Abstract: The evolutionary tree is an important topic in bioinformation. In 2006, Chen and Lindsay proposed a new method to build the mixture tree from DNA sequences. Mixture tree is a new type evolutionary tree, and it has two additional information besides the information of ordinary evolutionary tree. One of the information is time parameter, and the other is the set of mutated sites. In 2008, Lin and Juan proposed an algorithm to compute the distance between two mixture trees. Their algorithm computes the distance with only considering the time parameter between two mixture trees. In this paper, we proposes a method to measure the similarity of two mixture trees with considering the set of mutated sites and develops two algorithm to compute the distance between two mixture trees. The time complexity of these two proposed algorithms are O(n2 × max{h(T1), h(T2)}) and O(n2), respectively
Abstract: Polyphenolics and sugar are the components of many
fruit juices. In this work, the performance of ultra-filtration (UF) for
separating phenolic compounds from apple juice was studied by
performing batch experiments in a membrane module with an area of
0.1 m2 and fitted with a regenerated cellulose membrane of 1 kDa
MWCO. The effects of various operating conditions: transmembrane
pressure (3, 4, 5 bar), temperature (30, 35, 40 ºC), pH (2, 3, 4, 5),
feed concentration (3, 5, 7, 10, 15 ºBrix for apple juice) and feed flow
rate (1, 1.5, 1.8 L/min) on the performance were determined.
The optimum operating conditions were: transmembrane pressure
4 bar, temperature 30 ºC, feed flow rate 1 – 1.8 L/min, pH 3 and 10
Brix (apple juice). After performing ultrafiltration under these
conditions, the concentration of polyphenolics in retentate was
increased by a factor of up to 2.7 with up to 70% recovered in the
permeate and with approx. 20% of the sugar in that stream..
Application of diafiltration (addition of water to the concentrate) can
regain the flux by a factor of 1.5, which has been decreased due to
fouling. The material balance performed on the process has shown
the amount of deposits on the membrane and the extent of fouling in
the system. In conclusion, ultrafiltration has been demonstrated as a
potential technology to separate the polyphenolics and sugars from
their mixtures and can be applied to remove sugars from fruit juice.
Abstract: Commercially available lipases (Candida antarctica lipase B, Novozyme 435, Thermomyces lanuginosus lipase, and Lipozyme TL IM), as well as sol-gel immobilized lipases, have been screened for their ability to acylate regioselectively xylitol, sorbitol, and mannitol with a phenolic ester in a binary mixture of t-butanol and dimethylsulfoxide. HPLC and MALDI-TOF MS analysis revealed the exclusive formation of monoesters for all studied sugar alcohols. The lipases immobilized by the sol-gel entrapment method proved to be efficient catalysts, leading to high conversions (up to 60%) in the investigated acylation reactions. From a sequence of silane precursors with different nonhydrolyzable groups in their structure, the presence of octyl and i-butyl group was most beneficial for the catalytic activity of sol-gel entrapped lipases in the studied process.
Abstract: In the study the influence of the physical-chemical properties of a liquid, the width of a channel gap and the superficial liquid and gas velocities on the patterns formed during two phase flows in vertical, narrow mini-channels was investigated. The research was performed in the channels of rectangular cross-section and of dimensions: 15 x 0.65 mm and 7.5 x 0.73 mm. The experimental data were compared with the published criteria of the transitions between the patterns of two-phase flows.
Abstract: A process flowsheet was developed in ChemCad 6.4
to study the effect of feed moisture contents on the pre-esterification
of waste oils. Waste oils were modelled as a mixture of triolein
(90%), oleic acid (5%) and water (5%). The process mainly consisted
of feed drying, pre-esterification reaction and methanol recovery. The
results showed that the process energy requirements would be
minimized when higher degrees of feed drying and higher preesterification
reaction temperatures are used.
Abstract: The objective of this study is to investigate the
combustion in a pilot-ignited supercharged dual-fuel engine, fueled
with different types of gaseous fuels under various equivalence ratios.
It is found that if certain operating conditions are maintained,
conventional dual-fuel engine combustion mode can be transformed to
the combustion mode with the two-stage heat release. This mode of
combustion was called the PREMIER (PREmixed Mixture Ignition in
the End-gas Region) combustion. During PREMIER combustion,
initially, the combustion progresses as the premixed flame
propagation and then, due to the mixture autoignition in the end-gas
region, ahead of the propagating flame front, the transition occurs with
the rapid increase in the heat release rate.
Abstract: The paper presents a one-dimensional transient
mathematical model of compressible non-isothermal multicomponent
fluid mixture flow in a pipe. The set of the mass,
momentum and enthalpy conservation equations for gas phase is
solved in the model. Thermo-physical properties of multi-component
gas mixture are calculated by solving the Equation of State (EOS)
model. The Soave-Redlich-Kwong (SRK-EOS) model is chosen. Gas
mixture viscosity is calculated on the basis of the Lee-Gonzales-
Eakin (LGE) correlation. Numerical analysis of rapid gas
decompression process in rich and base natural gases is made on the
basis of the proposed mathematical model. The model is successfully
validated on the experimental data [1]. The proposed mathematical
model shows a very good agreement with the experimental data [1] in
a wide range of pressure values and predicts the decompression in
rich and base gas mixtures much better than analytical and
mathematical models, which are available from the open source
literature.
Abstract: A pot experiment was carried out under controlled
conditions to evaluate the residual effects of different doses of
atrazine+alachlor and foramsulfuron used in corn fields on the
growth and physiology of rapeseed (Brassica napus L.). A split-plot
experiment in CRD with 4 replications was used. The main plots
consisted of herbicide type (atrazine+alachlor mixture and
foramsulfuron) and the sub-plots were different residual doses of the
herbicides (0, 1%, 5%, 10%, 20%, 40%, 50% and 100%). 7 cm
diameter pots were filled with a virgin soil and seeds of rapeseed cv.
Hayola were planted in them. The pots were kept under controlled
conditions for 8 weeks after germination. At harvest, the growth
parameters and the chlorophyll contents of the leaves were
determined. The results showed that the growth of rapeseed plants
was completely prevented at the highest residual doses of the
herbicides (50 and 100 %). The growth parameters of rapeseed plants
were affected by all doses of both types of the herbicide as compared
to the controls. The residual effects of atrazine+alachlor mixture in
reducing the growth parameters of rapeseed were more pronounced
as compared to the residual effects of foramsulfuron alone.
Abstract: Partial Discharge measurement is a very important
means of assessing the integrity of insulation systems in a High
Voltage apparatus. In compressed gas insulation systems, floating
particles can initiate partial discharge activities which adversely
affect the working of insulation. Partial Discharges below the
inception voltage also plays a crucial in damaging the integrity of
insulation over a period of time. This paper discusses the effect of
loose and fixed Copper and Nichrome wire particles on the PD
characteristics in SF6-N2 (10:90) gas mixtures at a pressure of
0.4MPa. The Partial Discharge statistical parameters and their
correlation to the observed results are discussed.
Abstract: The objective of this study is to investigate the effect of adding coal to obtain insulating ceramic product. The preparation of mixtures is achieved with 04 types of different masse compositions, consisting of gray and yellow clay, and coal. Analyses are performed on local raw materials by adding coal as additive. The coal content varies from 5 to 20 % in weight by varying the size of coal particles ranging from 0.25mm to 1.60mm.
Initially, each natural moisture content of a raw material has been determined at the temperature of 105°C in a laboratory oven. The Influence of low-coal content on absorption, the apparent density, the contraction and the resistance during compression have been evaluated. The experimental results showed that the optimized composition could be obtained by adding 10% by weight of coal leading thus to insulating ceramic products with water absorption, a density and resistance to compression of 9.40 %, 1.88 g/cm3, 35.46 MPa, respectively. The results show that coal, when mixed with traditional raw materials, offers the conditions to be used as an additive in the production of lightweight ceramic products.
Abstract: The absolute Cu atoms density in Cu(2S1/22P1/2)
ground state has been measured by Resonance Optical Absorption
(ROA) technique in a DC magnetron sputtering deposition with
argon. We measured these densities under variety of operation
conditions: pressure from 0.6 μbar to 14 μbar, input power from
10W to 200W and N2 mixture from 0% to 100%. For measuring the
gas temperature, we used the simulation of N2 rotational spectra
with a special computer code. The absolute number density of Cu
atoms decreases with increasing the N2 percentage of buffer gas at
any conditions of this work. But the deposition rate, is not decreased
with the same manner. The deposition rate variation is very small
and in the limit of quartz balance measuring equipment accuracy. So
we conclude that decrease in the absolute number density of Cu
atoms in magnetron plasma has not a big effect on deposition rate,
because the diffusion of Cu atoms to the chamber volume and
deviation of Cu atoms from direct path (towards the substrate)
decreases with increasing of N2 percentage of buffer gas. This is
because of the lower mass of N2 atoms compared to the argon ones.
Abstract: α-Pinene is the main component of the most
turpentine oils. The hydration of α-pinene with acid catalysts leads to
a complex mixture of monoterpenes. In order to obtain more valuable
products, the α-pinene in the turpentine can be hydrated in dilute
mineral acid solutions to produce α-terpineol. The design of
separation processes requires information on phase equilibrium and
related thermodynamic properties. This paper reports the results of
study on liquid-liquid equilibrium (LLE) of system containing α-
pinene + water and α-terpineol + water.
Binary LLE for α-pinene + water system, and α-terpineol + water
systems were determined by experiment at 301K and atmospheric
pressure. The two component mixture was stirred for about 30min,
then the mixture was left for about 2h for complete phase separation.
The composition of both phases was analyzed by using a Gas
Chromatograph. The experimental data were correlated by
considering both NRTL and UNIQUAC activity coefficient models.
The LLE data for the system of α-pinene + water and α-terpineol +
water were correlated successfully by the NRTL model. The
experimental data were not satisfactorily fitted by the UNIQUAC
model. The NRTL model (α =0.3) correlates the LLE data for the
system of α-pinene + water at 301K with RMSD of 0.0404%. And
the NRTL model (α =0.61) at 301K with RMSD of 0.0058 %. The
NRTL model (α =0.3) correlates the LLE data for the system of α-
terpineol + water at 301K with RMSD of 0.1487% and the NRTL
model (α =0.6) at 301K with RMSD of 0.0032%, between the
experimental and calculated mole fractions.
Abstract: Given a bivariate normal sample of correlated variables,
(Xi, Yi), i = 1, . . . , n, an alternative estimator of Pearson’s correlation
coefficient is obtained in terms of the ranges, |Xi − Yi|.
An approximate confidence interval for ρX,Y is then derived, and
a simulation study reveals that the resulting coverage probabilities
are in close agreement with the set confidence levels. As well, a
new approximant is provided for the density function of R, the
sample correlation coefficient. A mixture involving the proposed
approximate density of R, denoted by hR(r), and a density function
determined from a known approximation due to R. A. Fisher is shown
to accurately approximate the distribution of R. Finally, nearly exact
density approximants are obtained on adjusting hR(r) by a 7th degree
polynomial.
Abstract: During the process of compaction in Hot-Mix Asphalt
(HMA) mixtures, the distance between aggregate particles decreases
as they come together and eliminate air-voids. By measuring the
inter-particle distances in a cut-section of a HMA sample the degree
of compaction can be estimated. For this, a calibration curve is
generated by computer simulation technique when the gradation and
asphalt content of the HMA mixture are known. A two-dimensional
cross section of HMA specimen was simulated using the mixture
design information (gradation, asphalt content and air-void content).
Nearest neighbor distance methods such as Delaunay triangulation
were used to study the changes in inter-particle distance and area
distribution during the process of compaction in HMA. Such
computer simulations would enable making several hundreds of
repetitions in a short period of time without the necessity to compact
and analyze laboratory specimens in order to obtain good statistics on
the parameters defined. The distributions for the statistical
parameters based on computer simulations showed similar trends as
those of laboratory specimens.
Abstract: In this article, we synthesize a novel chitosan -based
superabsorbent hydrogel via graft copolymerization of mixtures
acrylic acid (AA) and N-vinyl pyrollidon onto chitosan backbones.
The polymerization reaction was carried out in an aqueous medium
and in the presence of ammonium persulfate (APS) as an initiator and
N,N'-methylene bisacrylamide (MBA) as a crosslinker.The hydrogel
structures were confirmed by FTIR spectroscopy. The swelling
behavior of these absorbent polymers was also investigated in
various salt solutions. Results indicated that the swelling capacity
decreased with an increase in the ionic strength of the swelling
medium. Furthermore, the swelling of superabsorbing hydrogels was
examined in solutions with pH values ranging between 1.0 and 13.0.
It showed a reversible pH-responsive behavior at pHs 2.0 and 8.0.
This on-off switching behavior makes the synthesized hydrogels as
an excellent candidate for controlled delivery of bioactive agents.
Abstract: Coal tar is a liquid by-product of the process of coal
gasification and carbonation. This liquid oil mixture contains various
kinds of useful compounds such as phenol, o-cresol, and p-cresol.
These compounds are widely used as raw material for insecticides,
dyes, medicines, perfumes, coloring matters, and many others.
This research needed to be done that given the optimum conditions
for the separation of phenol, o-cresol, and p-cresol from the coal tar
by solvent extraction process. The aim of the present work was to
study the effect of two kinds of aqueous were used as solvents:
methanol and acetone solutions, the effect of temperature (298, 306,
and 313K) and mixing (30, 35, and 40rpm) for the separation of
phenol, o-cresol, and p-cresol from coal tar by solvent extraction.
Results indicated that phenol, o-cresol, and p-cresol in coal tar
were selectivity extracted into the solvent phase and these
components could be separated by solvent extraction. The aqueous
solution of methanol, mass ratio of solvent to feed, Eo/Ro=1,
extraction temperature 306K and mixing 35 rpm were the most
efficient for extraction of phenol, o-cresol, and p-cresol from coal tar.
Abstract: In electronegative-electropositive gas mixtures plasma, at a total pressure varying in the range of ten to hundred Torr, the appearance of a quasi-mochromatization effect of the emitted radiation was reported. This radiation could be the result of the generating mechanisms at molecular level, which is the case of the excimer radiation but also at atomic level. Thus, in the last case, in (Ne+1%Ar/Xe+H2) gas mixtures plasma in a dielectric barrier discharge, this effect, called M-effect, consists in the reduction of the discharge emission spectrum practice at one single, strong spectral line with λ = 585.3 nm. The present paper is concerned with the characteristics comparative investigation of the principal reaction mechanisms involved in the quasi-monochromatization effect existence in the case of the excimer radiation, respectively of the Meffect. Also, the paper points out the role of the metastable electronegative atoms in the appearance of the monochromatization – effect at atomic level.
Abstract: In this paper 2D Simulation of catalytic Fixed Bed Reactor in Fischer-Tropsch Synthesis of GTL technology has been performed utilizing computational fluid dynamics (CFD). Synthesis gas (a mixture of carbon monoxide and hydrogen) has been used as feedstock. The reactor was modeled and the model equations were solved employing finite volume method. The model was validated against the experimental data reported in literature. The comparison showed a good agreement between simulation results and the experimental data. In addition, the model was applied to predict the concentration contours of the reactants and products along the length of reactor.
Abstract: In this paper, the effect of addition the dune sand powder (DSP) on development of compressive strength and hydration of cement pastes was investigated as a function of water/binder ratio, was varied, on the one hand, the percentage of DSP and on the other, the fineness of DSP. In order to understand better the pozzolanic effect of dune sand powder in cement pastes, we followed the mixtures hydration (50% Pure Lime + 50% DSP) by X-ray diffraction. These mixtures the pastes present a hydraulic setting which is due to the formation of a C-S-H phase (calcium silicate hydrate). The latter is semi-crystallized. This study is a simplified approach to that of the mixtures (80% ordinary Portland cement + 20% DSP), in which the main reaction is the fixing of the lime coming from the cement hydration in the presence of DSP, to form calcium silicate hydrate semi-crystallized of second generation. The results proved that up to (20% DSP) as Portland cement replacement could be used with a fineness of 4000 cm²/g without affecting adversely the compressive strength. After 28 days, the compressive strength at 5, 10 and 15% DSP is superior to Portland cement, with an optimum effect for a percentage of the order of 5% to 10% irrespective of the w/b ratio and fineness of DSP.
Abstract: This paper presents a new version of the SVM mixture algorithm initially proposed by Kwok for classification and regression problems. For both cases, a slight modification of the mixture model leads to a standard SVM training problem, to the existence of an exact solution and allows the direct use of well known decomposition and working set selection algorithms. Only the regression case is considered in this paper but classification has been addressed in a very similar way. This method has been successfully applied to engine pollutants emission modeling.