Abstract: The removal of hydrogen sulphide is required for reasons of health, odour problems, safety and corrosivity problems. The means of removing hydrogen sulphide mainly depend on its concentration and kind of medium to be purified. The paper deals with a method of hydrogen sulphide removal from the air by its catalytic oxidation to elemental sulphur with the use of Fe-EDTA complex. The possibility of obtaining fibrous filtering materials able to remove small concentrations of H2S from the air were described. The base of these materials is fibrous ion exchanger with Fe(III)- EDTA complex immobilized on their functional groups. The complex of trivalent iron converts hydrogen sulphide to elemental sulphur. Bivalent iron formed in the reaction is oxidized by the atmospheric oxygen, so complex of trivalent iron is continuously regenerated and the overall process can be accounted as pseudocatalytic. In the present paper properties of several fibrous catalysts based on ion exchangers with different chemical nature (weak acid,weak base and strong base) were described. It was shown that the main parameters affecting the process of catalytic oxidation are:concentration of hydrogen sulphide in the air, relative humidity of the purified air, the process time and the content of Fe-EDTA complex in the fibres. The data presented show that the filtering layers with anion exchange package are much more active in the catalytic processes of hydrogen sulphide removal than cation exchanger and inert materials. In the addition to the nature of the fibres relative air humidity is a critical factor determining efficiency of the material in the air purification from H2S. It was proved that the most promising carrier of the Fe-EDTA catalyst for hydrogen sulphide oxidation are Fiban A-6 and Fiban AK-22 fibres.
Abstract: During the last couple of years, the degree of dependence on IT systems has reached a dimension nobody imagined to be possible 10 years ago. The increased usage of mobile devices (e.g., smart phones), wireless sensor networks and embedded devices (Internet of Things) are only some examples of the dependency of modern societies on cyber space. At the same time, the complexity of IT applications, e.g., because of the increasing use of cloud computing, is rising continuously. Along with this, the threats to IT security have increased both quantitatively and qualitatively, as recent examples like STUXNET or the supposed cyber attack on Illinois water system are proofing impressively. Once isolated control systems are nowadays often publicly available - a fact that has never been intended by the developers. Threats to IT systems don’t care about areas of responsibility. Especially with regard to Cyber Warfare, IT threats are no longer limited to company or industry boundaries, administrative jurisdictions or state boundaries. One of the important countermeasures is increased cooperation among the participants especially in the field of Cyber Defence. Besides political and legal challenges, there are technical ones as well. A better, at least partially automated exchange of information is essential to (i) enable sophisticated situational awareness and to (ii) counter the attacker in a coordinated way. Therefore, this publication performs an evaluation of state of the art Intrusion Detection Message Exchange protocols in order to guarantee a secure information exchange between different entities.
Abstract: Achievement motivation is believed to promote
giftedness attracting people to invest in many programs to adopt
gifted students providing them with challenging activities.
Intellectual giftedness is founded on the fluid intelligence and
extends to more specific abilities through the growth and inputs from
the achievement motivation. Acknowledging the roles played by the
motivation in the development of giftedness leads to an effective
nurturing of gifted individuals. However, no study has investigated
the direct and indirect effects of the achievement motivation and
fluid intelligence on intellectual giftedness. Thus, this study
investigated the contribution of motivation factors to giftedness
development by conducting tests of fluid intelligence using Cattell
Culture Fair Test (CCFT) and analytical abilities using culture
reduced test items covering problem solving, pattern recognition,
audio-logic, audio-matrices, and artificial language, and self report
questionnaire for the motivational factors. A number of 180 highscoring
students were selected using CCFT from a leading university
in Malaysia. Structural equation modeling was employed using Amos
V.16 to determine the direct and indirect effects of achievement
motivation factors (self confidence, success, perseverance,
competition, autonomy, responsibility, ambition, and locus of
control) on the intellectual giftedness. The findings showed that the
hypothesized model fitted the data, supporting the model postulates
and showed significant and strong direct and indirect effects of the
motivation and fluid intelligence on the intellectual giftedness.
Abstract: Inter-organizational Workflow (IOW) is commonly
used to support the collaboration between heterogeneous and
distributed business processes of different autonomous organizations
in order to achieve a common goal. E-government is considered as an
application field of IOW. The coordination of the different
organizations is the fundamental problem in IOW and remains the
major cause of failure in e-government projects. In this paper, we
introduce a new coordination model for IOW that improves the
collaboration between government administrations and that respects
IOW requirements applied to e-government. For this purpose, we
adopt a Multi-Agent approach, which deals more easily with interorganizational
digital government characteristics: distribution,
heterogeneity and autonomy. Our model integrates also different
technologies to deal with the semantic and technologic
interoperability. Moreover, it conserves the existing systems of
government administrations by offering a distributed coordination
based on interfaces communication. This is especially applied in
developing countries, where administrations are not necessary
equipped with workflow systems. The use of our coordination
techniques allows an easier migration for an e-government solution
and with a lower cost. To illustrate the applicability of the proposed
model, we present a case study of an identity card creation in Tunisia.
Abstract: Due to the high percentage of induction motors in industrial market, there exist a large opportunity for energy savings. Replacement of working induction motors with more efficient ones can be an important resource for energy savings. A calculation of energy savings and payback periods, as a result of such a replacement, based on nameplate motor efficiency or manufacture-s data can lead to large errors [1]. Efficiency of induction motors (IMs) can be extracted using some procedures that use the no-load test results. In the cases that we must estimate the efficiency on-line, some of these procedures can-t be efficient. In some cases the efficiency estimates using the rating values of the motor, but these procedures can have errors due to the different working condition of the motor. In this paper the efficiency of an IM estimated by using the genetic algorithm. The results are compared with the measured values of the torque and power. The results show smaller errors for this procedure compared with the conventional classical procedures, hence the cost of the equipments is reduced and on-line estimation of the efficiency can be made.
Abstract: Since the late 1980s, the new phenomena of 'employment subcentres' or 'polycentricity' has appeared in the metropolises of North American and Western Europe and it has been an interesting topic for academics and researchers. This paper specifically uses one case study-Guangzhou to explore the development and the mechanism of employment subcentres and polycentricity in Chinese metropolises by spatial analysis method on the basis of the first economic census data. In conclusion, the paper regards that the employment subcentres and polycentricity has existed in Chinese metropolises. And that, the mechanism of them is mainly from the secondary industry instead of the tertiary industry in North American and Western Europe
Abstract: The use of radar in Quantitative Precipitation Estimation (QPE) for radar-rainfall measurement is significantly beneficial. Radar has advantages in terms of high spatial and temporal condition in rainfall measurement and also forecasting. In Malaysia, radar application in QPE is still new and needs to be explored. This paper focuses on the Z/R derivation works of radarrainfall estimation based on rainfall classification. The works developed new Z/R relationships for Klang River Basin in Selangor area for three different general classes of rain events, namely low (10mm/hr, 30mm/hr) and also on more specific rain types during monsoon seasons. Looking at the high potential of Doppler radar in QPE, the newly formulated Z/R equations will be useful in improving the measurement of rainfall for any hydrological application, especially for flood forecasting.
Abstract: In this study, aerobic digestion of tannery industry
wastewater was carried out using mixed culture obtained from
common effluent treatment plant treating tannery wastewater. The
effect of pH, temperature, inoculum concentration, agitation speed
and initial substrate concentration on the reduction of organic matters
were found. The optimum conditions for COD reduction was found
to be pH - 7 (60%), temperature - 30ÔùªC (61%), inoculum
concentration - 2% (61%), agitation speed - 150rpm (65%) and initial
substrate concentration - 1560 mg COD/L (74%). Kinetics studies
were carried by using Monod model, First order, Diffusional model
and Singh model. From the results it was found that the Monod
model suits well for the degradation of tannery wastewater using
mixed microbial consortium.
Abstract: Increasing energy absorption is a significant parameter
in vehicle design. Absorbing more energy results in decreasing
occupant damage. Limitation of the deflection in a side impact results
in decreased energy absorption (SEA) and increased peak load (PL).
Hence a high crash force jeopardizes passenger safety and vehicle
integrity. The aims of this paper are to determine suitable dimensions
and material of a square beam subjected to side impact, in order to
maximize SEA and minimize PL. To achieve this novel goal, the
geometric parameters of a square beam are optimized using the
response surface method (RSM).multi-objective optimization is
performed, and the optimum design for different response features is
obtained.
Abstract: One of the long standing challenging aspect in mobile robotics is the ability to navigate autonomously, avoiding modeled and unmodeled obstacles especially in crowded and unpredictably changing environment. A successful way of structuring the navigation task in order to deal with the problem is within behavior based navigation approaches. In this study, Issues of individual behavior design and action coordination of the behaviors will be addressed using fuzzy logic. A layered approach is employed in this work in which a supervision layer based on the context makes a decision as to which behavior(s) to process (activate) rather than processing all behavior(s) and then blending the appropriate ones, as a result time and computational resources are saved.
Abstract: The recent global financial problem urges government
to play role in stimulating the economy due to the fact that private
sector has little ability to purchase during the recession. A concerned
question is whether the increased government spending crowds out
private consumption and whether it helps stimulate the economy. If
the government spending policy is effective; the private consumption
is expected to increase and can compensate the recent extra
government expense. In this study, the government spending is
categorized into government consumption spending and government
capital spending. The study firstly examines consumer consumption
along the line with the demand function in microeconomic theory.
Three categories of private consumption are used in the study. Those
are food consumption, non food consumption, and services
consumption. The dynamic Almost Ideal Demand System of the three
categories of the private consumption is estimated using the Vector
Error Correction Mechanism model. The estimated model indicates
the substituting effects (negative impacts) of the government
consumption spending on budget shares of private non food
consumption and of the government capital spending on budget share
of private food consumption, respectively. Nevertheless the result
does not necessarily indicate whether the negative effects of changes
in the budget shares of the non food and the food consumption means
fallen total private consumption. Microeconomic consumer demand
analysis clearly indicates changes in component structure of
aggregate expenditure in the economy as a result of the government
spending policy. The macroeconomic concept of aggregate demand
comprising consumption, investment, government spending (the
government consumption spending and the government capital
spending), export, and import are used to estimate for their
relationship using the Vector Error Correction Mechanism model.
The macroeconomic study found no effect of the government capital
spending on either the private consumption or the growth of GDP
while the government consumption spending has negative effect on
the growth of GDP. Therefore no crowding out effect of the
government spending is found on the private consumption but it is
ineffective and even inefficient expenditure as found reducing growth
of the GDP in the context of Thailand.
Abstract: Large scale systems such as computational Grid is
a distributed computing infrastructure that can provide globally
available network resources. The evolution of information processing
systems in Data Grid is characterized by a strong decentralization of
data in several fields whose objective is to ensure the availability and
the reliability of the data in the reason to provide a fault tolerance
and scalability, which cannot be possible only with the use of the
techniques of replication. Unfortunately the use of these techniques
has a height cost, because it is necessary to maintain consistency
between the distributed data. Nevertheless, to agree to live with
certain imperfections can improve the performance of the system by
improving competition. In this paper, we propose a multi-layer protocol
combining the pessimistic and optimistic approaches conceived
for the data consistency maintenance in large scale systems. Our
approach is based on a hierarchical representation model with tree
layers, whose objective is with double vocation, because it initially
makes it possible to reduce response times compared to completely
pessimistic approach and it the second time to improve the quality
of service compared to an optimistic approach.
Abstract: This study investigated a strategy of blending lead-laden sludge and Al-rich precursors to reduce the release of metals from the stabilized products. Using PbO as the simulated lead-laden sludge to sinter with γ-Al2O3 by Pb:Al molar ratios of 1:2 and 1:12, PbAl2O4 and PbAl12O19 were formed as final products during the sintering process, respectively. By firing the PbO + γ-Al2O3 mixtures with different Pb/Al molar ratios at 600 to 1000 °C, the lead transformation was determined through X-ray diffraction (XRD) data. In Pb/Al molar ratio of 1/2 system, the formation of PbAl2O4 is initiated at 700 °C, but an effective formation was observed above 750 °C. An intermediate phase, Pb9Al8O21, was detected in the temperature range of 800-900 °C. However, different incorporation behavior for sintering PbO with Al-rich precursors at a Pb/Al molar ratio of 1/12 was observed during the formation of PbAl12O19 in this system. In the sintering process, both temperature and time effect on the formation of PbAl2O4 and PbAl12O19 phases were estimated. Finally, a prolonged leaching test modified from the U.S. Environmental Protection Agency-s toxicity characteristic leaching procedure (TCLP) was used to evaluate the durability of PbO, Pb9Al8O21, PbAl2O4 and PbAl12O19 phases. Comparison for the leaching results of the four phases demonstrated the higher intrinsic resistance of PbAl12O19 against acid attack.
Abstract: In this paper, we analyzed the pattern of urban spatial structure of Siheung City that had been divided into two parts and presented alternative plans in order to get rid of these phenomena. Concerning patterns of urban spatial structure, we examined it through means of analyzing status of land use, population density and distribution of residence, status of distribution of main facilities, medical facilities, status of distribution of cultural facilities, distribution of land prices and traffic volume trends. The results of study revealed that status of facilities distribution and distribution of land prices, etc. were bisected by the surrounding area of former municipal office and the district of Sihwa, which were both regarded as one apex of the city divide, forming a duo-centric city. In order to get rid of this problem concerned with urban spatial structure that has been bisected, it is required that measures in order to expand facilities in Siheung City should be taken.
Abstract: Future space vehicles will require the use of non-toxic, cryogenic propellants, because of the performance advantages over the toxic hypergolic propellants and also because of the environmental and handling concerns. A prototypical capillary flow liquid acquisition device (LAD) for cryogenic propellants was fabricated with a mesh screen, covering a rectangular flow channel with a cylindrical outlet tube, and was tested with liquid oxygen (LOX). In order to better understand the performance in various gravity environments and orientations with different submersion depths of the LAD, a series of computational fluid dynamics (CFD) simulations of LOX flow through the LAD screen channel, including horizontally and vertically submersions of the LAD channel assembly at normal gravity environment was conducted. Gravity effects on the flow field in LAD channel are inspected and analyzed through comparing the simulations.
Abstract: This paper reports the results of an experimental work
conducted to investigate the effect of curing conditions on the
compressive strength of self-compacting geopolymer concrete
prepared by using fly ash as base material and combination of sodium
hydroxide and sodium silicate as alkaline activator. The experiments
were conducted by varying the curing time and curing temperature in
the range of 24-96 hours and 60-90°C respectively. The essential
workability properties of freshly prepared Self-compacting
Geopolymer concrete such as filling ability, passing ability and
segregation resistance were evaluated by using Slump flow,
V-funnel, L-box and J-ring test methods. The fundamental
requirements of high flowability and resistance to segregation as
specified by guidelines on Self-compacting Concrete by EFNARC
were satisfied. Test results indicate that longer curing time and curing
the concrete specimens at higher temperatures result in higher
compressive strength. There was increase in compressive strength
with the increase in curing time; however increase in compressive
strength after 48 hours was not significant. Concrete specimens cured
at 70°C produced the highest compressive strength as compared to
specimens cured at 60°C, 80°C and 90°C.
Abstract: This study was conducted to evaluate factors
regulating groundwater quality in an area with agriculture as main
use. Under this study twelve groundwater samples have been
collected from Padra taluka, Dabhoi taluka and Savli taluka of
Vadodara district. Groundwater samples were chemically analyzed
for major physicochemical parameter in order to understand the
different geochemical processes affecting the groundwater quality.
The analytical results shows higher concentration of total dissolved
solids (16.67%), electrical conductivity (25%) and magnesium
(8.33%) for pre monsoon and total dissolved solids (16.67%),
electrical conductivity (33.3%) and magnesium (8.33%) for post
monsoon which indicates signs of deterioration as per WHO and BIS
standards. On the other hand, 50% groundwater sample is unsuitable
for irrigation purposes based on irrigation quality parameters. The
study revealed that application of fertilizer for agricultural
contributing the higher concentration of ions in aquifer of Vadodara
district.
Abstract: Not with standing the importance of foreign highly
skilled professionals for host economies, there is a paucity of
research studies investigating the role of the corporate social context
during the integration process. This research aims to address this
paucity by exploring the role of social capital in the integration of
foreign health professionals. It does so by using a qualitative research
approach. In this pilot study the hospital sector forms this study-s
sample and interviews were conducted with HR managers, foreign
health professionals and external HR consultants. It was found that
most of the participating hospitals had not established specific HR
practices and had only partly linked the development of
organisational social capital with a successful integration process.
This research contributes, for example, to the HR literature on the
integration of self-initiated expatriates by analysing the role of HRM
in generating organisational social capital needed for a successful
integration process.
Abstract: Ensemble learning algorithms such as AdaBoost and
Bagging have been in active research and shown improvements in
classification results for several benchmarking data sets with mainly
decision trees as their base classifiers. In this paper we experiment to
apply these Meta learning techniques with classifiers such as random
forests, neural networks and support vector machines. The data sets
are from MAGIC, a Cherenkov telescope experiment. The task is to
classify gamma signals from overwhelmingly hadron and muon
signals representing a rare class classification problem. We compare
the individual classifiers with their ensemble counterparts and
discuss the results. WEKA a wonderful tool for machine learning has
been used for making the experiments.
Abstract: In developing a text-to-speech system, it is well
known that the accuracy of information extracted from a text is
crucial to produce high quality synthesized speech. In this paper, a
new scheme for converting text into its equivalent phonetic spelling
is introduced and developed. This method is applicable to many
applications in text to speech converting systems and has many
advantages over other methods. The proposed method can also
complement the other methods with a purpose of improving their
performance. The proposed method is a probabilistic model and is
based on Smooth Ergodic Hidden Markov Model. This model can be
considered as an extension to HMM. The proposed method is applied
to Persian language and its accuracy in converting text to speech
phonetics is evaluated using simulations.