] R.M. Rueff, E.D. Sloan, "Y.V. F, Heat capacity and Heat of dissociation
of methane hydrates”, AlChE Journal, vol. 34, pp. 1468, 1988
[18] J.S. Lievois, R. Perkins, R.J. Martin, R. Kobayashi, "Development of an
automated, High pressure heat flux calorimeter and its application to
measure the heat of dissociation and hydrate number of methane
hydrate”, Fluid Phase Equilib, vol. 59, pp.73, 1990
[19] J.P. Long, "Gas Hydrate Formation Mechanisim and Kinetic Inhibition”,
in, Colorado School of Mines, 1994.
[20] A. Delahaye, L. Fournaison, S. Marinhas, I. Chatti, J.-P Petitet, D.
Dalmazzone, W. F˜urst, "Effect of THF on Equilibrium Pressure and
Dissociation Enthalpy of CO2 Hydrate Applied to Secondary
Refrigeration”, Ind. Eng. Chem.Res, vol. 45, pp.391-397, 2006.
@article{"International Journal of Chemical, Materials and Biomolecular Sciences:64086", author = "Qazi Nasir and K. K. Lau and Bhajan Lal", title = "Enthalpies of Dissociation of Pure Methane and Carbon Dioxide Gas Hydrate", abstract = "In this study the enthalpies of dissociation for pure
methane and pure carbon dioxide was calculated using a hydrate
equilibrium data obtained in this study. The enthalpy of dissociation
was determined using Clausius-Clapeyron equation. The results were
compared with the values reported in literature obtained using
various techniques.
", keywords = "Enthalpies of dissociation, methane, carbon dioxide,
gas hydrate, natural gas.", volume = "8", number = "8", pages = "776-4", }
