Abstract: This first-attempt study revealed that decolorized
intermediates of azo dyes could act as redox mediators to assist
wastewater (WW) decolorization due to enhancement of
electron-transport phenomena. Electrochemical impedance spectra
indicated that hydroxyl and amino-substituent(s) were functional
group(s) as redox-mediator(s). As azo dyes are usually multiple
benzene-rings structured, their derived decolorized intermediates are
likely to play roles of electron shuttles due to lower barrier of energy
gap for electron shuttling. According to cyclic voltammetric profiles,
redox mediating characteristics of decolorized intermediates of azo
dyes (e.g., RBu171, RR198, RR141, RBk5) were clearly disclosed.
With supplementation of biodecolorized metabolites of RR141 and
198, decolorization performance of could be evidently augmented.
This study also suggested the optimal modes of microbial fuel cell
(MFC)-assisted WW decolorization would be plug-flow or batch
mode of operation with no mix. Single chamber-MFCs would be more
favourable than double chamber MFCs due to non-mixing contacting
reactor scheme for operation.
Abstract: A broadband wire monopole antenna loaded by inhomogeneous stack of annular dielectric ring resonators (DRRs) is proposed. The proposed antenna exhibits a broad impedance bandwidth from 3 to 30 GHz. This is achieved by adding an external step matching network at the antenna feed point. The matching network is comprised of three annular DRRs possessing different permittivity values and sharing the same axial over a finite ground plane. The antenna performance is characterized using full-wave EM simulation. Compared to previous-reported wire antennas with improved bandwidth achieved by DRRs, the proposed topology provides relatively compact realization and superior broadband performance.
Abstract: In this article was evaluated the protective effect of
the alternative concrete obtained from the binary mixture of fly ash,
and iron and steel slag. After mixing the cement with aggregates,
structural steel was inserted in the matrix cementitious. The study
was conducted comparatively with specimens exposed to natural
conditions free of chloride ion. The chloride ion effect on the
specimens accelerated under controlled conditions (3.5% NaCl and
25°C temperature). The impedance data were acquired in a range of 1
mHz to 100 kHz.
Abstract: In this paper, various methods of providing restricted
earth fault protection are discussed. The proper operation of high and
low impedance Restricted Earth Fault (REF) protection for various
applications has been discussed. The maloperation of a relay due to
improper placement of CTs has been identified and a simple/unique
solution has been proposed in this work with a case study. Moreover,
it is found that the proper placement of CT in high impedance method
will provide the same result with reduced CT. This methodology has
been successfully implemented in Al Takreer refinery for a 2000
KVA transformer. The outcome of the paper may be included in
IEEEC37.91 standard to give the proper guidance for protection
engineers to sort out the issues related to mal functioning of REF
relays.
Abstract: This paper proposes for the first time symbolic
formula of the power spectrum of CMOS Cross Couple Oscillator
and its modified circuit. Many principles existed to derived power
spectrum in microwave textbook such as impedance, admittance
parameters, ABCD, H parameters, etc. It can be compared by graph
of power spectrum which methodology is the best from the point of
view of practical measurement setup such as condition of impedance
parameter which used superposition of current to derived (its current
injection at the other port of the circuit is zero, which is impossible in
reality). Four graphs of impedance parameters of cross couple
oscillator are proposed. After that four graphs of scattering
parameters of CMOS cross coupled oscillator will be shown.
Abstract: The effect of carbon nanofibers (CNFs) on the
electrical properties of Poly(vinylidene fluoride-hexafluoropropylene)
(P(VdF-HFP)) based gel polymer electrolytes has been investigated
in the present work. The length and diameter ranges of CNFs used in
the present work are 5-50 μm and 200-600 nm respectively. The
nanocomposite gel polymer electrolytes have been synthesized by
solution casting technique with varying CNFs content in terms of
weight percentage. Electrochemical impedance analysis demonstrates
that the reinforcement of carbon nanofibers significantly enhances the
ionic conductivity of the polymer electrolyte. The decrease of
crystallinity of P(VdF-HFP) due the addition of CNFs has been
confirmed by X-ray diffraction (XRD). The interaction of CNFs with
various constituents of nanocomposite gel polymer electrolytes has
been assessed by Fourier Transform Infrared (FTIR) spectroscopy.
Moreover CNFs added gel polymer electrolytes offer superior
thermal stability as compared to that of CNFs free electrolytes as
confirmed by Thermogravimetric analysis (TGA).
Abstract: Cole-Cole parameters of 40 post-menopausal women
are compared with their DEXA bone mineral density measurements.
Impedance characteristics of four extremities are compared; left and
right extremities are statistically same, but lower extremities are
statistically different than upper ones due to their different fat
content. The correlation of Cole-Cole impedance parameters to bone
mineral density (BMD) is observed to be higher for dominant arm.
With the post-menopausal population, ANOVA tests of the dominant
arm characteristic frequency, as a predictor for DEXA classified
osteopenic and osteoporic population around lumbar spine, is
statistically very significant. When used for total lumbar spine
osteoporosis diagnosis, the area under the Receiver Operating Curve
of the characteristic frequency is 0.830, suggesting that the Cole-Cole
plot characteristic frequency could be a useful diagnostic parameter
when integrated into standard screening methods for osteoporosis.
Moreover, the characteristic frequency can be directly measured by
monitoring frequency driven angular behavior of the dominant arm
without performing any complex calculation.
Abstract: The microstrip antennas area has seen some inventive
work in recent years and is now one of the most dynamic fields of
antenna theory. A novel and simple wideband monopole antenna is
presented printed on a single dielectric substrate which is fed by a 50
ohm microstrip line having a low-profile antenna structure with two
parallel s-shaped meandered line of same size. This antenna is fed by
a coaxial feeding tube. In this research, S–form microstrip patch antenna is designed from
measuring the prototypes of the proposed antenna one available
bands with 10db return loss bandwidths of about GPS application
(GPS L2 1490 MHz) and covering the 1400 to 1580 MHz frequency
band at 1.5 GHz, the simulated results for main parameters such as
return loss, impedance bandwidth, radiation patterns, and gains are
also discussed herein. The modeling study shows that such antennas,
in simplicity design and supply, can satisfy GPS application. Two
parallel slots are incorporated to disturb the surface flow path,
introducing local inductive effect. This antenna is fed by a coaxial
feeding tube.
Abstract: In this work new macroporous Ni electrodes modified
with Au nanoparticles for hydrogen production have been developed.
The supporting macroporous Ni electrodes have been obtained by
means of the electrodeposition at high current densities. Then, the Au
nanoparticles were synthesized and added to the electrode surface.
The electrocatalytic behaviour of the developed electrocatalysts was
studied by means of pseudo-steady-state polarization curves,
electrochemical impedance spectroscopy (EIS) and hydrogen
discharge curves. The size of the Au synthetized nanoparticles shows
a monomodal distribution, with a very sharp band between 10 and 50
nm. The characteristic parameters d10, d50 and d90 were 14, 20 and
31 nm respectively. From Tafel polarization data has been concluded
that the Au nanoparticles improve the catalytic activity of the
developed electrodes towards the HER respect to the macroporous Ni
electrodes. EIS permits to obtain the electrochemically active area by
means of the roughness factor value. All the developed electrodes
show roughness factor values in the same order of magnitude. From
the activation energy results it can be concluded that the Au
nanoparticles improve the intrinsic catalytic activity of the
macroporous Ni electrodes.
Abstract: This paper investigates simple implicit force control
algorithms realizable with industrial robots. A lot of approaches
already published are difficult to implement in commercial robot
controllers, because the access to the robot joint torques is necessary
or the complete dynamic model of the manipulator is used. In
the past we already deal with explicit force control of a position
controlled robot. Well known schemes of implicit force control are
stiffness control, damping control and impedance control. Using such
algorithms the contact force cannot be set directly. It is further
the result of controller impedance, environment impedance and
the commanded robot motion/position. The relationships of these
properties are worked out in this paper in detail for the chosen
implicit approaches. They have been adapted to be implementable
on a position controlled robot. The behaviors of stiffness control
and damping control are verified by practical experiments. For this
purpose a suitable test bed was configured. Using the full mechanical
impedance within the controller structure will not be practical in the
case when the robot is in physical contact with the environment. This
fact will be verified by simulation.
Abstract: Background: Worldwide, at least 2.8 million people
die each year as a result of being overweight or obese, and 35.8
million (2.3%) of global DALYs are caused by overweight or
obesity. Obesity is acknowledged as one of the burning public
health problems reducing life expectancy and quality of life. The
body composition analysis of the university population is essential
in assessing the nutritional status, as well as the risk of developing
diseases associated with abnormal body fat content so as to make
nutritional recommendations. Objectives: The main aim was to
determine the prevalence of obesity and overweight in University
students using Anthropometric analysis and BIA methods. Material
and Methods: In this cross-sectional study, 283 university students
participated. The body composition analysis was undertaken by
using mainly: i) Anthropometric Measurement: Height, Weight,
BMI, waist circumference, hip circumference and skin fold
thickness, ii) Bio-electrical impedance was used for analysis of
body fat mass, fat percent and visceral fat which was measured by
Tanita SC-330P Professional Body Composition Analyzer. The
data so collected were compiled in MS Excel and analyzed for
males and females using SPSS 16. Results and Discussion: The
mean age of the male (n= 153) studied subjects was 25.37 ±2.39
years and females (n=130) was 22.53 ±2.31. The data of BIA
revealed very high mean fat per cent of the female subjects i.e.
30.3±6.5 per cent whereas mean fat per cent of the male subjects
was 15.60±6.02 per cent indicating a normal body fat range. The
findings showed high visceral fat of both males (12.92±3.02) and
females (16.86±4.98). BMI, BF% and WHR were higher among
females, and BMI was higher among males. The most evident
correlation was verified between BF% and WHR for female
students (r=0.902; p
Abstract: Dielectric ceramic samples in the BaO-Re2O3-TiO2
ternary system were synthesized with structural formula Ba2-
xRe4+2x/3Ti8O24 where Re= rare earth metal and Re= Sm and La where
x varies from 0.0 to 0.6 with step size 0.1. Polycrystalline samples
were prepared by the conventional solid state reaction technique. The
dielectric, electrical and impedance analysis of all the samples in the
frequency range 1KHz- 1MHz at room temperature (25°C) have been
done to get the understanding of electrical conduction and dielectric
relaxation and their correlation. Dielectric response of the samples at
lower frequencies shows dielectric dispersion while at higher
frequencies it shows dielectric relaxation. The ac conductivity is well
fitted by the Jonscher law. The spectroscopic data in the impedance
plane confirms the existence of grain contribution to the relaxation.
All the properties are found out to be function of frequency as well as
the amount of substitution.
Abstract: The atmospheres in many cities along the coastal lines
in the world have been rapidly changed to coastal-industrial
atmosphere. Hence, it is vital to investigate the corrosion behavior of
steel exposed to this kind of environment. In this present study,
Electrochemical Impedance Spectrography (EIS) and film thickness
measurement were applied to monitor the corrosion behavior of
weathering steel covered with a thin layer of the electrolyte in a
wet-dry cyclic condition, simulating a coastal-industrial environment
at 25oC and 60% RH. The results indicate that in all cycles, the
corrosion rate increases during the drying process due to an increase in
anion concentration and an acceleration of oxygen diffusion enhanced
by the effect of the thinning out of the electrolyte. During the wet-dry
cyclic corrosion test, the long-term corrosion behavior of this steel
depends on the periods of exposure. Corrosion process is first
accelerated and then decelerated. The decelerating corrosion process is
contributed to the formation of the protective rust, favored by the
wet-dry cycle and the acid regeneration process during the rusting
process.
Abstract: The coaxial transformer-coupled push-pull circuitry
has been used widely in HF and VHF amplifiers for many decades
without significant changes in the topology of the transformers. Basic
changes over the years concerned the construction and turns ratio of
the transformers as has been imposed upon the newer technologies
active devices demands. The balun transmission line transformers
applied in push-pull amplifiers enable input/output impedance
transformation, but are mainly used to convert the balanced output
into unbalanced and the input unbalanced into balanced. A simple
and affordable alternative solution over the traditional coaxial
transformer is the coreless planar balun. A key advantage over the
traditional approach lies in the high specifications repeatability;
simplifying the amplifier construction requirements as the planar
balun constitutes an integrated part of the PCB copper layout. This
paper presents the performance analysis of a planar LDMOS
MRFE6VP5600 Push-Pull amplifier that enables robust operation in
Band III, DVB-T, DVB-T2 standards but functions equally well in
Band II, for DRM+ new generation transmitters.
Abstract: In the present work, Electrochemical Impedance
Spectrocopy (EIS) is applied to study the transport of different metal
cations through a cation-exchange membrane. This technique enables
the identification of the ionic-transport characteristics and to
distinguish between different transport mechanisms occurring at
different current density ranges. The impedance spectra are
dependent on the applied dc current density, on the type of cation and
on the concentration.
When the applied dc current density increases, the diameter of the
impedance spectra loops increases because all the components of
membrane system resistance increase. The diameter of the impedance
plots decreases in the order of Na(I), Ni(II) and Cr(III) due to the
increased interactions between the negatively charged sulfonic
groups of the membrane and the cations with greater charge. Nyquist
plots are shifted towards lower values of the real impedance, and its
diameter decreases with the increase of concentration due to the
decrease of the solution resistance.
Abstract: Early diagnosis of infection like Hep-B virus in blood
is important for low cost medical treatment. For this purpose, it is
desirable to develop a point of care device which should be able to
detect trace quantities of the target molecule in blood. In this paper,
we report a nanoporous silicon oxide sensor which is capable of
detecting down to 1fM concentration of Hep-B surface antigen in
blood without the requirement of any centrifuge or pre-concentration.
This has been made possible by the presence of resonant peak in the
sensitivity characteristics. This peak is observed to be dependent only
on the concentration of the specific antigen and not on the interfering
species in blood serum. The occurrence of opposite impedance
change within the pores and at the bottom of the pore is responsible
for this effect. An electronic interface has also been designed to
provide a display of the virus concentration.
Abstract: Today’s VLSI networks demands for high speed. And
in this work the compact form mathematical model for current mode
signalling in VLSI interconnects is presented.RLC interconnect line
is modelled using characteristic impedance of transmission line and
inductive effect. The on-chip inductance effect is dominant at lower
technology node is emulated into an equivalent resistance. First order
transfer function is designed using finite difference equation, Laplace
transform and by applying the boundary conditions at the source and
load termination. It has been observed that the dominant pole
determines system response and delay in the proposed model. The
novel proposed current mode model shows superior performance as
compared to voltage mode signalling. Analysis shows that current
mode signalling in VLSI interconnects provides 2.8 times better
delay performance than voltage mode. Secondly the damping factor
of a lumped RLC circuit is shown to be a useful figure of merit.
Abstract: In recent years parasitic antenna play major role in
MIMO systems because of their gain and spectral efficiency. In this
paper, single RF chain MIMO transmitter is designed using
reconfigurable parasitic antenna. The Spatial Modulation (SM) is a
recently proposed scheme in MIMO scenario which activates only
one antenna at a time. The SM entirely avoids ICI and IAS, and only
requires a single RF chain at the transmitter. This would switch ON a
single transmit-antenna for data transmission while all the other
antennas are kept silent. The purpose of the parasitic elements is to
change the radiation pattern of the radio waves which is emitted from
the driven element and directing them in one direction and hence
introduces transmit diversity. Diode is connect between the patch and
ground by changing its state (ON and OFF) the parasitic element act
as reflector and director and also capable of steering azimuth and
elevation angle. This can be achieved by changing the input
impedance of each parasitic element through single RF chain. The
switching of diode would select the single parasitic antenna for
spatial modulation. This antenna is expected to achieve maximum
gain with desired efficiency.
Abstract: This paper presents circuit models to analyze the
conducted susceptibility of multiconductor shielded cables in
frequency domains using Branin’s method, which is referred to as the
method of characteristics. These models, which can be used directly
in the time and frequency domains, take into account the presence of
both the transfer impedance and admittance. The conducted
susceptibility is studied by using an injection current on the cable
shield as the source. Two examples are studied; a coaxial shielded
cable and shielded cables with two parallel wires (i.e., twinax cables).
This shield has an asymmetry (one slot on the side). Results obtained
by these models are in good agreement with those obtained by other
methods.
Abstract: Paints are the most widely used methods of protection
against atmospheric corrosion of metals. The aim of this work was to
determine the protective performance of epoxy coating against sea
water before and after damage.
Investigations are conducted using stationary and non-stationary
electrochemical tools such as electrochemical impedance
spectroscopy has allowed us to characterize the protective qualities of
these films. The application of the EIS on our damaged in-situ
painting shows the existence of several capacitive loops which is an
indicator of the failure of our tested paint. Microscopic analysis
(micrograph) helped bring essential elements in understanding the
degradation of our paint condition and immersion training corrosion
products.