Abstract: The development of renewable energies - particularly energy from wind, water, solar power and biomass - is a central aim of the European Commission's energy policy. There are several reasons for this choice: renewable energies are sustainable, nonpolluting, widely available and clean. Increasing the share of renewable energy in the energy balance enhances sustainability. It also helps to improve the security of energy supply by reducing the Community's growing dependence on imported energy sources.In this paper it was studied the possibility to realize three photovoltaic systems in the Italian Natural Park “Gola della Rossa e di Frasassi". The first photovoltaic system is a grid-connected system for Services and Documentation Center of Castelletta with a nominal power of about 6 kWp. The second photovoltaic system is a grid-connected integrated system on the ticket office-s roof with a nominal power of about 4 kWp. The third project is set up by five grid-connected systems integrated on the roofs of the bungalows in Natural Park-s tourist camping with a nominal power of about 10 kWp. The electricity which is generated by all these plants is purchased according to the Italian program called “Conto Energia". Economical analysis and the amount of the avoided CO2 emissions are elaborated for these photovoltaic systems.
Abstract: Multiphase flow transport in porous medium is very common and significant in science and engineering applications. For example, in CO2 Storage and Enhanced Oil Recovery processes, CO2 has to be delivered to the pore spaces in reservoirs and aquifers. CO2 storage and enhance oil recovery are actually displacement processes, in which oil or water is displaced by CO2. This displacement is controlled by pore size, chemical and physical properties of pore surfaces and fluids, and also pore wettability. In this study, a technique was developed to measure the pressure profile for driving gas/liquid to displace water in pores. Through this pressure profile, the impact of pore size on the multiphase flow transport and displacement can be analyzed. The other rig developed can be used to measure the static and dynamic pore wettability and investigate the effects of pore size, surface tension, viscosity and chemical structure of liquids on pore wettability.
Abstract: In this study, effects of premixed and equivalence
ratios on CO and HC emissions of a dual fuel HCCI engine are
investigated. Tests were conducted on a single-cylinder engine with
compression ratio of 17.5. Premixed gasoline is provided by a
carburetor connected to intake manifold and equipped with a screw
to adjust premixed air-fuel ratio, and diesel fuel is injected directly
into the cylinder through an injector at pressure of 250 bars. A heater
placed at inlet manifold is used to control the intake charge
temperature. Optimal intake charge temperature results in better
HCCI combustion due to formation of a homogeneous mixture,
therefore, all tests were carried out over the optimum intake
temperature of 110-115 ºC. Timing of diesel fuel injection has a great
effect on stratification of in-cylinder charge and plays an important
role in HCCI combustion phasing. Experiments indicated 35 BTDC
as the optimum injection timing. Varying the coolant temperature in
a range of 40 to 70 ºC, better HCCI combustion was achieved at 50
ºC. Therefore, coolant temperature was maintained 50 ºC during all
tests. Simultaneous investigation of effective parameters on HCCI
combustion was conducted to determine optimum parameters
resulting in fast transition to HCCI combustion. One of the
advantages of the method studied in this study is feasibility of easy
and fast transition of typical diesel engine to a dual fuel HCCI
engine. Results show that increasing premixed ratio, while keeping
EGR rate constant, increases unburned hydrocarbon (UHC)
emissions due to quenching phenomena and trapping of premixed
fuel in crevices, but CO emission decreases due to increase in CO to
CO2 reactions.
Abstract: The consumption of lactose in acid cheese whey
anaerobic fermentation process under fed-batch conditions was
studied. During fermentation for 100 hours the biogas production
(CO2 and CH4) was analyzed online. Among the standard analyses
FT-IR spectroscopy was used to follow the consumption of lactose by
bacteria. The absorption bands at 990, 894 and 787 cm-1 in the 2nd
derivative spectra were shown to be characteristic for lactose and
were used to follow the lactose conversion. It was shown that acid
cheese whey lactose was converted by bacteria in first 7 hours. In the
spectra of 17, 18 and 95 hour fermentation samples lactose was not
identified and these results correlated with the HPLC data.
Abstract: It is well recognized that the green house gases such
as Chlorofluoro Carbon (CFC), CH4, CO2 etc. are responsible
directly or indirectly for the increase in the average global temperature
of the Earth. The presence of CFC is responsible for
the depletion of ozone concentration in the atmosphere due to
which the heat accompanied with the sun rays are less absorbed
causing increase in the atmospheric temperature of the Earth. The
gases like CH4 and CO2 are also responsible for the increase in
the atmospheric temperature. The increase in the temperature level
directly or indirectly affects the dynamics of interacting species
systems. Therefore, in this paper a mathematical model is proposed
and analysed using stability theory to asses the effects of increasing
temperature due to greenhouse gases on the survival or extinction of
populations in a prey-predator system. A threshold value in terms
of a stress parameter is obtained which determines the extinction or
existence of populations in the underlying system.
Abstract: The objective of this work was to examine the changes
in non destructive properties caused by carbonation of CEM II
mortar. Samples of CEM II mortar were prepared and subjected to
accelerated carbonation at 20°C, 65% relative humidity and 20% CO2
concentration. We examined the evolutions of the gas permeability,
the thermal conductivity, the thermal diffusivity, the volume of the
solid phase by helium pycnometry, the longitudinal and transverse
ultrasonic velocities. The principal contribution of this work is that,
apart of the gas permeability, changes in other non destructive
properties have never been studied during the carbonation of cement
materials. These properties are important in predicting/measuring the
durability of reinforced concrete in CO2 environment. The
carbonation depth and the porosity accessible to water were also
reported in order to explain comprehensively the changes in non
destructive parameters.
Abstract: The use of amine mixtures employing
methyldiethanolamine (MDEA), monoethanolamine (MEA), and diethanolamine (DEA) have been investigated for a variety of cases
using a process simulation program called HYSYS. The results show that, at high pressures, amine mixtures have little or no advantage in the cases studied. As the pressure is lowered, it becomes more difficult for MDEA to meet residual gas requirements and mixtures can usually improve plant performance. Since the CO2 reaction rate
with the primary and secondary amines is much faster than with
MDEA, the addition of small amounts of primary or secondary amines to an MDEA based solution should greatly improve the overall reaction rate of CO2 with the amine solution. The addition of MEA caused the CO2 to be absorbed more strongly in the upper portion of the column than for MDEA along. On the other hand,
raising the concentration for MEA to 11%wt, CO2 is almost
completely absorbed in the lower portion of the column. The addition of MEA would be most advantageous.
Thus, in areas where MDEA cannot meet the residual gas
requirements, the use of amine mixtures can usually improve the plant
performance.
Abstract: Clean air in subway station is important to passengers. The Platform Screen Doors (PSDs) can improve indoor air quality in the subway station; however the air quality in the subway tunnel is degraded. The subway tunnel has high CO2 concentration and indoor particulate matter (PM) value. The Indoor Air Quality (IAQ) level in subway environment degrades by increasing the frequency of the train operation and the number of the train. The ventilation systems of the subway tunnel need improvements to have better air-quality. Numerical analyses might be effective tools to analyze the performance of subway twin-track tunnel ventilation systems. An existing subway twin-track tunnel in the metropolitan Seoul subway system is chosen for the numerical simulations. The ANSYS CFX software is used for unsteady computations of the airflow inside the twin-track tunnel when the train moves. The airflow inside the tunnel is simulated when one train runs and two trains run at the same time in the tunnel. The piston-effect inside the tunnel is analyzed when all shafts function as the natural ventilation shaft. The supplied air through the shafts is mixed with the pollutant air in the tunnel. The pollutant air is exhausted by the mechanical ventilation shafts. The supplied and discharged airs are balanced when only one train runs in the twin-track tunnel. The pollutant air in the tunnel is high when two trains run simultaneously in opposite direction and all shafts functioned as the natural shaft cases when there are no electrical power supplies in the shafts. The remained pollutant air inside the tunnel enters into the station platform when the doors are opened.
Abstract: The Platform Screen Doors improve Indoor Air Quality
(IAQ) in the subway station; however, and the air quality is degraded
in the subway tunnel. CO2 concentration and indoor particulate matter
value are high in the tunnel. The IAQ level in subway tunnel degrades
by increasing the train movements. Air-curtain installation reduces
dusts, particles and moving toxic smokes and permits traffic by
generating virtual wall. The ventilation systems of the subway tunnel
need improvements to have better air-quality. Numerical analyses
might be effective tools analyze the flowfield inside the air-curtain
installed subway tunnel. The ANSYS CFX software is used for steady
computations of the airflow inside the tunnel. The single-track subway
tunnel has the natural shaft, the mechanical shaft, and the PSDs
installed stations. The height and width of the tunnel are 6.0 m and 4.0
m respectively. The tunnel is 400 m long and the air-curtain is installed
at the top of the tunnel. The thickness and the width of the air-curtain
are 0.08 m and 4 m respectively. The velocity of the air-curtain
changes between 20 - 30 m/s. Three cases are analyzed depending on
the installing location of the air-curtain. The discharged-air through
the natural shafts increases as the velocity of the air-curtain increases
when the air-curtain is installed between the mechanical and the
natural shafts. The pollutant-air is exhausted by the mechanical and the
natural shafts and remained air is pushed toward tunnel end. The
discharged-air through the natural shaft is low when the air-curtain
installed before the natural shaft. The mass flow rate decreases in the
tunnel after the mechanical shaft as the air-curtain velocity increases.
The computational results of the air-curtain installed tunnel become
basis for the optimum design study. The air-curtain installing location
is chosen between the mechanical and the natural shafts. The velocity
of the air-curtain is fixed as 25 m/s. The thickness and the blowing
angles of the air-curtain are the design variables for the optimum
design study. The object function of the design optimization is
maximizing the discharged air through the natural shaft.
Abstract: An innovative approach utilizing highly alkaline oil
shale waste ash and carbon dioxide gas (CO2), associated with power
production, as a resource for production of precipitated calcium
carbonate (PCC) is introduced in this paper. The specifics and
feasibility of the integrated ash valorization and CO2 sequestration
process by indirect aqueous carbonation of lime-consisting ash were
elaborated and the main parameters established. Detailed description
of the formed precipitates was included. Complimentary carbonation
experiments with commercial CaO fine powder were conducted for
comparative characterization of the final products obtained on the
basis of two different raw materials. Finally, the expected CO2
uptake was evaluated.
Abstract: In this study, a reformer model simulation to use
refinery (Farashband refinery, Iran) waste natural gas. In the
petroleum and allied sectors where natural gas is being encountered
(in form of associated gas) without prior preparation for its positive
use, its combustion (which takes place in flares, an equipment through
which they are being disposed) has become a great problem because
of its associated environmental problems in form of gaseous emission.
The proposed model is used to product syngas from waste natural gas.
A detailed steady model described by a set of ordinary differential and
algebraic equations was developed to predict the behavior of the
overall process. The proposed steady reactor model was validated
against process data of a reformer synthesis plant recorded and a good
agreement was achieved. H2/CO ratio has important effect on Fischer-
Tropsch synthesis reactor product and we try to achieve this parameter
with best designing reformer reactor. We study different kind of
reformer reactors and then select auto thermal reforming process of
natural gas in a fixed bed reformer that adjustment H2/CO ratio with
CO2 and H2O injection. Finally a strategy was proposed for prevention
of extra natural gas to atmosphere.
Abstract: In this research sodium bicarbonate (NaHCO3) was introduced to generate carbon dioxide gas (CO2) to the existing nitrogen gas (N2) of elastomeric foam, to lower thermal conductivity (K). Various loadings of NaHCO3 (0 to 60 phr) were added into the azodicarbonamide (AZC)-containing compound and its properties were then determined. Two vulcanization methods, i.e., hot air and infrared (IR), were employed and compared in this study. Results revealed that compound viscosity tended to increase slightly with increasing NaHCO3 content but cure time was delayed. The effect of NaHCO3 content on thermal conductivity depended on the vulcanization method. For hot air method, the thermal conductivity was insignificantly changed with increasing NaHCO3 up to 40 phr whereas it tended to decrease gradually for IR method. At higher NaHCO3 content (60 phr), unexpected increase of thermal conductivity was observed. The water absorption was also determined and foam structures were then used to explain the results.
Abstract: Buildings and associated construction methods have a significant impact on the environment. As construction activity increases in Kuwait, there is a need to create design and construction strategies which will minimize the environmental impact of new buildings. Green construction is a design philosophy intended to improve the sustainability of construction by the minimization of resource depletion and CO2 emissions throughout the life cycle of buildings. This paper presents and discusses the results of a survey that was conducted in Kuwait, with the objective of investigating the awareness of developers and other stakeholders regarding their understanding and use of green construction strategies. The results of the survey demonstrate that whilst there seems to be a reasonable level of awareness amongst the stakeholders, this awareness is not currently well reflected in the design and construction practices actually being applied. It is therefore concluded is there is a pressing need for intervention from Government in order that the use of sustainable green design and construction strategies becomes the norm in Kuwait.
Abstract: Soil organic carbon (SOC) plays a key role in soil
fertility, hydrology, contaminants control and acts as a sink or source
of terrestrial carbon content that can affect the concentration of
atmospheric CO2. SOC supports the sustainability and quality of
ecosystems, especially in semi-arid region. This study was
conducted to determine relative importance of 13 different
exploratory climatic, soil and geometric factors on the SOC contents
in one of the semiarid watershed zones in Iran. Two methods
canonical discriminate analysis (CDA) and feed-forward back
propagation neural networks were used to predict SOC. Stepwise
regression and sensitivity analysis were performed to identify
relative importance of exploratory variables. Results from sensitivity
analysis showed that 7-2-1 neural networks and 5 inputs in CDA
models output have highest predictive ability that explains %70 and
%65 of SOC variability. Since neural network models outperformed
CDA model, it should be preferred for estimating SOC.
Abstract: Environmental performance of the U.S. States is investigated for the period of 1990 – 2007 using Stochastic Frontier Analysis (SFA). The SFA accounts for both efficiency measure and stochastic noise affecting a frontier. The frontier is formed using indicators of GDP, energy consumption, population, and CO2 emissions. For comparability, all indicators are expressed as ratios to total. Statistical information of the Energy Information Agency of the United States is used. Obtained results reveal the bell - shaped dynamics of environmental efficiency scores. The average efficiency scores rise from 97.6% in 1990 to 99.6% in 1999, and then fall to 98.4% in 2007. The main factor is insufficient decrease in the rate of growth of CO2 emissions with regards to the growth of GDP, population and energy consumption. Data for 2008 following the research period allow for an assumption that the environmental performance of the U.S. States has improved in the last years.
Abstract: Regenerative Thermal Oxidizer (RTO) is one of the
best solutions for removal of Volatile Organic Compounds (VOC)
from industrial processes. In the RTO, VOC in a raw gas are usually
decomposed at 950-1300 K and the combustion heat of VOC is
recovered by regenerative heat exchangers charged with ceramic
honeycombs. The optimization of the treatment of VOC leads to the
reduction of fuel addition to VOC decomposition, the minimization of
CO2 emission and operating cost as well.
In the present work, the thermal efficiency of the RTO was
investigated experimentally in a pilot-scale RTO unit using toluene as
a typical representative of VOC. As a result, it was recognized that the
radiative heat transfer was dominant in the preheating process of a raw
gas when the gas flow rate was relatively low. Further, it was found
that a minimum heat exchanger volume to achieve self combustion of
toluene without additional heating of the RTO by fuel combustion was
dependent on both the flow rate of a raw gas and the concentration of
toluene. The thermal efficiency calculated from fuel consumption and
the decomposed toluene ratio, was found to have a maximum value of
0.95 at a raw gas mass flow rate of 1810 kg·h-1 and honeycombs height
of 1.5m.
Abstract: This paper presents the feasibility study of CO2 sequestration from the sources to the sinks in the prospective of Italian Industries. CO2 produced at these sources captured, compressed to supercritical pressures, transported via pipelines and stored in underground geologic formations such as depleted oil and natural gas reservoirs, un-minable coal seams and deep saline aquifers. In this work, we present the optimized pipeline infrastructure for the CO2 with appropriate constraints to find lower cost system by the use of nonlinear optimization software LINGO 11.0. This study was conducted on CO2 transportation complex network of Italian Industries, to find minimum cost network for transporting the CO2 from sources to the sinks.
Abstract: In this paper, study on carbonation process of several types of advanced plasters on lime basis is presented. The movement of carbonation head was measured by colorimetric method using phenolphtalein. The rate of carbonation was accessed also by gravimetric method. Samples of studied materials were placed into the climatic chamber for simulation of environment with high concentration of CO2. The particular samples were on all lateral sides and on the bottom side provided by epoxy resin in order to arrange 1-D transport of CO2 into the studied samples. The carbonation rates of particular materials pointed to the time dependence of diffusion process of CO2 for all the studied plasters. From the quantitative point of view, the carbonation of advanced modified plasters was much faster than for the reference lime plaster, what is beneficial for the practical application of the tested newly developed materials.
Abstract: Natural gas is the most popular fossil fuel in the
current era and future as well. Natural gas is existed in underground
reservoirs so it may contain many of non-hydrocarbon components
for instance, hydrogen sulfide, nitrogen and water vapor. These
impurities are undesirable compounds and cause several technical
problems for example, corrosion and environment pollution.
Therefore, these impurities should be reduce or removed from natural
gas stream. Khurmala dome is located in southwest Erbil-Kurdistan
region. The Kurdistan region government has paid great attention for
this dome to provide the fuel for Kurdistan region. However, the
Khurmala associated natural gas is currently flaring at the field.
Moreover, nowadays there is a plan to recover and trade this gas and
to use it either as feedstock to power station or to sell it in global
market. However, the laboratory analysis has showed that the
Khurmala sour gas has huge quantities of H2S about (5.3%) and CO2
about (4.4%). Indeed, Khurmala gas sweetening process has been
removed in previous study by using Aspen HYSYS. However,
Khurmala sweet gas still contents some quintets of water about 23
ppm in sweet gas stream. This amount of water should be removed or
reduced. Indeed, water content in natural gas cause several technical
problems such as hydrates and corrosion. Therefore, this study aims
to simulate the prospective Khurmala gas dehydration process by
using Aspen HYSYS V. 7.3 program. Moreover, the simulation
process succeeded in reducing the water content to less than 0.1ppm.
In addition, the simulation work is also achieved process
optimization by using several desiccant types for example, TEG and
DEG and it also study the relationship between absorbents type and
its circulation rate with HCs losses from glycol regenerator tower.
Abstract: This paper describes the designs of a first and second
generation autonomous gas monitoring system and the successful
field trial of the final system (2nd generation). Infrared sensing
technology is used to detect and measure the greenhouse gases
methane (CH4) and carbon dioxide (CO2) at point sources. The
ability to monitor real-time events is further enhanced through the
implementation of both GSM and Bluetooth technologies to
communicate these data in real-time. These systems are robust,
reliable and a necessary tool where the monitoring of gas events in
real-time are needed.