Abstract: In this paper, the energy performance of a selected
UHDE Ammonia plant is optimized by conducting heat integration through waste heat recovery and the synthesis of a heat exchange
network (HEN). Minimum hot and cold utility requirements were estimated through IChemE spreadsheet. Supporting simulation was
carried out using HYSYS software. The results showed that there is
no need for heating utility while the required cold utility was found to
be around 268,714 kW. Hence a threshold pinch case was faced. Then, the hot and cold streams were matched appropriately. Also,
waste heat recovered resulted with savings in HP and LP steams of
approximately 51.0% and 99.6%, respectively. An economic analysis
on proposed HEN showed very attractive overall payback period not
exceeding 3 years. In general, a net saving approaching 35% was
achieved in implementing heat optimization of current studied UHDE Ammonia process.
Abstract: Even though most researchers would agree that in
symbiotic relationships, like the one between parent and child,
influences become reciprocal over time, empirical evidence
supporting this claim is limited. The aim of the current study was to
develop and test a model describing the reciprocal influence between
characteristics of the parent-child relationship, such as closeness and
conflict, and the child-s bullying and victimization experiences at
school. The study used data from the longitudinal Study of Early
Child-Care, conducted by the National Institute of Child Health and
Human Development. The participants were dyads of early
adolescents (5th and 6th graders during the two data collection waves)
and their mothers (N=1364). Supporting our hypothesis, the findings
suggested a reciprocal association between bullying and positive
parenting, although this association was only significant for boys.
Victimization and positive parenting were not significantly
interrelated.
Abstract: Two commercial proteases from Bacillus
licheniformis (Alcalase 2.4 L FG and Alcalase 2.5 L, Type DX) were
screened for the production of Z-Ala-Phe-NH2 in batch reaction.
Alcalase 2.4 L FG was the most efficient enzyme for the C-terminal
amidation of Z-Ala-Phe-OMe using ammonium carbamate as
ammonium source. Immobilization of protease has been achieved by
the sol-gel method, using dimethyldimethoxysilane (DMDMOS) and
tetramethoxysilane (TMOS) as precursors (unpublished results). In
batch production, about 95% of Z-Ala-Phe-NH2 was obtained at
30°C after 24 hours of incubation. Reproducibility of different
batches of commercial Alcalase 2.4 L FG preparations was also
investigated by evaluating the amidation activity and the entrapment
yields in the case of immobilization. A packed-bed reactor (0.68 cm
ID, 15.0 cm long) was operated successfully for the continuous
synthesis of peptide amides. The immobilized enzyme retained the
initial activity over 10 cycles of repeated use in continuous reactor at
ambient temperature. At 0.75 mL/min flow rate of the substrate
mixture, the total conversion of Z-Ala-Phe-OMe was achieved after 5
hours of substrate recycling. The product contained about 90%
peptide amide and 10% hydrolysis byproduct.
Abstract: The problem of frequent pattern discovery is defined
as the process of searching for patterns such as sets of features or items that appear in data frequently. Finding such frequent patterns
has become an important data mining task because it reveals associations, correlations, and many other interesting relationships
hidden in a database. Most of the proposed frequent pattern mining
algorithms have been implemented with imperative programming
languages. Such paradigm is inefficient when set of patterns is large
and the frequent pattern is long. We suggest a high-level declarative
style of programming apply to the problem of frequent pattern
discovery. We consider two languages: Haskell and Prolog. Our
intuitive idea is that the problem of finding frequent patterns should
be efficiently and concisely implemented via a declarative paradigm
since pattern matching is a fundamental feature supported by most
functional languages and Prolog. Our frequent pattern mining
implementation using the Haskell and Prolog languages confirms our
hypothesis about conciseness of the program. The comparative
performance studies on line-of-code, speed and memory usage of
declarative versus imperative programming have been reported in the
paper.
Abstract: The present work was conducted for the synthesis of
nano size zerovalent iron (nZVI) and hexavalent chromium (Cr(VI))
removal as a highly toxic pollutant by using this nanoparticles. Batch
experiments were performed to investigate the effects of Cr(VI),
nZVI concentration, pH of solution and contact time variation on
the removal efficiency of Cr(VI). nZVI was synthesized by
reduction of ferric chloride using sodium borohydrid. SEM and
XRD examinations applied for determination of particle size and
characterization of produced nanoparticles. The results showed that
the removal efficiency decreased with Cr(VI) concentration and pH
of solution and increased with adsorbent dosage and contact time.
The Langmuir and Freundlich isotherm models were used for the
adsorption equilibrium data and the Langmuir isotherm model was
well fitted. Nanoparticle ZVI presented an outstanding ability to
remove Cr(VI) due to high surface area, low particle size and high
inherent activity.
Abstract: In this paper; we are interested principally in dynamic modelling of quadrotor while taking into account the high-order nonholonomic constraints in order to develop a new control scheme as well as the various physical phenomena, which can influence the dynamics of a flying structure. These permit us to introduce a new state-space representation. After, the use of Backstepping approach for the synthesis of tracking errors and Lyapunov functions, a sliding mode controller is developed in order to ensure Lyapunov stability, the handling of all system nonlinearities and desired tracking trajectories. Finally simulation results are also provided in order to illustrate the performances of the proposed controller.
Abstract: Following the laser ablation studies leading to a
theory of nuclei confinement by a Debye layer mechanism, we
present here numerical evaluations for the known stable nuclei where
the Coulomb repulsion is included as a rather minor component
especially for lager nuclei. In this research paper the required
physical conditions for the formation and stability of nuclei
particularly endothermic nuclei with mass number greater than to
which is an open astrophysical question have been investigated.
Using the Debye layer mechanism, nuclear surface energy, Fermi
energy and coulomb repulsion energy it is possible to find conditions
under which the process of nucleation is permitted in early universe.
Our numerical calculations indicate that about 200 second after the
big bang at temperature of about 100 KeV and subrelativistic region
with nucleon density nearly equal to normal nuclear density namely,
10cm all endothermic and exothermic nuclei have been
formed.
Abstract: One of the most challengeable issues in ESL
(Electronic System Level) design is the lack of a general modeling
scheme for on chip communication architecture. In this paper some
of the mostly used methodologies for modeling and representation of
on chip communication are investigated. Our goal is studying the
existing methods to extract the requirements of a general
representation scheme for communication architecture synthesis. The
next step, will be introducing a modeling and representation method
for being used in automatically synthesis process of on chip
communication architecture.
Abstract: We investigated this hypothesis that arterial CO2 pressure (PaCO2) drives ventilation (V.E) with a time delay duringrecovery from short impulse-like exercise (10 s) with work load of 200 watts. V.E and end tidal CO2 pressure (PETCO2) were measured continuously during rest, warming up, exercise and recovery periods. PaCO2 was predicted (PaCO2 pre) from PETCO2 and tidal volume (VT). PETCO2 and PaCO2 pre peaked at 20 s of recovery. V.E increased and peaked at the end of exercise and then decreased during recovery; however, it peaked again at 30 s of recovery, which was 10 s later than the peak of PaCO2 pre. The relationship between V. E and PaCO2pre was not significant by using data of them obtained at the same time but was significant by using data of V.E obtained 10 s later for data of PaCO2 pre. The results support our hypothesis that PaCO2 drives V.E with a time delay.
Abstract: Customarily, the LMTD correction factor, FT, is used
to screen alternative designs for a heat exchanger. Designs with
unacceptably low FT values are discarded. In this paper, authors have
proposed a more fundamental criterion, based on feasibility of a
multipass exchanger as the only criteria, followed by economic
optimization. This criterion, coupled with asymptotic energy targets,
provide the complete optimization space in a heat exchanger network
(HEN), where cost-optimization of HEN can be performed with only
Heat Recovery Approach temperature (HRAT) and number-of-shells
as variables.
Abstract: This paper addresses the controller synthesis problem of discrete-time switched positive systems with bounded time-varying delays. Based on the switched copositive Lyapunov function approach, some necessary and sufficient conditions for the existence of state-feedback controller are presented as a set of linear programming and linear matrix inequality problems, hence easy to be verified. Another advantage is that the state-feedback law is independent on time-varying delays and initial conditions. A numerical example is provided to illustrate the effectiveness and feasibility of the developed controller.
Abstract: The main objective of this research is to synthesize silk fibroin fiber for indoor air particulate removal. Silk cocoons were de-gummed using 0.5 wt % Na2CO3 alkaline solutions at 90 Ó╣ìC for 60 mins, washed with distilled water, and dried at 80 Ó╣ìC for 3 hrs in a vacuum oven. Two sets of experiment were conducted to investigate the impacts of initial particulate matter (PM) concentration and that of air flow rate on the removal efficiency. Rice bran collected from a local rice mill in Ubonratchathani province was used as indoor air contaminant in this work. The morphology and physical properties of silk fibroin (SF) fiber were measured. The SEM revealed the deposition of PM on the used fiber. The PM removal efficiencies of 72.29 ± 3.03 % and 39.33 ± 1.99 % were obtained of PM10 and PM2.5, respectively, when using the initial PM concentration at 0.040 mg/m3 and 0.020 mg/m3 of PM10 and PM2.5, respectively, with the air flow rate of 5 L/min.
Abstract: This study assessed fish marketing as panacea towards
sustainable agriculture in Ogun State, Nigeria. Multi-stage sampling
technique was used in the selection of 150 fish marketers for this
study. Descriptive statistics were used for the objectives while
Product Pearson Moment Correlation was used to test the hypothesis.
Result of the findings revealed that the mean age of the respondents
was 38.60 years. Majority (93.33%) of the respondents had
acceptable levels of formal education. Many (44.00%) of the
respondents had spent 1-5 years in fish marketing. The average
quantity of fish sold in a day was 94.10kg. However, efficient fish
marketing were hindered by inadequate processing equipment,
storage rooms and ice holding facilities (86.67%). There was a
significant relationship between socio-economic characteristics and
profit realized from fish marketing (p < 0.05). It was recommended
that storage and warehousing facilities should be provided to the fish
marketers in the study area.
Abstract: This paper investigates how the use of machine learning techniques can significantly predict the three major dimensions of learner-s emotions (pleasure, arousal and dominance) from brainwaves. This study has adopted an experimentation in which participants were exposed to a set of pictures from the International Affective Picture System (IAPS) while their electrical brain activity was recorded with an electroencephalogram (EEG). The pictures were already rated in a previous study via the affective rating system Self-Assessment Manikin (SAM) to assess the three dimensions of pleasure, arousal, and dominance. For each picture, we took the mean of these values for all subjects used in this previous study and associated them to the recorded brainwaves of the participants in our study. Correlation and regression analyses confirmed the hypothesis that brainwave measures could significantly predict emotional dimensions. This can be very useful in the case of impassive, taciturn or disabled learners. Standard classification techniques were used to assess the reliability of the automatic detection of learners- three major dimensions from the brainwaves. We discuss the results and the pertinence of such a method to assess learner-s emotions and integrate it into a brainwavesensing Intelligent Tutoring System.
Abstract: The field of polymeric biomaterials is very important
from the socio-economical viewpoint. Synthetic carbohydrate
polymers are being increasingly investigated as biodegradable,
biocompatible and biorenewable materials. The aim of this study was
to synthesize and characterize some derivatives based on D-mannose.
D-mannose was chemically modified to obtain 1-O-allyl-2,3:5,6-di-
O-isopropylidene-D-mannofuranose and 1-O-(2-,3--epoxy-propyl)-
2,3:5,6-di-O-isopropylidene-D-mannofuranose.
The chemical structure of the resulting compounds was
characterized by FT-IR and NMR spectroscopy, and by HPLC-MS.
Abstract: Within dental-guided surgery, there has been a lack
of analytical methods for optimizing the treatment of the
rehabilitation concepts regarding geometrical variation. The purpose
of this study is to find the source of the greatest geometrical variation
contributor and sensitivity contributor with the help of virtual
variation simulation of a dental drill- and implant-guided surgery
process using a methodical approach. It is believed that lower
geometrical variation will lead to better patient security and higher
quality of dental drill- and implant-guided surgeries. It was found
that the origin of the greatest contributor to the most variation, and
hence where the foci should be set, in order to minimize geometrical
variation was in the assembly category (surgery). This was also the
category that was the most sensitive for geometrical variation.
Abstract: Recent changes in food retailing structure have led to the development of large supercenters in suburban areas of the United States. These changes have led some authors to suggest that there are food deserts in some urban areas, where food is difficult to access, especially for disadvantaged consumers. This study tests the food desert hypothesis by comparing the distance from food retailers to food secure and food insecure households in one urban, Midwest neighborhood. This study utilizes GIS to compare household survey respondent locations against the location of various types of area food retailers. Results of this study indicate no apparent difference between food secure and insecure households in the reported importance of distance on the decision to shop at various retailers. However, there were differences in the spatial relationship between households and retailers. Food insecure households tended to be located slightly farther from large food retailers and slightly closer to convenience stores. Furthermore, food insecure households reported traveling slightly farther to their primary food retailer. The differences between the two groups was, however, relatively small.
Abstract: Binary Decision Diagrams (BDDs) are useful data
structures for symbolic Boolean manipulations. BDDs are used in
many tasks in VLSI/CAD, such as equivalence checking, property
checking, logic synthesis, and false paths. In this paper we describe a
new approach for the realization of a BDD package. To perform
manipulations of Boolean functions, the proposed approach does not
depend on the recursive synthesis operation of the IF-Then-Else
(ITE). Instead of using the ITE operation, the basic synthesis
algorithm is done using Boolean NOR operation.
Abstract: Curing of paints by exposure to UV radiations is
emerging as one of the best film forming technique as an alternative
to traditional solvent borne oxidative and thermal curing coatings.
The composition and chemistry of UV curable coatings and role of
multifunctional and monofunctional monomers, oligomers, and
photoinitiators have been discussed. The limitations imposed by
thermodynamic equilibrium and tendency for acrylic double bond
polymerizations during synthesis of multifunctional acrylates have
been presented. Aim of present investigation was thus to explore the
reaction variables associated with synthesis of multifunctional
acrylates. Zirconium oxychloride was evaluated as catalyst against
regular acid functional catalyst. The catalyzed synthesis of glyceryl
acrylate and neopentyl glycol acrylate was conducted by variation of
following reaction parameters: two different reactant molar ratios-
1:4 and 1:6; catalyst usage in % by moles on polyol- 2.5, 5.0 and 7.5
and two different reaction temperatures- 45 and 75 0C. The reaction
was monitored by determination of acid value and hydroxy value at
regular intervals, besides TLC, HPLC, and FTIR analysis of
intermediates and products. On the basis of determination of reaction
progress over 1-60 hrs, the esterification reaction was observed to
follow 2nd order kinetics with rate constant varying from 1*10-4 to
7*10-4. The thermal and catalytic components of second order rate
constant and energy of activation were also determined. Uses of
these kinetic and thermodynamic parameters in design of reactor for
manufacture of multifunctional acrylate ester have been presented.
The synthesized multifunctional acrylates were used to formulate and
apply UV curable clear coat followed by determination of curing
characteristics and mechanical properties of cured film. The overall
curing rates less than 05 min. were easily attained indicating
economical viability of radiation curable system due to faster
production schedules
Abstract: The paper is included within the framework of a
complex research program, which was initiated from the hypothesis
arguing on the existence of a correlation between pineal indolic and
peptide hormones and the somatic development rhythm, including
thus the epithalamium-epiphysis complex involvement. At birds,
pineal gland contains a circadian oscillator, playing a main role in the
temporal organization of the cerebral functions. The secretion of
pineal indolic hormones is characterized by a high endogenous
rhythmic alternation, modulated by the light/darkness (L/D)
succession and by temperature as well. The research has been carried
out using 100 chicken broilers - “Ross" commercial hybrid,
randomly allocated in two experimental batches: Lc batch, reared
under a 12L/12D lighting schedule and Lexp batch, which was photic
pinealectomised through continuous exposition to light (150 lux, 24
hours, 56 days). Chemical and physical features of the meat issued
from breast fillet and thighs muscles have been studied, determining
the dry matter, proteins, fat, collagen, salt content and pH value, as
well. Besides the variations of meat chemical composition in relation
with lighting schedule, other parameters have been studied: live
weight dynamics, feed intake and somatic development degree. The
achieved results became significant since chickens have 7 days of
age, some variations of the studied parameters being registered,
revealing that the pineal gland physiologic activity, in relation with
the lighting schedule, could be interpreted through the monitoring of
the somatic development technological parameters, usually studied
within the chicken broilers rearing aviculture practice.