Abstract: Considering palm oil as non-drying oil owing to its
low iodine value, an attempt was taken to increase the unsaturation in
the fatty acid chains of palm oil for the preparation of alkyds. To
increase the unsaturation in the palm oil, sulphuric acid (SA) and
para-toluene sulphonic acid (PTSA) was used prior to alcoholysis for
the dehydration process. The iodine number of the oil samples was
checked for the unsaturation measurement by Wijs method. Alkyd
resin was prepared using the dehydrated palm oil by following
alcoholysis and esterification reaction. To improve the film properties
0.5wt.% multi-wall carbon nano tubes (MWCNTs) were used to
manufacture polymeric film. The properties of the resins were
characterized by various physico-chemical properties such as density,
viscosity, iodine value, saponification value, etc. Structural
elucidation was confirmed by Fourier transform of infrared
spectroscopy and proton nuclear magnetic resonance; surfaces of the
films were examined by field-emission scanning electron microscope.
In addition, pencil hardness and chemical resistivity was also
measured by using standard methods. The effect of enhancement of
the unsaturation in the fatty acid chain found significant and
motivational. The resin prepared with dehydrated palm oil showed
improved properties regarding hardness and chemical resistivity
testing. The incorporation of MWCNTs enhanced the thermal
stability and hardness of the films as well.
Abstract: In review the generalized data about biological
activity of anthraquinone-containing plants and specimens on their
basis is presented. Data of traditional medicine, results of
bioscreening and clinical researches of specimens are analyzed.
Abstract: Chemical vapor deposition (CVD) diamond coated
cutting tool has excellent cutting performance, it is the most ideal tool
for the processing of nonferrous metals and alloys, composites,
nonmetallic materials and other difficult-to-machine materials
efficiently and accurately. Depositing CVD diamond coating on the
cemented carbide with high cobalt content can improve its toughness
and strength, therefore, it is very important to research on the
preparation technology and cutting properties of CVD diamond coated
cemented carbide cutting tool with high cobalt content. The
preparation technology of boron-doped diamond (BDD) coating has
been studied and the coated drills were prepared. BDD coating were
deposited on the drills by using the optimized parameters and the SEM
results show that there are no cracks or collapses in the coating.
Cutting tests with the prepared drills against the silumin and aluminum
base printed circuit board (PCB) have been studied. The results show
that the wear amount of the coated drill is small and the machined
surface has a better precision. The coating does not come off during
the test, which shows good adhesion and cutting performance of the
drill.
Abstract: Epidermal Growth Factor (EGF, Mw=6,045) has been
reported to have high efficiency of wound repair and anti-wrinkle
effect. However, the half-life of EGF in the body is too short to exert
the biological activity effectively when applied in free form. Growth
Factors can be stabilized by immobilization with carbohydrates from
thermal and proteolytic degradation. Low molecular weight chitosan
(LMCS) and its derivate prepared by hydrogen peroxide has high
solubility. LM6A6DC was successfully prepared as a reactive
carbohydrate for the stabilization of EGF by the reactions of LMCS
with alkalization, tosylation, azidation and reduction. The structure of
LM6A6DC was confirmed by FT-IR, 1H NMR and elementary
analysis. For enhancing the stability of free EGF, EGF was attached
with LM6A6DC by using water-soluble carbodiimide.
EGF-LM6A6DC conjugates did not show any cytotoxicity on the
Normal Human Dermal Fibroblast (NHDF) 3T3 proliferation at least
under 100 μg/ml. In the result, it was considered that LM6A6DC is
suitable to immobilize of growth factor.
Abstract: Composite material based on Fe3Si micro-particles
and Mn-Zn nano-ferrite was prepared using powder metallurgy
technology. The sol-gel followed by autocombustion process was
used for synthesis of Mn0.8Zn0.2Fe2O4 ferrite. 3 wt.% of mechanically
milled ferrite was mixed with Fe3Si powder alloy. Mixed micro-nano
powder system was homogenized by the Resonant Acoustic Mixing
using ResodynLabRAM Mixer. This non-invasive homogenization
technique was used to preserve spherical morphology of Fe3Si
powder particles. Uniaxial cold pressing in the closed die at pressure
600 MPa was applied to obtain a compact sample. Microwave
sintering of green compact was realized at 800°C, 20 minutes, in air.
Density of the powders and composite was measured by
Hepycnometry. Impulse excitation method was used to measure
elastic properties of sintered composite. Mechanical properties were
evaluated by measurement of transverse rupture strength (TRS) and
Vickers hardness (HV). Resistivity was measured by 4 point probe
method. Ferrite phase distribution in volume of the composite was
documented by metallographic analysis.
It has been found that nano-ferrite particle distributed among
micro- particles of Fe3Si powder alloy led to high relative density
(~93%) and suitable mechanical properties (TRS >100 MPa, HV
~1GPa, E-modulus ~140 GPa) of the composite. High electric
resistivity (R~6.7 ohm.cm) of prepared composite indicate their
potential application as soft magnetic material at medium and high
frequencies.
Abstract: In this research the effects of adding silica and
alumina nanoparticles on flow ability and compressive strength of
cementitious composites based on Portland cement were investigated.
In the first stage, the rheological behavior of different samples
containing nanosilica, nanoalumina and polypropylene, polyvinyl
alcohol and polyethylene fibers were evaluated. With increasing of
nanoparticles in fresh samples, the slump flow diameter reduced.
Fibers reduced the flow ability of the samples and viscosity
increased. With increasing of the micro silica particles to cement
ratio from 2/1 to 2/2, the slump flow diameter increased. By adding
silica and alumina nanoparticles up to 3% and 2% respectively, the
compressive strength increased and after decreased. Samples
containing silica nanoparticles and fibers had the highest compressive
strength.
Abstract: This study is concerned with the optimization of
fermentation parameters for the hyper production of mannanase from
Fusarium oxysporum SS-25 employing two step statistical strategy
and kinetic characterization of crude enzyme preparation. The
Plackett-Burman design used to screen out the important factors in
the culture medium revealed 20% (w/w) wheat bran, 2% (w/w) each
of potato peels, soyabean meal and malt extract, 1% tryptone, 0.14%
NH4SO4, 0.2% KH2PO4, 0.0002% ZnSO4, 0.0005% FeSO4, 0.01%
MnSO4, 0.012% SDS, 0.03% NH4Cl, 0.1% NaNO3 in brewer’s spent
grain based medium with 50% moisture content, inoculated with
2.8×107 spores and incubated at 30oC for 6 days to be the main
parameters influencing the enzyme production. Of these factors, four
variables including soyabean meal, FeSO4, MnSO4 and NaNO3 were
chosen to study the interactive effects and their optimum levels in
central composite design of response surface methodology with the
final mannanase yield of 193 IU/gds. The kinetic characterization
revealed the crude enzyme to be active over broader temperature and
pH range. This could result in 26.6% reduction in kappa number with
4.93% higher tear index and 1% increase in brightness when used to
treat the wheat straw based kraft pulp. The hydrolytic potential of
enzyme was also demonstrated on both locust bean gum and guar
gum.
Abstract: Digital image correlation (DIC) is a contactless fullfield
displacement and strain reconstruction technique commonly
used in the field of experimental mechanics. Comparing with
physical measuring devices, such as strain gauges, which only
provide very restricted coverage and are expensive to deploy widely,
the DIC technique provides the result with full-field coverage and
relative high accuracy using an inexpensive and simple experimental
setup. It is very important to study the natural patterns effect on the
DIC technique because the preparation of the artificial patterns is
time consuming and hectic process. The objective of this research is
to study the effect of using images having natural pattern on the
performance of DIC. A systematical simulation method is used to
build simulated deformed images used in DIC. A parameter (subset
size) used in DIC can have an effect on the processing and accuracy
of DIC and even cause DIC to failure. Regarding to the picture
parameters (correlation coefficient), the higher similarity of two
subset can lead the DIC process to fail and make the result more
inaccurate. The pictures with good and bad quality for DIC methods
have been presented and more importantly, it is a systematic way to
evaluate the quality of the picture with natural patterns before they
install the measurement devices.
Abstract: The problem of psychologist training remains a key
priority in Armenia. During the Soviet period, the notion of a
psychologist was obscure not only in Armenia but also in other
Soviet republics. The breakup of the Soviet Union triggered a gradual
change in this area activating the cooperation with specialists from
other countries. The need for recovery from the psychological trauma
caused by the 1988 earthquake pushed forward the development of
practical psychology in Armenia. This phenomenon led to positive
changes in perception of and interest to a psychologist
profession.Armenian universities started designing special programs
for psychologists’ preparation. Armenian psychologists combined
their efforts in the field of training relevant specialists.
During the recent years, the Bologna educational system was
introduced in Armenia which led to implementation of education
quality improvement programs. Nevertheless, even today the issue of
psychologists’ training is not yet settled in Armenian universities. So
far graduate psychologists haven’t got a clear idea of personal and
professional qualities of a psychologist. Recently, as a result of
educational reforms, the psychology curricula underwent changes,
but so far they have not led to a desired outcome. Almost all curricula
in certain specialties are aimed to form professional competencies
and strengthen practical skills.
A survey conducted in Armenia aimed to identify what are the
ideas of young psychology specialists on the image of a psychologist.
The survey respondents were 45 specialists holding bachelor’s degree
as well as 30 master degree graduates, who have not been working
yet. The research reveals that we need to change the approach of
preparing psychology practitioners in the universities of Armenia.
Such an approach to psychologist training will make it possible to
train qualified specialists for enhancement of modern psychology
theory and practice.
Abstract: In situ modified cyclohexanone-formaldehyde resins
were prepared by addition of alendronic acid during resin
preparation. Clay nanocomposites in ketonic resins were achieved by
adding clay into the flask at the beginning of the resin preparation.
The prepared resins were used for the synthesis of fire resistant
polyurethanes foam. Both phosphorous containing modifier
compound alendronic acid and nanoclay increases fire resistance of
the cyclohexanone-formaldehyde resin thus polyurethane produced
from these resins. The effect of the concentrations of alendronic acid
and clay on the fire resistance and physical properties of
polyurethanes was studied.
Abstract: Passing the entrance exam to a university is a major
step in one's life. University entrance exam commonly known as
Kankor is the nationwide entrance exam in Afghanistan. This
examination is prerequisite for all public and private higher education
institutions at undergraduate level. It is usually taken by students who
are graduated from high schools. In this paper, we reflect the major
educational school graduates issues and propose ICT-based test
preparation environment, known as ‘Online Kankor Exam Prep
System’ to give students the tools to help them pass the university
entrance exam on the first try. The system is based on Intelligent
Tutoring System (ITS), which introduced an essential package of
educational technology for learners that features: (I) exam-focused
questions and content; (ii) self-assessment environment; and (iii) test
preparation strategies in order to help students to acquire the necessary
skills in their carrier and keep them up-to-date with instruction.
Abstract: Liposome plays an important role in medical and
pharmaceutical science as e.g. nano scale drug carriers. Liposomes
are vesicles of varying size consisting of a spherical lipid bilayer and
an aqueous inner compartment. Magnet-driven liposome used for the
targeted delivery of drugs to organs and tissues. These liposome
preparations contain encapsulated drug components and finely
dispersed magnetic particles.
Liposomes are vesicles of varying size consisting of a spherical
lipid bilayer and an aqueous inner compartment that are generated in
vitro. These are useful in terms of biocompatibility, biodegradability,
and low toxicity, and can control biodistribution by changing the size,
lipid composition, and physical characteristics. Furthermore,
liposomes can entrap both hydrophobic and hydrophilic drugs and are
able to continuously release the entrapped substrate, thus being useful
drug carriers. Magnetic liposomes (MLs) are phospholipid vesicles
that encapsulate magneticor paramagnetic nanoparticles. They are
applied as contrast agents for magnetic resonance imaging (MRI).
The biological synthesis of nanoparticles using plant extracts plays
an important role in the field of nanotechnology. Green-synthesized
magnetite nanoparticles-protein hybrid has been produced by treating
Iron (III) / Iron (II) chloride with the leaf extract of Datura inoxia.
The phytochemicals present in the leaf extracts act as a reducing as
well stabilizing agents preventing agglomeration, which include
flavonoids, phenolic compounds, cardiac glycosides, proteins and
sugars.
The magnetite nanoparticles-protein hybrid has been trapped
inside the aqueous core of the liposome prepared by reversed phase
evaporation (REV) method using oleic and linoleic acid which has
been shown to be driven under magnetic field confirming the
formation magnetic liposome (ML). Chemical characterization of
stealth magnetic liposome has been performed by breaking the
liposome and release of magnetic nanoparticles. The presence iron
has been confirmed by colour complex formation with KSCN and
UV-Vis study using spectrophotometer Cary 60, Agilent.
This magnet driven liposome using nanoparticles-protein hybrid
can be a smart vesicles for the targeted drug delivery.
Abstract: Background: Taiwan now is an aging society. Research
on the elderly should not be confined to caring for seniors, but should
also be focused on ways to improve health and the quality of life.
Senior citizens who participate in volunteer services could become
less lonely, have new growth opportunities, and regain a sense of
accomplishment. Thus, the question of how to get the elderly to
participate in volunteer service is worth exploring. Objective: Apply
the Transtheoretical Model to understand stages of change in regular
volunteer service and voluntary service behaviour among the seniors.
Methods: 1525 adults over the age of 65 from the Renai district of
Keelung City were interviewed. The research tool was a
self-constructed questionnaire, and individual interviews were
conducted to collect data. Then the data was processed and analyzed
using the IBM SPSS Statistics 20 (Windows version) statistical
software program. Results: In the past six months, research subjects
averaged 9.92 days of volunteer services. A majority of these elderly
individuals had no intention to change their regular volunteer services.
We discovered that during the maintenance stage, the self-efficacy for
volunteer services was higher than during all other stages, but
self-perceived barriers were less during the preparation stage and
action stage. Self-perceived benefits were found to have an important
predictive power for those with regular volunteer service behaviors in
the previous stage, and self-efficacy was found to have an important
predictive power for those with regular volunteer service behaviors in
later stages. Conclusions/Implications for Practice: The research
results support the conclusion that community nursing staff should
group elders based on their regular volunteer services change stages
and design appropriate behavioral change strategies.
Abstract: Children are more susceptible to medication errors
than adults. Medication administration process is the last stage in the
medication treatment process and most of the errors detected in this
stage. Little research has been undertaken about medication errors in
children in the Middle East countries. This study was aimed to
evaluate how the paediatric nurses adhere to the medication
administration policy and also to identify any medication preparation
and administration errors or any risk factors. An observational,
prospective study of medication administration process from when
the nurses preparing patient medication until administration stage
(May to August 2014) was conducted in Saudi Arabia. Twelve
paediatric nurses serving 90 paediatric patients were observed. 456
drug administered doses were evaluated. Adherence rate was variable
in 7 steps out of 16 steps. Patient allergy information, dose
calculation, drug expiry date were the steps in medication
administration with lowest adherence rates. 63 medication
preparation and administration errors were identified with error rate
13.8% of medication administrations. No potentially life-threating
errors were witnessed. Few logistic and administrative factors were
reported. The results showed that the medication administration
policy and procedure need an urgent revision to be more sensible for
nurses in practice. Nurses’ knowledge and skills regarding to the
medication administration process should be improved.
Abstract: Two Lithium Disilicate (LD) glass ceramics based on
SiO2-Li2O-K2O-Al2O3 system were prepared through a glass melting
method. The glass rods were then fabricated into dental crowns via a
hot pressing at 900˚C and 850˚C in order to study the effect of the
pressing temperatures on the phase formation and microstructure of
the glasses. Different samples of as cast glass and heat treated
samples (600˚C and 700˚C) were used to press for investigating the
effect of an initial microstructure on the hot pressing technique. Xray
diffraction (XRD) and scanning electron microscopy (SEM) were
performed to determine the phase formation and microstructure of the
samples, respectively. XRD results show that the main crystalline
structure was Li2Si2O5 by having Li3PO4, Li0.6Al0.6Si2O6, Li2SiO3,
Ca5 (PO4)3F and SiO2 as minor phases. Glass compositions with
different heat treatment temperatures exhibited a difference phase
formations but have less effect during pressing. SEM micrographs
showed the microstructure of Li2Si2O5 as lath-like shape in all
glasses. With increasing the initial heat treatment temperature, the
longer the lath-like crystals of lithium disilicate were increased
especially when using glass heat treatment at 700˚C followed by
pressing at 900˚C. This could be suggested that LD1 heat treatment at
700˚C which pressing at 900˚C presented the best formation by the
hot pressing and compiled microstructure.
Abstract: Asphaltic concrete for pavement construction in India
are produced by using crushed stone, gravels etc. as aggregate. In
north-Eastern region of India, there is a scarcity of stone aggregate.
Therefore the road engineers are always in search of an optional
material as aggregate which can replace the regularly used material.
The purpose of this work was to evaluate the utilization of
substandard or marginal aggregates in flexible pavement
construction. The investigation was undertaken to evaluate the effects
of using lower quality aggregates such as over burnt brick aggregate
on the preparation of asphalt concrete for flexible pavements. The
scope of this work included a review of available literature and
existing data, a laboratory evaluation organized to determine the
effects of marginal aggregates and potential techniques to upgrade
these substandard materials, and a laboratory evaluation of these
upgraded marginal aggregate asphalt mixtures. Over burnt brick
aggregates are water susceptible and can leads to moisture damage.
Moisture damage is the progressive loss of functionality of the
material owing to loss of the adhesion bond between the asphalt
binder and the aggregate surface. Hence zycosoil as an anti striping
additive were evaluated in this study. This study summarizes the
results of the laboratory evaluation carried out to investigate the
properties of asphalt concrete prepared with zycosoil modified over
burnt brick aggregate. Marshall specimen were prepared with stone
aggregate, zycosoil modified stone aggregate, over burnt brick
aggregate and zycosoil modified over burnt brick aggregate. Results
show that addition of zycosoil with stone aggregate increased
stability by 6% and addition of zycosoil with over burnt brick
aggregate increased stability by 30%.
Abstract: This paper evaluates the performance of a multi-lane
four legged modern roundabout operating in Muscat using SIDRA
model. The performance measures include Degree of Saturation
(DOS), average delay, and queue lengths. The geometric and traffic
data were used for model preparation. Gap acceptance parameters,
critical gap and follow up headway, were used for calibration of
SIDRA model. The results from the analysis showed that currently
the roundabout is experiencing delays up to 610 seconds per vehicle
with DOS 1.67 during peak hour. Further, sensitivity analysis for
general and roundabout parameters was performed, amongst lane
width, cruise speed, inscribed diameter, entry radius and entry angle
showed that inscribed diameter is most crucial factor affecting delay
and DOS. Up gradation of roundabout to fully signalized junction
was found as the suitable solution which will serve for future years
with LOS C for design year having DOS of 0.9 with average control
delay of 51.9 seconds per vehicle.
Abstract: Calcium phosphate cement (CPC) is one of the most
attractive bioceramics due to its moldable and shape ability to fill
complicated bony cavities or small dental defect positions. In this
study, CPC was produced by using mixture of tetracalcium phosphate
(TTCP, Ca4O(PO4)2) and dicalcium phosphate anhydrous (DCPA,
CaHPO4) in equimolar ratio (1/1) with aqueous solutions of acetic
acid (C2H4O2) and disodium hydrogen phosphate dehydrate
(Na2HPO4.2H2O) in combination with sodium alginate in order to
improve theirs moldable characteristic. The concentration of the
aqueous solutions and sodium alginate were varied to investigate the
effect of different aqueous solutions and alginate on properties of the
cements. The cement paste was prepared by mixing cement powder
(P) with aqueous solution (L) in a P/L ratio of 1.0g/0.35ml. X-ray
diffraction (XRD) was used to analyses phase formation of the
cements. Setting time and compressive strength of the set CPCs were
measured using the Gilmore apparatus and Universal testing
machine, respectively.
The results showed that CPCs could be produced by using both
basic (Na2HPO4.2H2O) and acidic (C2H4O2) solutions. XRD results
show the precipitation of hydroxyapatite in all cement samples. No
change in phase formation among cements using difference
concentrations of Na2HPO4.2H2O solutions. With increasing
concentration of acidic solutions, samples obtained less
hydroxyapatite with a high dicalcium phosphate dehydrate leaded to
a shorter setting time. Samples with sodium alginate exhibited higher
crystallization of hydroxyapatite than that of without alginate as a
result of shorten setting time in a basic solution but a longer setting
time in an acidic solution. The stronger cement was attained from
samples using the acidic solution with sodium alginate; however the
strength was lower than that of using the basic solution.
Abstract: Preparation of nanoparticles of cerium oxide and
adsorption of bovine serum albumin on them were studied. Particle
size distribution and influence of pH on zeta potential of prepared
CeO2 were determined. Average size of prepared cerium oxide
nanoparticles was 9 nm. The simultaneous measurements of the
bovine serum albumin adsorption and zeta potential determination of
the (adsorption) suspensions were carried out. The adsorption
isotherms were found to be of typical Langmuir type; values of the
bovine serum albumin adsorption capacities were calculated.
Increasing of pH led to decrease of zeta potential and decrease of
adsorption capacity of cerium oxide nanoparticles. The maximum
adsorption capacity was found for strongly acid suspension (am =
118 mg/g). The samples of nanoceria with positive zeta potential
adsorbed more bovine serum albumin on the other hand, the samples
with negative zeta potential showed little or no protein adsorption.
Surface charge or better say zeta potential of CeO2 nanoparticles
plays the key role in adsorption of proteins on such type of materials.
Abstract: Curcuma longa L. (Zingiberaceae), commonly known
as turmeric, has a long history of traditional uses for culinary
purposes as a spice and a food colorant. The present study aimed to
document the ethnobotanical knowledge about Curcuma longa, and
to assess the variation in the herbalists’ experience in Northeastern
Algeria. Data were collected using semi-structured questionnaires
and direct interviews with 30 herbalists. Ethnobotanical indices,
including the fidelity level (FL%), the relative frequency citation
(RFC), and use value (UV) were determined by quantitative methods.
Diversity in the level of knowledge was analyzed using univariate,
non-parametric, and multivariate statistical methods. Three main
categories of uses were recorded for C. longa: for food, for medicine,
and for cosmetic purposes. As a medicine, turmeric was used for the
treatment of gastrointestinal, dermatological, and hepatic diseases.
Medicinal and food uses were correlated with both forms of
preparation (rhizome and powder). The age group did not influence
the use. Multivariate analyses showed a significant variation in
traditional knowledge, associated with the use value, origin, quality,
and efficacy of the drug. The findings suggested that the geographical
origin of C. longa affected the use in Algeria.