Development of Fen4/C And Fen2/C Catalysts for Hydrodesulfurization and Hydrodearomitization of Model Compounds of Heavy Oil
Two novel hydrodesulfurization (HDS) catalysts:
FeN4/C and FeN2/C, were prepared using an impregnation-pyrolysis
method. The two materials were investigated as catalysts for
hydrodesulfurization (HDS) and hydrodearomitization (HDA) of
model compounds. The turnover frequency of the two FeN catalysts
is comparable to (FeN4/C) or even higher (FeN2/C) than that of
MoNi/Al2O3. The FeN4/C catalyst also exhibited catalytic activity
toward HDA.
[1] K Sakanishi, H. Taniguchi, H. Hasuo, I. Mochida, "Iron-based catalysts
supported on carbon nanoparticles of hollow structure for coal
liquefaction," Ind. Eng. Chem. Res., vol. 36, no. 2, pp. 306-309, Feb.
1997.
[2] G.T. Hager, X.X. Bi, P.C. Eklund, E.N. Givens, F.J. Derbyshire,
"Relative activity of nanoscale iron oxide, iron carbide, and iron sulfide
catalyst precursors for the liquefaction of a subbituminous coal," Energy
& Fuels, vol. 8, no. 1, pp. 88-93, Jan. 1994.
[3] H. Matsuhashi, K. Asari, K. Arata, "Catalytic activities of calcined iron
sulfates for hydrocracking of model compounds of coal," Energy &
Fuel, vol. 15, no. 6, pp. 1523-1527, Nov. 2001.
[4] P. D. Clark, M. J. Kirk, "Studies on the upgrading of bituminous oils
with water and transition metal catalysts," Energy & Fuel, vol. 8, no. 2,
pp. 380-387, Mar. 1994.
[5] C. Ovalles, E. Filgueiras, A. Alfredo, C.E. Scott, F. Gongalez-Gimenez,
B.P. Embaid, "Use of a dispersed iron catalyst for upgrading extra-heavy
crude oil using methane as source of hydrogen," Fuel, vol. 82, no. 8, pp.
887-892, May 2003.
[6] M Lefevre, E. Proietti, F. Joauen, J-P Dodelet, "Iron-Based Catalysts
with Improved Oxygen Reduction Activity in Polymer Electrolyte Fuel
Cells, " Science, vol. 324, no. 5923, pp. 71-74, Apr. 2009.
[7] CWB Bezerra, L Zhang, K Lee, H Liu, ALB Marques, EP Marques, H
Wang, J Zhang, "A review of Fe-N/C and Co-N/C catalysts for the
oxygen reduction reaction, " Electrochim Acta, vol. 53, no. 15, pp.
4937-4951, June 2008.
[8] F. Zhao, F. Harnisch, U. Schroder, F. Scholz, P. Bogdanoff, I.
Herrmann, "Application of pyrolysed iron(II) phthalocyanine and
CoTMPP based oxygen reduction catalysts as cathode materials in
microbial fuel cells, " Electrochem. Commun., vol. 7, no. 12, pp. 1405-
1410, Dec. 2005.
[9] L. Ding, Y. Zheng, H. Yang, R. Parviz, "LCO hydrotreating with Mo-Ni
and W-Ni supported on nano- and micro-sized zeolite beta," Appl. Catal.
A; General, vol. 353, no. 1, pp. 17-23, Jan. 2009.
[10] G. Lalande, G. Faubert, R. Cote, D. Guay, JP Dodelet, LT
Wneg, P Bertrand, "Catalytic activity and stability of
heat-treated iron phthalocyanines for the electroreduction
of oxygen in polymer electrolyte fuel cells," J. Power
Sources, vol. 61, no. 1-2, pp. 227-237, July-Aug. 1996.
[1] K Sakanishi, H. Taniguchi, H. Hasuo, I. Mochida, "Iron-based catalysts
supported on carbon nanoparticles of hollow structure for coal
liquefaction," Ind. Eng. Chem. Res., vol. 36, no. 2, pp. 306-309, Feb.
1997.
[2] G.T. Hager, X.X. Bi, P.C. Eklund, E.N. Givens, F.J. Derbyshire,
"Relative activity of nanoscale iron oxide, iron carbide, and iron sulfide
catalyst precursors for the liquefaction of a subbituminous coal," Energy
& Fuels, vol. 8, no. 1, pp. 88-93, Jan. 1994.
[3] H. Matsuhashi, K. Asari, K. Arata, "Catalytic activities of calcined iron
sulfates for hydrocracking of model compounds of coal," Energy &
Fuel, vol. 15, no. 6, pp. 1523-1527, Nov. 2001.
[4] P. D. Clark, M. J. Kirk, "Studies on the upgrading of bituminous oils
with water and transition metal catalysts," Energy & Fuel, vol. 8, no. 2,
pp. 380-387, Mar. 1994.
[5] C. Ovalles, E. Filgueiras, A. Alfredo, C.E. Scott, F. Gongalez-Gimenez,
B.P. Embaid, "Use of a dispersed iron catalyst for upgrading extra-heavy
crude oil using methane as source of hydrogen," Fuel, vol. 82, no. 8, pp.
887-892, May 2003.
[6] M Lefevre, E. Proietti, F. Joauen, J-P Dodelet, "Iron-Based Catalysts
with Improved Oxygen Reduction Activity in Polymer Electrolyte Fuel
Cells, " Science, vol. 324, no. 5923, pp. 71-74, Apr. 2009.
[7] CWB Bezerra, L Zhang, K Lee, H Liu, ALB Marques, EP Marques, H
Wang, J Zhang, "A review of Fe-N/C and Co-N/C catalysts for the
oxygen reduction reaction, " Electrochim Acta, vol. 53, no. 15, pp.
4937-4951, June 2008.
[8] F. Zhao, F. Harnisch, U. Schroder, F. Scholz, P. Bogdanoff, I.
Herrmann, "Application of pyrolysed iron(II) phthalocyanine and
CoTMPP based oxygen reduction catalysts as cathode materials in
microbial fuel cells, " Electrochem. Commun., vol. 7, no. 12, pp. 1405-
1410, Dec. 2005.
[9] L. Ding, Y. Zheng, H. Yang, R. Parviz, "LCO hydrotreating with Mo-Ni
and W-Ni supported on nano- and micro-sized zeolite beta," Appl. Catal.
A; General, vol. 353, no. 1, pp. 17-23, Jan. 2009.
[10] G. Lalande, G. Faubert, R. Cote, D. Guay, JP Dodelet, LT
Wneg, P Bertrand, "Catalytic activity and stability of
heat-treated iron phthalocyanines for the electroreduction
of oxygen in polymer electrolyte fuel cells," J. Power
Sources, vol. 61, no. 1-2, pp. 227-237, July-Aug. 1996.
@article{"International Journal of Chemical, Materials and Biomolecular Sciences:57372", author = "Chaojie Song and Lianhui Ding and Craig Fairbridge and Hansan Liu and Rob Hui and Jiujun Zhang", title = "Development of Fen4/C And Fen2/C Catalysts for Hydrodesulfurization and Hydrodearomitization of Model Compounds of Heavy Oil", abstract = "Two novel hydrodesulfurization (HDS) catalysts:
FeN4/C and FeN2/C, were prepared using an impregnation-pyrolysis
method. The two materials were investigated as catalysts for
hydrodesulfurization (HDS) and hydrodearomitization (HDA) of
model compounds. The turnover frequency of the two FeN catalysts
is comparable to (FeN4/C) or even higher (FeN2/C) than that of
MoNi/Al2O3. The FeN4/C catalyst also exhibited catalytic activity
toward HDA.", keywords = "catalyst, FeN2/C, FeN4/C, HDS, HDA", volume = "4", number = "5", pages = "320-3", }
