Abstract: The health and environmental risk of eating mushrooms grown in Abakaliki were evaluated in terms of heavy metals accumulation. Mushroom samples were collected from four different farms located at Izzi, Amajim, Amana and Amudo and analyzed for (iron, lead, manganese and cadmium) using Bulk Scientific Atomic Absorption Spectrophotometer 205. Results indicates mean range of concentrations of the trace metals in the mushrooms were Fe (0.22-152. 03), Mn (0.74-9.76), Pb (0.01.0.80), Cd (0.61-0.82) mg/L respectively. Accumulation of Cd on the four locations under investigation was higher than the UK Government Food Science Surveillance and World Health Organization maximum recommended levels in mushroom for human consumption. The Fe and Mn contaminants of Amudo were significant and show the impact of anthropogenic/atmospheric pollution. The potential sources of the heavy metals in the mushrooms were from urban waste, dust from mining and quarrying activities, natural geochemistry of the area, and use of inorganic fertilizers
Abstract: The main objective of this study was to investigate particulate matter concentration on main and secondary roadsides in urban area and study the concentration of some heavy metals including lead (Pb), zinc (Zn), copper (Cu) and cadmium (Cd) in particulate matter in the Bangkok area.
The averaged particle concentration for main roadsides is higher than secondary roadsides. The particulate matter less than 10 micron concentration contribute the majority of the Total Suspended Particulate matter for main roads and zinc concentrations were higher than copper and lead for both sites.
Abstract: The environmental pollution by heavy metals became
more problematic nowadays. To solve the problem of Cadmium
accumulation in human organs which lead to dangerous effects on
human health, and to determine its concentration, the organic legand
1-phenyl-3-benzoyl-2-thiourea was used to extract the cadmium ions
from its solution. This legand as one of thiourea derivatives was
successfully synthesized. The legand was characterized by NMR and
CHN elemental analysis, and used to extract the cadmium from its
solutions by formation of a stable complex at neutral pH. The
complex was characterized by elemental analysis and melting point.
The concentrations of cadmium ions before and after the extraction
were determined by Atomic Absorption Spectrophotometer (AAS).
The data show the percentage of the extract was more than 98.7% of
the concentration of cadmium used in the study
Abstract: The efficiency of heavy metals removal from sewage
sludge in bioleaching processes with heterotrophic, chemoautotrophic
(sulphur-oxidizing) sludge cenoses and chemical leaching (in
distilled water, weakly acidic or alkaline medium) was compared.
The efficacy of heavy metals removal from sewage sludge varies
from 83 % (Zn) up to 14 % (Cr) and follows the order: Zn > Mn > Cu
> Ni > Co > Pb > Cr. The advantages of metals bioleaching process
at heterotrophic metabolism were shown. A new process for
bioconversation of sewage sludge into fertilizer at middle
temperatures after partial heavy metals removal was developed. This
process is based on enhancing vital ability of heterotrophic
microorganisms by adding easily metabolized nutrients and synthesis
of metabolites by growing sludge cenoses. These metabolites possess
the properties of heavy metals extractants and flocculants which
provide the enhancement of sludge flocks sedimentation. The process
results in biomineral fertilizer of prolonged action with immobilized
sludge bioelements. The fertilizer satisfies the EU limits for the
sewage sludge of agricultural utilization. High efficiency of the
biomineral fertilizer obtained has been demonstrated in vegetation
experiments.
Abstract: Rapid industrialization has led to increased disposal of heavy metals into the environment. Activated carbon adsorption has proven to be an effective process for the removal of trace metal contaminants from aqueous media. This paper was investigated chromium adsorption efficiency by commercial activated carbon. The sorption studied as a function of activated carbon particle size, dose of activated carbon and initial pH of solution. Adsorption tests for the effects of these factors were designed with Taguchi approach. According to the Taguchi parameter design methodology, L9 orthogonal array was used. Analysis of experimental results showed that, the most influential factor was initial pH of solution. The optimum conditions for chromium adsorption by activated carbons were found to be as follows: initial feed pH 6, adsorbent particle size 0.412 mm and activated carbon dose 6 g/l. Under these conditions, nearly %100 of chromium ions was adsorbed by activated carbon after 2 hours.
Abstract: This paper involves a study of the heavy metal pollution of the soils around one of cement plants in Libya called Suk-Alkhameas and surrounding urban areas caused by cement kiln dust (CKD) emitted. Samples of soil was collected from sites at four directions around the cement factory at distances 250m, 1000m, and 3000m from the factory and at (0-10)cm deep in the soil. These samples are analyzed for Fe (iii), Zn(ii), and Pb (ii) as major pollutants. These values are compared with soils at 25 Km distances from the factory as a reference or control samples. The results show that the concentration of Fe ions in the surface soil was within the acceptable range of 1000ppm. However, for Zn and Pb ions the concentrations at the east and north sides of the factory were found six fold higher than the benchmark level. This high value was attributed to the wind which blows usually from south to north and from west to east. This work includes an investigation of the adsorption isotherms and adsorption efficiency of CKD as adsorbent of heavy metal ions (Fe (iii), Zn(ii), and Pb(ii)) from the polluted soils of Suk-Alkameas city. The investigation was conducted in batch and fixed bed column flow technique. The adsorption efficiency of the studied heavy metals ions removals onto CKD depends on the pH of the solution. The optimum pH values are found to be in the ranges of 8-10 and decreases at lower pH values. The removal efficiency of these heavy metals ions ranged from 93% for Pb, 94% for Zn, and 98% for Fe ions for 10 g.l-1 adsorbent concentration. The maximum removal efficiency of these ions was achieved at 50-60 minutes contact times at which equilibrium is reached. Fixed bed column experimental measurements are also made to evaluate CKD as an adsorbent for the heavy metals. Results obtained are with good agreement with Langmuir and Drachsal assumption of multilayer formation on the adsorbent surface.
Abstract: This research investigated treatment of crude carbon black produced from pyrolysis of waste tyres in order to evaluate its quality and possible industrial applications. A representative sample of crude carbon black was dry screened to determine the initial particle size distribution. This was followed by pulverizing the crude carbon black and leaching in hot concentrated sulphuric acid for the removal of heavy metals and other contaminants. Analysis of the refined carbon black showed a significant improvement of the product quality compared to crude carbon black. It was discovered that refined carbon black can be further classified into multiple high value products for various industrial applications such as filler, paint pigment, activated carbon and fuel briquettes.
Abstract: The highest extractable concentration in the artificial sweat fluid was observed for Ba (120mg/kg; d.w.). The highest extractable concentration in the artificial gastric fluid was observed for Al (9030mg/kg; d.w.). Furthermore, the extractable concentrations of Ba (550mg/kg; d.w.) and Zn (400mg/kg: d.w.) in the bottom ash using artificial gastric fluid were elevated. The extractable concentrations of all heavy metals in the artificial gastric fluid were higher than those in the artificial sweat fluid. These results are reasonable in the light of the fact that the pH of the artificial gastric fluid was extremely acidic both before (pH 1.54) and after (pH 1.94) extraction, whereas the pH of the artificial sweat fluid was slightly alkaline before (pH 6.50) and after extraction (pH 8.51).
Abstract: One of the causes of water pollution is the presence of heavy metals in water. In the present study, an adsorbent prepared from the raw bark of the Pongamia pinnata tree is used for the removal of ferrous or ferric ions from aqueous and waste water containing heavy metals. Adsorption studies were conducted at different pH, concentration of metal ion, amount of adsorbent, contact time, agitation and temperature. The Langmuir and Freundlich adsorption isotherm models were applied for the results. The Langmuir isotherms were best fitted by the equilibrium data. The maximum adsorption was found to 146mg/g in waste water at a temperature of 30°C which is in agreement as comparable to the adsorption capacity of different adsorbents reported in literature. Pseudo second order model best fitted the adsorption of both ferrous and ferric ions.
Abstract: Heavy metal transfer in soil profiles is a major
environmental concern because even slow transport through the soil
may eventually lead to deterioration of groundwater quality. The use
of sewage sludge and effluents from wastewater treatment plants for
irrigation of agricultural lands is on the rise particularly in peri-urban
area of developing countries. In this study soil samples under sludge
application and wastewater irrigation were studied and soil samples
were collected in the soil profiles from the surface to 100 cm in
depth. For this purpose, three plots were made in a treatment plant in
south of Tehran-Iran. First plot was irrigated just with effluent from
wastewater treatment plant, second plot with simulated heavy metals
concentration equal 50 years irrigation and in third plot sewage
sludge and effluent was used. Trace metals concentration (Cd, Cu)
were determined for soil samples. The results indicate movement of
metals was observed, but the most concentration of metals was found
in topsoil samples. The most of Cadmium concentration was
measured in the topsoil of plot 3, 4.5mg/kg and Maximum cadmium
movement was observed in 0-20 cm. The most concentration of
copper was 27.76mg/kg, and maximum percolation in 0-20 cm.
Metals (Cd, Cu) were measured in leached water. Preferential flow
and metal complexation with soluble organic apparently allow
leaching of heavy metals.
Abstract: Cabbage seedlings grown in vitro were exposed to
excess levels of heavy metals, including Cd, Mo, and Zn. High metal
levels affected plant growth at cotyledonary stage. Seedlings under
Cd, Mo, and Zn treatments could not produce root hairs and true
leaves. Under stress conditions, seedlings accumulated a higher
amount of anthocyanins in their cotyledons than those in the control.
The pigments isolated from Cd and Zn stressed seedling cotyledons
appeared as pink, while under Mo stress, was dark pink or purple.
Moreover, excess Mo stress increased antioxidant enzyme activities
of APX, CAT, SOD. These results suggest that, under excess Mo
stress, the induced antioxidant enzyme activity of cabbage seedlings
may function as a protective mechanism to shield the plants from
toxicity and exacerbated growth.
Abstract: The growing health hazardous impact of arsenic (As)
contamination in environment is the impetus of the present
investigation. Application of lactic acid bacteria (LAB) for the
removal of toxic and heavy metals from water has been reported.
This study was performed in order to isolate and characterize the Asresistant
LAB from mud and sludge samples for using as efficient As
uptaking probiotic. Isolation of As-resistant LAB colonies was
performed by spread plate technique using bromocresol purple
impregnated-MRS (BP-MRS) agar media provided with As @ 50
μg/ml. Isolated LAB were employed for probiotic characterization
process, acid and bile tolerance, lactic acid production, antibacterial
activity and antibiotic tolerance assays. After As-resistant and
removal characterizations, the LAB were identified using 16S rDNA
sequencing. A total of 103 isolates were identified as As-resistant
strains of LAB. The survival of 6 strains (As99-1, As100-2, As101-3,
As102-4, As105-7, and As112-9) was found after passing through the
sequential probiotic characterizations. Resistant pattern pronounced
hollow zones at As concentration >2000 μg/ml in As99-1, As100-2,
and As101-3 LAB strains, whereas it was found at ~1000 μg/ml in
rest 3 strains. Among 6 strains, the As uptake efficiency of As102-4
(0.006 μg/h/mg wet weight of cell) was higher (17 – 209%)
compared to remaining LAB. 16S rDNA sequencing data of 3 (As99-
1, As100-2, and As101-3) and 3 (As102-4, As105-7, and As112-9)
LAB strains clearly showed 97 to 99% (340 bp) homology to
Pediococcus dextrinicus and Pediococcus acidilactici, respectively.
Though, there was no correlation between the metal resistant and
removal efficiency of LAB examined but identified elevated As
removing LAB would probably be a potential As uptaking probiotic
agent. Since present experiment concerned with only As removal
from pure water, As removal and removal mechanism in natural
condition of intestinal milieu should be assessed in future studies.
Abstract: Tehran, one of the heavily-populated capitals, is
severely suffering from increasing air pollution. To show a
documented trend of such pollutants during last years, plane tree
species (Platanus orientalis) were suited to be studied as indicators,
for the species have been planted throughout the city many years
ago. Two areas (Saadatabad and Narmak districts) allotting different
contents of crowed and highly-traffic routs but the same ecological
characteristics were selected. Twelve sample individuals were cored
twice perpendicularly in each area. Tree-rings of each core were
measured by a binocular microscope and separated annually for the
last 25 years. Two heavy metals including Cd and Pb accompanied
by a mineral element (Ca) were analyzed using Hatch method. Treerings
analysis of the two areas showed different groups in term of
physiologically ability as the growths were plunged during the last
10 years in Saadatabad district and showed a slight decrease in the
same period for another studying area. In direct contrast to
decreasing growth trend in Saadatabad, all three mentioned elements
increased sharply during last 25 years in the same area. When it came
to Narmak district, the trend was completely different with
Saadatabad. There were some fluctuations in absorbing trace
elements like tree-rings widths were, yet calcium showed an upward
trend all the last 25 years. The results of the study proved the
possibility of using tree species of each region to monitor its air
pollution trends of the past, hence to depict a pollution assessment of
a populated city for last years and then to make appropriate decisions
for the future as it is well-known what the trend is. On the other
hand, risen values of calcium (as the stress-indicator element)
accompanied by increased trace elements suggests non-sustainable
state of the trees.
Abstract: A vast array of biological materials, especially algae have received increasing attention for heavy metal removal. Algae have been proven to be cheaper, more effective for the removal of metallic elements in aqueous solutions. A fresh water algal strain was isolated from Zoo Lake, Johannesburg, South Africa and identified as Desmodesmus sp. This paper investigates the efficacy of Desmodesmus sp.in removing heavy metals contaminating the Wonderfonteinspruit Catchment Area (WCA) water bodies. The biosorption data fitted the pseudo-second order and Langmuir isotherm models. The Langmuir maximum uptakes gave the sequence: Mn2+>Ni2+>Fe2+. The best results for kinetic study was obtained in concentration 120 ppm for Fe3+ and Mn2+, whilst for Ni2+ was at 20 ppm, which is about the same concentrations found in contaminated water in the WCA (Fe3+115 ppm, Mn2+ 121 ppm and Ni2+ 26.5 ppm).
Abstract: The treatment of the industrial wastewater can be
particularly difficult in the presence of toxic compounds. Excessive
concentration of Chromium in soluble form is toxic to a wide variety
of living organisms. Biological removal of heavy metals using natural
and genetically engineered microorganisms has aroused great interest
because of its lower impact on the environment. Ralston
metallidurans, formerly known as Alcaligenes eutrophus is a LProteobacterium
colonizing industrial wastewater with a high content
of heavy metals. Tris-buffered mineral salt medium was used for
growing Alcaligenes eutrophus AE104 (pEBZ141). The cells were
cultivated for 18 h at 30 oC in Tris-buffered mineral salt medium
containing 3 mM disodium sulphate and 46 mM sodium gluconate as
the carbon source. The cells were harvested by centrifugation,
washed, and suspended in 10 mM Tris HCl, pH 7.0, containing 46
mM sodium gluconate, and 5 mM Chromium. Interaction among
induction of chr resistance determinant, and chromate reduction have
been demonstrated. Results of this study show that the above bacteria
can be very useful for bioremediation of chromium from industrial
wastewater.
Abstract: This research aimed at investigating the Cr (III), Cd
(II) and Pb (II) removal efficiencies by using the newly synthesized
metal oxides/ polyethersulfone (PES), Al2O3/PES and ZrO2/PES,
membranes from synthetic wastewater and exploring fouling
mechanisms. A Comparative study between the removal efficiencies
of Cr (III), Cd (II) and Pb (II) from synthetic and natural wastewater
by using adsorption onto agricultural by products and the newly
synthesized Al2O3/PES and ZrO2/PES membranes was conducted to
assess the advantages and limitations of using the metal oxides/PES
membranes for heavy metals removal. The results showed that about
99 % and 88 % removal efficiencies were achieved by the tested
membranes for Pb (II) and Cr (III), respectively.
Abstract: The direct sewage sludge application is a relative
cheap method for their liquidation. In the past heavy metal contents
increase in soils treated with sewage sludge was observed. In 2003
there was acceptance on act n.188/2003 about sewage sludge
application on soils. The basic philosophy of act is a safety of the
environmental proof of sludge application on soils. The samples of
soils from wastewater treatment plant (WTP) Poprad (35) and WTP
Michalovce (33 samples) were analyzed which were chosen for
sludge application on soils. According to the results only 14 areas for
Poprad and 25 areas for Michalovce are suitable for sludge
application according to act No. 188/2003. The application dose of
sludge was calculated 50 t.ha-1 or 75 t. ha-1 once in 5 years to ensure
that heavy metal contents in treated soils will be kept.
Abstract: Heavy metals have bad effects on environment and
soils and it can uptake by natural HAP .natural Hap is an inexpensive
material that uptake large amounts of various heavy metals like Zn
(II) .Natural HAP (N-HAP), extracted from bovine cortical bone ash,
is a good choice for substitution of commercial HAP. Several
experiments were done to investigate the sorption capacity of Zn (II)
to N-HAP in various particles sizes, temperatures, initial
concentrations, pH and reaction times. In this study, the sorption of
Zinc ions from a Zn solution onto HAP particles with sizes of 1537.6
nm and 47.6 nm at three initial pH values of 4.50, 6.00 and 7.50 was
studied. The results showed that better performance was obtained
through a 47.6 nm particle size and higher pH values. The
experimental data were analyzed using Langmuir, Freundlich, and
Arrhenius equations for equilibrium, kinetic and thermodynamic
studies. The analysis showed a maximum adsorption capacity of NHAP
as being 1.562 mmol/g at a pH of 7.5 and small particle size.
Kinetically, the prepared N-HAP is a feasible sorbent that retains Zn
(II) ions through a favorable and spontaneous sorption process.
Abstract: The use of sewage sludge and effluents from
wastewater treatment plants for irrigation of agricultural lands is on
the rise particularly in peri-urban areas of developing countries.
The reuse of nutrients and organic matter in treated wastewater
and sewage sludge via land application is a desirable goal. However,
trace or heavy metals present in sludge pose the risk of human or
phytotoxicity from land application. Long-term use of sewage
sludge, heavy metals can accumulate to phytotoxic levels and results
in reduced plants growth and/or enhanced metal concentrations in
plants, which consumed by animals then enter the food chain. In this
research, the amount of heavy metals was measured in plants
irrigated with wastewater and sludge application. For this purpose,
three pilots were made in a Shush treatment plant in south of Tehran.
Three plants species, spinach, lettuce and radish were selected and
planted in the pilots.First pilot was irrigated just with wastewater of
treatment plant and second pilot was irrigated with wastewater and
sludge application .Third pilot was irrigated with simulated heavy
metals solution equal 50 years of irrigation. The results indicate that
the average of amount of heavy metals Pb, Cd in three plant species
in first pilot were lower than permissible limits .In second pilot,
Cadmium accumulations are high in three species plants and more
than the standard limits. Concentration of Cd , Pb have exceed their
permitted limits in plants in third pilot . It was concluded that the use
of wastewater and sludge application in agricultural lands enriched
soils with heavy metals to concentrations that may pose potential
environmental and health risks in the long-term.
Abstract: In this study, the reduction of Cr(VI) by use of scrap
iron, a cheap and locally available industrial waste, was investigated
in continuous system. The greater scrap iron efficiency observed for
the first two sections of the column filling indicate that most of the
reduction process was carried out in the bottom half of the column
filling. This was ascribed to a constant decrease of Cr(VI)
concentration inside the filling, as the water front passes from the
bottom to the top end of the column. While the bottom section of the
column filling was heavily passivated with secondary mineral phases,
the top section was less affected by the passivation process; therefore
the column filling would likely ensure the reduction of Cr(VI) for
time periods longer than 216 hours. The experimental results indicate
that fixed beds columns packed with scrap iron could be successfully
used for the first step of Cr(VI) polluted wastewater treatment.
However, the mass of scrap iron filling should be carefully estimated
since it significantly affects the Cr(VI) reduction efficiency.