Abstract: Nowadays there is a growing interest in biofuel production in most countries because of the increasing concerns about hydrocarbon fuel shortage and global climate changes, also for enhancing agricultural economy and producing local needs for transportation fuel. Ethanol can be produced from biomass by the hydrolysis and sugar fermentation processes. In this study ethanol was produced without using expensive commercial enzymes from sugarcane bagasse. Alkali pretreatment was used to prepare biomass before enzymatic hydrolysis. The comparison between NaOH, KOH and Ca(OH)2 shows NaOH is more effective on bagasse. The required enzymes for biomass hydrolysis were produced from sugarcane solid state fermentation via two fungi: Trichoderma longibrachiatum and Aspergillus niger. The results show that the produced enzyme solution via A. niger has functioned better than T. longibrachiatum. Ethanol was produced by simultaneous saccharification and fermentation (SSF) with crude enzyme solution from T. longibrachiatum and Saccharomyces cerevisiae yeast. To evaluate this procedure, SSF of pretreated bagasse was also done using Celluclast 1.5L by Novozymes. The yield of ethanol production by commercial enzyme and produced enzyme solution via T. longibrachiatum was 81% and 50% respectively.
Abstract: In the study the influence of the physical-chemical properties of a liquid, the width of a channel gap and the superficial liquid and gas velocities on the patterns formed during two phase flows in vertical, narrow mini-channels was investigated. The research was performed in the channels of rectangular cross-section and of dimensions: 15 x 0.65 mm and 7.5 x 0.73 mm. The experimental data were compared with the published criteria of the transitions between the patterns of two-phase flows.
Abstract: The conventional GA combined with a local search
algorithm, such as the 2-OPT, forms a hybrid genetic algorithm(HGA)
for the traveling salesman problem (TSP). However, the geometric
properties which are problem specific knowledge can be used to
improve the search process of the HGA. Some tour segments (edges)
of TSPs are fine while some maybe too long to appear in a short tour.
This knowledge could constrain GAs to work out with fine tour
segments without considering long tour segments as often.
Consequently, a new algorithm is proposed, called intelligent-OPT
hybrid genetic algorithm (IOHGA), to improve the GA and the 2-OPT
algorithm in order to reduce the search time for the optimal solution.
Based on the geometric properties, all the tour segments are assigned
2-level priorities to distinguish between good and bad genes. A
simulation study was conducted to evaluate the performance of the
IOHGA. The experimental results indicate that in general the IOHGA
could obtain near-optimal solutions with less time and better accuracy
than the hybrid genetic algorithm with simulated annealing algorithm
(HGA(SA)).
Abstract: The paper presents the results of theoretical and
numerical modeling of propagation of shock waves in bubbly liquids
related to nonlinear effects (realistic equation of state, chemical
reactions, two-dimensional effects). On the basis on the Rankine-
Hugoniot equations the problem of determination of parameters of
passing and reflected shock waves in gas-liquid medium for
isothermal, adiabatic and shock compression of the gas component is
solved by using the wide-range equation of state of water in the
analitic form. The phenomenon of shock wave intensification is
investigated in the channel of variable cross section for the
propagation of a shock wave in the liquid filled with bubbles
containing chemically active gases. The results of modeling of the
wave impulse impact on the solid wall covered with bubble layer are
presented.
Abstract: Three dimensional nanostructure materials have attracted the attention of many researches because the possibility to apply them for near future devices in sensors, catalysis and energy related. Tin dioxide is the most used material for gas sensing because its three-dimensional nanostructures and properties are related to the large surface exposed to gas adsorption. We propose the use of branch SnO2 nanowhiskers in interaction with ethanol. All Sn atoms are symmetric. The total energy, potential energy and Kinetic energy calculated for interaction between SnO2 and ethanol in different distances and temperatures. The calculations achieved by methods of Langevin Dynamic and Mont Carlo simulation. The total energy increased with addition ethanol molecules and temperature so interactions between them are endothermic.
Abstract: The objective of this study is to investigate the
combustion in a pilot-ignited supercharged dual-fuel engine, fueled
with different types of gaseous fuels under various equivalence ratios.
It is found that if certain operating conditions are maintained,
conventional dual-fuel engine combustion mode can be transformed to
the combustion mode with the two-stage heat release. This mode of
combustion was called the PREMIER (PREmixed Mixture Ignition in
the End-gas Region) combustion. During PREMIER combustion,
initially, the combustion progresses as the premixed flame
propagation and then, due to the mixture autoignition in the end-gas
region, ahead of the propagating flame front, the transition occurs with
the rapid increase in the heat release rate.
Abstract: The paper presents a one-dimensional transient
mathematical model of compressible non-isothermal multicomponent
fluid mixture flow in a pipe. The set of the mass,
momentum and enthalpy conservation equations for gas phase is
solved in the model. Thermo-physical properties of multi-component
gas mixture are calculated by solving the Equation of State (EOS)
model. The Soave-Redlich-Kwong (SRK-EOS) model is chosen. Gas
mixture viscosity is calculated on the basis of the Lee-Gonzales-
Eakin (LGE) correlation. Numerical analysis of rapid gas
decompression process in rich and base natural gases is made on the
basis of the proposed mathematical model. The model is successfully
validated on the experimental data [1]. The proposed mathematical
model shows a very good agreement with the experimental data [1] in
a wide range of pressure values and predicts the decompression in
rich and base gas mixtures much better than analytical and
mathematical models, which are available from the open source
literature.
Abstract: Partial Discharge measurement is a very important
means of assessing the integrity of insulation systems in a High
Voltage apparatus. In compressed gas insulation systems, floating
particles can initiate partial discharge activities which adversely
affect the working of insulation. Partial Discharges below the
inception voltage also plays a crucial in damaging the integrity of
insulation over a period of time. This paper discusses the effect of
loose and fixed Copper and Nichrome wire particles on the PD
characteristics in SF6-N2 (10:90) gas mixtures at a pressure of
0.4MPa. The Partial Discharge statistical parameters and their
correlation to the observed results are discussed.
Abstract: The objective of this study was to investigate hydrogen production from alcohol wastewater by anaerobic sequencing batch reactor (ASBR) under thermophillic operation. The ASBR unit used in this study had a liquid holding volume of 4 L and was operated at 6 cycles per day. The seed sludge taken from an upflow anaerobic sludge blanket unit treating the same wastewater was boiled at 95 °C for 15 min before being fed to the ASBR unit. The ASBR system was operated at different COD loading rates at a thermophillic temperature (55 °C), and controlled pH of 5.5. When the system was operated under optimum conditions (providing maximum hydrogen production performance) at a feed COD of 60 000 mg/l, and a COD loading rate of 68 kg/m3 d, the produced gas contained 43 % H2 content in the produced gas. Moreover, the hydrogen yield and the specific hydrogen production rate (SHPR) were 130 ml H2/g COD removed and 2100 ml H2/l d, respectively.
Abstract: Aldehydes as secondary lipid oxidation products are highly specific to the oxidative degradation of particular polyunsaturated fatty acids present in foods. Gas chromatographic analysis of those volatile compounds has been widely used for monitoring of the deterioration of food products. Developed static headspace gas chromatography method using flame ionization detector (SHS GC FID) was applied to monitor the aldehydes present in processed foods such as bakery, meat and confectionary products.
Five selected aldehydes were determined in samples without any sample preparation, except grinding for bakery and meat products. SHS–GC analysis allows the separation of propanal, pentanal, hexanal, heptanal and octanal, within 15min. Aldehydes were quantified in fresh and stored samples, and the obtained range of aldehydes in crackers was 1.62±0.05 – 9.95±0.05mg/kg, in sausages 6.62±0.46 – 39.16±0.39mg/kg; and in cocoa spread cream 0.48±0.01 – 1.13±0.02mg/kg. Referring to the obtained results, the following can be concluded, proposed method is suitable for different types of samples, content of aldehydes varies depending on the type of a sample, and differs in fresh and stored samples of the same type.
Abstract: A theoretical study is conducted to design and explore
the effect of different parameters such as heat loads, the tube size of
piping system, wick thickness, porosity and hole size on the
performance and capability of a Loop Heat Pipe(LHP). This paper
presents a steady state model that describes the different phenomena
inside a LHP. Loop Heat Pipes(LHPs) are two-phase heat transfer
devices with capillary pumping of a working fluid. By their original
design comparing with heat pipes and special properties of the
capillary structure, they-re capable of transferring heat efficiency for
distances up to several meters at any orientation in the gravity field,
or to several meters in a horizontal position. This theoretical model is
described by different relations to satisfy important limits such as
capillary and nucleate boiling. An algorithm is developed to predict
the size of the LHP satisfying the limitations mentioned above for a
wide range of applied loads. Finally, to assess and evaluate the
algorithm and all the relations considered, we have used to design a
new kind of LHP to recover the heat from the exhaust of an actual
Gas Turbine. By finding the results, it showed that we can use the
LHP as a very high efficient device to recover the heat even in high
amount of loads(exhaust of a gas turbine). The sizes of all parts of the
LHP were obtained using the developed algorithm.
Abstract: Proteins or genes that have similar sequences are likely to perform the same function. One of the most widely used techniques for sequence comparison is sequence alignment. Sequence alignment allows mismatches and insertion/deletion, which represents biological mutations. Sequence alignment is usually performed only on two sequences. Multiple sequence alignment, is a natural extension of two-sequence alignment. In multiple sequence alignment, the emphasis is to find optimal alignment for a group of sequences. Several applicable techniques were observed in this research, from traditional method such as dynamic programming to the extend of widely used stochastic optimization method such as Genetic Algorithms (GAs) and Simulated Annealing. A framework with combination of Genetic Algorithm and Simulated Annealing is presented to solve Multiple Sequence Alignment problem. The Genetic Algorithm phase will try to find new region of solution while Simulated Annealing can be considered as an alignment improver for any near optimal solution produced by GAs.
Abstract: A new fast correlation algorithm for calibrating the
wavelength of Optical Spectrum Analyzers (OSAs) was introduced
in [1]. The minima of acetylene gas spectra were measured and
correlated with saved theoretical data [2]. So it is possible to find the
correct wavelength calibration data using a noisy reference spectrum.
First tests showed good algorithmic performance for gas line spectra
with high noise. In this article extensive performance tests were made
to validate the noise resistance of this algorithm. The filter and
correlation parameters of the algorithm were optimized for improved
noise performance. With these parameters the performance of this
wavelength calibration was simulated to predict the resulting
wavelength error in real OSA systems. Long term simulations were
made to evaluate the performance of the algorithm over the lifetime
of a real OSA.
Abstract: This paper has examined the energy consumption characteristics in six different buildings including apartments, offices, commercial buildings, hospitals, hotels and educational facilities. Then 5-hectare (50000m2) development site for respective building-s type has been assumed as case study to evaluate the introduction effect of Combined Heat and Power (CHP). All kinds of CHP systems with different distributed generation technologies including Gas Turbine (GT), Gas Engine (GE), Diesel Engine (DE), Solid Oxide Fuel Cell (SOFC) and Polymer Electrolyte Fuel Cell (PEFC), have been simulated by using HEATMAP, CHP system analysis software. And their primary energy utilization efficiency, energy saving ratio and CO2 reduction ratio have evaluated and compared respectively. The results can be summarized as follows: Various buildings have their special heat to power ratio characteristics. Matching the heat to power ratio demanded from an individual building with that supplied from a CHP system is very important. It is necessary to select a reasonable distributed generation technologies according to the load characteristics of various buildings. Distributed generation technologies with high energy generating efficiency and low heat to power ratio, like SOFC and PEFC is more reasonable selection for Building Combined Heat and Power (BCHP). CHP system is an attractive option for hotels, hospitals and apartments in Japan. The users can achieve high energy saving and environmental benefit by introducing a CHP systems. In others buildings, especially like commercial buildings and offices, the introduction of CHP system is unreasonable.
Abstract: One of the important applications of gas turbines is
their utilization for heat recovery steam generator in combine-cycle technology. Exhaust flow and energy are two key parameters for
determining heat recovery steam generator performance which are mainly determined by the main gas turbine components performance
data. For this reason a method was developed for determining the
exhaust energy in the new edition of ASME PTC22. The result of this investigation shows that the method of standard has considerable
error. Therefore in this paper a new method is presented for modifying of the performance calculation. The modified method is
based on exhaust gas constituent analysis and combustion calculations. The case study presented here by two kind of General
Electric gas turbine design data for validation of methodologies. The
result shows that the modified method is more precise than the ASME PTC22 method. The exhaust flow calculation deviation from
design data is 1.5-2 % by ASME PTC22 method so that the deviation regarding with modified method is 0.3-0.5%. Based on precision of
analyzer instruments, the method can be suitable alternative for gas
turbine standard performance test. In advance two methods are
proposed based on known and unknown fuel in modified method procedure. The result of this paper shows that the difference between
the two methods is below than %0.02. In according to reasonable esult of the second procedure (unknown fuel composition), the
method can be applied to performance evaluation of gas turbine, so that the measuring cost and data gathering should be reduced.
Abstract: The previous researches focused on the influence of
anthropogenic greenhouse gases exerting global warming, but not
consider whether desert sand may warm the planet, this could be
improved by accounting for sand's physical and geometric properties.
Here we show, sand particles (because of their geometry) at the desert
surface form an extended surface of up to 1 + π/4 times the planar area
of the desert that can contact sunlight, and at shallow depths of the
desert form another extended surface of at least 1 + π times the planar
area that can contact air. Based on this feature, an enhanced heat
exchange system between sunlight, desert sand, and air in the spaces
between sand particles could be built up automatically, which can
increase capture of solar energy, leading to rapid heating of the sand
particles, and then the heating of sand particles will dramatically heat
the air between sand particles. The thermodynamics of deserts may
thus have contributed to global warming, especially significant to
future global warming if the current desertification continues to
expand.
Abstract: Recent research has shown that milk proteins can
yield bioactive peptides with opioid, mineral binding,
cytomodulatory, antihypertensive, immunostimulating, antimicrobial
and antioxidative activity in the human body. Bioactive peptides are
encrypted in milk proteins and are only released by enzymatic
hydrolysis in vivo during gastrointestinal digestion, food processing
or by microbial enzymes in fermented products. At present
significant research is being undertaken on the health effects of
bioactive peptides. A variety of naturally formed bioactive peptides
have been found in fermented dairy products, such as yoghurt, sour
milk and cheese. In particular, antihypertensive peptides have been
identified in fermented milks, whey and ripened cheese. Some of
these peptides have been commercialized in the form of fermented
milks. Bioactive peptides have the potential to be used in the
formulation of health-enhancing nutraceuticals, and as potent drugs
with well defined pharmacological effects.
Abstract: To produce sugar and ethanol, sugarcane processing
generates several agricultural residues, being straw and bagasse is
considered as the main among them. And what to do with this
residues has been subject of many studies and experiences in an
industry that, in recent years, highlighted by the ability to transform
waste into valuable products such as electric power. Cellulose is the
main component of these materials. It is the most common organic
polymer and represents about 1.5 x 1012 tons of total production of
biomass per year and is considered an almost inexhaustible source of
raw material. Pretreatment with mineral acids is one of the most
widely used as stage of cellulose extraction from lignocellulosic
materials for solubilizing most of the hemicellulose content. This
study had as goal to find the best reaction time of sugarcane bagasse
pretreatment with sulfuric acid in order to minimize the losses of
cellulose concomitantly with the highest possible removal of
hemicellulose and lignin. It was found that the best time for this
reaction was 40 minutes, in which it was reached a loss of
hemicelluloses around 70% and lignin and cellulose, around 15%.
Over this time, it was verified that the cellulose loss increased and
there was no loss of lignin and hemicellulose.
Abstract: In recent years, there have been attempts to store
natural gas in adsorptive form. This is called adsorptive natural gas,
or ANG. The problem with this technology is the low sorption
capacity. The purpose is to achieve compressed natural gas (CNG)
capacity of 230 V/V. Further research is required to achieve such
target. Several research studies have been performed with this target;
through either the modification or development of new sorbents or
the optimization of the operation sorption process itself. In this work,
storage of methane on molecular sieves 5A and 13X was studied on
dry basis, and on wet basis to certain extent. The temperature and the
pressure dynamics were investigated. The results indicated that
regardless of the charge pressure, the time for the peak temperature
during the methane charge process is always the same. This can be
used as a characteristic of the adsorbent. The total achieved
deliveries using molecular sieves were much lower than that of
activated carbons; 53.0 V/V for the case of 13X molecular sieves and
43 V/V for the case of 5A molecular sieves, both at 2oC and 4 MPa
(580 psi). Investigation of charge pressure dynamic using wet
molecular sieves at 2oC and a mass ratio of 0.5, revealed slowness of
the process and unexpected behavior.
Abstract: CO2 miscible displacement is not feasible in many oil fields due to high reservoir temperature as higher pressure is required to achieve miscibility. The miscibility pressure is far higher than the formation fracture pressure making it impossible to have CO2 miscible displacement. However, by using oleophilic chemicals, minimum miscibility pressure (MMP) could be lowered. The main objective of this research is to find the best oleophilic chemical in MMP reduction using slim-tube test and Vanishing Interfacial Tension (VIT) The chemicals are selected based on the characteristics that it must be oil soluble, low water solubility, have 4 – 8 carbons, semi polar, economical, and safe for human operation. The families of chemicals chosen are carboxylic acid, alcohol, and ketone. The whole experiment would be conducted at 100°C and the best chemical is said to be effective when it is able to lower CO2-crude oil MMP the most. Findings of this research would have great impact to the oil and gas industry in reduction of operation cost for CO2EOR which is applicable to both onshore and offshore operation.