Abstract: The FOSDT (the First Order Shear Deformation
Theory) is taking into consideration to study the static behavior of a
bimorph beam, with a delamination zone between the upper and the
lower layer. The effect of limit conditions and lengths of the
delamination zone are presented in this paper, with a PVDF
piezoelectric material application. A FEM “Finite Element Method”
is used to discretize the beam. In the axial displacement, a
displacement field appears in the debonded zone with inverse effect
between the upper and the lower layer was observed.
Abstract: In the past few decades, the field of chemistry
education has grown tremendously and researches indicated that after
traditional chemistry instruction students often lacked deep
conceptual understanding and failed to integrate their ideas into
coherent conceptual framework. For several concepts in chemistry,
students at all levels have demonstrated difficulty in changing their
initial perceptions. Their perceptions are most often wrong and don't
agree with correct scientific concepts. This study explored the
effectiveness of intervention discussion sections for a college general
chemistry course designed to apply research on students
preconceptions, knowledge integration and student explanation.
Three interventions discussions lasting three hours on bond energy
and spontaneity were done tested and intervention (treatment)
students’ performances were compared with that of control group
which did not use the experimental pedagogy. Results indicated that
this instruction which was capable of identifying students'
misconceptions, initial conceptions and integrating those ideas into
class discussion led to enhanced conceptual understanding and better
achievement for the experimental group.
Abstract: In this work, we report, a systematic study on the
structural and optical properties of Pr-doped ZnO nanostructures and
PVA:Zn98Pr2O polymer matrix nanocomposites free standing films.
These particles are synthesized through simple wet chemical route
and solution casting technique at room temperature, respectively.
Structural studies carried out by X-ray diffraction method confirm
that the prepared pure ZnO and Pr doped ZnO nanostructures are in
hexagonal wurtzite structure and the microstrain is increased upon
doping. TEM analysis reveals that the prepared materials are in sheet
like nature. Absorption spectra show free excitonic absorption band
at 370 nm and red shift for the Pr doped ZnO nanostructures. The
PVA:Zn98Pr2O composite film exhibits both free excitonic and PVA
absorption bands at 282 nm. Fourier transform infrared spectral
studies confirm the presence of A1 (TO) and E1 (TO) modes of Zn-O
bond vibration and the formation of polymer composite materials.
Abstract: In this paper 3D FEM analysis was carried out on
double lap bonded joint with composite adherents subjected to
dynamic shear. The adherents are made of Carbon/Epoxy while the
adhesive is epoxy Araldite 2031. The maximum average shear stress
and the stress homogeneity in the adhesive layer were examined.
Three fibers textures were considered: UD; 2.5D and 3D with same
volume fiber then a parametric study based on changing the thickness
and the type of fibers texture in 2.5D was accomplished. Moreover,
adherents’ dissimilarity was also investigated. It was found that the
main parameter influencing the behavior is the longitudinal stiffness
of the adherents. An increase in the adherents’ longitudinal stiffness
induces an increase in the maximum average shear stress in the
adhesive layer and an improvement in the shear stress homogeneity
within the joint. No remarkable improvement was observed for
dissimilar adherents.
Abstract: Comparisons of financial development across
countries are central to answering many of the questions on factors
leading to economic development. For this reason this study analyzes
the implications of financial system’s development on country’s
economic development. The aim of the article: to analyze the impact
of financial system’s development on economic development. The
following research methods were used: systemic, logical and
comparative analysis of scientific literature, analysis of statistical
data, time series model (Autoregressive Distributed Lag (ARDL)
Model). The empirical results suggest about positive short and long
term effect of stock market development on GDP per capita.
Abstract: In recent years, the hair building fiber has become
popular, in other words, it is an effective method which helps people
who suffer hair loss or sparse hair since the hair building fiber is
capable to create a natural look of simulated hair rapidly. In the
markets, there are a lot of hair fiber brands that have been designed to
formulate an intense bond with hair strands and make the hair appear
more voluminous instantly. However, those products have their own
set of properties. Thus, in this report, some measurement techniques
are proposed to identify those products. Up to five different brands of
hair fiber are tested. The electrostatic and dielectric properties of the
hair fibers are macroscopically tested using design DC and high
frequency microwave techniques. Besides, the hair fibers are
microscopically analysis by magnifying the structures of the fiber
using scanning electron microscope (SEM). From the SEM photos,
the comparison of the uniformly shaped and broken rate of the hair
fibers in the different bulk samples can be observed respectively.
Abstract: The use OF adhesive anchors for wooden constructions is an efficient technology to connect and design timber members in new timber structures and to rehabilitate the damaged structural members of historical buildings. Due to the lack of standard regulation in this specific area of structural design, designers’ choices are still supported by test analysis that enables knowledge, and the prediction, of the structural behaviour of glued in rod joints. The paper outlines an experimental research activity aimed at identifying the tensile resistance capacity of several new adhesive joint prototypes made of epoxy resin, steel bar and timber, Oak and Douglas Fir species. The development of new adhesive connectors has been carried out by using epoxy to glue stainless steel bars into pre-drilled holes, characterised by smooth and rough internal surfaces, in timber samples. The realization of a threaded contact surface using a specific drill bit has led to an improved bond between wood and epoxy. The applied changes have also reduced the cost of the joints’ production. The paper presents the results of this parametric analysis and a Finite Element analysis that enables identification and study of the internal stress distribution in the proposed adhesive anchors.
Abstract: Sandwich structure composites produced by epoxy
core and aluminium skin were developed as potential building
materials. Interface bonding between core and skin was controlled by
varying kenaf content. Five different weight percentage of kenaf
loading ranging from 10 wt% to 50 wt% were employed in the core
manufacturing in order to study the mechanical properties of the
sandwich composite. Properties of skin aluminium with epoxy were
found to be affected by drying time of the adhesive. Mechanical
behavior of manufactured sandwich composites in relation with
properties of constituent materials was studied. It was found that 30
wt% of kenaf loading contributed to increase the flexural strength and
flexural modulus up to 102 MPa and 32 GPa, respectively. Analysis
were done on the flatwise and edgewise compression test. For
flatwise test, it was found that 30 wt% of fiber loading could
withstand maximum force until 250 kN, with compressive strength
results at 96.94 MPa. However, at edgewise compression test, the
sandwich composite with same fiber loading only can withstand 31
kN of the maximum load with 62 MPa of compressive strength
results.
Abstract: The industrial process adds to engineering wood
products features absent in solid wood, with homogeneous structure
and reduced defects, improved physical and mechanical properties,
bio-deterioration, resistance and better dimensional stability,
improving quality and increasing the reliability of structures wood.
These features combined with using fast-growing trees, make them
environmentally ecological products, ensuring a strong consumer
market. The wood I-joists are manufactured by the industrial profiles
bonding flange and web, an important aspect of the production of
wooden I-beams is the adhesive joint that bonds the web to the
flange. Adhesives can effectively transfer and distribute stresses,
thereby increasing the strength and stiffness of the composite. The
objective of this study is to evaluate different resins in a shear strain
specimens with the aim of analyzing the most efficient resin and
possibility of using national products, reducing the manufacturing
cost. First was conducted a literature review, where established the
geometry and materials generally used, then established and analyzed
8 national resins and produced six specimens for each.
Abstract: In this paper, a nonlinear Finite Element Analysis
(FEA) was carried out using ANSYS software to build a model able
of predicting the behavior of Reinforced Concrete (RC) beams with
unbonded reinforcement. The FEA model was compared to existing
experimental data by other researchers. The existing experimental
data consisted of 16 beams that varied from structurally sound beams
to beams with unbonded reinforcement with different unbonded
lengths and reinforcement ratios. The model was able to predict the
ultimate flexural strength, load-deflection curve, and crack pattern of
concrete beams with unbonded reinforcement. It was concluded that
when the when the unbonded length is less than 45% of the span,
there will be no decrease in the ultimate flexural strength due to the
loss of bond between the steel reinforcement and the surrounding
concrete regardless of the reinforcement ratio. Moreover, when the
reinforcement ratio is relatively low, there will be no decrease in
ultimate flexural strength regardless of the length of unbond.
Abstract: Complexation of anthocyanins to mimic natural
copigmentation process was investigated. Cyanidin-rich extracts from
Zea mays L. ceritina Kulesh. and delphinidin-rich extracts from
Clitoria ternatea L. were used to form 4 anthocyanin complexes,
AC1, AC2, AC3 and AC4, in the presence of several polyphenols and
a trace metal. Characterizations of the ACs were conducted by UV,
FTIR, DSC/TGA and morphological observations. Bathochromic
shifts of the UV spectra of 4 formulas of ACs were observed at peak
wavelengths of about 510-620 nm by 10 nm suggesting complex
formation. FTIR spectra of the ACs indicate shifts of peaks from
1,733 cm-1 to 1,696 cm-1 indicating interactions and a decrease in the
peak areas within the wavenumber of 3,400-3,500 cm-1 indicating
changes in hydrogen bonding. Thermal analysis of all of the ACs
suggests increases in melting temperature after complexation. AC
with the highest melting temperature was morphologically observed
by SEM and TEM to be crystal-like particles within a range of 50 to
200 nm. Particle size analysis of the AC by laser diffraction gave a
range of 50-600 nm, indicating aggregation. This AC was shown to
have no cytotoxic effect on cultured HGEPp0.5 and HGF (all p>
0.05) by MTT. Therefore, complexation of anthocyanins was simple
and self-assembly process, potentially resulting in nanosized particles
of anthocyanin complex.
Abstract: Carbon fiber reinforced polymersarewidely used to strengthen steel structural elements. These structural elements are normally subjected to static, dynamic and fatigue loadings during their life-time. CFRP laminate is commonly used to strengthen these structures under the subjected loads. A number of studies have focused on the characteristics of CFRP sheets bonded to steel members under static, dynamic and fatigue loadings. However, there is a gap in understanding the bonding behavior between CFRP laminates and steel members under impact loading. This paper shows the effect of high load rates on this bond. CFRP laminate CFK 150/2000 was used to strengthen steel joints using Araldite 420 epoxy. The results show that applying a high load rate significantly affects the bond strength but has little influence on the effective bond length.
Abstract: Geopolymer concretes are new class of construction
materials that have emerged as an alternative to Ordinary Portland
cement concrete. Considerable researches have been carried out on
material development of geopolymer concrete; however, a few studies
have been reported on the structural use of them. This paper presents
the bond behaviors of reinforcement embedded in fly ash based
geopolymer concrete. The development lengths of reinforcement for
various compressive strengths of concrete, 20, 30 and 40 MPa, and
reinforcement diameters, 10, 16 and 25 mm, are investigated. Total 27
specimens were manufactured and pull-out test according to EN 10080
was applied to measure bond strength and slips between concrete and
reinforcements. The average bond strengths decreased from 23.06MPa
to 17.26 MPa, as the diameters of reinforcements increased from
10mm to 25mm. The compressive strength levels of geopolymer
concrete showed no significant influence on bond strengths in this
study. Also, the bond-slip relations between geopolymer concrete and
reinforcement are derived using non-linear regression analysis for
various experimental conditions.
Abstract: To develop AZ91D magnesium alloys with improved
properties, we have applied TiN and VN/TiN multilayer coatings
using DC magnetron sputter technique. Coating structure, surface
morphology, chemical bonding and corrosion resistance of coatings
were analyzed by x-ray diffraction (XRD), scanning electron
microscope (SEM), x-ray photoelectron spectroscopy (XPS), and
tafel extrapolation method, respectively. XPS analysis reveal that VN
overlayer reacts with oxygen at the VN/TiN interface and forms more
stable TiN layer. Morphological investigations and the corrosion
results show that VN/TiN multilayer thin film coatings are quite
effective to optimize the corrosion resistance of Mg alloys.
Abstract: PVC foam-fly ash composites (PVC-FA) are
characterized for their structural, morphological, mechanical and
thermal properties. The tensile strength of the composites increased
modestly with higher fly ash loading, while there was a significant
increase in the elastic modulus for the same composites. On the other
hand, a decrease in elongation at UTS was observed upon increasing
fly ash content due to increased rigidity of the composites. Similarly,
the flexural modulus increased as the fly ash loading increased,
where the composites containing 25 phr fly ash showed the highest
flexural strength. Thermal properties of PVC-fly ash composites were
determined by Thermo Gravimetric Analysis (TGA). The
microstructural properties were studied by Scanning Electron
Microscopy (SEM). SEM results confirm that fly ash particles were
mechanically interlocked in PVC matrix with good interfacial
interaction with the matrix. Particle agglomeration and debonding
was observed in samples containing higher amounts of fly ash.
Abstract: The financial crises caused a collapse in prices of
most asset classes, raising the attention on alternative investments
such as sukuk, a smaller, fast growing but often misunderstood
market. We study diversification benefits of sukuk, their correlation
with other asset classes and the effects of their inclusion in
investment portfolios of institutional and retail investors, through a
comprehensive comparison of their risk/return profiles during and
after the financial crisis.
We find a beneficial performance adjusted for the specific
volatility together with a lower correlation especially during the
financial crisis. The distribution of sukuk returns is positively skewed
and leptokurtic, with a risk/return profile similarly to high yield
bonds. Overall, our results suggest that sukuk present diversification
opportunities, a significant volatility-adjusted performance and lower
correlations especially during the financial crisis.
Our findings are relevant for a number of institutional investors.
Long term investors, such as life insurers would benefit from sukuk’s
protective features during financial crisis yet keeping return and
growth opportunities, whereas banks would gain due to their role of
placers, advisors, market makers or underwriters.
Abstract: Asphaltic concrete for pavement construction in India
are produced by using crushed stone, gravels etc. as aggregate. In
north-Eastern region of India, there is a scarcity of stone aggregate.
Therefore the road engineers are always in search of an optional
material as aggregate which can replace the regularly used material.
The purpose of this work was to evaluate the utilization of
substandard or marginal aggregates in flexible pavement
construction. The investigation was undertaken to evaluate the effects
of using lower quality aggregates such as over burnt brick aggregate
on the preparation of asphalt concrete for flexible pavements. The
scope of this work included a review of available literature and
existing data, a laboratory evaluation organized to determine the
effects of marginal aggregates and potential techniques to upgrade
these substandard materials, and a laboratory evaluation of these
upgraded marginal aggregate asphalt mixtures. Over burnt brick
aggregates are water susceptible and can leads to moisture damage.
Moisture damage is the progressive loss of functionality of the
material owing to loss of the adhesion bond between the asphalt
binder and the aggregate surface. Hence zycosoil as an anti striping
additive were evaluated in this study. This study summarizes the
results of the laboratory evaluation carried out to investigate the
properties of asphalt concrete prepared with zycosoil modified over
burnt brick aggregate. Marshall specimen were prepared with stone
aggregate, zycosoil modified stone aggregate, over burnt brick
aggregate and zycosoil modified over burnt brick aggregate. Results
show that addition of zycosoil with stone aggregate increased
stability by 6% and addition of zycosoil with over burnt brick
aggregate increased stability by 30%.
Abstract: Hydrogenated amorphous carbon (a-C:H) films have
been synthesized by a radio frequency plasma enhanced chemical
vapor deposition (rf-PECVD) technique with different bias voltage
from 0.0 to -0.5 kV. The Raman spectra displayed the polymer-like
hydrogenated amorphous carbon (PLCH) film with 0.0 to -0.1 and
a-C:H films with -0.2 to -0.5 kV of bias voltages. The surface chemical
information of all films were studied by X-ray photoelectron
spectroscopy (XPS) technique, presented to C-C (sp2 and sp3) and C-O
bonds, and relative carbon (C) and oxygen (O) atomics contents. The
O contamination had affected on structure and optical properties. The
true density of PLCH and a-C:H films were characterized by X-ray
refractivity (XRR) method, showed the result as in the range of
1.16-1.73 g/cm3 that depending on an increasing of bias voltage. The
hardness was proportional to the true density of films. In addition, the
optical properties i.e. refractive index (n) and extinction coefficient (k)
of these films were determined by a spectroscopic ellipsometry (SE)
method that give formation to in 1.62-2.10 (n) and 0.04-0.15 (k)
respectively. These results indicated that the optical properties
confirmed the Raman results as presenting the structure changed with
applied bias voltage increased.
Abstract: Stress Corrosion Crack (SCC) in pipeline is a type of
environmentally assisted cracking (EAC), since its discovery in 1965
as a possible cause of failure in pipeline, SCC has caused, on
average, one of two failures per year in the U.S, According to the
NACE SCC DA a pipe line segment is considered susceptible to SCC
if all of the following factors are met: The operating stress exceeds
60% of specified minimum yield strength (SMYS), the operating
temperature exceeds 38°C, the segment is less than 32 km
downstream from a compressor station, the age of the pipeline is
greater than 10 years and the coating type is other than Fusion
Bonded Epoxy(FBE). In this paper as a practical experience in
NISOC, Direct Assessment (DA) Method is used for identification
SCC defect in unpiggable pipeline located downstream of
compressor station.
Abstract: The paper deals with current issues in research of
advanced methods to increase reliability of traditional timber
structural elements. It analyses the issue of strengthening of bent
timber beams, such as ceiling beams in old (historical) buildings with
additional concrete slab in combination with externally bonded fibre -
reinforced polymer. The paper describes experimental testing of
composite timber-concrete beam with FRP reinforcement and
compares results with FEM analysis.