Abstract: An efficient and green method for oxidation of thiols
to the corresponding disulfides is reported using ionic liquid
[HSO3N(C2H4OSO3H)3] in the presence of free nano-Fe2O3 at 60°C.
Ionic liquid is selective oxidant for S-S Coupling variety aliphatic
and aromatic of thiols to corresponding disulfide in the presence of
free nano-Fe2O3 as recoverable catalyst. Reaction has been performed
in methanol as an inexpensive solvent. This reaction is clean and easy
work-up with no side reaction.
Abstract: Electric vehicles are one of the most complicated
electric devices to simulate due to the significant number of different
processes involved in electrical structure of it. There are concurrent
processes of energy consumption and generation with different
onboard systems, which make simulation tasks more complicated to
perform. More accurate simulation on energy consumption can
provide a better understanding of all energy management for electric
transport. As a result of all those processes, electric transport can
allow for a more sustainable future and become more convenient in
relation to the distance range and recharging time. This paper
discusses the problems of energy consumption simulations for
electric vehicles using different software packages to provide ideas
on how to make this process more precise, which can help engineers
create better energy management strategies for electric vehicles.
Abstract: The purpose of this study is to examine the possible
link between employee and customer satisfaction. The service
provided by employees, help to build a good relationship with
customers and can help at increasing their loyalty. Published data for
job satisfaction and indicators of customer services of banks were
gathered from relevant published works which included data from
five different countries. The scores of customers and employees
satisfaction of the different published works were transformed and
normalized to the scale of 1 to 100. The data were analyzed and a
regression analysis of the two parameters was used to describe the
link between employee’s satisfaction and customer’s satisfaction.
Assuming that employee satisfaction has a significant influence on
customer’s service and the resulting customer satisfaction, the
reviewed data indicate that employee’s satisfaction contributes
significantly on the level of customer satisfaction in the Banking
sector. There was a significant correlation between the two
parameters (Pearson correlation R2=0.52 P
Abstract: Web-based Cognitive Writing Instruction (WeCWI)’s
contribution towards language development can be divided into
linguistic and non-linguistic perspectives. In linguistic perspective,
WeCWI focuses on the literacy and language discoveries, while the
cognitive and psychological discoveries are the hubs in non-linguistic
perspective. In linguistic perspective, WeCWI draws attention to free
reading and enterprises, which are supported by the language
acquisition theories. Besides, the adoption of process genre approach
as a hybrid guided writing approach fosters literacy development.
Literacy and language developments are interconnected in the
communication process; hence, WeCWI encourages meaningful
discussion based on the interactionist theory that involves input,
negotiation, output, and interactional feedback. Rooted in the elearning
interaction-based model, WeCWI promotes online
discussion via synchronous and asynchronous communications,
which allows interactions happened among the learners, instructor,
and digital content. In non-linguistic perspective, WeCWI highlights
on the contribution of reading, discussion, and writing towards
cognitive development. Based on the inquiry models, learners’
critical thinking is fostered during information exploration process
through interaction and questioning. Lastly, to lower writing anxiety,
WeCWI develops the instructional tool with supportive features to
facilitate the writing process. To bring a positive user experience to
the learner, WeCWI aims to create the instructional tool with
different interface designs based on two different types of perceptual
learning style.
Abstract: In this paper we describe the Levenvberg-Marquardt
(LM) algorithm for identification and equalization of CDMA
signals received by an antenna array in communication channels.
The synthesis explains the digital separation and equalization of
signals after propagation through multipath generating intersymbol
interference (ISI). Exploiting discrete data transmitted and three
diversities induced at the reception, the problem can be composed
by the Block Component Decomposition (BCD) of a tensor of
order 3 which is a new tensor decomposition generalizing the
PARAFAC decomposition. We optimize the BCD decomposition by
Levenvberg-Marquardt method gives encouraging results compared to
classical alternating least squares algorithm (ALS). In the equalization
part, we use the Minimum Mean Square Error (MMSE) to perform
the presented method. The simulation results using the LM algorithm
are important.
Abstract: There is decagram of strategic decisions of operations
and production/service management (POSM) within operational
research (OR) which must collate, namely: design, inventory, quality,
location, process and capacity, layout, scheduling, maintain ace, and
supply chain. This paper presents an architectural configuration
conceptual framework of a decagram of sets decisions in a form of
mathematical complete graph and abelian graph.
Mathematically, a complete graph is undirected (UDG), and
directed (DG) a relationship where every pair of vertices is
connected, collated, confluent, and holomorphic.
There has not been any study conducted which, however,
prioritizes the holomorphic sets which of POMS within OR field of
study. The study utilizes OR structured technique known as The
Analytic Hierarchy Process (AHP) analysis for organizing, sorting
and prioritizing(ranking) the sets within the decagram of POMS
according to their attribution (propensity), and provides an analysis
how the prioritization has real-world application within the 21st
century.
Abstract: In this study, the performance analyses of the twenty
five Coal-Fired Power Plants (CFPPs) used for electricity generation
are carried out through various Data Envelopment Analysis (DEA)
models. Three efficiency indices are defined and pursued. During the
calculation of the operational performance, energy and non-energy
variables are used as input, and net electricity produced is used as
desired output (Model-1). CO2 emitted to the environment is used as
the undesired output (Model-2) in the computation of the pure
environmental performance while in Model-3 CO2 emissions is
considered as detrimental input in the calculation of operational and
environmental performance. Empirical results show that most of the
plants are operating in increasing returns to scale region and Mettur
plant is efficient one with regards to energy use and environment.
The result also indicates that the undesirable output effect is
insignificant in the research sample. The present study will provide
clues to plant operators towards raising the operational and
environmental performance of CFPPs.
Abstract: The Roma (Gypsies) is a transnational minority with a
high degree of consanguineous marriages. Similar to other
genetically isolated founder populations, the Roma harbor a number
of unique or rare genetic disorders. This paper discusses about a rare
form of Charcot-Marie-Tooth disease – type 4G (CMT4G), also
called Hereditary Motor and Sensory Neuropathy type Russe, an
autosomal recessive disease caused by mutation private to Roma
characterized by abnormally increased density of non-myelinated
axons. CMT4G was originally found in Bulgarian Roma and in 2009
two putative causative mutations in the HK1 gene were identified.
Since then, several cases were reported in Roma families mainly
from Bulgaria and Spain. Here we present a Slovak Roma family in
which CMT4G was diagnosed on the basis of clinical examination
and genetic testing. This case is a further proof of the role of the HK1
gene in pathogenesis of the disease. It confirms that mutation in the
HK1 gene is a common cause of autosomal recessive CMT disease in
Roma and should be considered as a common part of a diagnostic
procedure.
Abstract: Environmental impacts of six 3D printers using
various materials were compared to determine if material choice
drove sustainability, or if other factors such as machine type, machine
size, or machine utilization dominate. Cradle-to-grave life-cycle
assessments were performed, comparing a commercial-scale FDM
machine printing in ABS plastic, a desktop FDM machine printing in
ABS, a desktop FDM machine printing in PET and PLA plastics, a
polyjet machine printing in its proprietary polymer, an SLA machine
printing in its polymer, and an inkjet machine hacked to print in salt
and dextrose. All scenarios were scored using ReCiPe Endpoint H
methodology to combine multiple impact categories, comparing
environmental impacts per part made for several scenarios per
machine. Results showed that most printers’ ecological impacts were
dominated by electricity use, not materials, and the changes in
electricity use due to different plastics was not significant compared
to variation from one machine to another. Variation in machine idle
time determined impacts per part most strongly. However, material
impacts were quite important for the inkjet printer hacked to print in
salt: In its optimal scenario, it had up to 1/38th the impacts coreper
part as the worst-performing machine in the same scenario. If salt
parts were infused with epoxy to make them more physically robust,
then much of this advantage disappeared, and material impacts
actually dominated or equaled electricity use. Future studies should
also measure DMLS and SLS processes / materials.
Abstract: One of the major difficulties introduced with wind
power penetration is the inherent uncertainty in production originating
from uncertain wind conditions. This uncertainty impacts many
different aspects of power system operation, especially the balancing
power requirements. For this reason, in power system development
planing, it is necessary to evaluate the potential uncertainty in future
wind power generation. For this purpose, simulation models are
required, reproducing the performance of wind power forecasts.
This paper presents a wind power forecast error simulation models
which are based on the stochastic process simulation. Proposed
models capture the most important statistical parameters recognized
in wind power forecast error time series. Furthermore, two distinct
models are presented based on data availability. First model uses
wind speed measurements on potential or existing wind power plant
locations, while the seconds model uses statistical distribution of wind
speeds.
Abstract: Modular structural systems are constructed using a
method that they are assembled with prefabricated unit modular
frames on-site. This provides a benefit that can significantly reduce
building construction time. The structural design is usually carried out
under the assumption that their load-carrying mechanism is similar to
that of traditional steel moment-resisting systems. However, both
systems are different in terms of beam-column connection details
which may strongly influence the lateral structural behavior. Specially,
the presence of access holes in a beam-column joint of a unit modular
frame could cause undesirable failure during strong earthquakes.
Therefore, this study carried out finite element analyses (FEMs) of
unit modular frames to investigate the cyclic behavior of beam-column
joints with the access holes. Analysis results show that the unit
modular frames present stable cyclic response with large deformation
capacities and their joints are classified into semi-rigid connections
even if there are access holes.
Abstract: The Simulation based VLSI Implementation of
FELICS (Fast Efficient Lossless Image Compression System)
Algorithm is proposed to provide the lossless image compression and
is implemented in simulation oriented VLSI (Very Large Scale
Integrated). To analysis the performance of Lossless image
compression and to reduce the image without losing image quality
and then implemented in VLSI based FELICS algorithm. In FELICS
algorithm, which consists of simplified adjusted binary code for
Image compression and these compression image is converted in
pixel and then implemented in VLSI domain. This parameter is used
to achieve high processing speed and minimize the area and power.
The simplified adjusted binary code reduces the number of arithmetic
operation and achieved high processing speed. The color difference
preprocessing is also proposed to improve coding efficiency with
simple arithmetic operation. Although VLSI based FELICS
Algorithm provides effective solution for hardware architecture
design for regular pipelining data flow parallelism with four stages.
With two level parallelisms, consecutive pixels can be classified into
even and odd samples and the individual hardware engine is
dedicated for each one. This method can be further enhanced by
multilevel parallelisms.
Abstract: This paper describes a novel application of Fiber
Braggs Grating (FBG) sensors in the assessment of human postural
stability and balance on an unstable platform. In this work, FBG
sensor Stability Analyzing Device (FBGSAD) is developed for
measurement of plantar strain to assess the postural stability of
subjects on unstable platforms during different stances in eyes open
and eyes closed conditions on a rocker board. The studies are
validated by comparing the Centre of Gravity (CG) variations
measured on the lumbar vertebra of subjects using a commercial
accelerometer. The results obtained from the developed FBGSAD
depict qualitative similarities with the data recorded by commercial
accelerometer. The advantage of the FBGSAD is that it measures
simultaneously plantar strain distribution and postural stability of the
subject along with its inherent benefits like non-requirement of
energizing voltage to the sensor, electromagnetic immunity and
simple design which suits its applicability in biomechanical
applications. The developed FBGSAD can serve as a tool/yardstick to
mitigate space motion sickness, identify individuals who are
susceptible to falls and to qualify subjects for balance and stability,
which are important factors in the selection of certain unique
professionals such as aircraft pilots, astronauts, cosmonauts etc.
Abstract: We have developed a new computer program in
Fortran 90, in order to obtain numerical solutions of a system
of Relativistic Magnetohydrodynamics partial differential equations
with predetermined gravitation (GRMHD), capable of simulating
the formation of relativistic jets from the accretion disk of matter
up to his ejection. Initially we carried out a study on numerical
methods of unidimensional Finite Volume, namely Lax-Friedrichs,
Lax-Wendroff, Nessyahu-Tadmor method and Godunov methods
dependent on Riemann problems, applied to equations Euler in
order to verify their main features and make comparisons among
those methods. It was then implemented the method of Finite
Volume Centered of Nessyahu-Tadmor, a numerical schemes that
has a formulation free and without dimensional separation of
Riemann problem solvers, even in two or more spatial dimensions,
at this point, already applied in equations GRMHD. Finally, the
Nessyahu-Tadmor method was possible to obtain stable numerical
solutions - without spurious oscillations or excessive dissipation -
from the magnetized accretion disk process in rotation with respect
to a central black hole (BH) Schwarzschild and immersed in a
magnetosphere, for the ejection of matter in the form of jet over a
distance of fourteen times the radius of the BH, a record in terms
of astrophysical simulation of this kind. Also in our simulations,
we managed to get substructures jets. A great advantage obtained
was that, with the our code, we got simulate GRMHD equations in
a simple personal computer.
Abstract: The most important component affecting the
efficiency of photovoltaic power systems are solar panels. In other
words, efficiency of these systems are significantly affected due to
the being low efficiency of solar panel. Thus, solar panels should be
operated under maximum power point conditions through a power
converter. In this study, design of boost converter has been carried
out with maximum power point tracking (MPPT) algorithm which is
incremental conductance (Inc-Cond). By using this algorithm,
importance of power converter in MPPT hardware design, impacts of
MPPT operation have been shown. It is worth noting that initial
operation point is the main criteria for determining the MPPT
performance. In addition, it is shown that if value of load resistance is
lower than critical value, failure operation is realized. For these
analyzes, direct duty control is used for simplifying the control.
Abstract: A feeding experiment was conducted to determine the
optimum dietary protein and lipid levels for juvenile fancy carp. Eight
experimental diets were formulated to contain four protein levels (200,
300, 400 and 500 g kg-1) with two lipid levels (70 and 140 g kg-1).
Triplicate groups of fish (initial weight, 12.1±0.2 g fish-1) were
hand-fed the diets to apparent satiation for 8 weeks. Fish growth
performance, feed utilization and feed intake were significantly
(P0.05). Weight gain and feed efficiency ratio tended to
increase as dietary protein level increased up to 400 and 500 g kg-1,
respectively. Daily feed intake of fish decreased with increasing
dietary protein level and that of fish fed diet contained 500 g kg-1
protein was significantly lower than other fish groups. The protein
efficiency ratio of fish fed 400 and 500 g kg-1 protein was lower than
that of fish fed 200 and 300 g kg-1 protein. Moisture, crude protein and
crude lipid contents of muscle and liver were significantly affected by
dietary protein, but not by dietary lipid level (P>0.05). The increase in
dietary lipid level resulted in an increase in linoleic acid in liver and
muscle paralleled with a decrease in n-3 highly unsaturated fatty acids
content in muscle of fish. In considering these results, it was concluded
that the diet containing 400 g kg-1 protein with 70 g kg-1 lipid level is
optimal for growth and efficient feed utilization of juvenile fancy carp.
Abstract: Nowadays, the successful implementation of ICTs is
vital for almost any kind of organization. Good governance and ICT
management are essential for delivering value, managing
technological risks, managing resources and performance
measurement. In addition, outsourcing is a strategic IT service
solution which complements IT services provided internally in
organizations. This paper proposes the measurement tools of a new
holistic maturity model based on standards ISO/IEC 20000 and
ISO/IEC 38500, and the frameworks and best practices of ITIL and
COBIT, with a specific focus on IT outsourcing. These measurement
tools allow independent validation and practical application in the
field of higher education, using a questionnaire, metrics tables, and
continuous improvement plan tables as part of the measurement
process. Guidelines and standards are proposed in the model for
facilitating adaptation to universities and achieving excellence in the
outsourcing of IT services.
Abstract: Due to water shortage, application of saline water for
irrigation is an urgent in agriculture. In this study the effect of
calcium and potassium application as additive in saline root media for
reduce salinity adverse effects was investigated on tomato growth in
a hydroponic system with unequal distribution of salts in the root
media, which was divided in to two equal parts containing full
Johnson nutrient solution and 40 mMNaCl solution, alone or in
combination with KCl (6 mM), CaCl2 (4 mM), K+Ca (3+2 mM) or
half-strength Johnson nutrient solution. The root splits were
exchanged every 7 days. Results showed that addition of calcium,
calcium-potassium and nutrition elements equivalent to half the
concentration of Johnson formula to the saline-half of culture media
minimized the reduction in plant growth caused by NaCl, although
addition of potassium to culture media wasn’t effective. The greatest
concentration of sodium was observed at the shoot of treatments
which had smallest growth. According to the results of this study, in
case of dynamic and non-uniform distribution of salts in the root
media, by addition of additive to the saline solution, it would be
possible to use of saline water with no significant growth reduction.
Abstract: Starting in 2020, an EU-wide CO2-limitation of
95 g/km is scheduled for the average of an OEMs passenger car fleet.
Taking that into consideration additional improvement measures of
the Diesel cycle are necessary in order to reduce fuel consumption
and emissions while boosting, or at the least, keeping performance
values at the same time.
The present article deals with the possibilities of an optimized
air/water charge air cooler, also called iCAC (indirect Charge Air
Cooler) for a Diesel passenger car amongst extreme-boundary
conditions. In this context, the precise objective was to show the
impact of improved intercooling with reference to the engine working
process (fuel consumption and NOx-emissions). Several extremeboundaries
- e.g. varying ambient temperatures or mountainous
routes - that will become very important in the near future regarding
RDE (Real Driving emissions) were subject of the investigation.
With the introduction of RDE in 2017 (EU6c measure), the
controversial NEDC (New European Driving Cycle) will belong to
the past and the OEMs will have to avoid harmful emissions in any
conceivable real life situation.
This is certainly going to lead to optimization-measurements at the
powertrain, which again is going to make the implementation of
iCACs, presently solely used for the premium class, more and more
attractive for compact class cars. The investigations showed a benefit
in FC between 1 and 3% for the iCAC in real world conditions.
Abstract: Given the importance of ports as links in the global
supply chains and because they are key elements to induce
competitiveness in their hinterlands, the number of studies devoted to
port governance, management and operations has increased in the last
decades. Some of these studies address the port governance model as
an element to improve coordination among the actors of the portlogistics
chain and to generate a better port performance. In this
context, the present study analyzes the governance of Port of Santos
through individual interviews with port managers, based on a
conceptual model that considers the key dimensions associated with
port governance. The results reinforce the usefulness of the applied
model and highlight some existing improvement opportunities in the
port studied.