Abstract: This first-attempt study revealed that decolorized
intermediates of azo dyes could act as redox mediators to assist
wastewater (WW) decolorization due to enhancement of
electron-transport phenomena. Electrochemical impedance spectra
indicated that hydroxyl and amino-substituent(s) were functional
group(s) as redox-mediator(s). As azo dyes are usually multiple
benzene-rings structured, their derived decolorized intermediates are
likely to play roles of electron shuttles due to lower barrier of energy
gap for electron shuttling. According to cyclic voltammetric profiles,
redox mediating characteristics of decolorized intermediates of azo
dyes (e.g., RBu171, RR198, RR141, RBk5) were clearly disclosed.
With supplementation of biodecolorized metabolites of RR141 and
198, decolorization performance of could be evidently augmented.
This study also suggested the optimal modes of microbial fuel cell
(MFC)-assisted WW decolorization would be plug-flow or batch
mode of operation with no mix. Single chamber-MFCs would be more
favourable than double chamber MFCs due to non-mixing contacting
reactor scheme for operation.
Abstract: Online measurement of the product quality is a
challenging task in cement production, especially in the production of
Celitement, a novel environmentally friendly hydraulic binder. The
mineralogy and chemical composition of clinker in ordinary Portland
cement production is measured by X-ray diffraction (XRD) and
X-ray fluorescence (XRF), where only crystalline constituents can be
detected. But only a small part of the Celitement components can be
measured via XRD, because most constituents have an amorphous
structure. This paper describes the development of algorithms
suitable for an on-line monitoring of the final processing step of
Celitement based on NIR-data. For calibration intermediate products
were dried at different temperatures and ground for variable
durations. The products were analyzed using XRD and
thermogravimetric analyses together with NIR-spectroscopy to
investigate the dependency between the drying and the milling
processes on one and the NIR-signal on the other side. As a result,
different characteristic parameters have been defined. A short
overview of the Celitement process and the challenging tasks of the
online measurement and evaluation of the product quality will be
presented. Subsequently, methods for systematic development of
near-infrared calibration models and the determination of the final
calibration model will be introduced. The application of the model on
experimental data illustrates that NIR-spectroscopy allows for a quick
and sufficiently exact determination of crucial process parameters.
Abstract: Average temperatures worldwide are expected to
continue to rise. At the same time, major cities in developing
countries are becoming increasingly populated and polluted.
Governments are tasked with the problem of overheating and air
quality in residential buildings. This paper presents the development
of a model, which is able to estimate the occupant exposure
to extreme temperatures and high air pollution within domestic
buildings. Building physics simulations were performed using the
EnergyPlus building physics software. An accurate metamodel is
then formed by randomly sampling building input parameters and
training on the outputs of EnergyPlus simulations. Metamodels are
used to vastly reduce the amount of computation time required when
performing optimisation and sensitivity analyses. Neural Networks
(NNs) have been compared to a Radial Basis Function (RBF)
algorithm when forming a metamodel. These techniques were
implemented using the PyBrain and scikit-learn python libraries,
respectively. NNs are shown to perform around 15% better than RBFs
when estimating overheating and air pollution metrics modelled by
EnergyPlus.
Abstract: The increase in electric power demand in face of
environmental issues has intensified the participation of renewable
energy sources such as photovoltaics, in the energy matrix of various
countries. Due to their operational characteristics, they can generate
time-varying harmonic and inter-harmonic distortions. For this
reason, the application of methods of measurement based on
traditional Fourier analysis, as proposed by IEC 61000-4-7, can
provide inaccurate results. Considering the aspects mentioned herein,
came the idea of the development of this work which aims to present
the results of a comparative evaluation between a methodology
arising from the combination of the Prony method with the Kalman
filter and another method based on the IEC 61000-4-30 and IEC
61000-4-7 standards. Employed in this study were synthetic signals
and data acquired through measurements in a 50kWp photovoltaic
installation.
Abstract: Highly stable and homogeneously dispersed amino
acid coated silver nanoparticles (ANP) of ≈ 10 nm diameter, ranging
from 420 to 430 nm are prepared on AgNO3 solution addition to gum
of Azadirachta indica solution at 373.15 K. The amino acids were
selected based on their polarity. The synthesized nanoparticles were
characterized by UV-Vis, FTIR spectroscopy, HR-TEM, XRD, SEM
and 1H-NMR. The coated nanoparticles were used as catalyst for the
reduction of methylene blue dye in presence of Sn(II) in aqueous,
anionic and cationic micellar media. The rate of reduction of dye was
determined by measuring the absorbance at 660 nm,
spectrophotometrically and followed the order: Kcationic > Kanionic >
Kwater. After 12 min and in absence of the ANP, only 2%, 3% and 6%
of the dye reduction was completed in aqueous, anionic and cationic
micellar media respectively while, in presence of ANP coated by
polar neutral amino acid with non-polar -R group, the reduction
completed to 84%, 95% and 98% respectively. The ANP coated with
polar neutral amino acid having non-polar -R group, increased the
rate of reduction of the dye by 94, 3205 and 6370 folds in aqueous,
anionic and cationic micellar media respectively. Also, the rate of
reduction of the dye increased by three folds when the micellar media
was changed from anionic to cationic when the ANP is coated by a
polar neutral amino acid having a non-polar -R group.
Abstract: This paper focuses on the mathematical modeling for
solidification of Al alloy in a cube mold cavity to study the
solidification behavior of casting process. The parametric
investigation of solidification process inside the cavity was
performed by using computational solidification/melting model
coupled with Volume of fluid (VOF) model. The implicit filling
algorithm is used in this study to understand the overall process from
the filling stage to solidification in a model metal casting process.
The model is validated with past studied at same conditions. The
solidification process is analyzed by including the effect of pouring
velocity as well as natural convection from the wall and geometry of
the cavity. These studies show the possibility of various defects
during solidification process.
Abstract: Bezier curves have useful properties for path
generation problem, for instance, it can generate the reference
trajectory for vehicles to satisfy the path constraints. Both algorithms
join cubic Bezier curve segment smoothly to generate the path. Some
of the useful properties of Bezier are curvature. In mathematics,
curvature is the amount by which a geometric object deviates from
being flat, or straight in the case of a line. Another extrinsic example
of curvature is a circle, where the curvature is equal to the reciprocal
of its radius at any point on the circle. The smaller the radius, the
higher the curvature thus the vehicle needs to bend sharply. In this
study, we use Bezier curve to fit highway-like curve. We use
different approach to find the best approximation for the curve so that
it will resembles highway-like curve. We compute curvature value by
analytical differentiation of the Bezier Curve. We will then compute
the maximum speed for driving using the curvature information
obtained. Our research works on some assumptions; first, the Bezier
curve estimates the real shape of the curve which can be verified
visually. Even though, fitting process of Bezier curve does not
interpolate exactly on the curve of interest, we believe that the
estimation of speed are acceptable. We verified our result with the
manual calculation of the curvature from the map.
Abstract: In this paper, according to the classical algorithm
LSQR for solving the least-squares problem, an iterative method is
proposed for least-squares solution of constrained matrix equation. By
using the Kronecker product, the matrix-form LSQR is presented to
obtain the like-minimum norm and minimum norm solutions in a
constrained matrix set for the symmetric arrowhead matrices. Finally,
numerical examples are also given to investigate the performance.
Abstract: In this paper, von Mises and Drucker-Prager yield criteria, as typical ones that consider the effect of intermediate principal stress σ2, have been selected and employed for investigating the influence of σ2 on the solution of a typical stability problem. The bearing capacity factors have been calculated under plane strain condition (strip footing) and axisymmetric condition (circular footing) using the method of stress characteristics together with the criteria mentioned. Different levels of σ2 relative to the other two principal stresses have been considered. While a higher σ2 entry in yield criterion gives a higher bearing capacity; its entry in equilibrium equations (axisymmetric) causes substantial reduction.
Abstract: Since the advances in digital imaging technologies have led to
development of high quality digital devices, there are a lot of illegal copies
of copyrighted video content on the Internet. Also, unauthorized editing is
occurred frequently. Thus, we propose an editing prevention technique for
high-quality (HQ) video that can prevent these illegally edited copies from
spreading out. The proposed technique is applied spatial and temporal gradient
methods to improve the fidelity and detection performance. Also, the scheme
duplicates the embedding signal temporally to alleviate the signal reduction
caused by geometric and signal-processing distortions. Experimental results
show that the proposed scheme achieves better performance than previously
proposed schemes and it has high fidelity. The proposed scheme can be used
in unauthorized access prevention method of visual communication or traitor
tracking applications which need fast detection process to prevent illegally
edited video content from spreading out.
Abstract: As one of the convenient and noninvasive sensing
approaches, the automatic limb girth measurement has been applied
to detect intention behind human motion from muscle deformation.
The sensing validity has been elaborated by preliminary researches
but still need more fundamental studies, especially on kinetic
contraction modes. Based on the novel fabric strain sensors, a soft
and smart limb girth measurement system was developed by the
authors’ group, which can measure the limb girth in-motion.
Experiments were carried out on elbow isometric flexion and elbow
isokinetic flexion (biceps’ isokinetic contractions) of 90°/s, 60°/s, and
120°/s for 10 subjects (2 canoeists and 8 ordinary people). After
removal of natural circumferential increments due to elbow position,
the joint torque is found not uniformly sensitive to the limb
circumferential strains, but declining as elbow joint angle rises,
regardless of the angular speed. Moreover, the maximum joint torque
was found as an exponential function of the joint’s angular speed.
This research highly contributes to the application of the automatic
limb girth measuring during kinetic contractions, and it is useful to
predict the contraction level of voluntary skeletal muscles.
Abstract: Rivers have transient storage or dead zones where
injected pollutants or solutes are entrapped for considerable period of
time, known as residence time, before being released into the main
flowing zones of rivers. In this study, a new empirical expression for
residence time, implementing genetic programming on published
dispersion data, has been derived. The proposed expression uses few
hydraulic and geometric characteristics of rivers which are normally
known to the authorities. When compared with some reported
expressions, based on various statistical indices, it can be concluded
that the proposed expression predicts the residence time of pollutants
in natural rivers more accurately.
Abstract: This paper aimed to introduce the solution of concrete
slump recovery using chemical admixture type-F (superplasticizer,
naphthalene base) to the practice in order to solve unusable concrete
problem due to concrete loss its slump, especially for those tropical
countries that have faster slump loss rate. In the other hand, randomly
adding superplasticizer into concrete can cause concrete to segregate.
Therefore, this paper also develops the estimation model used to
calculate amount of second dose of superplasticizer need for concrete
slump recovery. Fresh properties of ordinary Portland cement
concrete with volumetric ratio of paste to void between aggregate
(paste content) of 1.1-1.3 with water-cement ratio zone of 0.30 to
0.67 and initial superplasticizer (naphthalene base) of 0.25%-1.6%
were tested for initial slump and slump loss for every 30 minutes for
one and half hour by slump cone test. Those concretes with slump
loss range from 10% to 90% were re-dosed and successfully
recovered back to its initial slump. Slump after re-dosed was tested
by slump cone test. From the result, it has been concluded that, slump
loss was slower for those mix with high initial dose of
superplasticizer due to addition of superplasticizer will disturb
cement hydration. The required second dose of superplasticizer was
affected by two major parameters, which were water-cement ratio
and paste content, where lower water-cement ratio and paste content
cause an increase in require second dose of superplasticizer. The
amount of second dose of superplasticizer is higher as the solid
content within the system is increase, solid can be either from cement
particles or aggregate. The data was analyzed to form an equation use
to estimate the amount of second dosage requirement of
superplasticizer to recovery slump to its original.
Abstract: The end panels of a large rectangular industrial duct,
which experience significant internal pressures, also experience
considerable transverse shear due to transfer of gravity loads to the
supports. The current design practice of such thin plate panels for
shear load is based on methods used for the design of plate girder
webs. The structural arrangements, the loadings and the resulting
behavior associated with the industrial duct end panels are, however,
significantly different from those of the web of a plate girder. The
large aspect ratio of the end panels gives rise to multiple bands of
tension fields, whereas the plate girder web design is based on one
tension field. In addition to shear, the industrial end panels are
subjected to internal pressure which in turn produces significant
membrane action. This paper reports a study which was undertaken
to review the current industrial analysis and design methods and to
propose a comprehensive method of designing industrial duct end
panels for shear resistance. In this investigation, a nonlinear finite element model was
developed to simulate the behavior of industrial duct end panel, along
with the associated edge stiffeners, subjected to transverse shear and
internal pressures. The model considered the geometric imperfections
and constitutive relations for steels. Six scale independent
dimensionless parameters that govern the behavior of such end panel
were identified and were then used in a parametric study. It was
concluded that the plate slenderness dominates the shear strength of
stockier end panels, and whereas, both the plate slenderness and the
aspect ratio influence the shear strength of slender end panels. Based
on these studies, this paper proposes design aids for estimating the
shear strength of rectangular duct end panels.
Abstract: The Haussmannization plan of Cairo in 1867 formed a
regular network of roundabout spaces, though deteriorated at present.
The method of identifying the spatial structure of roundabout Cairo
for conservation matches the voronoi diagram with the space syntax
through their geometrical property of spatial convexity. In this
initiative, the primary convex hull of first-order voronoi adopts the
integral and control measurements of space syntax on Cairo’s
roundabout generators. The functional essence of royal palaces
optimizes the roundabout structure in terms of spatial measurements
and the symbolic voronoi projection of 'Tahrir Roundabout' over the
Giza Nile and Pyramids. Some roundabouts of major public and
commercial landmarks surround the pole of 'Ezbekia Garden' with a
higher control than integral measurements, which filter the new
spatial structure from the adjacent traditional town. Nevertheless, the
least integral and control measures correspond to the voronoi
contents of pollutant workshops and the plateau of old Cairo Citadel
with the visual compensation of new royal landmarks on top.
Meanwhile, the extended suburbs of infinite voronoi polygons
arrange high control generators of chateaux housing in 'garden city'
environs. The point pattern of roundabouts determines the
geometrical characteristics of voronoi polygons. The measured
lengths of voronoi edges alternate between the zoned short range at
the new poles of Cairo and the distributed structure of longer range.
Nevertheless, the shortest range of generator-vertex geometry
concentrates at 'Ezbekia Garden' where the crossways of vast Cairo
intersect, which maximizes the variety of choice at different spatial
resolutions. However, the symbolic 'Hippodrome' which is the largest
public landmark forms exclusive geometrical measurements, while
structuring a most integrative roundabout to parallel the royal syntax.
Overview of the symbolic convex hull of voronoi with space syntax
interconnects Parisian Cairo with the spatial chronology of scattered
monuments to conceive one universal Cairo structure. Accordingly,
the approached methodology of 'voronoi-syntax' prospects the future
conservation of roundabout Cairo at the inferred city-level concept.
Abstract: The aim of the study was to investigate the effect of
Saccharomyces cerevisiae (SC) live yeast culture on microbial
protein supply to small intestine in Kivircik male yearlings when fed
with different ratio of forage and concentrate diets. Four Kivircik
male yearlings with permanent rumen canula were used in the
experiment. The treatments were allocated to a 4x4 Latin square
design. Diet I consisted of 70% alfalfa hay and 30% concentrate, Diet
II consisted of 30% alfalfa hay and 70% concentrate, Diet I and II
were supplemented with a SC. Daily urine was collected and stored at
-20°C until analysis. Calorimetric methods were used for the
determination of urinary allantoin and creatinine levels. The
estimated microbial N supply to small intestine for Diets I, I+SC, II
and II+SC were 2.51, 2.64, 2.95 and 3.43 g N/d respectively.
Supplementation of Diets I and II with SC significantly affected the
allantoin levels in μmol/W0.75 (p
Abstract: The aim of this work is to detect geometrical shape
objects in an image. In this paper, the object is considered to be as a
circle shape. The identification requires find three characteristics,
which are number, size, and location of the object. To achieve the
goal of this work, this paper presents an algorithm that combines
from some of statistical approaches and image analysis techniques.
This algorithm has been implemented to arrive at the major
objectives in this paper. The algorithm has been evaluated by using
simulated data, and yields good results, and then it has been applied
to real data.
Abstract: The aim of this study is to evaluate the effect of
supplementing broiler starter diet with different levels of an essential
oil blend (EOB) containing capsaicin, carvacrol and cinnamaldehyde
on the performance of broilers. A total of 300 day-old straight-run
Cobb broiler chicks were randomly assigned to three treatments after
7-day group brooding following a completely randomized design
(CRD). Birds assigned in treatment 1 were given starter basal diet
while those in treatments 2 and 3 were given starter basal diet with
400 mg/kg antibiotic growth promoter (AGP) and 150 mg/kg EOB,
respectively, until the 28th day. Basal finisher feed were given for all
the treatments until harvest. Following 37 d feeding, body weight
gain, feed consumption, feed efficiency, dressing percentage,
livability and jejunal villi height were determined. Results showed no
significant differences (P>0.05) in growth performance. However,
villi height and crypt depth was significantly lower for birds fed
EOB.
Abstract: Background: Breast milk may impact early brain
development, with potentially important biological, medical and
social implications. There is an important discussion on which is the
adequate breastfeeding extension to the development consolidation
and how the children breastfeeding affects their psychomotor
development, in the first year of life, and in following periods as
well. Some special fats (LC PUFA) contained in breast milk play a
key role in the brain’s maturation and cognitive development or
social skills. These capacities created during breastfeeding time
would be unfolded throughout all lifespan. Aim of the study: In our research, we have studied the effect of
breastfeeding in preschooler's psychomotor assessment.
Method: This study was conducted in a sample of 158 preschool
children in Vlorë, Albania. We have measured the psychometric
parameters of preschoolers with ASQ-3 (Age&Stage Questionnaires-
3). The studied sample was divided in three groups according to their
breastfeeding duration (3, 6 and 12 months). Results: Children breastfed for only 3 months have definitely
lower psychometric scores compared to the ones with 6 or more
months of breastfeeding (respectively 217 to 239 ASQ-3 scores). Six
and twelvemonth breastfed children have progressively more odds to
have high levels of psychomotor development comparing to those
with only 3 months of breastfeeding. The most affected psychometric
domains by shortness of breastfeeding are Communication and
Global motor. Conclusion: This leads to conclusion that to ensure high
psychomotor parameters during childhood is necessary breastfeeding
for at least 6 months.
Abstract: The floor beams of steel buildings, cold-formed steel
floor joists in particular, often require large web openings, which may
affect their shear capacities. A cost effective way to mitigate the
detrimental effects of such openings is to weld/fasten reinforcements.
A difficulty associated with an experimental investigation to establish
suitable reinforcement schemes for openings in shear zone is that
moment always coexists with the shear, and thus, it is impossible to
create pure shear state in experiments, resulting in moment
influenced results. However, Finite Element Method (FEM) based
analysis can be conveniently used to investigate the pure shear
behaviour of webs including webs with reinforced openings. This
paper presents the details associated with the finite element analysis
of thick/thin-plates (representing the web of hot-rolled steel beam,
and the web of a cold-formed steel member) having a large
reinforced opening. The study considered simply-supported
rectangular plates subjected to in-plane shear loadings until failure
(including post-buckling behaviour). The plate was modelled using
geometrically non-linear quadrilateral shell elements, and non-linear
stress-strain relationship based on experiments. Total Langrangian
with large displacement/small strain formulation was used for such
analyses. The model also considered the initial geometric
imperfections. This study considered three reinforcement schemes,
namely, flat, lip, and angle reinforcements. This paper discusses the
modelling considerations and presents the results associated with the
various reinforcement schemes under consideration.