Abstract: In this study, the effects and interactions of reaction
time and capping agent assistance during sol-gel synthesis of
magnesium substituted hydroxyapatite nanopowder (MgHA) on
hydroxyapatite (HA) to β-tricalcium phosphate (β-TCP) ratio, Ca/P
ratio and mean crystallite size was examined experimentally as well
as through statistical analysis. MgHA nanopowders were synthesized
by sol-gel technique at room temperature using aqueous solution of
calcium nitrate tetrahydrate, magnesium nitrate hexahydrate and
potassium dihydrogen phosphate as starting materials. The reaction
time for sol-gel synthesis was varied between 15 to 60 minutes. Two
process routes were followed with and without addition of
triethanolamine (TEA) in the solutions. The elemental compositions
of as-synthesized powders were determined using X-ray fluorescence
(XRF) spectroscopy. The functional groups present in the assynthesized
MgHA nanopowders were established through Fourier
Transform Infrared Spectroscopy (FTIR). The amounts of phases
present, Ca/P ratio and mean crystallite sizes of MgHA nanopowders
were determined using X-ray diffraction (XRD). The HA content in
biphasic mixture of HA and β-TCP and Ca/P ratio in as-synthesized
MgHA nanopowders increased effectively with reaction time of sols
(p0.15, two way ANOVA). The MgHA nanopowders
synthesized with TEA assistance exhibited 14 nm lower crystallite
size (p
Abstract: This study evaluated the acute toxicity and tissue
distribution of intravenously administered gold nanoparticles
(AuNPs) in male rabbits. Rabbits were exposed to single dose of
AuNPs (300 μg/ kg). Toxic effects were assessed via general
behavior, hematological parameters, serum biochemical parameters,
and histopathological examination of various rabbits’ organs.
Inductively coupled plasma–mass spectrometry (ICP-MS) was used
to determine gold concentrations in tissue samples collected at
predetermined time intervals. After one week, AuNPs exerted no
obvious acute toxicity in rabbits. However, inflammatory reactions
were observed in liver, lungs and kidneys accompanied with mild
absolute neutrophilia and significant monocytosis. The highest gold
levels were found in the spleen and liver followed by lungs, and
kidneys. These results indicated that AuNPs could be distributed
extensively to various tissues in the body, but primarily in the spleen
and liver.
Abstract: In this paper, for an arbitrary multiplicative functional
f from the set of all upper triangular fuzzy matrices to the fuzzy
algebra, we prove that there exist a multiplicative functional F and a
functional G from the fuzzy algebra to the fuzzy algebra such that the
image of an upper triangular fuzzy matrix under f can be represented
as the product of all the images of its main diagonal elements under
F and other elements under G.
Abstract: The Haussmannization plan of Cairo in 1867 formed a
regular network of roundabout spaces, though deteriorated at present.
The method of identifying the spatial structure of roundabout Cairo
for conservation matches the voronoi diagram with the space syntax
through their geometrical property of spatial convexity. In this
initiative, the primary convex hull of first-order voronoi adopts the
integral and control measurements of space syntax on Cairo’s
roundabout generators. The functional essence of royal palaces
optimizes the roundabout structure in terms of spatial measurements
and the symbolic voronoi projection of 'Tahrir Roundabout' over the
Giza Nile and Pyramids. Some roundabouts of major public and
commercial landmarks surround the pole of 'Ezbekia Garden' with a
higher control than integral measurements, which filter the new
spatial structure from the adjacent traditional town. Nevertheless, the
least integral and control measures correspond to the voronoi
contents of pollutant workshops and the plateau of old Cairo Citadel
with the visual compensation of new royal landmarks on top.
Meanwhile, the extended suburbs of infinite voronoi polygons
arrange high control generators of chateaux housing in 'garden city'
environs. The point pattern of roundabouts determines the
geometrical characteristics of voronoi polygons. The measured
lengths of voronoi edges alternate between the zoned short range at
the new poles of Cairo and the distributed structure of longer range.
Nevertheless, the shortest range of generator-vertex geometry
concentrates at 'Ezbekia Garden' where the crossways of vast Cairo
intersect, which maximizes the variety of choice at different spatial
resolutions. However, the symbolic 'Hippodrome' which is the largest
public landmark forms exclusive geometrical measurements, while
structuring a most integrative roundabout to parallel the royal syntax.
Overview of the symbolic convex hull of voronoi with space syntax
interconnects Parisian Cairo with the spatial chronology of scattered
monuments to conceive one universal Cairo structure. Accordingly,
the approached methodology of 'voronoi-syntax' prospects the future
conservation of roundabout Cairo at the inferred city-level concept.
Abstract: Agricultural machinery industry plays an important
role in the industrial development especially the production industry
of the country. There has been continuing development responding to
the higher demand of the production. However, the problem in
agricultural machinery production still exists. Thus, the purpose of
this research is to investigate problems on fundamental factors of
industry based on the entrepreneurs’ point of view. The focus was on
the small and medium size industry receiving factory license type
number 0660 from the Department of Industrial Works. The
investigation was on the comparison between the management of the
small and medium size agricultural industry in 3 provinces in the
central region of Thailand. Population in this study consisted of 189
company managers or managing directors, of which 101 were from
the small size and 88 were from the medium size industry. The data
were analyzed to find percentage, arithmetic mean, and standard
deviation with independent sample T-test at the statistical
significance .05. The results showed that the small and medium size
agricultural machinery manufacturers in the central region of
Thailand reported high problems in every aspect. When compared the
problems on basic factors in running the business, it was found that
there was no statistically difference at .05 in managing of the small
and medium size agricultural machinery manufacturers. However,
there was a statistically significant difference between the small and
medium size agricultural machinery manufacturers on the aspect of
policy and services of the government. The problems reported by the
small and medium size agricultural machinery manufacturers were
the services on public tap water and the problem on politic and
stability of the country.
Abstract: The myocardium is composed of specialized muscle
which relies mainly on fatty acid and sugar metabolism and it is
widely contribute to the heart functioning. The changes of the cardiac
energy-producing system during heart failure have been proved using
autoradiography techniques. This study focused on evaluating sugar
and fatty acid metabolism in myocardium as cardiac energy getting
system using heart-accumulated radiopharmaceuticals. Two sets of
autoradiographs of heart cross sections of Lewis male rats were
analyzed and the time- accumulation curve obtained with use of the
MATLAB image processing software to evaluate fatty acid and sugar
metabolic functions.
Abstract: Over the past few decades, manufacturing has evolved
from a more labor-intensive set of mechanical processes to a
sophisticated set of information based technology processes. With the
existence of various advanced manufacturing technologies (AMTs),
more and more functions or jobs are performed by these machines
instead of human labour. This study was undertaken in order to
research the extent of AMTs adoption in manufacturing companies in
Kenya. In order to investigate a survey was conducted via
questionnaires that were sent to 183 selected AMT manufacturing
companies in Kenya. 92 companies responded positively. All the
surveyed companies were found to have a measure of investment in
at least two of the 14 types of AMTs investigated. In general the
company surveyed showed that the level of AMT adoption in Kenya
is very low with investments levels at a mean of 2.057 and
integration levels at a mean of 1.639 in a scale of 1-5.
Abstract: We present probabilistic multinomial Dirichlet
classification model for multidimensional data and Gaussian process
priors. Here, we have considered efficient computational method that
can be used to obtain the approximate posteriors for latent variables
and parameters needed to define the multiclass Gaussian process
classification model. We first investigated the process of inducing a
posterior distribution for various parameters and latent function by
using the variational Bayesian approximations and important sampling
method, and next we derived a predictive distribution of latent
function needed to classify new samples. The proposed model is
applied to classify the synthetic multivariate dataset in order to verify
the performance of our model. Experiment result shows that our model
is more accurate than the other approximation methods.
Abstract: Project Portfolio Management (PPM) is an essential
component of an organisation’s strategic procedures, which requires
attention of several factors to envisage a range of long-term outcomes
to support strategic project portfolio decisions. To evaluate overall
efficiency at the portfolio level, it is essential to identify the
functionality of specific projects as well as to aggregate those
findings in a mathematically meaningful manner that indicates the
strategic significance of the associated projects at a number of levels
of abstraction. PPM success is directly associated with the quality of
decisions made and poor judgment increases portfolio costs. Hence,
various Multi-Criteria Decision Making (MCDM) techniques have
been designed and employed to support the decision-making
functions. This paper reviews possible options to enhance the
decision-making outcomes in organisational portfolio management
processes using the Analytic Hierarchy Process (AHP) both from
academic and practical perspectives and will examine the usability,
certainty and quality of the technique. The results of the study will
also provide insight into the technical risk associated with current
decision-making model to underpin initiative tracking and strategic
portfolio management.
Abstract: The purpose of the study is to investigate the level of
intrinsic motivation of trainers after attending a Continuous
Professional Development Course (CPD) organized by Institute of
Teacher Training Malaysia titled, “Transformation of Teaching and
Learning the Fun Way”. This study employed a survey whereby 96
teacher trainers were given Situational Intrinsic Motivational Scale
(SIMS) Instruments. Confirmatory factor analysis was carried out to
get the validity of this instrument in local setting. Data were analyzed
with SPSS for descriptive statistic. Semi- structured interviews were
also administrated to collect qualitative data on participants’
experiences after participating in the two-day fun-filled program. The
findings showed that the participants’ level of intrinsic motivation
showed higher mean than the amotivation. The results revealed that
the intrinsic motivation mean is 19.0 followed by Identified
regulation with a mean of 17.4, external regulation 9.7 and
amotivation 6.9. The interview data also revealed that the participants
were motivated after attending this training program. It can be
concluded that this program, which was organized by Institute of
Teacher Training Malaysia, was able to enhance participants’ level of
motivation. Self-Determination Theory (SDT) as a multidimensional
approach to motivation was utilized. Therefore, teacher trainers may
have more success using the “The fun way approach” in conducting
training program in future.
Abstract: The power electronic components within Electric Vehicles (EV) need to operate in several important modes. Some modes directly influence safety, while others influence vehicle performance. Given the variety of functions and operational modes required of the power electronics, it needs to meet efficiency requirements to minimize power losses. Another challenge in the control and construction of such systems is the ability to support bidirectional power flow. This paper considers the construction, operation, and feasibility of available converters for electric vehicles with feasible configurations of electrical buses and loads. This paper describes logic and control signals for the converters for different operations conditions based on the efficiency and energy usage bases.
Abstract: In this paper, a robust fault detection and isolation
(FDI) scheme is developed to monitor a multivariable nonlinear
chemical process called the Chylla-Haase polymerization reactor,
when it is under the cascade PI control. The scheme employs a radial
basis function neural network (RBFNN) in an independent mode to
model the process dynamics, and using the weighted sum-squared
prediction error as the residual. The Recursive Orthogonal Least
Squares algorithm (ROLS) is employed to train the model to
overcome the training difficulty of the independent mode of the
network. Then, another RBFNN is used as a fault classifier to isolate
faults from different features involved in the residual vector. Several
actuator and sensor faults are simulated in a nonlinear simulation of
the reactor in Simulink. The scheme is used to detect and isolate the
faults on-line. The simulation results show the effectiveness of the
scheme even the process is subjected to disturbances and
uncertainties including significant changes in the monomer feed rate,
fouling factor, impurity factor, ambient temperature, and
measurement noise. The simulation results are presented to illustrate
the effectiveness and robustness of the proposed method.
Abstract: A model to predict the plastic zone size for material
under plane stress condition has been developed and verified
experimentally. The developed model is a function of crack size,
crack angle and material property (dislocation density). Simulation
and validation results show that the model developed show good
agreement with experimental results. Samples of low carbon steel
(0.035%C) with included surface crack angles of 45o, 50o, 60o, 70o
and 90o and crack depths of 2mm and 4mm were subjected to low
strain rate between 0.48 x 10-3 s-1 – 2.38 x 10-3 s-1. The mechanical
properties studied were ductility, tensile strength, modulus of
elasticity, yield strength, yield strain, stress at fracture and fracture
toughness. The experimental study shows that strain rate has no
appreciable effect on the size of plastic zone while crack depth and
crack angle plays an imperative role in determining the size of the
plastic zone of mild steel materials.
Abstract: The modelling of physical phenomena, such as the
earth’s free oscillations, the vibration of strings, the interaction of
atomic particles, or the steady state flow in a bar give rise to Sturm-
Liouville (SL) eigenvalue problems. The boundary applications of
some systems like the convection-diffusion equation, electromagnetic
and heat transfer problems requires the combination of Dirichlet and
Neumann boundary conditions. Hence, the incorporation of Robin
boundary condition in the analyses of Sturm-Liouville problem. This
paper deals with the computation of the eigenvalues and
eigenfunction of generalized Sturm-Liouville problems with Robin
boundary condition using the finite element method. Numerical
solution of classical Sturm–Liouville problem is presented. The
results show an agreement with the exact solution. High results
precision is achieved with higher number of elements.
Abstract: Strong anthropogenic impact has uncontrolled
consequences on the nature of the soil. Hence, up-to-date sustainable
methods of soil state improvement are essential. Investigators provide
the evidence that biochar can positively effects physical, chemical,
and biological soil properties and the abundance of mycorrhizal fungi
which are in the focus of this study. The main aim of the present
investigation is to demonstrate the effect of two types of plant growth
promoting bacteria (PGPB) inoculums along with the beech wood
biochar and mineral N additives on mycorrhizal colonization.
Experiment has been set up in laboratory conditions with containers
filled with arable soil from the protection zone of the main water
source “Brezova nad Svitavou”. Lactuca sativa (lettuce) has been
selected as a model plant. Based on the obtained data, it can be
concluded that mycorrhizal colonization increased as the result of
combined influence of biochar and PGPB inoculums amendment. In
addition, correlation analyses showed that the numbers of main
groups of cultivated bacteria were dependent on the degree of
mycorrhizal colonization.
Abstract: In this paper, we propose the variational EM inference
algorithm for the multi-class Gaussian process classification model
that can be used in the field of human behavior recognition. This
algorithm can drive simultaneously both a posterior distribution of a
latent function and estimators of hyper-parameters in a Gaussian
process classification model with multiclass. Our algorithm is based
on the Laplace approximation (LA) technique and variational EM
framework. This is performed in two steps: called expectation and
maximization steps. First, in the expectation step, using the Bayesian
formula and LA technique, we derive approximately the posterior
distribution of the latent function indicating the possibility that each
observation belongs to a certain class in the Gaussian process
classification model. Second, in the maximization step, using a derived
posterior distribution of latent function, we compute the maximum
likelihood estimator for hyper-parameters of a covariance matrix
necessary to define prior distribution for latent function. These two
steps iteratively repeat until a convergence condition satisfies.
Moreover, we apply the proposed algorithm with human action
classification problem using a public database, namely, the KTH
human action data set. Experimental results reveal that the proposed
algorithm shows good performance on this data set.
Abstract: The Com-Poisson (CMP) model is one of the most
popular discrete generalized linear models (GLMS) that handles
both equi-, over- and under-dispersed data. In longitudinal context,
an integer-valued autoregressive (INAR(1)) process that incorporates
covariate specification has been developed to model longitudinal
CMP counts. However, the joint likelihood CMP function is
difficult to specify and thus restricts the likelihood-based estimating
methodology. The joint generalized quasi-likelihood approach
(GQL-I) was instead considered but is rather computationally
intensive and may not even estimate the regression effects due
to a complex and frequently ill-conditioned covariance structure.
This paper proposes a new GQL approach for estimating the
regression parameters (GQL-III) that is based on a single score vector
representation. The performance of GQL-III is compared with GQL-I
and separate marginal GQLs (GQL-II) through some simulation
experiments and is proved to yield equally efficient estimates as
GQL-I and is far more computationally stable.
Abstract: The 1:1 cocrystal of 2-amino-4-chloro-6-
methylpyrimidine (2A4C6MP) with 4-methylbenzoic acid (4MBA)
(I) has been prepared by slow evaporation method in methanol,
which was crystallized in monoclinic C2/c space group, Z = 8, and a
= 28.431 (2) Å, b = 7.3098 (5) Å, c = 14.2622 (10) Å and β =
109.618 (3)°. The presence of unionized –COOH functional group in
cocrystal I was identified both by spectral methods (1H and 13C
NMR, FTIR) and X-ray diffraction structural analysis. The
2A4C6MP molecule interact with the carboxylic group of the
respective 4MBA molecule through N—H⋯O and O—H⋯N
hydrogen bonds, forming a cyclic hydrogen–bonded motif R2
2(8).
The crystal structure was stabilized by Npyrimidine—H⋯O=C and
C=O—H⋯Npyrimidine types hydrogen bonding interactions.
Theoretical investigations have been computed by HF and density
function (B3LYP) method with 6–311+G (d,p)basis set. The
vibrational frequencies together with 1H and 13C NMR chemical
shifts have been calculated on the fully optimized geometry of
cocrystal I. Theoretical calculations are in good agreement with the
experimental results. Solvent–free formation of this cocrystal I is
confirmed by powder X-ray diffraction analysis.
Abstract: It is very important for a developing nation to
developing their infrastructure on the prime priority because their
infrastructure particularly their roads and transportation functions as a
blood in the system. Almost 1.1 billion populations share the travel
and transportation industry in India. On the other hand, the Pakistan
transportation industry is also extensive and elevating about 170
million users of transportation. Indian and Pakistani specifically
within bus industry are well connected within and between the urban
and rural areas. The transportation industry is radically helping the
economic alleviation of both countries. Due to high economic
instability, unemployment and poverty rate both countries
governments are very serious and committed to help for boosting
their economy. They believe that any form of transportation
development would play a vital role in the development of land,
infrastructure which could indirectly support many other industries’
developments, such as tourism, freighting and shipping businesses,
just to mention a few. However, it seems that their previous
transportation planning in the due course has failed to meet the fast
growing demand. As with the span of time, both the countries are
looking forward to a long-term, and economical solutions, because
the demand is from time to time keep appreciating and reacting
according to other key economic drivers. Content analysis method
and case study approach is used in this paper and secondary data
from the bureau of statistic is used for case analysis. The paper
focused on the mobility concerns of the lower and middle-income
people in India and Pakistan. The paper is aimed to highlight the
weaknesses, opportunities and limitations resulting from low priority
industry for a government, which is making the either country's
public suffer. The paper has concluded that the main issue is
identified as the slow, inappropriate, and unfavorable decisions which
are not in favor of long-term country’s economic development and
public interest. The paper also recommends to future research
avenues for public and private transportation, which is continuously
failing to meet the public expectations.
Abstract: To maintain a healthy balanced loyalty, whether to art
or society, posits a debatable issue. The artist is always on the look
out for the potential tension between those two realms. Therefore,
one of the most painful dilemmas the artist finds is how to function in
a society without sacrificing the aesthetic values of his/her work. In
other words, the life-long awareness of failure which derives from the
concept of the artist as caught between unflattering social realities
and the need to invent genuine art forms becomes a fertilizing soil for
the artists to be tackled. Thus, within the framework of this dilemma,
the question of the responsibility of the artist and the relationship of
the art to politics will be illuminating. To a larger extent, however, in
drama, this dilemma is represented by the fictional characters of the
play. The present paper tackles the idea of the amorality of the artist in
selected plays by Tom Stoppard. However, Stoppard’s awareness of
his situation as a refugee has led him to keep at a distance from
politics. He tried hard to avoid any intervention into the realms of
political debate, especially in his earliest work. On the one hand, it is
not meant that he did not interest in politics as such, but rather he
preferred to question it than to create a fixed ideological position. On
the other hand, Stoppard’s refusal to intervene in politics is ascribed
to his feeling of gratitude to Britain where he settled. As a result,
Stoppard has frequently been criticized for a lack of political
engagement and also for not leaning too much for the left when he
does engage. His reaction to these public criticisms finds expression
in his self-conscious statements which defensively stressed the
artifice of his work. He, like Oscar Wilde thinks that the
responsibility of the artist is devoted to the realm of his/her art.
Consequently, his consciousness for the role of the artist is truly
reflected in his two plays, Artist Descending a Staircase (1972) and
Travesties (1974).