Wet Flue Gas Desulfurization Using a New O-Element Design Which Replaces the Venturi Scrubber

Scrubbing by a liquid spraying is one of the most
effective processes used for removal of fine particles and soluble
gas pollutants (such as SO2, HCl, HF) from the flue gas. There are
many configurations of scrubbers designed to provide contact
between the liquid and gas stream for effectively capturing
particles or soluble gas pollutants, such as spray plates, packed bed
towers, jet scrubbers, cyclones, vortex and venturi scrubbers. The
primary function of venturi scrubber is the capture of fine particles
as well as HCl, HF or SO2 removal with effect of the flue gas
temperature decrease before input to the absorption column. In this
paper, sulfur dioxide (SO2) from flue gas was captured using new
design replacing venturi scrubber (1st degree of wet scrubbing).
The flue gas was prepared by the combustion of the carbon
disulfide solution in toluene (1:1 vol.) in the flame in the reactor.
Such prepared flue gas with temperature around 150°C was
processed in designed laboratory O-element scrubber. Water was
used as absorbent liquid. The efficiency of SO2 removal, pressure
drop and temperature drop were measured on our experimental
device. The dependence of these variables on liquid-gas ratio was
observed. The average temperature drop was in the range from
150°C to 40°C. The pressure drop was increased with increasing of
a liquid-gas ratio, but no too much as for the common venturi
scrubber designs. The efficiency of SO2 removal was up to 70 %.
The pressure drop of our new designed wet scrubber is similar to
commonly used venturi scrubbers; nevertheless the influence of
amount of the liquid on pressure drop is not so significant.





References:
[1] Saarnio K., Frey A., Niemi J.V., Timonen H., Ronkko T., Karjalainen
P., Vestenius M., Teinilä K., Pirjola L., Niemela V., Keskinen J.,
Häyrinen A., Hillamo R. Chemical composition and size of particle in
emissions of coal-fired power plant with flue gas desulphurization. J.
Aerosol Science 73, 14-26, 2014.
[2] Xiao Y.J., Li C.T., Li S.H., Zeng G.M., Wen Q.B., Guo G.Q., Song
J.K. Optimal design of a wet-type desulphurization absorber by the
numerical simulation method. Chem. Eng. Research and Design 92,
1257-1266, 2014.
[3] Gutierrez Ortiz F.J., Vidal F., Ollero P., Salvador L., Cortes V.,
Gimenez A. Pilot-plant technical assessment of wet flue gas
desulfurization using limestone. Ind. Eng. Chem. Res. 45, 1466-1477,
2006.
[4] Bandyapadhyay A., Biswas M.N. Prediction of the removal efficiency
of a novel two-stage hyrid scrubber for flue gas desulphurization.
Chem. Eng. Technol. 29, 130-145, 2006.
[5] Dou B., Pan W., Jin Q., Wang W., Li Y. Prediction of SO2 removal
efficiency for wet flue gas desulphurization. Energy Conversion and
Management 50, 2547-2553, 2009.
[6] Shimono A., Koda S. Laser-spectrometric measurement of uptake
coefficient of SO2 an aqueous surfaces. J. Phys. Chem. 100, 10269-
10276, 1996.
[7] Warych J, Szymanowski M. Model of the wet limestone flue gas
desulfurization process for cost optimization. Ind. Eng. Chem. Res.
40, 2597–2605, 2001.
[8] Liu S, Xiao W. Modeling and simulation of a bubbling SO2 absorber
with granular limestone slurry and an organic acid additive. Chem.
Eng. Technol. 29, 1167–1173, 2006.
[9] Chisholm D., Two-Phase Flow in Pipelines and Heat Exchangers.
Longman Higher Education, 1983. ISBN 0711457484.
[10] Hewitt G.F., Shires G.L., Polezhaev Y.V. International Encyclopedia
of Heat and Mass Transfer. CRC Press, 1997. ISBN 0849393566.
[11] Fore L.B., Dukler A.E. The distribution of drop size and velocity in
gas-liquid annular flow. Int. J. Multiphase Flow 21, 137-149, 1995.
[12] Sewant P., Ishii M., Mori M. Droplet entrainment correlation in
vertical upward co-current annular two-phase flow. Nuclear
Engineering and Design 238, 1342-1352, 2008.
[13] Ramm V., Absorbcija gazov. Moskva: Chimija, 1966, 654 p.
[14] Gilliland E.R., Sherwood T.K. Diffusion of vapors into air streams.
Industrial and Engineering Chemistry 26, 516-523, 1934.
[15] Clift R., Grace J.R., Weber M.E. Bubbles, drops, and particles:
normal operation and upset conditions. New York: Academic Press,
1978, 380 p. ISBN 01-217-6950-X.
[16] Gao H., Li C., Zeng G., Zhang W., Shi L., Li S., Zeng Y., Fan X.,
Wen Q., Shu X. Flue gas desulphurization based on limestonegypsum
with a novel wet-type PCF device. Separation and
Purification Technology 76, 253-260, 2011.