Abstract: Hydrogen is considered to be the most promising
candidate as a future energy carrier. One of the most used
technologies for the electrolytic hydrogen production is alkaline
water electrolysis. However, due to the high energy requirements, the
cost of hydrogen produced in such a way is high. In continuous
search to improve this process using advanced electrocatalytic
materials for the hydrogen evolution reaction (HER), Ni type Raney
and macro-porous Ni-Co electrodes were prepared on AISI 304
stainless steel substrates by electrodeposition. The developed
electrodes were characterized by SEM and confocal laser scanning
microscopy. HER on these electrodes was evaluated in 30 wt.% KOH
solution by means of hydrogen discharge curves and galvanostatic
tests. Results show that the developed electrodes present a most
efficient behaviour for HER when comparing with the smooth Ni
cathode. It has been reported a reduction in the energy consumption
of the electrolysis cell of about 25% by using the developed coatings
as cathodes.
Abstract: Energy generated by the force of water in hydropower
can provide a more sustainable, non-polluting alternative to fossil
fuels, along with other renewable sources of energy, such as wind,
solar and tidal power, bio energy and geothermal energy. Small scale
hydroelectricity in Iran is well suited for “off-grid" rural electricity
applications, while other renewable energy sources, such as wind,
solar and biomass, can be beneficially used as fuel for pumping
groundwater for drinking and small scale irrigation in remote rural
areas or small villages. Small Hydro Power plants in Iran have very
low operating and maintenance costs because they consume no fossil
or nuclear fuel and do not involve high temperature processes. The
equipment is relatively simple to operate and maintain. Hydropower
equipment can adjust rapidly to load changes. The extended
equipment life provides significant economic advantages. Some
hydroelectric plants installed 100 years ago still operate reliably. The
Polkolo river is located on Karun basin at southwest of Iran. Situation
and conditions of Polkolo river are evaluated for construction of
small hydropower in this article. The topographical conditions and
the existence of permanent water from springs provide the suitability
to install hydroelectric power plants on the river Polkolo. The
cascade plant consists of 9 power plants connected with each other
and is having the total head as 1100m and discharge about 2.5cubic
meter per second. The annual production of energy is 105.5 million
kwh.
Abstract: We have developed an analytic model for the radial pn-junction in a nanowire (NW) core-shell structure utilizing as a new
building block in different semiconductor devices. The potential distribution through the p-n-junction is calculated and the analytical expressions are derived to compute the depletion region widths. We
show that the widths of space charge layers, surrounding the core, are
the functions of core radius, which is the manifestation of so called classical size effect. The relationship between the depletion layer width and the built-in potential in the asymptotes of infinitely large
core radius transforms to square-root dependence specific for conventional planar p-n-junctions. The explicit equation is derived to
compute the capacitance of radial p-n-junction. The current-voltage behavior is also carefully determined taking into account the “short
base" effects.
Abstract: The electrochemical coagulation of a kaolin
suspension was investigated at the currents of 0.06, 0.12, 0.22, 0.44,
0.85 A (corresponding to 0.68, 1.36, 2.50, 5.00, 9.66 mA·cm-2,
respectively) for the contact time of 5, 10, 20, 30, and 50 min. The
TSS removal efficiency at currents of 0.06 A, 0.12 A and 0.22 A
increased with the amount of iron generated by the sacrificial anode,
while the removal efficiencies did not increase proportionally with
the amount of iron generated at the currents of 0.44 and 0.85 A,
where electroflotation was clearly observed. Zeta potential
measurement illustrated the presence of the highly positive charged
particles created by sorption of highly charged polymeric metal
hydroxyl species onto the negative surface charged kaolin particles at
both low and high applied currents. The disappearance of the
individual peaks after certain contact times indicated the attraction
between these positive and negative charged particles causing
agglomeration. It was concluded that charge neutralization of the
individual species was not the only mechanism operating in the
electrocoagulation process at any current level, but electrostatic
attraction was likely to co-operate or mainly operate.
Abstract: In most study fields, a phenomenon may not be
studied directly but it will be examined indirectly by phenomenon
model. Making an accurate model of system, there is attained new
information from modeled phenomenon without any charge, danger,
etc... there have been developed more solutions for describing and
analyzing the recent complicated systems but few of them have
analyzed the performance in the range of system description. Petri
nets are of limited solutions which may make such union. Petri nets
are being applied in problems related to modeling and designing the
systems. Theory of Petri nets allow a system to model
mathematically by a Petri net and analyzing the Petri net can then
determine main information of modeled system-s structure and
dynamic. This information can be used for assessing the performance
of systems and suggesting corrections in the system. In this paper,
beside the introduction of Petri nets, a real case study will be studied
in order to show the application of generalized stochastic Petri nets in
modeling a resource sharing production system and evaluating the
efficiency of its machines and robots. The modeling tool used here is
SHARP software which calculates specific indicators helping to
make decision.
Abstract: Laboratory experiments have been performed to investigate photocatalytic detoxification by using TiO2 photocatalyst for treating dairy effluent. Various operational parameters such as catalyst concentration, initial concentration, angle of tilt of solar flat plate reactor and flow rate were investigated. Results indicated that the photocatalytic detoxification process can efficiently treat dairy effluent. Experimental runs with dairy wastewater can be used to identify the optimum operational parameters to perform wastewater degradation on large scale for recycling purpose. Also effect of two different types of reactors on degradation process was analyzed.
Abstract: Laser engraving is a manufacturing method for those applications where previously Electrical Discharge Machining (EDM) was the only choice. Laser engraving technology removes material layer-by-layer and the thickness of layers is usually in the range of few microns. The aim of the present work is to investigate the influence of the process parameters on the surface quality when machined by laser engraving. The examined parameters were: the pulse frequency, the beam speed and the layer thickness. The surface quality was determined by the surface roughness for every set of parameters. Experimental results on Al7075 material showed that the surface roughness strictly depends on the process parameters used.
Abstract: To judge whether the memristor can be interpreted as
the fourth fundamental circuit element, we propose a variable-relation
criterion of fundamental circuit elements. According to the criterion,
we investigate the nature of three fundamental circuit elements and the
memristor. From the perspective of variables relation, the memristor
builds a direct relation between the voltage across it and the current
through it, instead of a direct relation between the magnetic flux and
the charge. Thus, it is better to characterize the memristor and the
resistor as two special cases of the same fundamental circuit element,
which is the memristive system in Chua-s new framework. Finally, the
definition of memristor is refined according to the difference between
the magnetic flux and the flux linkage.
Abstract: This paper presents the combination of different precipitation data sets and the distributed hydrological model, in order to examine the flood runoff reproductivity of scattered observation catchments. The precipitation data sets were obtained from observation using rain-gages, satellite based estimate (TRMM), and numerical weather prediction model (NWP), then were coupled with the super tank model. The case study was conducted in three basins (small, medium, and large size) located in Central Vietnam. Calculated hydrographs based on ground observation rainfall showed best fit to measured stream flow, while those obtained from TRMM and NWP showed high uncertainty of peak discharges. However, calculated hydrographs using the adjusted rainfield depicted a promising alternative for the application of TRMM and NWP in flood modeling for scattered observation catchments, especially for the extension of forecast lead time.
Abstract: The investigation results of high-density hydrogen
heating by high-current electric arc are presented at initial pressure
from 5 MPa to 160 MPa with current amplitude up to 1.6 MA and
current rate of rise 109-1011 A/s. When changing the initial pressure
and current rate of rise, channel temperature varies from several
electronvolts to hundreds electronvolts. Arc channel radius is several
millimeters. But the radius of the discharge chamber greater than the
radius of the arc channel on approximately order of magnitude. High
efficiency of gas heating is caused by radiation absorption of
hydrogen surrounding the arc. Current channel consist from vapor of
the initiating wire. At current rate of rise of 109 A/s and relatively
small current amplitude gas heating occurs due to radiation
absorption in the band transparency of hydrogen by the wire vapours
with photon energies less than 13.6 eV. At current rate of rise of
1011 A/s gas heating is due to hydrogen absorption of soft X-rays
from discharge channel.
Abstract: Amphawa is the most popular weekend destination for
both domestic and international tourists in Thailand. More than 112
homestays and resorts have been developed along the water
resources. This research aims to initiate appropriate environmental
management system for riverside tourist accommodations in
Amphawa by investigating current environmental characteristics.
Eighty-eight riverside tourist accommodations were survey from
specific questionnaire, GPS data were also gathered for spatial
analysis. The results revealed that the accommodations are welled
manage in regards to some environmental aspects. In order to reduce
economic costs, energy efficiency equipment is utilized. A substantial
number of tourist accommodations encouraged waste separation,
followed by transfer to local administration organization. Grease
traps also utilized in order to decrease chemical discharged, grease
and oil from canteen and restaurants on natural environment. The
most notable mitigation is to initiate environmental friendly cleansers
for tourist accommodation along the riverside in tourism destinations.
Abstract: Pyrite (FeS2) is a promising candidate for cathode
materials in batteries because of it`s high theoretical capacity, low
cost and non-toxicity. In this study, nano size iron disulfide thin film
was prepared on graphite substrate through a new method as battery
cathode. In this way, acetylene black and poly vinylidene fluoride
were used as electron conductor and binder, respectively. Fabricated
thin films were analyzed by XRD and SEM. These results and
electrochemical data confirm improvement of battery discharge
capacity in comparison with commercial type of pyrite.
Abstract: Smoke discharging is a main reason of air pollution
problem from industrial plants. The obstacle of a building has an
affect with the air pollutant discharge. In this research, a mathematical
model of the smoke dispersion from two sources and one source with
a structural obstacle is considered. The governing equation of the
model is an isothermal mass transfer model in a viscous fluid. The
finite element method is used to approximate the solutions of the
model. The triangular linear elements have been used for discretising
the domain, and time integration has been carried out by semi-implicit
finite difference method. The simulations of smoke dispersion in
cases of one chimney and two chimneys are presented. The maximum
calculated smoke concentration of both cases are compared. It is then
used to make the decision for smoke discharging and air pollutant
control problems on industrial area.
Abstract: Run-offs are considered as important hydrological factors in feasibility studies of river engineering and irrigation-related projects under arid and semi-arid condition. Flood control is one of the crucial factor, the management of which while mitigates its destructive consequences, abstracts considerable volume of renewable water resources. The methodology applied here was based on Mizumura, which applied a mathematical model for simple tank to simulate the rainfall-run-off process in a particular water basin using the data from the observational hydrograph. The model was applied in the Dez River water basin adjacent to Greater Dezful region, Iran in order to simulate and estimate the floods. Results indicated that the calculated hydrographs using the simple tank method, SCS-CN model and the observation hydrographs had a close proximity. It was also found that on average the flood time and discharge peaks in the simple tank were closer to the observational data than the CN method. On the other hand, the calculated flood volume in the CN model was significantly closer to the observational data than the simple tank model.
Abstract: This paper investigates the influence of various
parameters on the behaviour of water droplets on polymeric surfaces
under high electric fields. An inclined plane test was carried out to
understand the droplet behaviour in strong electric field. Parameters
such as water droplet conductivity, droplet volume, polymeric
surface roughness and droplet positioning with respect to the
electrodes were studied. The flashover voltage is affected by all
aforementioned parameters. The droplet positioning is in some cases
more vital than the droplet volume. Surface damages were analysed
using Scanning Electron Microscopy (SEM) studies and by Energy
dispersive X-ray Analysis (EDAX). It is observes that magnitude of
discharge have direct influence on amount of surface da
Abstract: An HPLC-UV analytical method was developed to
determine ethylenediaminetetraacetic acid (EDTA) in dairy
wastewater and surface water. The optimizing separation was achieved
by reversed–phase ion-pair liquid chromatography on a C18 column
using methanol as mobile phase solvent, tetrabutylammonium bromide
as the ion-pair reagent in pH 3.3 formate buffer solution at a flow rate
of 0.9 mL min-1 with a UV detector at 265 nm. No interference of Ca,
Mg or NO3
- was detected. Method performance was evaluated in terms
of linearity, repeatability and reproducibility. The method detection
limit was 5 μg L-1. The contents of EDTA in dairy effluents were 72 ~
261 μg L-1 at a large dairy site. A change of EDTA concentration was
observed downstream of the dairy effluent discharge, but this was well
under the predicted no effect concentration for aquatic ecosystem.
Abstract: In the present work, an attempt has been made to
understand the feasibility of using UHF technique for identification
of any corona discharges/ arcing in insulating material due to water
droplets. The sensors of broadband type are useful for identification
of such discharges. It is realised that arcing initiated by liquid droplet
radiates UHF signals in the entire bandwidth up to 2 GHz. The
frequency content of the UHF signal generated due to corona/arcing
is not much varied in epoxy nanocomposites with different weight
percentage of clay content. The exfoliated/intercalated properties
were analysed through TEM studies. It is realized that corona
initiated discharges are of intermittent process. The hydrophobicity
of the material characterized through contact angle measurement. It
is realized that low Wt % of nanoclay content in epoxy resin reduces
the surface carbonization due to arcing/corona discharges. The results
of the study with gamma irradiated specimen indicates that contact
angle, discharge inception time and evaporation time of the liquid are
much lower than the virgin epoxy nanocomposite material.
Abstract: This paper presents an efficient emission constrained
hydrothermal scheduling algorithm that deals with nonlinear
functions such as the water discharge characteristics, thermal cost,
and transmission loss. It is then incorporated into the hydrothermal
coordination program. The program has been tested on a practical
utility system having 32 thermal and 12 hydro generating units. Test
results show that a slight increase in production cost causes a
substantial reduction in emission.
Abstract: There are reports of gas and oil wells fire due to different accidents. Many different methods are used for fire fighting in gas and oil industry. Traditional fire extinguishing techniques are mostly faced with many problems and are usually time consuming and needs lots of equipments. Besides, they cause damages to facilities, and create health and environmental problems. This article proposes innovative approach in fire extinguishing techniques in oil and gas industry, especially applicable for burning oil wells located offshore. Fire extinguishment employing a turbojet is a novel approach which can help to extinguishment the fire in short period of time. Divergent and convergent turbojets modeled in laboratory scale along with a high pressure flame were used. Different experiments were conducted to determine the relationship between output discharges of trumpet and oil wells. The results were corrected and the relationship between dimensionless parameters of flame and fire extinguishment distances and also the output discharge of turbojet and oil wells in specified distances are demonstrated by specific curves.
Abstract: An experimental study is realized in order to verify the
Mini Heat Pipe (MHP) concept for cooling high power dissipation
electronic components and determines the potential advantages of
constructing mini channels as an integrated part of a flat heat pipe. A
Flat Mini Heat Pipe (FMHP) prototype including a capillary structure
composed of parallel rectangular microchannels is manufactured and
a filling apparatus is developed in order to charge the FMHP. The
heat transfer improvement obtained by comparing the heat pipe
thermal resistance to the heat conduction thermal resistance of a
copper plate having the same dimensions as the tested FMHP is
demonstrated for different heat input flux rates. Moreover, the heat
transfer in the evaporator and condenser sections are analyzed, and
heat transfer laws are proposed. In the theoretical part of this work, a
detailed mathematical model of a FMHP with axial microchannels is
developed in which the fluid flow is considered along with the heat
and mass transfer processes during evaporation and condensation.
The model is based on the equations for the mass, momentum and
energy conservation, which are written for the evaporator, adiabatic,
and condenser zones. The model, which permits to simulate several
shapes of microchannels, can predict the maximum heat transfer
capacity of FMHP, the optimal fluid mass, and the flow and thermal
parameters along the FMHP. The comparison between experimental
and model results shows the good ability of the numerical model to
predict the axial temperature distribution along the FMHP.