Abstract: Control of honey frauds is needed in Ecuador to
protect bee keepers and consumers because simple syrups and new
syrups with eucalyptus are sold as genuine honeys. Authenticity of
Ecuadorian commercial honeys was tested with a vortex emulsion
consisting on one volume of honey:water (1:1) dilution, and two
volumes of diethyl ether. This method allows a separation of phases
in one minute to discriminate genuine honeys that form three phase
and fake honeys that form two phases; 34 of the 42 honeys analyzed
from five provinces of Ecuador were genuine. This was confirmed
with 1H NMR spectra of honey dilutions in deuterated water with an
enhanced amino acid region with signals for proline, phenylalanine
and tyrosine. Classic quality indicators were also tested with this
method (sugars, HMF), indicators of fermentation (ethanol, acetic
acid), and residues of citric acid used in the syrup manufacture. One
of the honeys gave a false positive for genuine, being an admixture of
genuine honey with added syrup, evident for the high sucrose.
Sensory analysis was the final confirmation to recognize the honey
groups studied here, namely honey produced in combs by Apis
mellifera, fake honey, and honey produced in cerumen pots by
Geotrigona, Melipona, and Scaptotrigona. Chloroform extractions of
honey were also done to search lipophilic additives in NMR spectra.
This is a valuable contribution to protect honey consumers, and to
develop the beekeeping industry in Ecuador.
Abstract: The intrinsic contradictions of entrepreneurship
development and self-development strategies complicate the task of
reaching compliance between the state economic policy and the
company entrepreneurship policy: on the one hand, there is a
contradiction between the social and the competitive order within
economic order policy and on the other hand, the contradiction exists
between entrepreneurship strategy and entrepreneurship culture
within entrepreneurship policy.
Abstract: This paper presents a study the effect of nose radius
(Rz-mm) on cutting force components and temperatures during the
machining simulation in an orthogonal cutting process for titanium
alloy (Ti-6Al-4V). The cutting process was performed at various
nose radiuses (Rz-mm) while the depth of cut (d-mm), feed rate (fmm/
tooth) and cutting speed (vc-m/ min) were remained constant.
The main cutting force (Fc), feed cutting force (Ft) and temperatures
were estimated by using finite element modeling (FEM) through
ABAQUS/EXPLICIT software and the simulation was developed the
two-dimension via an orthogonal cutting process during machining
titanium alloy (Ti-6Al-4V). The results led to the conclusion that the
nose radius (Rz-mm) has affected directly on the cutting force
components. However, temperature gave no indication or has no
significant relation with nose radius during machining titanium alloy
(Ti-6Al-4V). Hence, any increase or decrease in the nose radius (Rzmm)
during machining operation led to effect on the cutting forces
and thus it will be effective on surface finish, quality, and quantity of
products.
Abstract: In emerging economies, recycling is an opportunity
for the cities to increase the lifespan of sanitary landfills, reduce the
costs of the solid waste management, decrease the environmental
problems of the waste treatment through reincorporate waste in the
productive cycle and protect and develop people’s livelihoods of
informal waste pickers. However, few studies have analysed the
possibilities and strategies to integrate formal and informal sectors in
the solid waste management for the benefit of both. This study seek
to make a strength, weakness, opportunity, and threat (SWOT)
analysis in three recycling associations of Bogotá with the aim to
understand and determine the situation of recycling from perspective
of informal sector in its transition to enter as authorized waste
providers. Data used in the analysis are derived from multiple
strategies such as literature review, the Bogota’s recycling database,
focus group meetings, governmental reports, national laws and
regulations and specific interviews with key stakeholders. Results of
this study show as the main stakeholders of formal and informal
sector of waste management can identify the internal and internal
conditions of recycling in Bogotá. Several strategies were designed
based on the SWOTs determined, could be useful for Bogotá to
advance and promote recycling as a key strategy for integrated
sustainable waste management in the city.
Abstract: An innovative flooring underlayment was produced
and tested. The composite system is made of common OSB boards
and a layer of eco-friendly non-cement gypsum based material
(GeoGypTM). It was found that the shear bond between the two
materials is sufficient to secure the composite interaction between the
two. The very high compressive strength and relatively high tensile
strength of the non-cement based component together with its high
modulus of elasticity provides enough strength and stiffness for the
composite product to cover wider spacing between the joists. The
initial findings of this study indicate that with joist spacing as wide as
800 mm, the flooring system provides enough strength without
compromising the serviceability requirements of the building codes.
Abstract: Scrubbing by a liquid spraying is one of the most
effective processes used for removal of fine particles and soluble
gas pollutants (such as SO2, HCl, HF) from the flue gas. There are
many configurations of scrubbers designed to provide contact
between the liquid and gas stream for effectively capturing
particles or soluble gas pollutants, such as spray plates, packed bed
towers, jet scrubbers, cyclones, vortex and venturi scrubbers. The
primary function of venturi scrubber is the capture of fine particles
as well as HCl, HF or SO2 removal with effect of the flue gas
temperature decrease before input to the absorption column. In this
paper, sulfur dioxide (SO2) from flue gas was captured using new
design replacing venturi scrubber (1st degree of wet scrubbing).
The flue gas was prepared by the combustion of the carbon
disulfide solution in toluene (1:1 vol.) in the flame in the reactor.
Such prepared flue gas with temperature around 150°C was
processed in designed laboratory O-element scrubber. Water was
used as absorbent liquid. The efficiency of SO2 removal, pressure
drop and temperature drop were measured on our experimental
device. The dependence of these variables on liquid-gas ratio was
observed. The average temperature drop was in the range from
150°C to 40°C. The pressure drop was increased with increasing of
a liquid-gas ratio, but no too much as for the common venturi
scrubber designs. The efficiency of SO2 removal was up to 70 %.
The pressure drop of our new designed wet scrubber is similar to
commonly used venturi scrubbers; nevertheless the influence of
amount of the liquid on pressure drop is not so significant.
Abstract: This paper is concerned with knowledge representation
and extraction of fuzzy if-then rules using Interval Type-2
Context-based Fuzzy C-Means clustering (IT2-CFCM) with the aid of
fuzzy granulation. This proposed clustering algorithm is based on
information granulation in the form of IT2 based Fuzzy C-Means
(IT2-FCM) clustering and estimates the cluster centers by preserving
the homogeneity between the clustered patterns from the IT2 contexts
produced in the output space. Furthermore, we can obtain the
automatic knowledge representation in the design of Radial Basis
Function Networks (RBFN), Linguistic Model (LM), and Adaptive
Neuro-Fuzzy Networks (ANFN) from the numerical input-output data
pairs. We shall focus on a design of ANFN in this paper. The
experimental results on an estimation problem of energy performance
reveal that the proposed method showed a good knowledge
representation and performance in comparison with the previous
works.
Abstract: This paper presents a part of the project solving which
is dedicated to the identification of the hazardous waste with the most
critical production within the Czech Republic with the aim to study
and find the optimal composition of the cement matrix that will
ensure maximum content disposal of chosen hazardous waste. In the
first stage of project solving – which represents this paper – a specific
hazardous waste was chosen, its properties were identified and
suitable solidification agents were chosen. Consequently
solidification formulas and testing methodology was proposed.
Abstract: Moving into a new era of healthcare, new tools and
devices are developed to extend and improve health services, such as
remote patient monitoring and risk prevention. In this concept,
Internet of Things (IoT) and Cloud Computing present great
advantages by providing remote and efficient services, as well as
cooperation between patients, clinicians, researchers and other health
professionals. This paper focuses on patients suffering from bipolar
disorder, a brain disorder that belongs to a group of conditions
called affective disorders, which is characterized by great mood
swings. We exploit the advantages of Semantic Web and Cloud
Technologies to develop a patient monitoring system to support
clinicians. Based on intelligently filtering of evidence-knowledge and
individual-specific information we aim to provide treatment
notifications and recommended function tests at appropriate times or
concluding into alerts for serious mood changes and patient’s nonresponse
to treatment. We propose an architecture as the back-end
part of a cloud platform for IoT, intertwining intelligence devices
with patients’ daily routine and clinicians’ support.
Abstract: Reliability of long-term storage products is related to
the availability of the whole system, and the evaluation of storage life
is of great necessity. These products are usually highly reliable and
little failure information can be collected. In this paper, an analytical
method based on data from accelerated storage life test is proposed to
evaluate the reliability index of the long-term storage products. Firstly,
singularities are eliminated by data normalization and residual
analysis. Secondly, with the preprocessed data, the degradation path
model is built to obtain the pseudo life values. Then by life distribution
hypothesis, we can get the estimator of parameters in high stress levels
and verify failure mechanism consistency. Finally, the life distribution
under the normal stress level is extrapolated via the acceleration model
and evaluation of the actual average life is available. An application
example with the camera stabilization device is provided to illustrate
the methodology we proposed.
Abstract: We have conducted the optimal synthesis of rootmean-
squared objective filter to estimate the state vector in the case if
within the observation channel with memory the anomalous noises
with unknown mathematical expectation are complement in the
function of the regular noises. The synthesis has been carried out for
linear stochastic systems of continuous - time.
Abstract: We investigate relaxation dynamics of a quantum
dipole emitter (QDE), e.g., a molecule or quantum dot, located near a
metal nanoparticle (MNP) exhibiting a dipolar localized surface
plasmon (LSP) resonance at the frequency of the QDE radiative
transition. It is shown that under the condition of the QDE-MNP
characteristic relaxation time being much shorter than that of the
QDE in free-space but much longer than the LSP lifetime. It is also
shown that energy dissipation in the QDE-MNP system is relatively
weak with the probability of the photon emission being about 0.75, a
number which, rather surprisingly, does not explicitly depend on the
metal absorption characteristics. The degree of entanglement
measured by the concurrency takes the maximum value, while the
distances between the QDEs and metal ball approximately are equal.
Abstract: Early diagnosis of infection like Hep-B virus in blood
is important for low cost medical treatment. For this purpose, it is
desirable to develop a point of care device which should be able to
detect trace quantities of the target molecule in blood. In this paper,
we report a nanoporous silicon oxide sensor which is capable of
detecting down to 1fM concentration of Hep-B surface antigen in
blood without the requirement of any centrifuge or pre-concentration.
This has been made possible by the presence of resonant peak in the
sensitivity characteristics. This peak is observed to be dependent only
on the concentration of the specific antigen and not on the interfering
species in blood serum. The occurrence of opposite impedance
change within the pores and at the bottom of the pore is responsible
for this effect. An electronic interface has also been designed to
provide a display of the virus concentration.
Abstract: Testability modeling is a commonly used method in
testability design and analysis of system. A dependency matrix will be
obtained from testability modeling, and we will give a quantitative
evaluation about fault detection and isolation.
Based on the dependency matrix, we can obtain the diagnosis tree.
The tree provides the procedures of the fault detection and isolation.
But the dependency matrix usually includes built-in test (BIT) and
manual test in fact. BIT runs the test automatically and is not limited
by the procedures. The method above cannot give a more efficient
diagnosis and use the advantages of the BIT.
A Comprehensive method of fault detection and isolation is
proposed. This method combines the advantages of the BIT and
Manual test by splitting the matrix. The result of the case study shows
that the method is effective.
Abstract: Propylene self-metathesis to ethylene and butene was
studied over WOx/SiO2 catalysts at 450oC and atmospheric pressure.
The WOx/SiO2 catalysts were prepared by incipient wetness
impregnation of ammonium metatungstate aqueous solution. It was
found that, adding nano-sized extra supports (SiO2 and TiO2) by
physical mixing with the WOx/SiO2 enhanced propylene conversion.
The UV-Vis and FT-Raman results revealed that WOx could migrate
from the original silica support to the extra support, leading to a
better dispersion of WOx. The ICP-OES results also indicate that
WOx existed on the extra support. Coke formation was investigated
on the catalysts after 10 h time-on-stream by TPO. However, adding
nano-sized extra supports led to higher coke formation which may be
related to acidity as characterized by NH3-TPD.
Abstract: This paper presents the design and fabrication of an
optical window for an optical modulator toward image sensing
applications. An optical window consists of micrometer-order SiO2
capillaries (porous solid) that can modulate transmission light
intensity by moving the liquid in and out of porous solid. A high
optical transmittance of the optical window can be achieved due to
refractive index matching when the liquid is penetrated into the
porous solid. Otherwise, its light transmittance is lower because of
light reflection and scattering by air holes and capillary walls. Silicon
capillaries fabricated by deep reactive ion etching (DRIE) process are
completely oxidized to form the SiO2 capillaries. Therefore, high
aspect ratio SiO2 capillaries can be achieved based on silicon
capillaries formed by DRIE technique. Large compressive stress of
the oxide causes bending of the capillary structure, which is reduced
by optimizing the design of device structure. The large stress of the
optical window can be released via thin supporting beams. A 7.2 mm
x 9.6 mm optical window area toward a fully integrated with the
image sensor format is successfully fabricated and its optical
transmittance is evaluated with and without inserting liquids (ethanol
and matching oil). The achieved modulation range is approximately
20% to 35% with and without liquid penetration in visible region
(wavelength range from 450 nm to 650 nm).
Abstract: A cyclostationary Gaussian linearization method is
formulated for investigating the time average response of nonlinear
system under sinusoidal signal and white noise excitation. The
quantitative measure of cyclostationary mean, variance, spectrum of
mean amplitude, and mean power spectral density of noise are
analyzed. The qualitative response behavior of stochastic jump and
bifurcation are investigated. The validity of the present approach in
predicting the quantitative and qualitative statistical responses is
supported by utilizing Monte Carlo simulations. The present analysis
without imposing restrictive analytical conditions can be directly
derived by solving non-linear algebraic equations. The analytical
solution gives reliable quantitative and qualitative prediction of mean
and noise response for the Duffing system subjected to both sinusoidal
signal and white noise excitation.
Abstract: This paper presents a model for a modified T-junction
device for microspheres generation. The numerical model is
developed using a commercial software package: COMSOL
Multiphysics. In order to test the accuracy of the numerical model,
multiple variables, such as the flow rate of cross-flow, fluid properties,
structure, and geometry of the microdevice are applied. The results
from the model are compared with the experimental results in the
diameter of the microsphere generated. The comparison shows a good
agreement. Therefore the model is useful in further optimization of the
device and feedback control of microsphere generation if any.
Abstract: The capability of exploiting the electronic charge and
spin properties simultaneously in a single material has made diluted
magnetic semiconductors (DMS) remarkable in the field of
spintronics. We report the designing of DMS based on zinc-blend
ZnO doped with Cr impurity. The full potential linearized augmented
plane wave plus local orbital FP-L(APW+lo) method in density
functional theory (DFT) has been adapted to carry out these
investigations. For treatment of exchange and correlation energy,
generalized gradient approximations have been used. Introducing Cr
atoms in the matrix of ZnO has induced strong magnetic moment
with ferromagnetic ordering at stable ground state. Cr:ZnO was found
to favor the short range magnetic interaction that
reflect tendency of Cr clustering. The electronic structure of ZnO is
strongly influenced in the presence of Cr impurity atoms where
impurity bands appear in the band gap.
Abstract: Although, lanthanum carbonate has not been approved
by the FDA for treatment of hyperphosphatemia, we prospectively
evaluated the efficacy of the combination of Calcium hydroxyapatite
(CHAp) and Lanthanum Carbonate (LaC) for the treatment of
hyperphosphatemia on mice. CHAp was prepared by co-precipitation
method using Ca(OH)2, H3PO4, NH4OH with calcination at 1200ºC.
Lanthanum carbonate was prepared by chemical method using
NaHCO3 and LaCl3 at low pH environment, below 4.0. The
structures were characterized by FTIR spectra and SEM -EDX
analysis. The study group included 16 subjects-mice divided into four
groups according to the administered substance: lanthanum carbonate
(group A), CHAp (group B), lanthanum carbonate + CHAp (group C)
and salt water (group D). The results indicate a phosphate decrease
when subjects (mice) were treated with CHAp and lanthanum
carbonate (0.5% CMC), in a single dose of 1500 mg/kg. Serum
phosphate concentration decreased [(from 4.5 ± 0.8 mg/dL) to
4.05 ± 0.2 mg/dL), P < 0.01] in group A and in group C (to 3.6
± 0.2 mg/dL) at 12 hours from the administration. The combination
of CHAp and lanthanum carbonate is a suitable regimen for
hyperphosphatemia treatment because it avoids both the
hypercalcemia of CaCO3 and the adverse effects of CHAp.