Modification and Characterization of Bacterial Cellulose Biopolymer as Proton Conducting Membrane
This study describes the preparation of a novel proton
conducting membranes based on bacterial cellulose (BC) modified by
grafting of 2-acrylamido-2-methyl-1 -propanesulfonic acid (AMPS)
through UV-induced graft polymerization. These AMPS-g-BC
membranes have been characterized by various techniques including
FTIR, SEM and TGA, to find their successful grafting of AMPS on
BC, surface morphology and thermal stability, respectively. Physical
properties of AMPS-g-BC membranes have been assessed in terms of
Lamda value( λ ), ion exchange capacity(IEC) and proton
conductivity. The relationship between degree of grafting and AMPS
concentration used for grafting has been determined by weight gain
method. An optimum proton conductivity equal to 2.89x10-2 S cm-1
and IEC value equal to 1.79 mmol g-1 have been obtained when 20
wt% AMPS concentration is used for grafting (i.e. the corresponding
membrane is notated as AMPS20-g-BC).
[1] O. D. Klemm, D. Schumann, U. Udhardt, S. Marsch, Prog. Polym. Sci. 26
(2001) 1561-1603.
[2] A. Svensson, E. Nicklasson, T. Harrah, B. Panilaitis, D. Kaplan, M.
Brittberg. P. Gatenholm, Biomaterials 26 (2005) 419-431.
[3] J. George, K.V. Ramana, S.N. Sabapathy, J.H. Jagannath, A.S. Bawa
Journal of Biological Macromolecules 37 (2005) 189-194.
[4] Y. Wan, K.A.M. Creber, B. Peppley, V.T. Bui, J. Membr. Sci. 280 (2006)
666-674.
[5] B.R. Evans, H.M. O'Neill, V.P. Malyvanh, I. Lee, J. Woodward,
Biosensors and Bioelectronics, 18 (2003) 917-923.
[6] K. Brajter, K. Slonawska, Anal Chim Acta 185 (1986) 271-277.
[7] W. Li, H. Zhao, PR. Teasdale, R. John S. Zhang, Anal Chim Acta 464
(2002) 331-339.
[8] J. Yang, D. Sun, J. Li , X. Yang, J. Yu, Q. Hao, W. Liu, J. Liu, Z. Zou, J.
Gu, Electrochimica Acta 54 (2009) 6300-6305.
[9] O.A. Kazantsev, A.V. Igolkin, K.V. Shirshin, N.A. Kuznetsova, A.N.
Spirina, A.P. Malyshev, Russ. J. Appl. Chem.75 (2002) 465-469.
[10] C.W. Walker Jr., J. Power Sources 110 (2002) 144-151.
[11] J. Qiao, T. Hamaya, T. Okada, J. Mater. Chem., 15 (2005) 4414-4423
[12] L.E. Karlsson, B. Wessle'n, P. Jannasch, Electrochimica Acta 47 (2002)
3269-3275.
[13] P.A. Dworjanyn, J.L. Garnett, J. Polym. Chem. Polym. Lett. Ed. 26
(1988) 135-138.
[14] J.R. Hollahan, Plasma Chemistry Industrial Application, Wiley, New
York, 1974
[15] C.A. Wilkie, C. Deacon, Graft copolymerization of acrylic acid on to
acrylonitrile-butadienestyrene terpolymer and thermal analysis of the
copolymers, Eur. Polym. J. 32 (1996) 451-455.
[16] S. Hasegawa, Y. Suzuki, Y. Maekawa, Radiat. Phys. Chem. 77 (2008)
617-621.
[17] M.M. Nasef, J. Appl. Polym. Sci. 77 (2000) 1003-1012.
[18] E. O. Stejskal, J. E. Tanner, J Chem Phys 43 (1965) 3597-3603.
[19] A. M. Kannan, A. Menghal, I.V. Barsukov Electrochemistry
Communications 8 (2006) 887-891
[20] G. Oster, O. Shibata, J Polym Sci 26 (1957) 233-234.
[21] K. Watanabe, Y. Eto, S. Takano, S. Nakamori, H. Shibai, S. Yoshinaka,
Cytotechnol 13 (1993) 107-114.
[22] Y. Choi, Y. Ahn, M. Kang, H. Jun, I. Kim, S. Moon, J Chem Technol
Biotechnol 79 (2004) 79-84.
[23] M. Roman, W.T. Winter, Biomacromolecules 5( 2004) 1671-1677
[1] O. D. Klemm, D. Schumann, U. Udhardt, S. Marsch, Prog. Polym. Sci. 26
(2001) 1561-1603.
[2] A. Svensson, E. Nicklasson, T. Harrah, B. Panilaitis, D. Kaplan, M.
Brittberg. P. Gatenholm, Biomaterials 26 (2005) 419-431.
[3] J. George, K.V. Ramana, S.N. Sabapathy, J.H. Jagannath, A.S. Bawa
Journal of Biological Macromolecules 37 (2005) 189-194.
[4] Y. Wan, K.A.M. Creber, B. Peppley, V.T. Bui, J. Membr. Sci. 280 (2006)
666-674.
[5] B.R. Evans, H.M. O'Neill, V.P. Malyvanh, I. Lee, J. Woodward,
Biosensors and Bioelectronics, 18 (2003) 917-923.
[6] K. Brajter, K. Slonawska, Anal Chim Acta 185 (1986) 271-277.
[7] W. Li, H. Zhao, PR. Teasdale, R. John S. Zhang, Anal Chim Acta 464
(2002) 331-339.
[8] J. Yang, D. Sun, J. Li , X. Yang, J. Yu, Q. Hao, W. Liu, J. Liu, Z. Zou, J.
Gu, Electrochimica Acta 54 (2009) 6300-6305.
[9] O.A. Kazantsev, A.V. Igolkin, K.V. Shirshin, N.A. Kuznetsova, A.N.
Spirina, A.P. Malyshev, Russ. J. Appl. Chem.75 (2002) 465-469.
[10] C.W. Walker Jr., J. Power Sources 110 (2002) 144-151.
[11] J. Qiao, T. Hamaya, T. Okada, J. Mater. Chem., 15 (2005) 4414-4423
[12] L.E. Karlsson, B. Wessle'n, P. Jannasch, Electrochimica Acta 47 (2002)
3269-3275.
[13] P.A. Dworjanyn, J.L. Garnett, J. Polym. Chem. Polym. Lett. Ed. 26
(1988) 135-138.
[14] J.R. Hollahan, Plasma Chemistry Industrial Application, Wiley, New
York, 1974
[15] C.A. Wilkie, C. Deacon, Graft copolymerization of acrylic acid on to
acrylonitrile-butadienestyrene terpolymer and thermal analysis of the
copolymers, Eur. Polym. J. 32 (1996) 451-455.
[16] S. Hasegawa, Y. Suzuki, Y. Maekawa, Radiat. Phys. Chem. 77 (2008)
617-621.
[17] M.M. Nasef, J. Appl. Polym. Sci. 77 (2000) 1003-1012.
[18] E. O. Stejskal, J. E. Tanner, J Chem Phys 43 (1965) 3597-3603.
[19] A. M. Kannan, A. Menghal, I.V. Barsukov Electrochemistry
Communications 8 (2006) 887-891
[20] G. Oster, O. Shibata, J Polym Sci 26 (1957) 233-234.
[21] K. Watanabe, Y. Eto, S. Takano, S. Nakamori, H. Shibai, S. Yoshinaka,
Cytotechnol 13 (1993) 107-114.
[22] Y. Choi, Y. Ahn, M. Kang, H. Jun, I. Kim, S. Moon, J Chem Technol
Biotechnol 79 (2004) 79-84.
[23] M. Roman, W.T. Winter, Biomacromolecules 5( 2004) 1671-1677
@article{"International Journal of Chemical, Materials and Biomolecular Sciences:55803", author = "C. W. Lin and S.W. Chen", title = "Modification and Characterization of Bacterial Cellulose Biopolymer as Proton Conducting Membrane", abstract = "This study describes the preparation of a novel proton
conducting membranes based on bacterial cellulose (BC) modified by
grafting of 2-acrylamido-2-methyl-1 -propanesulfonic acid (AMPS)
through UV-induced graft polymerization. These AMPS-g-BC
membranes have been characterized by various techniques including
FTIR, SEM and TGA, to find their successful grafting of AMPS on
BC, surface morphology and thermal stability, respectively. Physical
properties of AMPS-g-BC membranes have been assessed in terms of
Lamda value( λ ), ion exchange capacity(IEC) and proton
conductivity. The relationship between degree of grafting and AMPS
concentration used for grafting has been determined by weight gain
method. An optimum proton conductivity equal to 2.89x10-2 S cm-1
and IEC value equal to 1.79 mmol g-1 have been obtained when 20
wt% AMPS concentration is used for grafting (i.e. the corresponding
membrane is notated as AMPS20-g-BC).", keywords = "Bacterial cellulose, 2-acrylamido-2-methyl-1-propanesulfonic acid, Proton conducting membrane, Self diffusioncoefficient, Fuel cell", volume = "6", number = "5", pages = "449-5", }