Abstract: This study describes the preparation of a novel proton
conducting membranes based on bacterial cellulose (BC) modified by
grafting of 2-acrylamido-2-methyl-1 -propanesulfonic acid (AMPS)
through UV-induced graft polymerization. These AMPS-g-BC
membranes have been characterized by various techniques including
FTIR, SEM and TGA, to find their successful grafting of AMPS on
BC, surface morphology and thermal stability, respectively. Physical
properties of AMPS-g-BC membranes have been assessed in terms of
Lamda value( λ ), ion exchange capacity(IEC) and proton
conductivity. The relationship between degree of grafting and AMPS
concentration used for grafting has been determined by weight gain
method. An optimum proton conductivity equal to 2.89x10-2 S cm-1
and IEC value equal to 1.79 mmol g-1 have been obtained when 20
wt% AMPS concentration is used for grafting (i.e. the corresponding
membrane is notated as AMPS20-g-BC).