Abstract: Coal tar is a liquid by-product of coal pyrolysis
processes. This liquid oil mixture contains various kinds of useful
compounds such as benzoic aromatic compounds and phenolic
compounds. These compounds are widely used as raw material for
insecticides, dyes, medicines, perfumes, coloring matters, and many
others. The coal tar was collected by pyrolysis process of coal
obtained from PT Kaltim Prima Coal and Arutmin-Kalimantan. The
experiments typically occurred at the atmospheric pressure in a
laboratory furnace at temperatures ranging from 300 to 550oC with a
heating rate of 10oC/min and a holding time of 1 hour at the pyrolysis
temperature. The Gas Chromatography-Mass Spectroscopy (GC-MS)
was used to analyze the coal tar components. The obtained coal tar
has the viscosity of 3.12 cp, the density of 2.78 g/cm3, the calorific
value of 11,048.44 cal/g, and the molecular weight of 222.67. The
analysis result showed that the coal tar contained more than 78
chemical compounds such as benzene, cresol, phenol, xylene,
naphtalene, etc. The total phenolic compounds contained in coal tar
are 33.25% (PT KPC) and 17.58% (Arutmin-Kalimantan). The total
naphtalene compounds contained in coal tar is 14.15% (PT KPC) and
17.13% (Arutmin-Kalimantan).
Abstract: Synthesis of gold nanoparticles has attracted much
attention since the pioneering discovery of the high catalytic activity
of supported gold nanoparticles in the reaction of CO oxidation at
low temperature. In this research field, we used Na-montmorillonite
for gold nanoparticles stabilization; various gold loading percentage
1, 2 and 5% were used for gold nanoparticles preparation. The gold
nanoparticles were obtained using chemical reduction method using
NaBH4 as reductant agent. The obtained gold nanoparticles stabilized
in Na-montmorillonite were used as catalysts for the reduction of 4-
nitrophenol to aminophenol with sodium borohydride at room
temperature. The UV-Vis results confirmed directly the gold
nanoparticles formation. The XRD and N2 adsorption results showed
the formation of gold nanoparticles in the pores of montmorillonite
with an average size of 5 nm obtained on samples with 2% gold
loading percentage. The gold particles size increased with the
increase of gold loading percentage. The reduction reaction of 4-
nitrophenol into 4-aminophenol with NaBH4 catalyzed by Au-Namontmorillonite
catalyst exhibits remarkably a high activity; the
reaction was completed within 9 min for 1%Au-Na-montmorillonite
and within 3 min for 2%Au-Na-montmorillonite.
Abstract: Geographical routing protocol requires node physical
location information to make forwarding decision. Geographical
routing uses location service or position service to obtain the position
of a node. The geographical information is a geographic coordinates
or can be obtained through reference points on some fixed coordinate
system. Link can be formed between two nodes. Link lifetime plays a
crucial role in MANET. Link lifetime represent how long the link is
stable without any failure between the nodes. Link failure may occur
due to mobility and because of link failure energy of nodes can be
drained. Thus this paper proposes survey about link lifetime
prediction using geographical information.
Abstract: Mobile Ad hoc Network is a set of self-governing
nodes which communicate through wireless links. Dynamic topology
MANETs makes routing a challenging task. Various routing
protocols are there, but due to various fundamental characteristic
open medium, changing topology, distributed collaboration and
constrained capability, these protocols are tend to various types of
security attacks. Black hole is one among them. In this attack,
malicious node represents itself as having the shortest path to the
destination but that path not even exists. In this paper, we aim to
develop a routing protocol for detection and prevention of black hole
attack by modifying AODV routing protocol. This protocol is able to
detect and prevent the black hole attack. Simulation is done using
NS-2, which shows the improvement in network performance.
Abstract: Life cycle assessment is a technique to assess the
environmental aspects and potential impacts associated with a
product, process, or service, by compiling an inventory of relevant
energy and material inputs and environmental releases; evaluating the
potential environmental impacts associated with identified inputs and
releases; and interpreting the results to help you make a more
informed decision. In this paper, the life cycle assessment of
aluminum and beech wood as two commonly used materials in Egypt
for window frames are heading, highlighting their benefits and
weaknesses. Window frames of the two materials have been assessed
on the basis of their production, energy consumption and
environmental impacts. It has been found that the climate change of
the windows made of aluminum and beech wood window, for a
reference window (1.2m×1.2m), are 81.7 mPt and -52.5 mPt impacts
respectively. Among the most important results are: fossil fuel
consumption, potential contributions to the green building effect and
quantities of solid waste tend to be minor for wood products
compared to aluminum products; incineration of wood products can
cause higher impacts of acidification and eutrophication than
aluminum, whereas thermal energy can be recovered.
Abstract: In this paper, analysis of an infinite beam resting on
multilayer tensionless extensible geosynthetic reinforced granular
fill-poor soil system overlying soft soil strata under moving load with
constant velocity is presented. The beam is subjected to a
concentrated load moving with constant velocity. The upper
reinforced granular bed is modeled by a rough membrane embedded
in Pasternak shear layer overlying a series of compressible nonlinear
winkler springs representing the underlying the very poor soil. The
multilayer tensionless extensible geosynthetic layer has been
assumed to deform such that at interface the geosynthetic and the soil
have some deformation. Nonlinear behaviour of granular fill and the
very poor soil has been considered in the analysis by means of
hyperbolic constitutive relationships. Governing differential
equations of the soil foundation system have been obtained and
solved with the help of appropriate boundary conditions. The solution
has been obtained by employing finite difference method by means of
Gauss-Siedal iterative scheme. Detailed parametric study has been
conducted to study the influence of various parameters on the
response of soil–foundation system under consideration by means of
deflection and bending moment in the beam and tension mobilized in
the geosynthetic layer. These parameters include magnitude of
applied load, velocity of load, damping, ultimate resistance of poor
soil and granular fill layer. Range of values of parameters has been
considered as per Indian Railway conditions. This study clearly
observed that the comparisons of multilayer tensionless extensible
geosynthetic reinforcement with poor foundation soil and magnitude
of applied load, relative compressibility of granular fill and ultimate
resistance of poor soil has significant influence on the response of
soil–foundation system.
Abstract: A solution methodology without using integral
transformation is proposed to develop analytical solutions for
transient heat conduction in nonuniform hollow cylinders with
time-dependent boundary condition at the outer surface. It is shown
that if the thermal conductivity and the specific heat of the medium
are in arbitrary polynomial function forms, the closed solutions of the
system can be developed. The influence of physical properties on the
temperature distribution of the system is studied. A numerical
example is given to illustrate the efficiency and the accuracy of the
solution methodology.
Abstract: Background: Muscle Energy Techniques (MET) have
been widely used by manual therapists over the past years, but still
limited research validated its use and there was limited evidence to
substantiate the theories used to explain its effects. Objective: To
investigate the effect of Muscle Energy Technique (MET) on anterior
pelvic tilt in patients with lumbar spondylosis. Design: Randomized
controlled trial. Subjects: Thirty patients with anterior pelvic tilt from
both sexes were involved, aged between 35 to 50 years old and they
were divided into MET and control groups with 15 patients in each.
Methods: All patients received 3sessions/week for 4 weeks where the
study group received MET, Ultrasound and Infrared, and the control
group received U.S and I.R only. Pelvic angle was measured by
palpation meter, pain severity by the visual analogue scale and
functional disabilities by the Oswestry disability index. Results: Both
groups showed significant improvement in all measured variables.
The MET group was significantly better than the control group in
pelvic angle, pain severity, and functional disability as p-value were
(0.001, 0.0001, 0.0001) respectively. Conclusion and implication: the
study group fulfilled greater improvement in all measured variables
than the control group which implies that application of MET in
combination with U.S and I.R were more effective in improving
pelvic tilting angle, pain severity and functional disabilities than
using electrotherapy only.
Abstract: This paper presents results of the survey regarding the
awareness about HIV/AIDS among HIV-infected individuals. A
questionnaire covering various aspects of HIV-infection was
conducted among 110 HIV-infected individuals who attended the
G.A. Zaharyan Moscow Tuberculosis Clinic, Department for
treatment of TB patients with HIV. The questionnaire included
questions about modes of HIV transmission and preventive measures
against HIV/AIDS, as well as questions about age, gender, education
and employment status. The survey revealed that the respondents in
the whole had a good knowledge regarding modes of HIV
transmission and preventive measures against HIV/AIDS: about
83,6% male respondents and 85,7% female respondents gave an
accurate answers regarding the HIV-infection. However, the
overwhelming majority of the study participants, that is, 88,5% men
and 98% women, was quite ignorant about the risk of acquiring HIV
through saliva and toothbrush of HIV-infected individual. Though
that risk is rather insignificant, it is still biologically possible. And
this gap in knowledge needs to be filled. As the study showed another
point of concern was the fact, that despite the knowledge of HIV
transmission risk through unprotected sex about 40% percent of HIVpositive
men and 25% of HIV-positive women did not insist on using
condoms with their sexual partners. These findings indicate that there
are still some aspects about HIV-infection which needed to be
clarified and explained through more detailed and specific
educational programs.
Abstract: A novel chromium-free protective coating films based
on a zeolite coating was growing onto a FeCrAlloy metal using in –
situ hydrothermal method. The zeolite film was obtained using in-situ
crystallization process that is capable of coating large surfaces with
complex shape and in confined spaces has been developed. The
zeolite coating offers an advantage of a high mechanical stability and
thermal stability. The physicochemical properties were investigated
using X-ray diffraction (XRD), Electron Microscopy (SEM), Energy
Dispersive X–ray Analysis (EDX) and Thermogravimetric Analysis
(TGA). The transition from oxide-on-alloy wires to hydrothermally
synthesised uniformly zeolite coated surfaces was followed using
SEM and XRD. In addition, the robustness of the prepared coating
was confirmed by subjecting these to thermal cycling (ambient to
550oC).
Abstract: In this paper, the secure BioSemantic Scheme is
presented to bridge biological/biomedical research problems and
computational solutions via semantic computing. Due to the diversity
of problems in various research fields, the semantic capability
description language (SCDL) plays and important role as a common
language and generic form for problem formalization. SCDL is
expected the essential for future semantic and logical computing in
Biosemantic field. We show several example to Biomedical problems
in this paper. Moreover, in the coming age of cloud computing, the
security problem is considered to be crucial issue and we presented a
practical scheme to cope with this problem.
Abstract: Spacer grid assembly supporting the nuclear fuel rods
is an important concern in the design of structural components of a
Pressurized Water Reactor (PWR). The spacer grid is composed by
springs and dimples which are formed from a strip sheet by means of
blanking and stamping processes. In this paper, the blanking process
and tooling parameters are evaluated by means of a 2D plane-strain
finite element model in order to evaluate the punch load and quality
of the sheared edges of Inconel 718 strips used for nuclear spacer
grids. A 3D finite element model is also proposed to predict the
tooling loads resulting from the stamping process of a preformed
Inconel 718 strip and to analyse the residual stress effects upon the
spring and dimple design geometries of a nuclear spacer grid.
Abstract: This paper presents thermal annealing de-wetting
technique for the preparation of porous metal membrane for Thin
Film Encapsulation (TFE) application. Thermal annealing de-wetting
experimental results reveal that pore size formation in porous metal
membrane depend upon i.e. 1. The substrate at which metal is
deposited, 2. Melting point of metal used for porous metal cap layer
membrane formation, 3. Thickness of metal used for cap layer, 4.
Temperature used for formation of porous metal membrane. In order
to demonstrate this technique, Silver (Ag) was used as a metal for
preparation of porous metal membrane on amorphous silicon (a-Si)
and silicon oxide. The annealing of the silver thin film of various
thicknesses was performed at different temperature. Pores in porous
silver film were analyzed using Scanning Electron Microscope
(SEM). In order to check the usefulness of porous metal film for TFE
application, the porous silver film prepared on amorphous silicon (a-
Si) and silicon oxide was released using XeF2 and VHF, respectively.
Finally, guide line and structures are suggested to use this porous
membrane for robust TFE application.
Abstract: The aim of the present study is to investigate
consumers' determinants of intention toward the adoption of Smart
Grid solutions and technologies. Ajzen's Theory of Planned
Behaviour (TPB) model is applied and tested to explain the formation
of such adoption intention. An exogenous variable, taking into
account the resistance to change of individuals, was added to the
basic model. The elicitation study allowed obtaining salient modal
beliefs, which were used, with the support of literature, to design the
questionnaire. After the screening phase, data collected from the
main survey were analysed for evaluating measurement model's
reliability and validity. Consistent with the theory, the results of
structural equation analysis revealed that attitude, subjective norm,
and perceived behavioural control positively, which affected the
adoption intention. Specifically, the variable with the highest estimate
loading factor was found to be the perceived behavioural control,
and, the most important belief related to each construct was
determined (e.g., energy saving was observed to be the most
significant belief linked with attitude). Further investigation indicated
that the added exogenous variable has a negative influence on
intention; this finding confirmed partially the hypothesis, since this
influence was indirect: such relationship was mediated by attitude.
Implications and suggestions for future research are discussed.
Abstract: Chalcopyrite (CuFeS2) is the most common primary
mineral used for the commercial production of copper. The low
dissolution efficiency of chalcopyrite in sulfate media has prevented
an efficient industrial leaching of this mineral in sulfate media. Ferric
ions, bacteria, oxygen and other oxidants have been used as oxidizing
agents in the leaching of chalcopyrite in sulfate and chloride media
under atmospheric or pressure leaching conditions. Two leaching
methods were studied to evaluate chalcopyrite (CuFeS2) dissolution
in acid media. First, the conventional oxidative acid leaching method
was carried out using sulfuric acid (H2SO4) and potassium
dichromate (K2Cr2O7) as oxidant at atmospheric pressure. Second,
microwave-assisted acid leaching was performed using the
microwave accelerated reaction system (MARS) for same reaction
media. Parameters affecting the copper extraction such as leaching
time, leaching temperature, concentration of H2SO4 and
concentration of K2Cr2O7 were investigated. The results of
conventional acid leaching experiments were compared to the
microwave leaching method. It was found that the copper extraction
obtained under high temperature and high concentrations of oxidant
with microwave leaching is higher than those obtained
conventionally. 81% copper extraction was obtained by the
conventional oxidative acid leaching method in 180 min, with the
concentration of 0.3 mol/L K2Cr2O7 in 0.5M H2SO4 at 50 ºC, while
93.5% copper extraction was obtained in 60 min with microwave
leaching method under same conditions.
Abstract: Biodiesel is one of the alternative fuels that promising
for substituting petro diesel as energy source which is advantage on
sustainability and ecofriendly. Due to the raw material that tend to
decompose during storage, biodiesel also have the same characteristic
that tend to decompose and formed higher acid value which is the
result of oxidation to double bond on a chain of ester. Decomposition of biodiesel due to oxidation reaction could
prevent by introduce a small amount of antioxidant. The origin of raw
materials and the process for producing biodiesel will determine the
effectiveness of antioxidant. The quality degradation on biodiesel
could evaluate by measuring iodine value and acid number of
biodiesel. Biodiesel made from high fatty acid Jatropha curcas oil by using
esterification and transesterification process will stand on the quality
by introduce 90 ppm pyrogallol powder on the biodiesel, which could
increase Induction period time from 2 hours to more than 6 hours in
rancimat test evaluation.
Abstract: Mobile Adhoc Networks (MANETs) are
infrastructure-less, dynamic network of collections of wireless mobile
nodes communicating with each other without any centralized
authority. A MANET is a mobile device of interconnections through
wireless links, forming a dynamic topology. Routing protocols have a
big role in data transmission across a network. Routing protocols,
two major classifications are unipath and multipath. This study
evaluates performance of an on-demand multipath routing protocol
named Adhoc On-demand Multipath Distance Vector routing
(AOMDV). This study proposes Energy Aware AOMDV (EAAOMDV)
an extension of AOMDV which decreases energy
consumed on a route.
Abstract: Based on application requirements, nodes are static or
mobile in Wireless Sensor Networks (WSNs). Mobility poses
challenges in protocol design, especially at the link layer requiring
mobility adaptation algorithms to localize mobile nodes and predict
link quality to be established with them. This study implements
XMAC and Berkeley Media Access Control (BMAC) routing
protocols to evaluate performance under WSN’s static and mobility
conditions. This paper gives a comparative study of mobility-aware
MAC protocols. Routing protocol performance, based on Average
End to End Delay, Average Packet Delivery Ratio, Average Number
of hops, and Jitter is evaluated.
Abstract: This paper presents modeling and simulation of
flexible robot in an underwater environment. The underwater
environment completely contrasts with ground or space environment.
The robot in an underwater situation is subjected to various dynamic
forces like buoyancy forces, hydrostatic and hydrodynamic forces.
The underwater robot is modeled as Rayleigh beam. The developed
model further allows estimating the deflection of tip in two
directions. The complete dynamics of the underwater robot is
analyzed, which is the main focus of this investigation. The control of
robot trajectory is not discussed in this paper. Simulation is
performed using Symbol Shakti software.
Abstract: The Composite Shear Walls (CSW) with steel encased
profiles can be used as lateral-load resisting systems for buildings
that require considerable large lateral-load capacity. The aim of this
work is to propose the experimental work conducted on CSW having
L section folded plate (L shape steel made-up sections) as
longitudinal reinforcement in boundary regions. The study in this
paper present the experimental test conducted on CSW having L
section folded plate as longitudinal reinforcement in boundary
regions. The tested 1/3 geometric scaled CSW has aspect ratio of 3.2.
L-shape structural steel materials with 2L-19x57x7mm dimensions
were placed in shear wall boundary zones. The seismic behavior of
CSW test specimen was investigated by evaluating and interpreting
the hysteresis curves, envelope curves, rigidity and consumed energy
graphs of this tested element. In addition to this, the experimental
results, deformation and cracking patterns were evaluated, interpreted
and suggestions of the design recommendations were proposed.