Abstract: In the following text, we show that by introducing
universal kinetic scheme, the origin of rate retardation and inhibition
period which observed in dithiobenzoate-mediated RAFT
polymerization can be described properly. We develop our model by
utilizing the method of moments, then we apply our model to
different monomer/RAFT agent systems, both homo- and
copolymerization. The modeling results are in an excellent
agreement with experiments and imply the validity of universal
kinetic scheme, not only for dithiobenzoate-mediated systems, but
also for different types of monomer/RAFT agent ones.
Abstract: In recent years, there has been an increasing interest in using daylight to save energy in buildings. In tropical regions, daylighting is always an energy saver. On the other hand, daylight provides visual comfort. According to standards, it shows that many criteria should be taken into consideration in order to have daylight utilization and visual comfort. The current standard in Malaysia, MS 1525 does not provide sufficient guideline. Hence, more research is needed on daylight performance. If architects do not consider daylight design, it not only causes inconvenience in working spaces but also causes more energy consumption as well as environmental pollution. This research had surveyed daylight performance in 5 selected office buildings from different area of Malaysian through experimental method. Several parameters of daylight quality such as daylight factor, surface luminance and surface luminance ratio were measured in different rooms in each building. The result of this research demonstrated that most of the buildings were not designed for daylight utilization. Therefore, it is very important that architects follow the daylight design recommendation to reduce consumption of electric power for artificial lighting while the sufficient quality of daylight is available.
Abstract: An effective approach for realizing the binary tree structure, representing a combinational logic functionality with enhanced throughput, is discussed in this paper. The optimization in maximum operating frequency was achieved through delay minimization, which in turn was possible by means of reducing the depth of the binary network. The proposed synthesis methodology has been validated by experimentation with FPGA as the target technology. Though our proposal is technology independent, yet the heuristic enables better optimization in throughput even after technology mapping for such Boolean functionality; whose reduced CNF form is associated with a lesser literal cost than its reduced DNF form at the Boolean equation level. For cases otherwise, our method converges to similar results as that of [12]. The practical results obtained for a variety of case studies demonstrate an improvement in the maximum throughput rate for Spartan IIE (XC2S50E-7FT256) and Spartan 3 (XC3S50-4PQ144) FPGA logic families by 10.49% and 13.68% respectively. With respect to the LUTs and IOBUFs required for physical implementation of the requisite non-regenerative logic functionality, the proposed method enabled savings to the tune of 44.35% and 44.67% respectively, over the existing efficient method available in literature [12].
Abstract: Using a force balanced translational-radial dynamics,
phase space of the moving single bubble sonoluminescence (m-
SBSL) in 85% wt sulfuric acid has been numerically calculated. This
phase space is compared with that of single bubble sonoluminescence
(SBSL) in pure water which has been calculated by using the mere
radial dynamics. It is shown that in 85% wt sulfuric acid, in a general
agreement with experiment, the bubble-s positional instability
threshold lays under the shape instability threshold. At the onset of
spatial instability of moving sonoluminescing (SL) bubble in 85%
wt sulfuric acid, temporal effects of the hydrodynamic force on the
bubble translational-radial dynamics have been investigated. The
appearance of non-zero history force on the moving SL bubble is
because of proper condition which was produced by high viscosity of
acid. Around the moving bubble collapse due to the rapid contraction
of the bubble wall, the inertial based added mass force overcomes the
viscous based history force and induces acceleration on the bubble
translational motion.
Abstract: Subcritical water extraction was investigated as a
novel and alternative technology in the food and pharmaceutical
industry for the separation of Mannitol from olive leaves and its
results was compared with those of Soxhlet extraction. The effects of
temperature, pressure, and flow rate of water and also momentum
and mass transfer dimensionless variables such as Reynolds and
Peclet Numbers on extraction yield and equilibrium partition
coefficient were investigated. The 30-110 bars, 60-150°C, and flow
rates of 0.2-2 mL/min were the water operating conditions. The
results revealed that the highest Mannitol yield was obtained at
100°C and 50 bars. However, extraction of Mannitol was not
influenced by the variations of flow rate. The mathematical modeling
of experimental measurements was also investigated and the model is
capable of predicting the experimental measurements very well. In
addition, the results indicated higher extraction yield for the
subcritical water extraction in contrast to Soxhlet method.
Abstract: This study was conducted to investigate the efficacy
of five herbicides on narrow leaved weeds and growth and yield of
wheat. An experiment was conducted at Agronomic Research
Farm, University of Agriculture Faisalabad. The experiment was
laid out in randomized complete block designee (RCBD) with three
replications. Treatments studied were clodinafop (Topic-15 WG) at
37 g a.i. ha-1, clodinafop (Topaz-15 WG) at 45 g a.i. ha-1,
fenoxaprop-p-ethyl (Puma Super-75 EW) at 45 g a.i. ha-1,
fenoxaprop-p-ethyl (Gramicide-6.9 EW) at 85 g a.i. ha-1,
fenoxaprop-p-ethyl (Chinlima-6.9 EW) at 85 g a.i. ha-1 and weedy
check. Plots treated with fenoxaprop-p-ethyl (Puma Super-75 EW)
at 45 g a.i. ha-1 produced relatively less weed biomass, more plant
height, number of spike bearing tillers, number of grains per spike,
1000-grain weight and grain yield (4.20 t ha-1).
Abstract: The main objective of this study was to determine if a
minimal increase in road light level (luminance) could lead to
improved driving performance among older adults. Older, middleaged
and younger adults were tested in a driving simulator following
vision and cognitive screening. Comparisons were made for the
performance of simulated night driving under two road light
conditions (0.6 and 2.5 cd/m2). At each light level, the effects of self
reported night driving avoidance were examined along with the
vision/cognitive performance. It was found that increasing road light
level from 0.6 cd/m2 to 2.5 cd/m2 resulted in improved recognition of
signage on straight highway segments. The improvement depends on
different driver-related factors such as vision and cognitive abilities,
and confidence. On curved road sections, the results showed that
driver-s performance worsened. It is concluded that while increasing
road lighting may be helpful to older adults especially for sign
recognition, it may also result in increased driving confidence and
thus reduced attention in some driving situations.
Abstract: Ciprofloxacin (CIP) and Carbamazepine (CBZ), nonbiodegradable pharmaceutical residues, were become emerging pollutants in several aquatic environments. The objectives of this research were to study the possibility to recover these pharmaceuticals residues from pharmaceutical wastewater by increasing the selective adsorption on synthesized functionalized porous silicate, comparing with powdered activated carbon (PAC). Hexagonal mesoporous silicate (HMS), functionalized HMSs (3- aminopropyltriethoxy, 3- mercaptopropyltrimethoxy and noctyldimethyl) were synthesized and characterized physico-chemical characteristics. Obtained adsorption kinetics and isotherms showed that 3-mercaptopropyltrimethoxy functional groups grafted on HMS provided highest CIP and CBZ adsorption capacities; however, it was still lower than that of PAC. The kinetic results were compatible with pseudo-second order. The hydrophobicity and hydrogen bonding might play a key role on the adsorption. Furthermore, the capacities were affected by varying pH values due to the strength of hydrogen bonding between targeted compounds and adsorbents. Electrostatic interaction might not affect the adsorption capacities.
Abstract: This paper is taken into consideration the problem of cryptanalysis of stream ciphers. There is some attempts need to improve the existing attacks on stream cipher and to make an attempt to distinguish the portions of cipher text obtained by the encryption of plain text in which some parts of the text are random and the rest are non-random. This paper presents a tutorial introduction to symmetric cryptography. The basic information theoretic and computational properties of classic and modern cryptographic systems are presented, followed by an examination of the application of cryptography to the security of VoIP system in computer networks using LFSR algorithm. The implementation program will be developed Java 2. LFSR algorithm is appropriate for the encryption and decryption of online streaming data, e.g. VoIP (voice chatting over IP). This paper is implemented the encryption module of speech signals to cipher text and decryption module of cipher text to speech signals.
Abstract: Polyurethanes (PURs) are very versatile polymeric
materials with a wide range of physical and chemical properties.
PURs have desirable properties such as high abrasion resistance, tear
strength, shock absorption, flexibility and elasticity. Although they
have relatively poor thermal stability, this can be improved by using
treated clay. Polyurethane/clay nanocomposites have been
synthesized from renewable sources. A polyol for the production of
polyurethane by reaction with an isocyanate was obtained by the
synthesis of palm oil-based oleic acid with glycerol. Dodecylbenzene
sulfonic acid (DBSA) was used as catalyst and emulsifier. The
unmodified clay (kunipia-F) was treated with cetyltrimethyl
ammonium bromide (CTAB-mont) and octadodecylamine (ODAmont).
The d-spacing in CTAB-mont and ODA-mont were 1.571 nm
and 1.798 nm respectively and larger than that of the pure-mont
(1.142 nm). The organoclay was completely intercalated in the
polyurethane, as confirmed by a wide angle x-ray diffraction
(WAXD) pattern.
The results showed that adding clay demonstrated better thermal
stability in comparison with the virgin polyurethane. Onset
degradation of pure PU is at 200oC, and is lower than that of the
CTAB-mont PU and ODA-mont PU which takes place at about
318oC and 330oC, respectively. The mechanical properties (including
the dynamic mechanical properties) of pure polyurethane (PU) and
PU/clay nanocomposites, were measured. The modified organoclay
had a remarkably beneficial effect on the strength and elongation at
break of the nanocomposites, which both increased with increasing
clay content with the increase of the tensile strength of more than
214% and 267% by the addition of only 5 wt% of the
montmorillonite CTAB-mont PU and ODA-mont PU, respectively.
Abstract: Genetic algorithms (GAs) have been widely used for
global optimization problems. The GA performance depends highly
on the choice of the search space for each parameter to be optimized.
Often, this choice is a problem-based experience. The search space
being a set of potential solutions may contain the global optimum
and/or other local optimums. A bad choice of this search space
results in poor solutions. In this paper, our approach consists in
extending the search space boundaries during the GA optimization,
only when it is required. This leads to more diversification of GA
population by new solutions that were not available with fixed search
space boundaries. So, these dynamic search spaces can improve the
GA optimization performances. The proposed approach is applied to
power system stabilizer optimization for multimachine power system
(16-generator and 68-bus). The obtained results are evaluated and
compared with those obtained by ordinary GAs. Eigenvalue analysis
and nonlinear system simulation results show the effectiveness of the
proposed approach to damp out the electromechanical oscillation and
enhance the global system stability.
Abstract: We summarize information that facilitates choosing an ontology language for knowledge intensive applications. This paper is a short version of the ontology language state-of-the-art and evolution analysis carried out for choosing an ontology language in the IST Esperonto project. At first, we analyze changes and evolution that took place in the filed of Semantic Web languages during the last years, in particular, around the ontology languages of the RDF/S and OWL family. Second, we present current trends in development of Semantic Web languages, in particular, rule support extensions for Semantic Web languages and emerging ontology languages such as WSMO languages.
Abstract: In this paper, an extended method of the directionally constrained minimization of power (DCMP) algorithm for broadband signals is proposed. The DCMP algorithm is one of the useful techniques of extracting a target signal from observed signals of a microphone array system. In the DCMP algorithm, output power of the microphone array is minimized under a constraint of constant responses to directions of arrival (DOAs) of specific signals. In our algorithm, by limiting the directional constraint to the perpendicular direction to the sensor array system, the calculating time is reduced.
Abstract: In this paper, a new dependable algorithm based on an adaptation of the standard variational iteration method (VIM) is used for analyzing the transition from steady convection to chaos for lowto-intermediate Rayleigh numbers convection in porous media. The solution trajectories show the transition from steady convection to chaos that occurs at a slightly subcritical value of Rayleigh number, the critical value being associated with the loss of linear stability of the steady convection solution. The VIM is treated as an algorithm in a sequence of intervals for finding accurate approximate solutions to the considered model and other dynamical systems. We shall call this technique as the piecewise VIM. Numerical comparisons between the piecewise VIM and the classical fourth-order Runge–Kutta (RK4) numerical solutions reveal that the proposed technique is a promising tool for the nonlinear chaotic and nonchaotic systems.
Abstract: Cassava is one of the top five crops in Cameroon. Its
evolution has remained constant since the independence period and
the production has more than tripled. It is a crop with multiple
industrial capacities but the sector-s business opportunities are
underexploited. Using Strengths, Weaknesses, Opportunities and
Threats analysis method, this paper examines the cassava actual state.
It appraises the sector-s strengths (S), considers suitable measures to
strengthen weaknesses (W), evaluates strategies to fully benefit from
the sector numerous business opportunities (O) and explore means to
convert threats (T) into opportunities. Data were collected from the
ministry of agriculture and rural development and different actors.
The results show that cassava sector embodies many business
opportunities and stands as a raw material provider for many
industries but ultimately requires challenges to be tackled
appropriately.
Abstract: From the beginning of creation, human being has ever
fought against the ecosystem by changes has made in environment.
The most environmental changes on the nature have been done after
starting the concentrated life in the same region. Dams are one of the
most important buildings in water resources and transferring. These
buildings have been made from old times without access to
hydrological, hydraulically, hydro mechanical information. Dams
have positive and negative effects on environment. Constructing a
dam relatively causes equal ecological consequences. According to
different criteria, environmental effects of dams can lead short term
and long term damages. These effects may influence on the situation
and treatment of meteorology, biology, culture, ancient works, etc
and severely causes to change and complicate it. So considering
importance of positive effects of dam construction, it is necessary to
minimize negative environmental effects of dams to achieve a stable
development. In this article the considered effects and their solutions
in influencing on assessment of destructive environmental effects of
dams construction have been surveyed and presented.
Abstract: the purpose of this research is to identify and clarify
factors which have positive effect among user satisfaction and their
social networking through websites. The examined factors in this
research are; innovation, ease of use, trustworthy and customer
support which are defined as satisfaction factors. To obtain reliable
research approaches and to have better result in this research four
hypothesizes used to test. This hypothesis testing has been done by
correlation, regression and test of normality by using “SPSS16" also
the data which was analyzed by this software. this data was gathered
from prepaid questionnaire.
Abstract: This paper addresses linear quadratic regulation (LQR)
for variable speed variable pitch wind turbines. Because of the
inherent nonlinearity of wind turbine, a set of operating conditions is
identified and then a LQR controller is designed for each operating
point. The feedback controller gains are then interpolated linearly to
get control law for the entire operating region. Besides, the
aerodynamic torque and effective wind speed are estimated online to
get the gain-scheduling variable for implementing the controller. The
potential of the method is verified through simulation with the help of
MATLAB/Simulink and GH Bladed. The performance and
mechanical load when using LQR are also compared with that when
using PI controller.
Abstract: Environmental contamination is a common problem in ex-industrial and industrial sites. This article gives a brief description of general applied environmental investigation methodologies and possible remediation applications in Latvia. Most of contaminated areas are situated in former and active industrial, military areas and ports. Industrial and logistic activities very often have been with great impact for more than hundred years thus the contamination level with heavy metals, hydrocarbons, pesticides, persistent organic pollutants is high and is threatening health and environment in general. 242 territories now are numbered as contaminated and fixed in the National Register of contaminated territories in Latvia. Research and remediation of contamination in densely populated areas are of important environmental policy domain. Four different investigation case studies of contaminated areas are given describing the history of use, environmental quality assessment as well as planned environmental management actions. All four case study locations are situated in Riga - the capital of the Republic of Latvia. The aim of this paper is to analyze the situation and problems with management of contaminated areas in Latvia, give description of field research methods and recommendations for remediation industry based on scientific data and innovations.
Abstract: The paper presents the design of a mini-UAV attitude
controller using the backstepping method. Starting from the nonlinear
dynamic equations of the mini-UAV, by using the backstepping
method, the author of this paper obtained the expressions of the
elevator, rudder and aileron deflections, which stabilize the UAV, at
each moment, to the desired values of the attitude angles. The attitude
controller controls the attitude angles, the angular rates, the angular
accelerations and other variables that describe the UAV longitudinal
and lateral motions. To design the nonlinear controller, by using the
backstepping technique, the nonlinear equations and the Lyapunov
analysis have been directly used. The designed controller has been
implemented in Matlab/Simulink environment and its effectiveness
has been tested with a campaign of numerical simulations using data
from the UAV flight tests. The obtained results are very good and
they are better than the ones found in previous works.