Abstract: A new chelating resin is prepared by coupling
Amberlite XAD-4 with 1-amino-2-naphthole through an azo spacer.
The resulting sorbent has been characterized by FT-IR, elemental
analysis and thermogravimetric analysis (TGA) and studied for
preconcentrating of Cu (II) using flame atomic absorption
spectrometry (FAAS) for metal monitoring. The optimum pH value
for sorption of the copper ions was 6.5. The resin was subjected to
evaluation through batch binding of mentioned metal ion.
Quantitative desorption occurs instantaneously with 0.5 M HNO3.
The sorption capacity was found 4.8 mmol.g-1 of resin for Cu (II) in
the aqueous solution. The chelating resin can be reused for 10 cycles
of sorption-desorption without any significant change in sorption
capacity. A recovery of 99% was obtained the metal ions with 0.5 M
HNO3 as eluting agent. The method was applied for metal ions
determination from industrial waste water sample.
Abstract: Semiconductor detector arrays are widely used in
high-temperature plasma diagnostics. They have a fast response,
which allows observation of many processes and instabilities in
tokamaks. In this paper, there are reviewed several diagnostics based
on semiconductor arrays as cameras, AXUV photodiodes (referred
often as fast “bolometers") and detectors of both soft X-rays and
visible light installed on the COMPASS tokamak recently. Fresh
results from both spring and summer campaigns in 2012 are
introduced. Examples of the utilization of the detectors are shown on
the plasma shape determination, fast calculation of the radiation
center, two-dimensional plasma radiation tomography in different
spectral ranges, observation of impurity inflow, and also on
investigation of MHD activity in the COMPASS tokamak discharges.
Abstract: White scar oyster (Crassostrea belcheri) is often eaten
raw and being the leading vehicle for foodborne disease, especially
Salmonella Weltevreden which exposed the prominent and most
resistant to radiation. Gamma irradiation at a low dose of 1 kGy was
enough to eliminate S. Weltevreden contaminated in oyster meat at a
level up to 5 log CFU/g while it still retain the raw characteristics and
equivalent sensory quality as the non-irradiated one. Process
development of ready-to-eat chilled oyster meat was conducted by
shucking the meat, individually packed in plastic bags, subjected to 1
kGy gamma radiation at chilled condition and then stored in 4oC
refrigerated temperature. Microbiological determination showed the
absence of S. Weltevreden (5 log CFU/g initial inoculated) along the
whole storage time of 30 days. Sensory evaluation indicated the
decreasing in sensory scores along storage time which determining
the product shelf life to be 18 days compared to 15 days of nonirradiated
one. The most advantage of developed process was to
provide the safe raw oyster to consumers and in addition sensory
quality retained and 3-day extension shelf life also exist.
Abstract: This study aims to demonstrate the quantification of
peptides based on isotope dilution surface enhanced Raman
scattering (IDSERS). SERS spectra of phenylalanine (Phe), leucine
(Leu) and two peptide sequences TGQIFK (T13) and
YSFLQNPQTSLCFSESIPTPSNR (T6) as part of the 22-kDa
human growth hormone (hGH) were obtained on Ag-nanoparticle
covered substrates. On the basis of the dominant Phe and Leu
vibrational modes, precise partial least squares (PLS) prediction
models were built enabling the determination of unknown T13 and
T6 concentrations. Detection of hGH in its physiological
concentration in order to investigate the possibility of protein
quantification has been achieved.
Abstract: Basic objective of this study is to create a regression
analysis method that can estimate the length of a plastic hinge which
is an important design parameter, by making use of the outcomes of
(lateral load-lateral displacement hysteretic curves) the experimental
studies conducted for the reinforced square concrete columns. For
this aim, 170 different square reinforced concrete column tests results
have been collected from the existing literature. The parameters
which are thought affecting the plastic hinge length such as crosssection
properties, features of material used, axial loading level,
confinement of the column, longitudinal reinforcement bars in the
columns etc. have been obtained from these 170 different square
reinforced concrete column tests. In the study, when determining the
length of plastic hinge, using the experimental test results, a
regression analysis have been separately tested and compared with
each other. In addition, the outcome of mentioned methods on
determination of plastic hinge length of the reinforced concrete
columns has been compared to other methods available in the
literature.
Abstract: Whereas cellular wireless communication systems are
subject to short-and long-term fading. The effect of wireless channel
has largely been ignored in most of the teletraffic assessment
researches. In this paper, a mathematical teletraffic model is proposed
to estimate blocking and forced termination probabilities of cellular
wireless networks as a result of teletraffic behavior as well as the
outage of the propagation channel. To evaluate the proposed
teletraffic model, gamma inter-arrival and general service time
distributions have been considered based on wireless channel fading
effect. The performance is evaluated and compared with the classical
model. The proposed model is dedicated and investigated in different
operational conditions. These conditions will consider not only the
arrival rate process, but also, the different faded channels models.
Abstract: The hydrolysis kinetics of polycrystalline lithium hydride (LiH) in argon at various low humidities was measured by gravimetry and Raman spectroscopy with ambient water concentration ranging from 200 to 1200 ppm. The results showed that LiH hydrolysis curve revealed a paralinear shape, which was attributed to two different reaction stages that forming different products as explained by the 'Layer Diffusion Control' model. Based on the model, a novel two-stage rate equation for LiH hydrolysis reactions was developed and used to fit the experimental data for determination of Li2O steady thickness Hs and the ultimate hydrolysis rate vs. The fitted data presented a rise of Hs as ambient water concentration cw increased. However, in spite of the negative effect imposed by Hs increasing, the upward trend of vs remained, which implied that water concentration, rather than Li2O thickness, played a predominant role in LiH hydrolysis kinetics. In addition, the proportional relationship between vsHs and cw predicted by rate equation and confirmed by gravimetric data validated the model in such conditions.
Abstract: Soil stabilization has been widely used to improve
soil strength and durability or to prevent erosion and dust generation.
Generally to reduce problems of clayey soils in engineering work and
to stabilize these soils additional materials are used. The most
common materials are lime, fly ash and cement. Using this materials,
although improve soil property , but in some cases due to financial
problems and the need to use special equipment are limited .One of
the best methods for stabilization clayey soils is neutralization the
clay particles. For this purpose we can use ion exchange materials.
Ion exchange solution like CBR plus can be used for soil
stabilization. One of the most important things in using CBR plus is
determination the amount of this solution for various soils with
different properties. In this study a laboratory experiment is conduct
to evaluate the ion exchange capacity of three soils with various
plasticity index (PI) to determine amount or required CBR plus
solution for soil stabilization.
Abstract: This paper considers the problem of Null-Steering beamforming using Neural Network (NN) approach for antenna array system. Two cases are presented. First, unlike the other authors, the estimated Direction Of Arrivals (DOAs) are used for antenna array weights NN-based determination and the imprecise DOAs estimations are taken into account. Second, the blind null-steering beamforming is presented. In this case the antenna array outputs are presented at the input of the NN without DOAs estimation. The results of computer simulations will show much better relative mean error performances of the first NN approach compared to the NNbased blind beamforming.
Abstract: In this work a novel approach for color image
segmentation using higher order entropy as a textural feature for
determination of thresholds over a two dimensional image histogram
is discussed. A similar approach is applied to achieve multi-level
thresholding in both grayscale and color images. The paper discusses
two methods of color image segmentation using RGB space as the
standard processing space. The threshold for segmentation is decided
by the maximization of conditional entropy in the two dimensional
histogram of the color image separated into three grayscale images of
R, G and B. The features are first developed independently for the
three ( R, G, B ) spaces, and combined to get different color
component segmentation. By considering local maxima instead of the
maximum of conditional entropy yields multiple thresholds for the
same image which forms the basis for multilevel thresholding.
Abstract: Biochemical Oxygen Demand (BOD) is a measure of
the oxygen used in bacteria mediated oxidation of organic substances
in water and wastewater. Theoretically an infinite time is required for
complete biochemical oxidation of organic matter, but the
measurement is made over 5-days at 20 0C or 3-days at 27 0C test
period with or without dilution. Researchers have worked to further
reduce the time of measurement.
The objective of this paper is to review advancement made in
BOD measurement primarily to minimize the time and negate the
measurement difficulties. Survey of literature review in four such
techniques namely BOD-BARTTM, Biosensors, Ferricyanidemediated
approach, luminous bacterial immobilized chip method.
Basic principle, method of determination, data validation and their
advantage and disadvantages have been incorporated of each of the
methods.
In the BOD-BARTTM method the time lag is calculated for the
system to change from oxidative to reductive state. BIOSENSORS
are the biological sensing element with a transducer which produces
a signal proportional to the analyte concentration. Microbial species
has its metabolic deficiencies. Co-immobilization of bacteria using
sol-gel biosensor increases the range of substrate. In ferricyanidemediated
approach, ferricyanide has been used as e-acceptor instead
of oxygen. In Luminous bacterial cells-immobilized chip method,
bacterial bioluminescence which is caused by lux genes was
observed. Physiological responses is measured and correlated to
BOD due to reduction or emission.
There is a scope to further probe into the rapid estimation of BOD.
Abstract: Natural frequencies and dynamic response of a spur
gear sector are investigated using a two dimensional finite element
model that offers significant advantages for dynamic gear analyses.
The gear teeth are analyzed for different operating speeds. A primary
feature of this modeling is determination of mesh forces using a
detailed contact analysis for each time step as the gears roll through
the mesh. ANSYS software has been used on the proposed model to
find the natural frequencies by Block Lanczos technique and
displacements and dynamic stresses by transient mode super position
method. The effect of rotational speed of the gear on the dynamic
response of gear tooth has been studied and design limits have been
discussed.
Abstract: Green house effect has becomes a serious concern in
many countries due to the increase consumption of the fossil fuel.
There have been many studies to find an alternative power source.
Wind energy found to be one of the most useful solutions to help in
overcoming the air pollution and global. There is no agreed solution
to conversion of wind energy to electrical energy. In this paper, the
advantages of using a Switched Reluctance Generator (SRG) for
wind energy applications. The theoretical study of the self excitation
of a SRG and the determination of the variable parameters in a SRG
design are discussed. The design parameters for the maximum power
output of the SRG are computed using Matlab simulation. The
designs of the circuit to control the variable parameters in a SRG to
provide the maximum power output are also discussed.
Abstract: In this study the adsorption of Cu (II) ions from aqueous solutions on synthetic zeolite NaA was evaluated. The effect of solution temperature and the determination of the kinetic parameters of adsorption of Cu(II) from aqueous solution on zeolite NaA is important in understanding the adsorption mechanism. Variables of the system include adsorption time, temperature (293- 328K), initial solution concentration and pH for the system. The sorption kinetics of the copper ions were found to be strongly dependent on pH (the optimum pH 3-5), solute ion concentration and temperature (293 – 328 K). It was found, the pseudo-second-order model was the best choice among all the kinetic models to describe the adsorption behavior of Cu(II) onto ziolite NaA, suggesting that the adsorption mechanism might be a chemisorptions process The activation energy of adsorption (Ea) was determined as Cu(II) 13.5 kJ mol-1. The low value of Ea shows that Cu(II) adsorption process by zeolite NaA may be an activated chemical adsorption. The thermodynamic parameters (ΔG0, ΔH0, and ΔS0) were also determined from the temperature dependence. The results show that the process of adsorption Cu(II) is spontaneous and endothermic process and rise in temperature favors the adsorption.
Abstract: Burnishing is a method of finishing and hardening
machined parts by plastic deformation of the surface. Experimental
work based on central composite second order rotatable design has
been carried out on a lathe machine to establish the effects of ball
burnishing parameters on the surface roughness of brass material.
Analysis of the results by the analysis of variance technique and the
F-test show that the parameters considered, have significant effects
on the surface roughness.
Abstract: An artificial neural network (ANN) model is
presented for the prediction of kinematic viscosity of binary mixtures
of poly (ethylene glycol) (PEG) in water as a function of temperature,
number-average molecular weight and mass fraction. Kinematic
viscosities data of aqueous solutions for PEG (0.55419×10-6 –
9.875×10-6 m2/s) were obtained from the literature for a wide range
of temperatures (277.15 - 338.15 K), number-average molecular
weight (200 -10000), and mass fraction (0.0 – 1.0). A three layer
feed-forward artificial neural network was employed. This model
predicts the kinematic viscosity with a mean square error (MSE) of
0.281 and the coefficient of determination (R2) of 0.983. The results
show that the kinematic viscosity of binary mixture of PEG in water
could be successfully predicted using an artificial neural network
model.
Abstract: Studies regarding the determination of population
trend of Lipaphis erysimi (kalt.) and its associated natural enemies in
different Brassica lines along with the effect of gamma radiation on
their population were conducted at Agricultural Research Farm,
Malakandher, Khyber Pakhtunkhwa Agricultural University
Peshawar during spring 2006. Three different Brassica lines F6B3,
F6B6 and F6B7 were used, which were replicated four times in
Randomized Complete Block Design. The data revealed that aphid
infestation invariably stated in all three varieties during last week of
February 2006 (1st observation). The peak population of 4.39 aphids
leaf-1 was s recorded during 2nd week of March and lowest population
of 1.02 aphids leaf-1 was recorded during 5th week of March. The
species of lady bird beetle (Coccinella septempunctata) and Syrphid
fly (Syrphus balteatus) first appeared on 24th February with a mean
number of 0.40 lady bird beetle leaf-1 and 0.87 Syrphid fly leaf-1,
respectively. At the time when aphid population started to increase
the peak population of C. septempunctata (0.70 lady bird beetle leaf-
1) and S. balteatus (1.04 syrphid fly leaf-1) was recorded on the 2nd
week of March. Chrysoperla carnea appeared in the 1st week of
March and their peak population was recorded during the 3rd week of
March with mean population of 1.46 C. carnea leaf-1. Among all the
Brassica lines, F6B7 showed comparatively more resistance as
compared to F6B3 F6B6. F6B3 showed least resistance against L.
erysimi, which was found to be the most susceptible cultivar. F6B7
was also found superior in terms of natural enemies. Maximum
number of all natural enemies was recorded on this variety followed
by F6B6. Lowest number of natural enemies was recorded in F6B3.
No significant effect was recorded for the effect of gamma radiation
on the population of aphids, natural enemies and on the varieties.
Abstract: The mechanism of abiotic stress tolerance is crucial
for plants to survive in harsh condition and the knowledge of this
mechanism can be use to solve the problem of declining productivity
of plants or crops around the world. However in-depth description is
still unclear and it is argued, in particular that there is a relationship
between high salinity tolerance and the ability to tolerate high light
condition. In this study, Dunaliella salina, which can withstand high
salt was used as a model. Chlorophyll fluorometer for nonphotochemical
quenching (NPQ) measurement and high-performance
liquid chromatography for pigment determination was used. The
results show that NPQ value and the amount of pigment were
increased along with the levels of salinity. However, it establish a
clear relationship between high salt and high light but the further
study to optimized the solutions mentioned above is still required.
Abstract: A new, simple and highly sensitive kinetic
spectrophotometric method was developed for the determination of
trace amounts of Ru(III) in the range of 0.06-20 ng/ml .The method
is based on the inhibitory effect of ruthenium(III) on the oxidation of
Rhodamine B by bromate in acidic and micellar medium. The
reaction was monitored spectrophotometrically by measuring the
decreasing in absorbance of Rhodamine B at 554 nm with a fixedtime
method..The limit of detection is 0.04 ng/ml Ru(III).The relative
standard deviation of 5 and 10 ng/ml Ru(III) was 2.3 and 2.7 %,
respectively. The method was applied to the determination of
ruthenium in real water samples
Abstract: Stress Concentration Factors are significant in
machine design as it gives rise to localized stress when any change in
the design of surface or abrupt change in the cross section occurs.
Almost all machine components and structural members contain
some form of geometrical or microstructural discontinuities. These
discontinuities are very dangerous and lead to failure. So, it is very
much essential to analyze the stress concentration factors for critical
applications like Turbine Rotors. In this paper Finite Element
Analysis (FEA) with extremely fine mesh in the vicinity of the
blades of Steam Turbine Rotor is applied to determine stress
concentration factors. A model of Steam Turbine Rotor is shown in
Fig. 1.