Abstract: Food is widely packaged with plastic materials to
prevent microbial contamination and spoilage. Ionizing radiation is
widely used to sterilize the food-packaging materials. Sterilization by
γ-radiation causes degradation such as embrittlement, stiffening,
softening, discoloration, odour generation, and decrease in molecular
weight. Many antioxidants can prevent γ-degradation but most of
them are toxic. The migration of antioxidants to its environment
gives rise to major concerns in case of food packaging plastics. In
this attempt, we have aimed to utilize synergistic mixtures of
stabilizers which are approved for food-contact applications.
Ethylene-propylene-diene terpolymer has been melt-mixed with
hindered amine stabilizers (HAS), phenolic antioxidants and organophosphites
(hydroperoxide decomposer). Results were discussed by
comparing the stabilizing efficiency of mixtures with and without
phenol system. Among phenol containing systems where we mostly
observed discoloration due to the oxidation of hindered phenol, the
combination of secondary HAS, tertiary HAS, organo-phosphite and
hindered phenol exhibited improved stabilization efficiency than
single or binary additive systems. The mixture of secondary HAS and
tertiary HAS, has shown antagonistic effect of stabilization.
However, the combination of organo-phosphite with secondary HAS,
tertiary HAS and phenol antioxidants have been found to give
synergistic even at higher doses of Gamma-irradiation. The effects
have been explained through the interaction between the stabilizers.
After γ-irradiation, the consumption of oligomeric stabilizer
significantly depends on the components of stabilization mixture. The
effect of the organo-phosphite antioxidant on the overall stability has
been discussed.
Abstract: Liver disorders are one of the major problems of the
world. Despite its frequent occurrence, high morbidity and high
mortality, its medical management is currently inadequate. This study
was designed to evaluate the hepatoprotective effect of saponin
extract of the root of Garcinia kola on the integrity of the liver of
paracetamol induced wistar albino rats. Twenty five (25) male adult
wistar albino rats were divided into five (5) groups. Group I was the
Control group that received distilled water only, group II was the
negative control that received 2 g/kg of paracetamol on the 13th day,
and group III, IV and V were pre-treated with 100, 200 and
400mg/kg of the saponin extract before inducing the liver damage on
the 13th day with 2 g/kg of paracetamol. Twenty four (24) h after
administration, the rats were sacrificed and blood samples were
collected. The serum Alanine Transaminase (ALT), Aspartate
Transaminase (AST), Alkaline Phosphatase (ALP) activities,
Bilirubin and conjugated bilirubin, glucose and protein
concentrations were evaluated. The liver was fixed immediately in
Formalin and was processed and stained in Haematoxylin and Eosin
(H&E). Administration of saponin extract from the root of Garcinia
kola significantly decreased paracetamol induced elevated enzymes
in the test group. Also histological observations showed that saponin
extract of the root of Garcinia kola exhibited a significant liver
protection against the toxicant as evident by the cells trying to return
to normal. Saponin extract from the root of Garcinia kola indicated a
protection of structural integrity of the hepatocytic cell membrane
and regeneration of the damaged liver.
Abstract: Composite materials, due to their unique properties
such as high strength to weight ratio, corrosion resistance, and impact
resistance have huge potential as structural materials in automotive,
construction and transportation applications. However, these
properties often come at higher cost owing to complex design
methods, difficult manufacturing processes and raw material cost.
Traditionally, tapered laminated composite structures are
manufactured using autoclave manufacturing process by ply drop off
technique. Autoclave manufacturing though very powerful suffers
from high capital investment and higher energy consumption. As per
the current trends in composite manufacturing, Out of Autoclave
(OoA) processes are looked as emerging technologies for
manufacturing the structural composite components for aerospace
and defense applications. However, there is a need for improvement
among these processes to make them reliable and consistent. In this
paper, feasibility of using out of autoclave process to manufacture the
variable thickness cantilever beam is discussed. The minimum weight
design for the composite beam is obtained using constant stress beam
concept by tailoring the thickness of the beam. Ply drop off
techniques was used to fabricate the variable thickness beam from
glass/epoxy prepregs. Experiments were conducted to measure
bending stresses along the span of the cantilever beam at different
intervals by applying the concentrated load at the free end.
Experimental results showed that the stresses in the bean at different
intervals were constant. This proves the ability of OoA process to
manufacture the constant stress beam. Finite element model for the
constant stress beam was developed using commercial finite element
simulation software. It was observed that the simulation results
agreed very well with the experimental results and thus validated
design and manufacturing approach used.
Abstract: A capacity spectrum method (CSM), one of methodologies to evaluate seismic fragilities of building structures, has been long recognized as the most convenient method, even if it contains several limitations to predict the seismic response of structures of interest. This paper proposes the procedure to estimate seismic fragility curves using an incremental dynamic analysis (IDA) rather than the method adopting a CSM. To achieve the research purpose, this study compares the seismic fragility curves of a 5-story reinforced concrete (RC) moment frame obtained from both methods; an IDA method and aCSM. Both seismic fragility curves are similar in slight and moderate damage states whereas the fragility curve obtained from the IDA method presents less variation (or uncertainties) in extensive and complete damage states. This is due to the fact that the IDA method can properly capture the structural response beyond yielding rather than the CSM and can directly calculate higher mode effects. From these observations, the CSM could overestimate seismic vulnerabilities of the studied structure in extensive or complete damage states.
Abstract: In view of a possible application in optical data
storage devices, diffraction grating efficiency of an organic dye, Acid
Fuchsin doped in PMMA matrix was studied under excitation with
CW diode pumped Nd: YAG laser at 532 nm. The open aperture Zscan
of dye doped polymer displayed saturable absorption and the
closed aperture Z-scan of the samples exhibited negative
nonlinearity. The diffraction efficiency of the grating is the ratio of
the intensity of the first order diffracted power to the incident read
beam power. The dye doped polymer films were found to be good
media for recording. It is observed that the formation of gratings
strongly depend on the concentration of dye in the polymer film, the
intensity ratios of the writing beams and the angle between the
writing beams. It has been found that efficient writing can be made at
an angle of 20o and when the intensity ratio of the writing beams is
unity.
Abstract: The final energy use can be divided mainly in four sectors: commercial, industrial, residential, and transportation. The trend in final energy consumption by sector plays as a most straightforward way to provide a wide indication of progress for reducing energy consumption and associated environmental impacts by different end use sectors. The average share of end use energy for residential sector in the world was nearly 20% until 2011, in Germany a higher proportion is between 25% and 30%. However, it remains less studied than energy use in other three sectors as well its impacts on climate and environment. The reason for this involves a wide range of fields, including the diversity of residential construction like different housing building design and materials, living or energy using behavioral patterns, climatic condition and variation as well other social obstacles, market trend potential and financial support from government.
This paper presents an extensive and in-depth analysis of the manner by which projects researched and operated by authors in the fields of energy efficiency primarily from the perspectives of both technical potential and initiative energy saving consciousness in the residential sectors especially in social housing buildings.
Abstract: Replacement of plastics used in the food industry
seems to be a serious issue to overcome mainly the environmental
problems in recent years. This study investigates the hydrophilicity
and permeability properties of starch biopolymer which ethylene
vinyl alcohol (EVOH) (0-10%) and nanocrystalline cellulose (NCC)
(1-15%) were used to enhance its properties. Starch -EVOH
nanocomposites were prepared by casting method in different
formulations. NCC production by acid hydrolysis was confirmed by
scanning electron microscopy. Solubility, water vapor permeability,
water vapor transmission rate and moisture absorbance were
measured on each of the nanocomposites. The results were analyzed
by SAS software. The lowest moisture absorbance was measured in
pure starch nanocomposite containing 8% NCC. The lowest
permeability to water vapor belongs to starch nanocomposite
containing 8% NCC and the sample containing 7.8% EVOH and 13%
NCC. Also the lowest solubility was observed in the composite
contains the highest amount of EVOH. Applied Process resulted in
production of bio films which have good resistance to water vapor
permeability and solubility in water. The use of NCC and EVOH
leads to reduced moisture absorbance property of the biofilms.
Abstract: This paper identifies limitations of existing two e-
Governance services viz. railway ticket booking and passport service
in India. The comparison has been made as to how in the past these
two citizen services were operating manually and how these services
are taken online via e-Governance. Different e-Governance projects,
investment aspects, and role of corporate are discussed. For Indian
Railway online ticketing a comparison has been made between state
run booking website and popular private firm run booking websites.
For passport service, observations through personal visit to passport
center is described. Suggestions are made to improve these services
further to improve citizen service experiences.
Abstract: This paper presents optimization of makespan for ‘n’
jobs and ‘m’ machines flexible job shop scheduling problem with
sequence dependent setup time using genetic algorithm (GA)
approach. A restart scheme has also been applied to prevent the
premature convergence. Two case studies are taken into
consideration. Results are obtained by considering crossover
probability (pc = 0.85) and mutation probability (pm = 0.15). Five
simulation runs for each case study are taken and minimum value
among them is taken as optimal makespan. Results indicate that
optimal makespan can be achieved with more than one sequence of
jobs in a production order.
Abstract: Due to water shortage, application of saline water for
irrigation is an urgent in agriculture. In this study the effect of
calcium and potassium application as additive in saline root media for
reduce salinity adverse effects was investigated on tomato growth in
a hydroponic system with unequal distribution of salts in the root
media, which was divided in to two equal parts containing full
Johnson nutrient solution and 40 mMNaCl solution, alone or in
combination with KCl (6 mM), CaCl2 (4 mM), K+Ca (3+2 mM) or
half-strength Johnson nutrient solution. The root splits were
exchanged every 7 days. Results showed that addition of calcium,
calcium-potassium and nutrition elements equivalent to half the
concentration of Johnson formula to the saline-half of culture media
minimized the reduction in plant growth caused by NaCl, although
addition of potassium to culture media wasn’t effective. The greatest
concentration of sodium was observed at the shoot of treatments
which had smallest growth. According to the results of this study, in
case of dynamic and non-uniform distribution of salts in the root
media, by addition of additive to the saline solution, it would be
possible to use of saline water with no significant growth reduction.
Abstract: Developing young people’s employability is a key
policy issue for ensuring their successful transition to the labour
market and their access to career oriented employment. The youths of
today irrespective of their gender need to acquire the knowledge,
skills and attitudes that will enable them to create or find jobs as well
as cope with unpredictable labour market changes throughout their
working lives. In a study carried out to determine the influence of
gender on job-competencies requirements of chemical-based
industries and undergraduate-competencies acquisition by chemists
working in the industries, all chemistry graduates working in twenty
(20) chemical-based industries that were randomly selected from six
sectors of chemical-based industries in Lagos and Ogun States of
Nigeria were administered with Job-competencies required and
undergraduate-competencies acquired assessment questionnaire. The
data were analysed using means and independent sample t-test. The
findings revealed that the population of female chemists working in
chemical-based industries is low compared with the number of male
chemists; furthermore, job-competencies requirements are found not
to be gender biased while there is no significant difference in
undergraduate-competencies acquisition of male and female
chemists. This suggests that females should be given the same
opportunity of employment in chemical-based industries as their male
counterparts. The study also revealed the level of acquisition of
undergraduate competencies as related to the needs of chemicalbased
industries.
Abstract: In this paper, effect of marginal quality groundwater
on yield of cotton crop and soil salinity was studied. In this
connection, three irrigation treatments each with four replications
were applied. These treatments were i) use of canal water (T1), ii) use
of marginal quality groundwater from tubewell (T2), and iii)
conjunctive use by mixing with the ratio of 1:1 of canal water and
marginal quality tubewell water (T3).
Water was applied to the crop cultivated in Kharif season 2011; its
quantity has been measured using cut-throat flume. Total 11 watering
each of 50 mm depth have been applied from 20th April to 20th July,
2011. Further, irrigations were stopped due to monsoon rainfall up to
crop harvesting.
Maximum crop yield (seed cotton) was observed under T1 which
was 1,517 kg/ha followed by T3 (mixed canal and tubewell water)
having 1009 kg/ha and T2 i.e. marginal quality groundwater having
709 kg/ha. This concludes that crop yield in T2 and T3 in comparison
to T1was reduced by about 53 and 30% respectively.
It has been observed that yield of cotton crop is below potential
limit for three treatments due to unexpected rainfall at the time of full
flowering season; thus the yield was adversely affected.
However, salt deposition in soil profiles was not observed that is
due to leaching effect of heavy rainfall occurred during monsoon
season.
Abstract: Over the last few decades, oilfield service rolling
equipment has significantly increased in weight, primarily because of
emissions regulations, which require larger/heavier engines, larger
cooling systems, and emissions after-treatment systems, in some
cases, etc. Larger engines cause more vibration and shock loads,
leading to failure of electronics and control systems.
If the vibrating frequency of the engine matches the system
frequency, high resonance is observed on structural parts and mounts.
One such existing automated control equipment system comprising
wire rope mounts used for mounting computers was designed
approximately 12 years ago. This includes the use of an industrialgrade
computer to control the system operation. The original
computer had a smaller, lighter enclosure. After a few years, a newer
computer version was introduced, which was 10 lbm heavier. Some
failures of internal computer parts have been documented for cases in
which the old mounts were used. Because of the added weight, there
is a possibility of having the two brackets impact each other under
off-road conditions, which causes a high shock input to the computer
parts. This added failure mode requires validating the existing mount
design to suit the new heavy-weight computer.
This paper discusses the modal finite element method (FEM)
analysis and experimental modal analysis conducted to study the
effects of vibration on the wire rope mounts and the computer. The
existing mount was modelled in ANSYS software, and resultant
mode shapes and frequencies were obtained. The experimental modal
analysis was conducted, and actual frequency responses were
observed and recorded.
Results clearly revealed that at resonance frequency, the brackets
were colliding and potentially causing damage to computer parts. To
solve this issue, spring mounts of different stiffness were modeled in
ANSYS software, and the resonant frequency was determined.
Increasing the stiffness of the system increased the resonant
frequency zone away from the frequency window at which the engine
showed heavy vibrations or resonance. After multiple iterations in
ANSYS software, the stiffness of the spring mount was finalized,
which was again experimentally validated.
Abstract: Securing the confidential data transferred via wireless
network remains a challenging problem. It is paramount to ensure
that data are accessible only by the legitimate users rather than by the
attackers. One of the most serious threats to organization is jamming,
which disrupts the communication between any two pairs of nodes.
Therefore, designing an attack-defending scheme without any packet
loss in data transmission is an important challenge. In this paper,
Dependence based Malicious Route Defending DMRD Scheme has
been proposed in multi path routing environment to prevent jamming
attack. The key idea is to defend the malicious route to ensure
perspicuous transmission. This scheme develops a two layered
architecture and it operates in two different steps. In the first step,
possible routes are captured and their agent dependence values are
marked using triple agents. In the second step, the dependence values
are compared by performing comparator filtering to detect malicious
route as well as to identify a reliable route for secured data
transmission. By simulation studies, it is observed that the proposed
scheme significantly identifies malicious route by attaining lower
delay time and route discovery time; it also achieves higher
throughput.
Abstract: In this research, waterglass based aerogel powder was
prepared by sol–gel process and ambient pressure drying. Inspired by
limited dust releasing, aerogel powder was introduced to the PET
electrospinning solution in an attempt to create required bulk and
surface structure for the nanofibers to improve their hydrophobic and
insulation properties. The samples evaluation was carried out by
measuring density, porosity, contact angle, heat transfer, FTIR, BET,
and SEM. According to the results, porous silica aerogel powder was
fabricated with mean pore diameter of 24 nm and contact angle of
145.9º. The results indicated the usefulness of the aerogel powder
confined into nanofibers to control surface roughness for
manipulating superhydrophobic nanowebs with water contact angle
of 147º. It can be due to a multi-scale surface roughness which was
created by nanowebs structure itself and nanofibers surface
irregularity in presence of the aerogels while a layer of fluorocarbon
created low surface energy. The wettability of a solid substrate is an
important property that is controlled by both the chemical
composition and geometry of the surface. Also, a decreasing trend in
the heat transfer was observed from 22% for the nanofibers without
any aerogel powder to 8% for the nanofibers with 4% aerogel
powder. The development of thermal insulating materials has become
increasingly more important than ever in view of the fossil energy
depletion and global warming that call for more demanding energysaving
practices.
Abstract: Software Architecture is the basic structure of
software that states the development and advancement of a software
system. Software architecture is also considered as a significant tool
for the construction of high quality software systems. A clean design
leads to the control, value and beauty of software resulting in its
longer life while a bad design is the cause of architectural erosion
where a software evolution completely fails. This paper discusses the
occurrence of software architecture erosion and presents a set of
methods for the detection, declaration and prevention of architecture
erosion. The causes and symptoms of architecture erosion are
observed with the examples of prescriptive and descriptive
architectures and the practices used to stop this erosion are also
discussed by considering different types of software erosion and their
affects. Consequently finding and devising the most suitable
approach for fighting software architecture erosion and in some way
reducing its affect is evaluated and tested on different scenarios.
Abstract: This paper presents observations on the early
supervised internships in Psychology, currently called basic
internships in Brazil, and its importance in professional training. The
work is an experience report and focuses on the Professional training,
illustrated by the reality of a Brazilian institution, used as a case
study. It was developed from the authors' experience as academic
supervisors of this kind of practice throughout this undergraduate
course, combined with aspects investigated in the post-doctoral
research of one of them. Theoretical references on the subject and
related national legislation are analyzed, as well as reports of students
who experienced at least one semester of this type of practice,
articulated to the observations of the authors. The results demonstrate
the importance of the early supervised internships as a way of
creating opportunities for the students of a first contact with the
professional reality and the practice of psychologists in different
fields of insertion, preparing them for further experiments that require
more involvement in activities of training and practices in
Psychology.
Abstract: Rhodamine B (RB) is a toxic dye used extensively in
textile industry, which must be remediated before its drainage to
environment. In the present study, supported gold nanoparticles on
commercially available titania and zincite were successfully prepared
and then their activity on the photodegradation of RB under UV A
light irradiation were evaluated. The synthesized photocatalysts were
characterized by ICP, BET, XRD, and TEM. Kinetic results showed
that Au/TiO2 was an inferior photocatalyst to Au/ZnO. This
observation could be attributed to the strong reflection of UV
irradiation by gold nanoparticles over TiO2 support.
Abstract: Lead being a toxic heavy metal that mankind is
exposed to the highest levels of this metal from environmental
pollutants. A total of 180 Male scalp hair samples were collected
from different environments in Greater Cairo (GC), i.e. industrial,
heavy traffic and rural areas (60 samples from each) having different
activities during the period of, 1/5/2010 to 1/11/2012. Hair samples
were collected during five stages. Data proved that the concentration
of lead in male industrial areas of Cairo ranged between 6.2847 to
19.0432 μg/g, with mean value of 12.3288 μg/g. On the other hand,
lead content of hair samples of residential-traffic areas ranged
between 2.8634 to 16.3311 μg/g with mean value of 9.7552 μg/g.
While lead concentration on the hair of the male residents living in
rural area ranged between 1.0499-9.0402μg/g with mean value of
4.7327 μg/g. The Pb concentration in scalp hair of Cairo residents of
residential-traffic and rural traffic areas was observed to follow the
same pattern. The pattern was that of decrease concentration of
summer and its increase in winter. Then, there was a marked increase
in Pb concentration of summer 2012, and this increase was
significant. These were obviously seen for the residential-traffic and
rural areas residents. Pb pollution in residents of industrial areas
showed the same seasonal pattern, but there was marked to decrease
in Pb concentration of summer 2012, and this decrease was
significant. Lead pollution in residents of GC was serious. It is worth
noting that the atmosphere is still contaminated by lead despite a
decade of using unleaded gasoline. Strong seasonal variation in
higher Pb concentration on winter than in summer was found. Major
contributions to the pollution with Pb could include industry
emissions, motor vehicle emissions and long transported dust from
outside Cairo. More attention should be paid to the reduction of Pb
content of the urban aerosol and to the Pb pollution health.
Abstract: Now-a-days autonomous mobile robots have found
applications in diverse fields. An autonomous robot system must be
able to behave in an intelligent manner to deal with complex and
changing environment. This work proposes the performance of path
planning and navigation of autonomous mobile robot using
Gravitational Search Algorithm (GSA), Simulated Annealing (SA)
and Particle Swarm optimization (PSO) based intelligent controllers
in an unstructured environment. The approach not only finds a valid
collision free path but also optimal one. The main aim of the work is
to minimize the length of the path and duration of travel from a
starting point to a target while moving in an unknown environment
with obstacles without collision. Finally, a comparison is made
between the three controllers, it is found that the path length and time
duration made by the robot using GSA is better than SA and PSO
based controllers for the same work.