Abstract: The mesoporous MoO3/γ-Al2O3 catalyst was prepared
by incipient wetness impregnation method aiming to investigate the
effect of drying method and molybdenum content on the catalyst
property and performance towards the oxidation of benzothiophene
(BT), dibenzothiophene (DBT) and 4,6-dimethyle dibenzothiophene
(4,6-DMDBT) with H2O2 for deep oxidative desulfurization of diesel
fuel. The catalyst was characterized by XRD, BET, BJH and SEM
method. The catalyst with 10wt.% and 15wt.% Mo content represent
same optimum performance for DBT and 4,6-DMDBT removal, but
a catalyst with 10wt.% Mo has higher efficiency than 15wt.% Mo for
BT conversion. The SEM images show that use of rotary evaporator
in drying step reaches a more homogenous impregnation. The
oxidation reactivity of different sulfur compounds was studied which
followed the order of DBT>4,6-DMDBT>>BT.
Abstract: E-learning is not restricted to the use of new technologies for the online content, but also induces the adoption of new approaches to improve the quality of education. This quality depends on the ability of these approaches (technical and pedagogical) to provide an adaptive learning environment. Thus, the environment should include features that convey intentions and meeting the educational needs of learners by providing a customized learning path to acquiring a competency concerned In our proposal, we believe that an individualized learning path requires knowledge of the learner. Therefore, it must pass through a personalization of diagnosis to identify precisely the competency gaps to fill, and reduce the cognitive load To personalize the diagnosis and pertinently measure the competency gap, we suggest implementing the formative assessment in the e-learning environment and we propose the introduction of a pre-regulation process in the area of formative assessment, involving its individualization and implementation in e-learning.
Abstract: In this paper, a new pseudo affine projection (AP)
algorithm based on Gauss-Seidel (GS) iterations is proposed for
acoustic echo cancellation (AEC). It is shown that the algorithm is
robust against near-end signal variations (including double-talk).
Abstract: We present the results of a case study aiming to assess the reflection of the tourism community in the Web and its usability to propose new ways to communicate visually. The wealth of information contained in the Web and the clear facilities to communicate personals points of view makes of the social web a new space of exploration. In this way, social web allow the sharing of information between communities with similar interests. However, the tourism community remains unexplored as is the case of the information covered in travel stories. Along the Web, we find multiples sites allowing the users to communicate their experiences and personal points of view of a particular place of the world. This cultural heritage is found in multiple documents, usually very little supplemented with photos, so they are difficult to explore due to the lack of visual information. This paper explores the possibility of analyzing travel stories to display them visually on maps and generate new knowledge such as patterns of travel routes. This way, travel narratives published in electronic formats can be very important especially to the tourism community because of the great amount of knowledge that can be extracted. Our approach is based on the use of a Geoparsing Web Service to extract geographic coordinates from travel narratives in order to draw the geo-positions and link the documents into a map image.
Abstract: Two novel hydrodesulfurization (HDS) catalysts:
FeN4/C and FeN2/C, were prepared using an impregnation-pyrolysis
method. The two materials were investigated as catalysts for
hydrodesulfurization (HDS) and hydrodearomitization (HDA) of
model compounds. The turnover frequency of the two FeN catalysts
is comparable to (FeN4/C) or even higher (FeN2/C) than that of
MoNi/Al2O3. The FeN4/C catalyst also exhibited catalytic activity
toward HDA.
Abstract: The importance for manipulating an incorporated
scaffold and directing cell behaviors is well appreciated for tissue
engineering. Here, we developed newly nano-topographic oxidized
silicon nanosponges capable of being various chemical modifications
to provide much insight into the fundamental biology of how cells
interact with their surrounding environment in vitro. A wet etching
technique is exerted to allow us fabricated the silicon nanosponges in a
high-throughput manner. Furthermore, various organo-silane
chemicals enabled self-assembled on the surfaces by vapor deposition.
We have found that Chinese hamster ovary (CHO) cells displayed
certain distinguishable morphogenesis, adherent responses, and
biochemical properties while cultured on these chemical modified
nano-topographic structures in compared with the planar oxidized
silicon counterparts, indicating that cell behaviors can be influenced
by certain physical characteristic derived from nano-topography in
addition to the hydrophobicity of contact surfaces crucial for cell
adhesion and spreading. Of particular, there were predominant
nano-actin punches and slender protrusions formed while cells were
cultured on the nano-topographic structures. This study shed potential
applications of these nano-topographic biomaterials for controlling
cell development in tissue engineering or basic cell biology research.
Abstract: Determination of wellbore problems during a
production/injection process might be evaluated thorough
temperature log analysis. Other applications of this kind of log
analysis may also include evaluation of fluid distribution analysis
along the wellbore and identification of anomalies encountered
during production/injection process. While the accuracy of such
prediction is paramount, the common method of determination of a
wellbore temperature log includes use of steady-state energy balance
equations, which hardly describe the real conditions as observed in
typical oil and gas flowing wells during production operation; and
thus increase level of uncertainties. In this study, a practical method
has been proposed through development of a simplified semianalytical
model to apply for predicting temperature profile along the
wellbore. The developed model includes an overall heat transfer
coefficient accounting all modes of heat transferring mechanism,
which has been focused on the prediction of a temperature profile as
a function of depth for the injection/production wells. The model has
been validated with the results obtained from numerical simulation.
Abstract: The present paper concerns with the influence of fiber
packing on the transverse plastic properties of metal matrix
composites. A micromechanical modeling procedure is used to
predict the effective mechanical properties of composite materials at
large tensile and compressive deformations. Microstructure is
represented by a repeating unit cell (RUC). Two fiber arrays are
considered including ideal square fiber packing and random fiber
packing defined by random sequential algorithm. The
micromechanical modeling procedure is implemented for
graphite/aluminum metal matrix composite in which the
reinforcement behaves as elastic, isotropic solids and the matrix is
modeled as an isotropic elastic-plastic solid following the von Mises
criterion with isotropic hardening and the Ramberg-Osgood
relationship between equivalent true stress and logarithmic strain.
The deformation is increased to a considerable value to evaluate both
elastic and plastic behaviors of metal matrix composites. The yields
strength and true elastic-plastic stress are determined for
graphite/aluminum composites.
Abstract: In this study, synthesis of biomemitic patterned nano
hydroxyapatite-starch biocomposites using different concentration of
starch to evaluate effect of polymer alteration on biocomposites
structural properties has been reported. Formation of hydroxyapatite
nano particles was confirmed by X-ray diffraction (XRD) and Fourier
transform infrared spectroscopy (FT-IR). Size and morphology of the
samples were characterized using scanning and transmission electron
microscopy (SEM and TEM). It seems that by increasing starch
content, the more active site of polymer (oxygen atoms) can be
provided for interaction with Ca2+ followed by phosphate and
hydroxyl group.
Abstract: Post cracking behavior and load –bearing capacity of
the steel fiber reinforced high-strength concrete (SFRHSC) are
dependent on the number of fibers are crossing the weakest crack
(bridged the crack) and their orientation to the crack surface. Filling
the mould by SFRHSC, fibers are moving and rotating with the
concrete matrix flow till the motion stops in each internal point of the
concrete body. Filling the same mould from the different ends
SFRHSC samples with the different internal structures (and different
strength) can be obtained. Numerical flow simulations (using Newton
and Bingham flow models) were realized, as well as single fiber
planar motion and rotation numerical and experimental investigation
(in viscous flow) was performed. X-ray pictures for prismatic
samples were obtained and internal fiber positions and orientations
were analyzed. Similarly fiber positions and orientations in cracked
cross-section were recognized and were compared with numerically
simulated. Structural SFRHSC fracture model was created based on
single fiber pull-out laws, which were determined experimentally.
Model predictions were validated by 15x15x60cm prisms 4 point
bending tests.
Abstract: Electrochemical-oxidation of Reactive Black-5 (RB- 5) was conducted for degradation using DSA type Ti/RuO2-SnO2- Sb2O5 electrode. In the study, for electro-oxidation, electrode was indigenously fabricated in laboratory using titanium as substrate. This substrate was coated using different metal oxides RuO2, Sb2O5 and SnO2 by thermal decomposition method. Laboratory scale batch reactor was used for degradation and decolorization studies at pH 2, 7 and 11. Current density (50mA/cm2) and distance between electrodes (8mm) were kept constant for all experiments. Under identical conditions, removal of color, COD and TOC at initial pH 2 was 99.40%, 55% and 37% respectively for initial concentration of 100 mg/L RB-5. Surface morphology and composition of the fabricated electrode coatings were characterized using scanning electron microscopy (SEM) and energy dispersive X-ray spectroscopy (EDX) respectively. Coating microstructure was analyzed by X-ray diffraction (XRD). Results of this study further revealed that almost 90% of oxidation occurred within 5-10 minutes.
Abstract: The effect of notch depth on the elastic new strainconcentration
factor (SNCF) of rectangular bars with single edge Unotch
under combined loading is studied here. The finite element
method (FEM) and super position technique are used in the current
study. This new SNCF under combined loading of static tension and
pure bending has been defined under triaxial stress state. The
employed specimens have constant gross thickness of 16.7 mm and
net section thickness varied to give net-to-gross thickness ratio ho/Ho
from 0.2 to 0.95. The results indicated that the elastic SNCF for
combined loading increases with increasing notch depth up to ho/Ho =
0.7 and sharply decreases with increasing notch depth. It is also
indicated that the elastic SNCF of combined loading is greater than
that of pure bending and less than that of the static tension for 0.2 ≤
ho/Ho ≤ 0.7. However, the elastic SNCF of combined loading is the
elastic SNCF for static tension and less than that of pure bending for
shallow notches (i.e. 0.8 ≤ ho/Ho ≤ 0.95).
Abstract: The main aim of this paper is to develop and calibrate
an econometric model for modeling prices of long term electricity
futures contracts. The calibration of our model is performed on data
from EEX AG allowing us to capture the specific features of German
electricity market. The data sample contains several structural breaks
which have to be taken into account for modeling. We model the data
with an ARIMAX model which reveals high correlation between the
price of electricity futures contracts and prices of LT futures
contracts of fuels (namely coal, natural gas and crude oil). Besides
this, also a share price index of representative electricity companies
traded on Xetra, spread between 10Y and 1Y German bonds and
exchange rate between EUR and USD appeared to have significant
explanatory power over these futures contracts on EEX.
Abstract: We numerically study the three-dimensional
magnetohydrodynamics (MHD) stability of oscillatory natural
convection flow in a rectangular cavity, with free top surface, filled
with a liquid metal, having an aspect ratio equal to A=L/H=5, and
subjected to a transversal temperature gradient and a uniform
magnetic field oriented in x and z directions. The finite volume
method was used in order to solve the equations of continuity,
momentum, energy, and potential. The stability diagram obtained in
this study highlights the dependence of the critical value of the
Grashof number Grcrit , with the increase of the Hartmann number
Ha for two orientations of the magnetic field. This study confirms
the possibility of stabilization of a liquid metal flow in natural
convection by application of a magnetic field and shows that the
flow stability is more important when the direction of magnetic field
is longitudinal than when the direction is transversal.
Abstract: Food and fibre production in arid and semi-arid regions has emerged as one of the major challenges for various socio-economic and political reasons such as the food security and self-sufficiency. Productive use of the renewable water resources has risen on top ofthe decision-making agenda. For this reason, efficient operation and maintenance of modern irrigation and drainage schemes become part and parcel and indispensible reality in agricultural policy making arena. The aim of this paper is to investigate the complexity of operating and maintaining such schemes, mainly focussing on challenges which enhance and opportunities that impedsustainable food and fibre production. The methodology involved using secondary data complemented byroutine observations and stakeholders views on issues that influence the O&M in the Dez command area. The SPSS program was used as an analytical framework for data analysis and interpretation.Results indicate poor application efficiency in most croplands, much of which is attributed to deficient operation of conveyance and distribution canals. These in turn, are reportedly linked to inadequate maintenance of the pumping stations and hydraulic structures like turnouts,flumes and other control systems particularly in the secondary and tertiary canals. Results show that the aforementioned deficiencies have been the major impediment to establishing regular flow toward the farm gates which subsequently undermine application efficiency and tillage operationsat farm level. Results further show that accumulative impact of such deficiencies has been the major causes of poorcrop yield and quality that deem production system in these croplands uneconomic. Results further show that the present state might undermine the sustainability of agricultural system in the command area. The overall conclusion being that present water management is unlikely to be responsive to challenges that the sector faces. And in the absence of coherent measures to shift the status quo situation in favour of more productive resource use, it would be hard to fulfil the objectives of the National Economic and Socio-cultural Development Plans.
Abstract: This paper proposes a way to track persons by making use of multiple non-overlapping cameras. Tracking persons on multiple non-overlapping cameras enables data communication among cameras through the network connection between a camera and a computer, while at the same time transferring human feature data captured by a camera to another camera that is connected via the network. To track persons with a camera and send the tracking data to another camera, the proposed system uses a hierarchical human model that comprises a head, a torso, and legs. The feature data of the person being modeled are transferred to the server, after which the server sends the feature data of the human model to the cameras connected over the network. This enables a camera that captures a person's movement entering its vision to keep tracking the recognized person with the use of the feature data transferred from the server.
Abstract: The development and application of wind power for
renewable energy has attracted growing interest in recent years. Renewable energy sources are attracting much alteration as they can
reduce both environmental damage and dependence on fossil fuels. With the growing need for sustainable energy supplies, a case is made
for decentralized, stand-alone power supplies (SAPS) as an alternative to power grids. In the era which traditional petroleum energy resource
decreasing and the green house affect significant increasing, the development and usage of regenerative resources is inevitable. Due to the contribution of the pioneers, the development of regenerative resources already has a remarkable achievement; however, in the view of economy and quantity, it is still a long road for regenerative energy
to replace traditional petroleum energy. In our prospective, in stead of
investigate larger regenerative energy equipment, it is much wiser to
think about the blind side and breakthrough of the current technique.
Abstract: Design of Converter transformer insulation is a major
challenge. The insulation of these transformers is stressed by both
AC and DC voltages. Particle contamination is one of the major
problems in insulation structures, as they generate partial discharges
leading it to major failure of insulation. Similarly corona discharges
occur in transformer insulation. This partial discharge due to particle
movement / corona formation in insulation structure under different
voltage wave shapes, are different. In the present study, UHF
technique is adopted to understand the discharge activity and could
be realized that the characteristics of UHF signal generated under
low and high fields are different. In the case of corona generated
signal, the frequency content of the UHF sensor output lies in the
range 0.3-1.2 GHz and is not much varied except for its increase in
magnitude of discharge with the increase in applied voltage. It is
realized that the current signal injected due to partial
discharges/corona is about 4ns duration measured for first one half
cycle. Wavelet technique is adopted in the present study. It allows
one to identify the frequency content present in the signal at different
instant of time. The STD-MRA analysis helps one to identify the
frequency band in which the energy content of the UHF signal is
maximum.
Abstract: Modern building automation needs to deal with very
different types of demands, depending on the use of a building and the
persons acting in it. To meet the requirements of situation awareness
in modern building automation, scenario recognition becomes more
and more important in order to detect sequences of events and to react
to them properly. We present two concepts of scenario recognition
and their implementation, one based on predefined templates and the
other applying an unsupervised learning algorithm using statistical
methods. Implemented applications will be described and their advantages
and disadvantages will be outlined.
Abstract: In competitive electricity markets all over the world, an adoption of suitable transmission pricing model is a problem as transmission segment still operates as a monopoly. Transmission pricing is an important tool to promote investment for various transmission services in order to provide economic, secure and reliable electricity to bulk and retail customers. The nodal pricing based on SRMC (Short Run Marginal Cost) is found extremely useful by researchers for sending correct economic signals. The marginal prices must be determined as a part of solution to optimization problem i.e. to maximize the social welfare. The need to maximize the social welfare subject to number of system operational constraints is a major challenge from computation and societal point of views. The purpose of this paper is to present a nodal transmission pricing model based on SRMC by developing new mathematical expressions of real and reactive power marginal prices using GA-Fuzzy based optimal power flow framework. The impacts of selecting different social welfare functions on power marginal prices are analyzed and verified with results reported in literature. Network revenues for two different power systems are determined using expressions derived for real and reactive power marginal prices in this paper.