Abstract: Electrical resistivity is a fundamental parameter of metals or electrical conductors. Since resistivity is a function of temperature, in order to completely understand the behavior of metals, a temperature dependent theoretical model is needed. A model based on physics principles has recently been developed to obtain an equation that relates electrical resistivity to temperature. This equation is dependent upon a parameter associated with the electron travel time before being scattered, and a parameter that relates the energy of the atoms and their separation distance. Analysis of the energy parameter reveals that the equation is optimized if the proportionality term in the equation is not constant but varies over the temperature range. Additional analysis reveals that the theoretical equation can be used to determine the mean free path of conduction electrons, the number of defects in the atomic lattice, and the ‘equivalent’ charge associated with the metallic bonding of the atoms. All of this analysis provides validation for the theoretical model and provides insight into the behavior of metals where performance is affected by temperatures (e.g., integrated circuits and temperature sensors).
Abstract: This study extends research on the relationship
between marketing strategy and market segmentation by
investigating on market segments in the cement industry.
Competitive strength and rivals distance from the factory were used
as business environment. A three segment (positive, neutral or
indifferent and zero zones) were identified as strategic segments. For
each segment a marketing strategy (aggressive, defensive and
decline) were developed. This study employed data from cement
industry to fulfill two objectives, the first is to give a framework to
the segmentation of cement industry and the second is developing
marketing strategy with varying competitive strength. Fifty six
questionnaires containing close-and open-ended questions were
collected and analyzed. Results supported the theory that segments
tend to be more aggressive than defensive when competitive strength
increases. It is concluded that high strength segments follow total
market coverage, concentric diversification and frontal attack to their
competitors. With decreased competitive strength, Business tends to
follow multi-market strategy, product modification/improvement and
flank attack to direct competitors for this kind of segments. Segments
with weak competitive strength followed focus strategy and decline
strategy.
Abstract: Soil microbial activity is adversely affected by pollutants such as heavy metals, antibiotics and pesticides. Organic amendments including sewage sludge, municipal compost and vermicompost are recently used to improve soil structure and fertility. But, these materials contain heavy metals including Pb, Cd, Zn, Ni and Cu that are toxic to soil microorganisms and may lead to occurrence of more tolerant microbes. Among these, Pb is the most abundant and has more negative effect on soil microbial ecology. In this study, Pb levels of 0, 100, 200, 300, 400 and 500 mg Pb [as Pb(NO3)2] per kg soil were added to the pots containing 2 kg of a loamy soil and incubated for 6 months at 25°C with soil moisture of - 0.3 MPa. Dehydrogenase activity of soil as a measure of microbial activity was determined on 15, 30, 90 and 180 days after incubation. Triphenyl tetrazolium chloride (TTC) was used as an electron acceptor in this assay. PICTs (IC50 values) were calculated for each Pb level and incubation time. Soil microbial activity was decreased by increasing Pb level during 30 days of incubation but the induced tolerance appeared on day 90 and thereafter. During 90 to 180 days of incubation, the PICT was gradually developed by increasing Pb level up to 200 mg kg-1, but the rate of enhancement was steeper at higher concentrations.
Abstract: In molecular biology, microarray technology is widely and successfully utilized to efficiently measure gene activity. If working with less studied organisms, methods to design custom-made microarray probes are available. One design criterion is to select probes with minimal melting temperature variances thus ensuring similar hybridization properties. If the microarray application focuses on the investigation of metabolic pathways, it is not necessary to cover the whole genome. It is more efficient to cover each metabolic pathway with a limited number of genes. Firstly, an approach is presented which minimizes the overall melting temperature variance of selected probes for all genes of interest. Secondly, the approach is extended to include the additional constraints of covering all pathways with a limited number of genes while minimizing the overall variance. The new optimization problem is solved by a bottom-up programming approach which reduces the complexity to make it computationally feasible. The new method is exemplary applied for the selection of microarray probes in order to cover all fungal secondary metabolite gene clusters for Aspergillus terreus.
Abstract: The geometric errors in the manufacturing process can
be reduced by optimal positioning of the fixture elements in the
fixture to make the workpiece stiff. We propose a new fixture layout
optimization method N-3-2-1 for large metal sheets in this paper that
combines the genetic algorithm and finite element analysis. The
objective function in this method is to minimize the sum of the nodal
deflection normal to the surface of the workpiece. Two different
kinds of case studies are presented, and optimal position of the
fixturing element is obtained for different cases.
Abstract: Model-checking tools such as Symbolic Model Verifier
(SMV) and NuSMV are available for checking hardware designs.
These tools can automatically check the formal legitimacy of a
design. However, NuSMV is too low level for describing a complete
hardware design. It is therefore necessary to translate the system
definition, as designed in a language such as Verilog or VHDL, into
a language such as NuSMV for validation. In this paper, we present
a meta hardware description language, Melasy, that contains a code
generator for existing hardware description languages (HDLs) and
languages for model checking that solve this problem.
Abstract: In this paper we present modeling and simulation for
physical vapor deposition for metallic bipolar plates. In the models
we discuss the application of different models to simulate the
transport of chemical reactions of the gas species in the gas chamber.
The so called sputter process is an extremely sensitive process to
deposit thin layers to metallic plates. We have taken into account
lower order models to obtain first results with respect to the gas
fluxes and the kinetics in the chamber.
The model equations can be treated analytically in some
circumstances and complicated multi-dimensional models are solved
numerically with a software-package (UG unstructed grids, see [1]).
Because of multi-scaling and multi-physical behavior of the models,
we discuss adapted schemes to solve more accurate in the different
domains and scales. The results are discussed with physical
experiments to give a valid model for the assumed growth of thin
layers.
Abstract: Geometry optimizations of metal complexes of Salen(bis(Salicylidene)1,2-ethylenediamine) were carried out at HF and DFT methods employing Lanl2DZ basis set. In this work structural, energies, bond lengths and other physical properties between Mn2+,Cu2+ and Ni2+ ions coordinated by salen–type ligands are examined. All calculations were performed using Gaussian 98W program series. To investigate local aromaticities, NICS were calculated at all centers of rings. The higher the band gap indicating a higher global aromaticity. The possible binding energies have been evaluated. We have evaluated Frequencies and Zero-point energy with freq calculation. The NICS(Nucleous Independent Chemical Shift) Results show Ni(II) complexes are antiaromatic and aromaticites of Mn(II) complexes are larger than Cu(II) complexes. The energy Results show Cu(II) complexes are stability than Mn(II) and Ni(II) complexes.
Abstract: In this paper, the bond strength of thermal spray
coatings in high speed shafts has been studied. The metallurgical and
mechanical studies has been made on the coated samples and shaft
using optical microscopy, scanning electron microscopy (SEM).
Abstract: Laser Metal Deposition (LMD) is an additive manufacturing process with capabilities that include: producing new
part directly from 3 Dimensional Computer Aided Design (3D CAD)
model, building new part on the existing old component and repairing an existing high valued component parts that would have
been discarded in the past. With all these capabilities and its advantages over other additive manufacturing techniques, the
underlying physics of the LMD process is yet to be fully understood probably because of high interaction between the processing
parameters and studying many parameters at the same time makes it
further complex to understand. In this study, the effect of laser power
and powder flow rate on physical properties (deposition height and
deposition width), metallurgical property (microstructure) and
mechanical (microhardness) properties on laser deposited most
widely used aerospace alloy are studied. Also, because the Ti6Al4V
is very expensive, and LMD is capable of reducing buy-to-fly ratio
of aerospace parts, the material utilization efficiency is also studied.
Four sets of experiments were performed and repeated to establish repeatability using laser power of 1.8 kW and 3.0 kW, powder flow
rate of 2.88 g/min and 5.67 g/min, and keeping the gas flow rate and
scanning speed constant at 2 l/min and 0.005 m/s respectively. The
deposition height / width are found to increase with increase in laser
power and increase in powder flow rate. The material utilization is favoured by higher power while higher powder flow rate reduces
material utilization. The results are presented and fully discussed.
Abstract: The main objective of this research was to investigate
the biosorption capacity for biofilms of sulphate reducing bacteria
(SRB) to remove heavy metals, such as Zn, Pb and Cd from
rainwater using laboratory-scale reactors containing mixed support
media. Evidence showed that biosorption had contributed to removal
of heavy metals including Zn, Pb and Cd in presence of SRB and
SRB were also found in the aqueous samples from reactors.
However, the SRB and specific families (Desulfobacteriaceae and
Desulfovibrionaceae) were found mainly in the biomass samples
taken from all reactors at the end of the experiment. EDX-analysis
of reactor solids at end of experiment showed that heavy metals Zn,
Pb and Cd had also accumulated in these precipitates.
Abstract: Knowledge of factors, which influence stress and its
distribution, is of key importance to the successful production of
durable restorations. One of this is the marginal geometry. The
objective of this study was to evaluate, by finite element analysis
(FEA), the influence of different marginal designs on the stress
distribution in teeth prepared for cast metal crowns. Five margin
designs were taken into consideration: shoulderless, chamfer,
shoulder, sloped shoulder and shoulder with bevel. For each kind of
preparation three dimensional finite element analyses were initiated.
Maximal equivalent stresses were calculated and stress patterns were
represented in order to compare the marginal designs. Within the
limitation of this study, the shoulder and beveled shoulder margin
preparations of the teeth are preferred for cast metal crowns from
biomechanical point of view.
Abstract: Several different cements have been tested to evaluate
their potential to leach calcium, chromium and aluminum ions in soft
water environment. The research allows comparing some different
cements in order to the potential risk of water contamination. This
can be done only in the same environment. To reach the results in
reasonable short time intervals and to make heavy metals
measurements with high accuracy, demineralized water was used. In
this case the conditions of experiments are far away from the water
supply practice, but short time experiments and measurably high
concentrations of elements in the water solution are an important
advantage. Moreover leaching mechanisms can be recognized, our
experiments reported here refer to this kind of cements evaluation.
Abstract: The use of additions in cement in manufacturing,
mortar and concrete offers economic and ecological advantages. Cements with additions such as limestone, slag and natural
pouzzolana are produced in cement factories in Algeria. Several studies analyzed the effect of these additions on the physical and
mechanical properties as well as the durability of concrete. However,
few studies were conducted on the effect of local metakaolin on
mechanical properties and durability of concrete. The main purpose
of this paper is to analyze the performance of mortar and concrete with local metakaolin. The preparation of the metakaolin was carried
out by calcination of kaolin at a temperature of 850 °C for a period of 3 hours. The experimental results have shown that the rates of
substitutions of 10 and 15% metakaolin increases the compressive
strength and flexural strength at both early age and long term. The durability and the permeability were also improved by reducing the
coefficient of sorptivity.
Abstract: CIM is the standard formalism for modeling management
information developed by the Distributed Management Task
Force (DMTF) in the context of its WBEM proposal, designed to
provide a conceptual view of the managed environment. In this
paper, we propose the inclusion of formal knowledge representation
techniques, based on Description Logics (DLs) and the Web Ontology
Language (OWL), in CIM-based conceptual modeling, and then we
examine the benefits of such a decision. The proposal is specified
as a CIM metamodel level mapping to a highly expressive subset
of DLs capable of capturing all the semantics of the models. The
paper shows how the proposed mapping provides CIM diagrams with
precise semantics and can be used for automatic reasoning about the
management information models, as a design aid, by means of newgeneration
CASE tools, thanks to the use of state-of-the-art automatic
reasoning systems that support the proposed logic and use algorithms
that are sound and complete with respect to the semantics. Such a
CASE tool framework has been developed by the authors and its
architecture is also introduced. The proposed formalization is not
only useful at design time, but also at run time through the use of
rational autonomous agents, in response to a need recently recognized
by the DMTF.
Abstract: Magnesium alloys have gained increased attention in recent years in automotive, electronics, and medical industry. This because of magnesium alloys have better properties than aluminum alloys and steels in respects of their low density and high strength to weight ratio. However, the main problems of magnesium alloy welding are the crack formation and the appearance of porosity during the solidification. This paper proposes a unique technique to weld two thin sheets of AZ31B magnesium alloy using a paste containing Ag nanoparticles. The paste containing Ag nanoparticles of 5 nm in average diameter and an organic solvent was used to coat the surface of AZ31B thin sheet. The coated sheet was heated at 100 °C for 60 s to evaporate the solvent. The dried sheet was set as a lower AZ31B sheet on the jig, and then lap fillet welding was carried out by using a pulsed Nd:YAG laser in a closed box filled with argon gas. The characteristics of the microstructure and the corrosion behavior of the joints were analyzed by opticalmicroscopy (OM), energy dispersive spectrometry (EDS), electron probe micro-analyzer (EPMA), scanning electron microscopy (SEM), and immersion corrosion test. The experimental results show that the wrought AZ31B magnesium alloy can be joined successfully using Ag nanoparticles. Ag nanoparticles insert promote grain refinement, narrower the HAZ width and wider bond width compared to weld without and insert. Corrosion rate of welded AZ31B with Ag nanoparticles reduced up to 44 % compared to base metal. The improvement of corrosion resistance of welded AZ31B with Ag nanoparticles due to finer grains and large grain boundaries area which consist of high Al content. β-phase Mg17Al12 could serve as effective barrier and suppressed further propagation of corrosion. Furthermore, Ag distribution in fusion zone provide much more finer grains and may stabilize the magnesium solid solution making it less soluble or less anodic in aqueous
Abstract: The present work consecutively on synthesis and
characterization of composites, Al/Al alloy A 384.1 as matrix in
which the main ingredient as Al/Al-5% MgO alloy based metal
matrix composite. As practical implications the low cost processing
route for the fabrication of Al alloy A 384.1 and operational
difficulties of presently available manufacturing processes based in
liquid manipulation methods. As all new developments, complete
understanding of the influence of processing variables upon the final
quality of the product. And the composite is applied comprehensively
to the acquaintance for achieving superiority of information
concerning the specific heat measurement of a material through the
aid of thermographs. Products are evaluated concerning relative
particle size and mechanical behavior under tensile strength.
Furthermore, Taguchi technique was employed to examine the
experimental optimum results are achieved, owing to effectiveness of
this approach.
Abstract: This paper presents the development of an MODAPTS based cost estimating system to help designers in estimating the manufacturing cost of a assembly products which is belonged from the workers in working fields. Competitiveness of manufacturing cost is getting harder because of the development of Information and telecommunication, but also globalization. Therefore, the accuracy of the assembly cost estimation is getting important. DFA and MODAPTS is useful method for measuring the working hour. But these two methods are used just as a timetable. Therefore, in this paper, we suggest the process of measuring the working hours by MODAPTS which includes the working field-s accurate information. In addition, we adduce the estimation method of accuracy assembly cost with the real information. This research could be useful for designers that can estimate the assembly cost more accurately, and also effective for the companies that which are concerned to reduce the product cost.
Abstract: At present, increased concerns about global
environmental problems have magnified the importance of
sustainability management. To move towards sustainability,
companies need to look at everything from a holistic perspective in
order to understand the interconnections between economic growth
and environmental and social sustainability. This paper aims to gain
an understanding of key determinants that drive sustainability
management and barriers that hinder its development. It employs
semi-structured interviews with key informants, site observation and
documentation. The informants are production, marketing and
environmental managers of the leading wine producer, which aims to
become an Asia-s leader in wine & wine based products. It is found
that corporate image and top management leadership are the primary
factors influencing the adoption of sustainability management. Lack
of environmental knowledge and inefficient communication are
identified as barriers.
Abstract: Zeolite A and MCM-41 have extensive applications in basic science, petrochemical science, energy conservation/storage, medicine, chemical sensor, air purification, environmentally benign composite structure and waste remediation. However, the use of zeolite A and MCM-41 in these areas, especially environmental remediation, are restricted due to prohibitive production cost. Efficient recycling of and resource recovery from coal fly ash has been a major topic of current international research interest, aimed at achieving sustainable development of human society from the viewpoints of energy, economy, and environmental strategy. This project reported an original, novel, green and fast methods to produce nano-porous zeolite A and MCM-41 materials from coal fly ash. For zeolite A, this novel production method allows a reduction by half of the total production time while maintaining a high degree of crystallinity of zeolite A which exists in a narrower particle size distribution. For MCM-41, this remarkably green approach, being an environmentally friendly process and reducing generation of toxic waste, can produce pure and long-range ordered MCM-41 materials from coal fly ash. This approach took 24 h at 25 oC to produce 9 g of MCM-41 materials from 30 g of the coal fly ash, which is the shortest time and lowest reaction temperature required to produce pure and ordered MCM-41 materials (having the largest internal surface area) compared to the values reported in the literature. Performance evaluation of the produced zeolite A and MCM-41 materials in wastewater treatment and air pollution control were reported. The residual fly ash was also converted to zeolite Na-P1 which showed good performance in removal of multi-metal ions in wastewater. In wastewater treatment, compared to commercial-grade zeolite A, adsorbents produced from coal fly ash were effective in removing multi heavy metal ions in water and could be an alternative material for treatment of wastewater. In methane emission abatement, the zeolite A (produced from coal fly ash) achieved similar methane removal efficiency compared to the zeolite A prepared from pure chemicals. This report provides the guidance for production of zeolite A and MCM-41 from coal fly ash by a cost-effective approach which opens potential applications of these materials in environmental industry. Finally, environmental and economic aspects of production of zeolite A and MCM-41 from coal fly ash were discussed.